NOx Production Research Articles

Flow field and emission characterization of a novel enclosed jet-in-hot-coflow canonical burner

The jet-in-hot-coflow is a canonical combustion setup, which has been used in several studies to study Flameless/MILD combustion and auto-ignition of fuels. However, the NOx and CO emission measurements from these combustion setups were not possible due to the entrainment of laboratory air and a lack of a well-defined physical system limit. These limitations have been overcome by a new enclosed jet-in-hot-coflow setup. The combustor was operated by injecting a mixture of CH4-Air in the central jet, and the coflow comprised of hot products from CH4-Air combustion in burners upstream. The coflow composition was further controlled by adding diluents such as N2 and CO2. Measurements were done using stereoscopic particle image velocimetry, suction probe gas analysis, thermocouples, and chemiluminescence imaging. Increasing central jet velocity and equivalence ratio led to lower NOx and a reaction zone that enlarged and shifted downstream. The reduction in NOx emission was attributed to the returning mechanism. Adding CO2 and N2 as diluents in the coflow resulted in a longer combustion zone and reduced temperatures in the combustion chamber, leading to decreased NOx production and increased reburning. These experiments provide relevant flowfield and emissions data for modelers and help characterize combustion regimes such as Flameless/MILD.

Efficient natural gas combustion and NOx reduction: A novel application of simultaneous over-fire air (OFA) and flue gas recirculation (FGR) in a 250 MW opposed firing steam power plant boiler

OFAGR, as a new controllable technology, combines over-fire air (OFA) and flue gas recirculation (FGR) systems for modifying combustion characteristics and enhancing boiler efficiency. It also reduces NOx generation considerably. The effects of OFA and FGR on the combustion are reported for coal-fired boilers, however, no reference was found for the application of OFAGR, especially in boilers with natural gas fuel so far. Furthermore, the method of adjusting the ratio of OFA and FGR in OFAGR nozzles to achieve the required combustion modification is not investigated and this fact should be even covered for different types of boilers. For analysis of complicated combustive mixed fuel (natural gas) and air in furnace, computational fluid dynamics (CFD) simulated the flow by the use of Eddy-Dissipation Concept (EDC) and developing reactions by Jones-Lindstedt mechanism. Simulation results are validated by the measured boiler operation data for a 250 MW steam power plant boiler. The staged combustion in each burner is modeled by considering three inlet air flows (primary, secondary, and tertiary) with swirl. The effects of different ratios of OFA and FGR streams on characteristics of combustion and NOx production are investigated. The combustion efficiency, temperature profile, distribution of species, and the transferred heat flux to water-walls are computed, and analyzed. Results showed injecting only OFA from OFAGR nozzles, reduced NOx generation up to 55.4 % but lowered the furnace efficiency from 95.3 % to 93.1 %. When the OFAGR stream contained 25 % FGR and 75 % OFA (case study 2), an ideal state existed for increasing the combustion efficiency from 95.3 % to 96.0 % and NOx reduction by 58 %. Increasing the share of FGR in the OFAGR stream by more than 25 % improved the NOx reduction but reduced the combustion efficiency from 95.3 % due to the drop in the usable absorption heat of the boiler. Calculations showed that the OFAGR injection stream containing 64.1 % OFA and 35.9 % FGR reduced NOx formation from 274 to 112 ppm without losing furnace efficiency.

Nitric and nitrous acid formation in plasma-treated water: Decisive role of nitrogen oxides (NOx=1–3)

Nitrogen fixation using low-temperature plasma, particularly in relation to plasma-treated water (PTW) and its chemical and physical properties, has received a renewed research focus. Dissolving highly concentrated nitrogen oxides (NOx = 1–3) generated by air discharge into water results in the formation of two aqueous oxiacids (nitrous and nitric acids; HNOy = 2,3) and their conjugates (nitrate and nitrite ions; NOy-). Nonlinear formation of these species in PTW with respect to plasma conditions has been observed; however, the significance of the time-varying NOx on this nonlinearity has not yet been thoroughly investigated. Here, we demonstrate real-time observations of HNOy/NOy- as well as NOx production in a surface dielectric barrier discharge reactor containing distilled water. Synchronized two optical absorption spectroscopy systems were employed to simultaneously measure gas-phase NOx and liquid-phase HNOy/NOy- in the plasma reactor operated under different oxygen contents of 5, 20, and 50%. Our results showed that reducing the oxygen content in the reactor accelerated the chemical transition from O3 and NO3 to NO1,2, leading to a predominance of nitrite in PTW. Specifically, the NO3-rich period was extended with increasing O2 content, resulting in the production of nitrate-dominant PTW at low pH levels. Our findings highlight the potential for the selective generation of HNOy/NOy- in PTW through the active and passive control of NOx in a plasma reactor. The direct, real-time observation of NOx–HNOy/NOy- conversion presented here has potential for improving the control and optimization of PTW, thereby enhancing its applicability.

Highly Stable Perovskite Oxides for Electrocatalytic Acidic NOx− Reduction Streamlining Ammonia Synthesis from Air

AbstractElectrochemical nitrogen oxide ions reduction reaction (NOx−RR) shows great opportunity for ammonia production under ambient conditions. Yet, performing NOx−RR in strong acidic conditions remains challenging due to the corrosion effect on the catalyst and competing hydrogen evolution reactions. Here, we demonstrate a stable La1.5Sr0.5Ni0.5Fe0.5O4 perovskite oxide for the NOx−RR at pH 0, achieving a Faradaic efficiency for ammonia of approaching 100 % at a current density of 2 A cm−2 in a H‐type cell. At industrially relevant current density, the NOx−RR system shows stable cell voltage and Faradaic efficiency for >350 h in membrane electrode assembly (MEA) at pH 0. By integrating the catalyst in a stacked MEA with a series connection, we have successfully obtained a record‐breaking 2.578 g h−1 NH3 production rate at 20 A. This catalyst‘s unique acid‐operability streamlines downstream ammonia utilization for direct ammonium salt production and upstream integration with NOx sources. Techno‐economic and lifecycle assessments reveal substantial economic advantages for this ammonia production strategy, even when coupled with a plasma‐based NOx production system, presenting a sustainable complement to the conventional Haber–Bosch process.

Highly Stable Perovskite Oxides for Electrocatalytic Acidic NOx - Reduction Streamlining Ammonia Synthesis from Air.

Electrochemical nitrogen oxide ions reduction reaction (NOx -RR) shows great opportunity for ammonia production under ambient conditions. Yet, performing NOx -RR in strong acidic conditions remains challenging due to the corrosion effect on the catalyst and competing hydrogen evolution reactions. Here, we demonstrate a stable La1.5Sr0.5Ni0.5Fe0.5O4 perovskite oxide for the NOx -RR at pH 0, achieving a Faradaic efficiency for ammonia of approaching 100 % at a current density of 2 A cm-2 in a H-type cell. At industrially relevant current density, the NOx -RR system shows stable cell voltage and Faradaic efficiency for >350 h in membrane electrode assembly (MEA) at pH 0. By integrating the catalyst in a stacked MEA with a series connection, we have successfully obtained a record-breaking 2.578 g h-1 NH3 production rate at 20 A. This catalyst's unique acid-operability streamlines downstream ammonia utilization for direct ammonium salt production and upstream integration with NOx sources. Techno-economic and lifecycle assessments reveal substantial economic advantages for this ammonia production strategy, even when coupled with a plasma-based NOx production system, presenting a sustainable complement to the conventional Haber-Bosch process.

Investigating the effect of fuel properties and environmental parameters on low-octane gasoline-like fuel spray combustion and emissions using machine learning-global sensitivity analysis method

The gasoline compression ignition mode is an advanced combustion mode that achieves high efficiency with low emissions. This study constructs a global sensitivity analysis (GSA) by coupling machine learning (ML) algorithms and conducts a comprehensive investigation into the statistical correlations between research octane number (RON), fuel sensitivity (S), three initial ambient parameters, and the spray combustion characteristics of gasoline-like fuels. Eighty sets of CFD numerical simulation data were used for training the machine learning model. Results show liquid length (LL) is most sensitive to changes in ambient pressure while ambient temperature significantly influences vapor penetration length (VPL). Regarding combustion behaviors, ignition delay (ID) and flame lift-off length (LOL) show the highest sensitivity to ambient temperature. The occurrence of distinct ignition points in the domain also advances from 1.75 ms to 0.42 ms as the ambient temperature rises from 1000K to 1200K. Additionally, the ambient temperature has higher-order interaction effects with ambient pressure on LOL. The production of NOx in the field is also more closely correlated with ambient temperature, with higher temperatures promoting its generation. Furthermore, ambient temperature exhibits a positive interaction effect with both ambient pressure and oxygen concentration on NOx emissions.

Dissecting the Photochemical Reactivity of Metal Ions during Atmospheric Nitrate Transformations on Photoactive Mineral Dust.

Dissecting the photochemical reactivity of metal ions is a significant contribution to understanding secondary pollutant formation, as they have a role to be reckoned with atmospheric chemistry. However, their photochemical reactivity has received limited attention within the active nitrogen cycle, particularly at the gas-solid interface. In this study, we delve into the contribution of magnesium ion (Mg2+) and ferric ion (Fe3+) to nitrate decomposition on the surface of photoactive mineral dust. Under simulated sunlight irradiation, the observed NOX production rate differs by an order of magnitude in the presence of Mg2+ (6.02 × 10-10 mol s-1) and Fe3+ (2.07 × 10-11 mol s-1). The markedly decreased fluorescence lifetime induced by Mg2+ and the change in the valence of Fe3+ revealed that Mg2+ and Fe3+ significantly affect the concentration of nitrate decomposition products by distinct photochemical reactivity with photogenerated electrons. Mg2+ promotes NOX production by accelerating charge transfer, while Fe3+ hinders nitrate decomposition by engaging in a redox cyclic reaction with Fe2+ to consume photogenerated carriers continuously. Furthermore, when Fe3+ coexists with other metal ions (e.g., Mg2+, Ca2+, Na+, and K+) and surpasses a proportion of approximately 12%, the photochemical reactivity of Fe3+ tends to be dominant in depleting photogenerated electrons and suppressing nitrate decomposition. Conversely, below this threshold, the released NOX concentration increases sharply as the proportion of Fe3+ decreases. This research offers valuable insights into the role of metal ions in nitrate transformation and the generation of reactive nitrogen species, contributing to a deep understanding of atmospheric photochemical reactions.

Sustainable nitrogen fixation by novel gliding arc plasma reactor for the production of nitrogen fertilizers

AbstractA novel plasma reactor is being investigated for green NOx production, crucial for nitrate‐based fertilizer manufacturing. Various parameters, including air flow rates, gas ratios, ozone, and catalyst effects are explored for NO → NO2 conversion. NOx concentrations reach ~0.6 vol%, with a total production of ~9.7 gr/h and energy cost of ~3.0 mJ/mol, notably favorable for atmospheric gliding arc plasma. Selectivity (~75%) towards NO2 is achieved with ozone addition or catalytic treatment, pivotal for nitrate fertilizer and HNO3 production.

Furnace-height FGR location impact of a cascade-arch-firing configuration in ameliorating low-NOx combustion and eliminating hopper overheating for a large-scale arch-fired furnace

This study analyses an alternative to the existing multiple-injection and multiple-staging combustion technique (MIMSCT) of large-scale arch-fired furnaces. The alternative approach is a cascade-arch-firing, low-NOx, and high-efficiency configuration (CLHC) with flue gas recirculation (FGR). The research is necessary as typical 600 MWe large-scale arch-fired furnaces produce high concentrations of NOx and have a high risk of overheating in their hoppers when firing low-volatile coals. Three furnace-height FGR locations were considered in descending order (i.e., FGR through (i) primary burners to mitigate fuel-NO (FGR-PB), (ii) tertiary air to restrain thermal-NO (FGR-TA), and (iii) auxiliary burners to reduce NO (FGR-AB)). Industrial-scale measurements and simulations were conducted in the existing MIMSCT furnace (which was used to verify simulations and compare with the subsequent CLHC furnace results), followed by numerical investigations of the CLHC furnace at the three FGR-locations. The FGR’s NO inhibition in the upstream zone decreased in the following order: FGR-PB > FGR-TA > FGR-AB. Initial combustion and NO generation in the reburning stage was most intense in the FGR-TA configuration (producing the highest NO amounts) whereas the FGR-AB configuration contributed the lowest amounts. As the FGR locations descended, burnout loss dropped a little, while NOx production was initially elevated and then descended. The FGR-PB was optimal among the three options, with a low NOx output of 604 mg/m3 (O2 = 6 %) and combustible level in fly ash of about 5 %. Compared to the MIMSCT, the CLHC not only enhanced the low-NOx environment and shortened the flame penetration but also improved combustion intensity and extended the overfire air penetration. This sharply reduced NOx without affecting burnout nor lowering apparent hopper temperatures. The above results demonstrate that a staged FGR consisting of primary FGR-PB and supplementary FGR-AB, is a promising solution to lower NOx while retaining high furnace burnout levels.

Effects of secondary air on the emission characteristics of ammonia–hydrogen co-firing flames with LES-FGM method

Ammonia, being a carbon-free fuel, is garnering increasing attention in the combustion community. However, its application is still impeded by its limited stability range and significantly NOx emissions. This study delves into the impact of primary and overall equivalence ratios (ϕpri and ϕovr) on emissions production in ammonia–hydrogen co-firing flames, utilizing a two-stage swirling model gas turbine combustor. The emissions concentration is measured using Fourier Transform Infrared Spectroscopy (FTIR). The physical and chemical processes influencing emissions production are comprehensively analyzed through a combination of Large Eddy Simulation (LES) and Flamelet-Generated Manifold (FGM) method. The reliability of the simulation is validated by the experimental data, showing a good capability in predicting the combustion. Results indicate that the two-stage combustion strategy exhibits significantly controlling effects on NOx and unburned NH3 emission. The NO emission exhibits a non-monotonic variation with ϕpri, reaching its lowest value at ϕpri≈ 1.2. Further analysis shows that ϕpri plays a crucial role in determining the temperature and OH concentration in the primary combustion zone, thereby influencing NOx production in this area. When the primary zone is operated at lean condition, the reduction on NO in secondary zone is primarily attributed to dilution effect by the secondary air. In contrast, when ϕpri> 1, the concentrations of the main emissions in secondary zone are dominated by chemical effects. In this scenario, unburned NH3 and H2 from the primary zone are consumed, resulting in a substantial production of NO in the secondary combustion zone. Additionally, with an increase in ϕpri, the secondary NO production also increases. The ϕovr exhibits two considerable effects. On one hand, an increase in ϕovr results in a higher local equivalence ratio in the secondary zone, thereby promoting local NOx production. Simultaneously, the elevated flame temperature enhances the consumption of N2O. On the other hand, the rise in ϕovr results in a reduction in vortex scale and residence time in the secondary combustion zone, leading to a decrease in local NO production.

Lightning NOx in the 29–30 May 2012 Deep Convective Clouds and Chemistry (DC3) Severe Storm and Its Downwind Chemical Consequences

AbstractA cloud‐resolved storm and chemistry simulation of a severe convective system in Oklahoma constrained by anvil aircraft observations of NOx was used to estimate the mean production of NOx per flash in this storm. An upward ice flux scheme was used to parameterize flash rates in the model. Model lightning was also constrained by observed lightning flash types and the altitude distribution of flash channel segments. The best estimate of mean NOx production by lightning in this storm was 80–110 mol per flash, which is smaller than many other literature estimates. This result is likely due to the storm having been a high flash rate event in which flash extents were relatively small. Over the evolution of this storm a moderate negative correlation was found between the total flash rate and flash extent and energy per flash. A longer‐term simulation at 36‐km horizontal resolution with parameterized convection was used to simulate the downwind transport and chemistry of the anvil outflow from the same storm. Convective transport of low‐ozone air from the boundary layer decreased ozone in the anvil outflow by up to 20–40 ppbv compared with the initial conditions, which contained stratospheric influence. Photochemical ozone production in the lightning‐NOx enhanced convective plume proceeded at a rate of 10–11 ppbv per day in the 9–11 km outflow layer over the 24‐hr period of downwind transport to the Southern Appalachians. Photochemical production plays a large role in the restoration of upper tropospheric ozone following deep convection.

Effect of excess air ratio and ignition timing on the combustion and emission characteristics of the ammonia-hydrogen Wankel rotary engine

As a hydrogen carrier, ammonia can suppress knock and enhance thermal efficiency of the hydrogen-fueled Wankel rotary engine (WRE), and achieve zero carbon emissions. This research established a three-dimensional fluid dynamics model coupled with detailed reaction kinetics of ammonia and hydrogen and verified it based on experiments. Incorporating 10% volume fraction of ammonia into the hydrogen-fueled WRE eliminates knock and decreases the excess air ratio (λ) from 1.8 to 1.4, effectively improving the indicated mean effective pressure (IMEP). The results indicate that when λ exceeds 1.4, flame propagation accelerates with higher concentration of the mixture. This enhances peak in-cylinder pressure and heat release rate, but it results higher NOx emissions. As λ varies from 1.8 to 1.4, NOx emission levels rise by 47.4%. At λ ≤ 1.2, the rapid flame propagation leads to short combustion duration, diminishing the power output. At this stage, the NO formation is dominated by H radicals, and the NOx production reaches its minimum value at λ of 1.0. In summary, the ammonia-hydrogen WRE achieves optimal performance at λ of 1.4 and ignition timing of −5 °CA after top dead center, the indicated thermal efficiency reaches 36.9% and the IMEP achieves 0.683 MPa.

Combustion characteristics and nitrogen conversion mechanism in ammonia/coal Co-firing process

The coupled combustion of coal with the carbon-free fuel NH3 is an effective technology for reducing CO2 emissions. Based on elemental analysis, proximate analysis, Fourier Transform infrared spectroscopy (FTIR), Carbon-13 Nuclear Magnetic Resonance (13C NMR), and X-ray photoelectron spectroscopy (XPS) characterizations, a coal macromolecular model was constructed. The combustion characteristics of coal/NH3 co-firing were investigated by reactive force field molecular dynamics simulations (ReaxFF MD). The transformation mechanism of elemental N was elucidated. The influence of temperature, oxygen concentration, and NH3 co-firing ratio (CR) on products was investigated. The results showed that during the non-isothermal combustion phase, the coal macromolecules decomposed more rapidly when the heating rate was low. In the isothermal phase, high temperatures promoted secondary reactions. The production of inorganic gases increased with increasing temperature. As the molar fraction of NH3 increased, the production of CO2 and CO was effectively reduced. There were three main pathways for NO formation. As NH3 decomposed to form NH2, NH2 was subsequently converted to NH, and NH reacted with O2 to form NO. The NH2 could also react with O radicals to form HNO, which was then converted to NO. Besides, both thermal NOx and prompt NOx were generated since the N2 was involved in the reaction. In addition, the production of NOx increased significantly at oxygen concentrations greater than 1.4.

Detonation properties and nitrogen oxide production in ammonia–hydrogen–air mixtures

Ammonia is a promising compound for chemical storage of renewable energy produced from non-continuous sources. However, the low reactivity of ammonia requires to use ammonia–hydrogen blends as a fuel for combustion applications. The present study corresponds to a first numerical assessment of the potential of ammonia–hydrogen–air mixtures as reactive mixtures for detonation engine applications. Both ideal and curved detonation models were employed to calculate the detonation properties, entropy production, and NOx production for mixtures with varying amounts of ammonia and hydrogen under a wide range of initial thermodynamics conditions. Interestingly, our calculations show that the entropy production and the amount of nitrogen oxides produced at the Chapman–Jouguet state respectively decreases and increases with the proportion of hydrogen in the ammonia–hydrogen blend. These aspects could have a great impact on engine efficiency and air pollution and should be considered with care. Our results also demonstrate that only mixtures with relatively low amounts of ammonia, i.e., XNH3 lower than 0.25 of the fuel blend, can be employed for detonation engine applications.

Hydrogen addition impacts on flashback phenomenon in combustion chamber

The purpose of this work is to investigate the effects of adding hydrogen to the fuel on the combustion induced vortex breakdown flashback phenomenon in a combustion chamber. An atmospheric research burner is selected for studies and the analysis is performed using numerical simulations. In order to model the turbulence-chemistry interactions, the EDC combustion model is utilized and the GRI 2.11 reaction mechanism is used to investigate the combustion process as carefully as possible. The present studies are performed keeping the exit temperature constant. To do this, by adding any amount of hydrogen to the premixed inlet flow, the methane is decreased by using the trial-and-error until the mass averaged exit temperature remains almost constant. The purpose of applying this limitation is to keep the cycle operational condition unchanged that is important for adding hydrogen to the existing combustion chambers especially from technological viewpoint. In addition, the thermal NOx production is controlled. In the following, the effect of hydrogen addition on the flame thickness and flame shape is investigated and finally, the effect of operating pressure on the flashback behavior is analyzed.

Temperature-driven dynamic evolution process of Ag species on silver-loaded Zr0.2Sn0.8O2 catalyst for selective catalytic oxidation of ammonia

Silver-based catalysts are extensively utilized in the selective catalytic oxidation of ammonia (NH3-SCO). However, enhancing low-temperature activity often causes a decline in N2 selectivity, presenting a substantial challenge in balancing activity and N2 selectivity. In this work, we introduced zirconium into the SnO2 support, resulting in a significant enhancement of low-temperature activity by 200 °C for the Ag/Zr0.2Sn0.8O2 catalyst; yet, this also led to the formation of N2O at low temperatures and NOx at high temperatures. Characterizations such as XPS and in situ DRIFTS revealed that the dynamic changes of silver species driven by temperature had a profound impact on the reaction mechanism and guided the formation of different products. Below 200 °C, the predominance of Ag+ directed the imide mechanism, with the –HNO species being the key intermediate leading to the production of N2O. Above 300 °C, Ag0 became dominant, favoring the internal selective catalytic reduction (i-SCR) mechanism and the production of NOx. This work provides novel insights into improving N2 selectivity of Ag-based catalysts and contributes to a deeper understanding of the reaction mechanisms.

Comparative Experimental Assessment of Pollutant Emission Behavior in Combustion of Untreated and Thermally Treated Solid Biofuels from Spruce Chips and Rapeseed Straw

Biomass energy for heating is going to be part of the spectrum of renewable energy sources. However, biomass combustion produces emissions of various pollutants with negative effects at both local and global scales. To reduce some of the locally important pollutant load, thermally treated biomass fuels may offer a partial solution. In this study, two biomass feedstocks, i.e., spruce chips and rapeseed straw, were thermally treated at 300 °C to produce biochars. Subsequently, both original materials and biochars were burned in a 25 kW retort combustion device. In both cases, the biochar showed lower emissions of carbon monoxide and nitrogen oxides, usually almost across the whole range of tested combustion conditions. In total, for the emission production per unit of net calorific value, the spruce biochar showed reductions in CO and NOx productions of 10.8% and 14.5%, respectively. More importantly, in rapeseed straw biochar, the difference was more pronounced. The total production was reduced by 28% and 42%, again in CO and NOx emissions, respectively.

Experimental study on variation characteristics of combustion heat load in circulating fluidized bed under fuel high-temperature preheating modification

This study introduces an innovative application of fuel high-temperature preheating modification technology to circulating fluidized bed (CFB), intending to enhance the variable load rate of CFB and reduce its NOx emissions. The variable combustion heat load (CHL) experiments were conducted on a novel CFB experimental platform comprising a preheating modification device (PMD) and CFB. The findings indicate that implementing fuel high-temperature preheating modification technology allows the CFB to operate stably within the range of 30%–100% CHL while maintaining superior combustion efficiency. Moreover, it reduces NOx emissions by over 28% compared to conventional combustion. The decrease in NOx emissions can be attributed to the fuel's preheating modification process inhibiting NOx production and establishing conditions conducive to NOx reduction in CFB. Furthermore, after employing the fuel high-temperature preheating modification technology, the CHL change rate of CFB reached 1.79%/min and 2.27%/min for the transition from 50% CHL to 75% CHL and from 75% CHL to 100% CHL, respectively. These rates represent an increase of 1.59 and 1.80 times compared to the rates observed in conventional combustion processes. The increase in the CHL change rate of different CHL variation intervals is primarily due to the production of high-temperature coal gas and modified char following fuel preheating modification. High-temperature coal gas exhibits a rapid combustion rate, while modified char has a smaller particle size, more developed pore structure, and enhanced reactivity than raw coal.

LES investigation of a swirl stabilized technically premixed hydrogen flame with FGM and TFM models

Climate change due to carbon emissions is one of the aspects that must be kept under control nowadays. In this fashion, the employment of hydrogen as fuel provides a fundamental solution for both power generation and transportation since lean premixed combustions allow to reset the carbon emissions and reduce the pollutant ones. Indeed, the higher reactivity of hydrogen permits to operate with a very low equivalence ratio which can drastically limit the NOx production with respect to the common fossil fuels. On the other hand, lean hydrogen mixtures are characterized by peculiar aspects that make their study through CFD simulations not straightforward. The present work aims to analyze through two different numerical approaches a technically premixed hydrogen flame experimentally investigated at the Technische Universität Berlin (TUB). In particular, the main differences between the Flamelet Generated Manifold and the Thickened Flame Model strategy are deeply analyzed as well as the effects of the thermal boundary conditions on the flame stabilization mechanism. The comparison with the experimental data shows the treatment employed drastically influences the accuracy of the obtained outcomes.

Experimental Study on Flame Chemical Composition of Coal and Ammonia Gas-Solid Jet in Flat Flame Burner.

Ammonia as a fuel to partially or completely replace fossil fuels is one of the effective ways to reduce carbon dioxide, and the research on ammonia coal cocombustion is of great significance. The combustion characteristics of ammonia are very different from those of pulverized coal, resulting in the ignition and emission characteristics of ammonia and pulverized coal gas flow that is different from traditional pulverized coal flame. In this paper, the effect of pulverized coal concentration in coal and ammonia mixed combustion jet on the ignition distance and gas-phase components at different positions of the jet flame were studied experimentally on the flat flame burner, and the conditions of ignition and ignition stability of coal and ammonia gas-solid fuel were expounded. It was found that the ammonia mixed with pulverized coal changed the temperature field of the flat flame burner and therefore the ignition characteristics of the jet were changed. The ignition delay time at the same jet speed was positively correlated with the pulverized coal concentration, but when the pulverized coal concentration continued to decrease, the influence on the ignition delay time gradually became smaller. The composition of coal ammonia gas-solid fuel changed the heat transfer path and share during combustion, and finally, the flame temperature was negatively correlated with the concentration of pulverized coal. Therefore, the reduction of the pulverized coal concentration was conducive to the stable combustion of coal ammonia mixed fuel. When HAB = 100 mm, the conversion rate of fuel N to NOx per unit mass of coal ammonia mixture increased with the increase of pulverized coal concentration. The NOx production amount first increased and then decreased with the increase of pulverized coal concentration, and the amount of N2O and NO2 decreased rapidly with the increase of HAB. The proportion of NOx in NO exceeded 94%, which was conducive to achieving low nitrogen combustion of coal and ammonia gas-solid fuel. In general, the O2 concentration in the ammonia coal jet flame decreased, the flue gas temperature, and NOx and CO generation increased after mixing ammonia, and the optimal pulverized coal concentration in this experiment was 0.41 kgc/kga (mass ratio of pulverized coal to the sum of N2 and NH3).