Sustainable and efficient waste management requires involvement of symbiotic solutions to various types of wastes, and so to achieve circular economy. Through this motivation, in this study, combined thermochemical conversion (pyrolysis) of plastics, biomass and marble processing effluents physicochemical treatment sludge (K1) were studied. In this combination, plastics were petroleum-based synthetic aromatic (PET) and aliphatic (PP) organics, while olive pomace-OP was natural agricultural residue. K1 was mineral product, which was first introduced in the literature as pyrolysis catalyst by the authors. In the study, co-pyrolysis of polymers and biomass was catalyzed by mineral waste containing CaCO3. The effect of plastic type and pyrolyzed material mixture ratio on pyrolysis fractions were investigated. Moreover, material recovery potential from pyrolysis fractions were discussed. In catalytic co-pyrolysis, by increasing the plastic ratio in the mixture, the pyrolytic liquid and oligomer fraction increased while the solid (char) and gas fraction decreased. For 70%PP+15%OP+15%K1 mixture, liquid product was dominant, whereas with 60%PET+20%OP+20%K1 much more pyrolytic gas fraction produced. The thermal degradation of char products did not exceed 2-3% up to 600°C and this stability continues up to approximately 700°C reveals the potential of the char to be used in alternative areas as a material with high thermal resistance. The catalytic co-pyrolysis liquid products contain alkanes, alkenes, acids, phenols, benzene, aldehydes, esters, alcohols, ketones. Benzene, acid and alcohol groups were dominant in liquids, while alkane, alkene and alkyne groups were dominant in gases.
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