The removal of organic particulates from septic tank waste waters is the most crucial part of biological treatment processes. In this regard, the present study explores the potential applications of septic tank waste water treatment (STWW) system in the removal of organic matter and energy generation using Microbial fuel cells. The effect of acrylic varnish coating over the clay cup along with stirring (ACS- SMFC) has produced 70% more electricity than the uncoated clay cups without stirring, with the OCV of 984 ± 2 mV, current and power density of 706 ± 5.78 mA/m3 and 61.17 ± 0.29 mW/m3. The fabrication of the clay cup proves the presence of Niobium and chlorine functional groups in EDAX analysis, which affirms its high electron flow and superconductivity for better electricity production. SEM and confocal laser scanning microscopy affirmed the catabolic conversion of organic substrates of STWW through microbial communities of biofilm on bioelectricity production. Thus the higher COD removal value of 60.3 ± 0.09% was achieved in the ACS –SMFC module by utilizing STWW as substrate. Acrylic varnishing's efficacy on clay cups was confirmed via Fourier transform infrared spectroscopy with prominent peaks between 700 cm−1 to 3612 cm−1.