Leather is a material with unique mechanical properties, making it widely used in the production of footwear, clothing, sports articles, and in the field of coverings, such as in the automotive, furniture, marine and aeronautical industries. Leather processing involves three major stages: beamhouse, tanning, and finishing. In each of these stages, characteristic effluents are generated, which typically reach the Wastewater Treatment Plant (WWTP) mixed, for the so called end-of-pipe treatment, consisting of primary and secondary treatment. The objective of this study is to analyze the characteristics of the effluents generated in each processing stage individually and when mixed, in order to assess how the mixture impacts degradability. For the evaluation, wastewater corresponding to the three stages was generated, using raw hides for (i) beamhouse and (ii) tanning, and wet-blue leather for (iii) wet finishing. Subsequently, chemical inputs were added to the wastewater, forming synthetic effluents. The (iv) mixture of the effluent generated in the three stages was made based on the proportion of each effluent in relation to the total generated. Analyses of Biological Oxygen Demand (BOD) and Total Organic Carbon (TOC) were performed for the four samples. The BOD obtained for the mixture was zero, while the other three effluents obtained high values for the same analysis. This result indicates that an inhibitory environment to microbial growth was formed, preventing biodegradation. The TOC results indicate that the mixture contains an organic load proportional to the effluents that compose it. It was concluded that the organic load and biodegradability of the effluent can be strongly influenced by the processing methods of each tannery, such as the amount of water and inputs used, and that the secondary treatment of mixed effluents tends to be compromised compared to segregated treatment.
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