Conversion Process Research Articles

Design of physical and functional properties of zeolitic porous monoliths by combining different foaming additives

Self-supporting zeolitic foams were synthesized by a geopolymer gel conversion process, employing silicon powder and hydrogen peroxide as foaming additives. The influence of silicon and hydrogen peroxide combination on the physical properties, mechanical characteristics, and pore distribution was studied. Correlations between these properties were drawn. This approach allows to manufacture porous monoliths tuned in terms of zeolite type and amount and characterized by bulk density ranging between 573 and 762 kg/m3 and thermal conductivity 0.33–0.53 W/mK. Pore structure, size, and distribution were dominated by the type of foaming agent: the foamed samples showed the presence of two classes of pores, the first of the order of magnitude of 1 μm, the second of the order of magnitude of 100 μm. The use of hydrogen peroxide enhanced the porosity in the meso-macropore range (0.1–5 μm). The hydrothermal treatment performed on the foamed geopolymer allowed to achieve the crystallization of zeolites within the solid geopolymer. Mainly FAU and LTA were the zeolitic phases present in the foams, whereas the use of silicon as foaming agent locally increased the Si/Al ratio on the geopolymer surface, promoting the nucleation of FAU.

Disorder optimization in the mixed convective dynamics of nonlinear shear thinning materials with the significance of wavy surface amplitude and thermal resistance

A mixed convective driven wavy motion of the pseudo-plastic materials is very significant in different practical fields, like the production of paints and ketchup, etc. Blood flow through wavy vessels is another very practical aspect of this study. Energy conversion processes and effective resource use are one of the burning and hot topics when studying heat flow rate through materials. Main theme of this work is to optimize the heat energy conversion by introducing irreversible viscous dissipation and thermally radiative factors. In particular cases, the heat flow rate needs to be enhanced for low energy consumption. This is why, in such cases, the wavy surface flows are preferred by plane surfaces. The proposed problem is presented with highly non-linear mathematical equations. Some assumptions and variables address the mathematical equations in easily solvable forms. The findings are shown regarding the material's velocity, concentration, temperature, resistive forces, and heat-mass flow rates. A remarkable reduction in liquid velocity and enhancement in concentration and temperature is observed with the variation in amplitude of the wavy surface. The irreversible process is maximized due to the higher involvement of temperature ratio and thermal radiation factors, respectively. The ratio of infinite and zero shear rate viscosities reduced the concentration of the liquid. For method validation, a best-matched comparison is provided with literature.

Innovative Recycling and Conversion of Aluminum Waste to Hydrogen and Aluminum Chloride: Enhancing Economic Feasibility and Sustainability in Saudi Arabia

The rapid industrialization and urbanization in Saudi Arabia have led to significant challenges in waste management, particularly in recycling aluminum waste. This study explores an innovative approach for converting aluminum waste, specifically beverage cans, into valuable products such as aluminum chloride (AlCl3) and hydrogen (H2). The process involves the chemical reaction of aluminum with hydrochloric acid (HCl), producing AlCl3 and H2, and is modeled using Aspen Plus software. Two scenarios are evaluated: one without recycling and one incorporating recycling processes. In the first scenario, the direct conversion process yields 355 tons of AlCl3 and 9 tons of H2 per day from 100 metric tons of aluminum waste. The minimum selling price (MSP) of AlCl3 is calculated to be $764 per ton, with an annual profit of $25 million, assuming a market price of $1000 per ton. However, the economic viability of this scenario is highly sensitive to conversion efficiencies and market conditions. The second scenario integrates a recycling loop, processing 90% of the aluminum waste back into aluminum, significantly enhancing economic stability. This scenario produces 35 tons of AlCl3 and 1 ton of H2 per day, with an MSP of $1068 per ton. Despite the higher MSP, the inclusion of recycled aluminum, sold at $2400 per ton, results in a higher annual profit of $38 million, demonstrating greater economic resilience and sustainability. This study provides a comprehensive techno-economic analysis, highlighting the dual benefits of waste reduction and resource recovery. By optimizing reaction conditions and incorporating recycling, the proposed process aligns with Saudi Arabia's Vision 2030 sustainability goals, offering a viable pathway for enhancing economic feasibility and environmental sustainability in aluminum waste management.

Heat transfer research on the cooling process of waxy crude oil storage in the vault tank based on VOF model

This paper focuses on the static cooling process for waxy crude oil stored in dome roof tanks. For the three phases of gas on top, liquid crude oil, and bottom water in storage tank, the VOF method is used to describe the evolution of physical quantities at the “oil–water”/“oil–gas” interface. The porous medium method is used to quantitatively characterize the sol–gel conversion process for waxy crude oil. A physical and mathematical models are established to describe the flow-heat transfer coupling behavior of the three-phase medium of crude oil, gas on top, and water at the bottom of the dome roof tank. In terms of the overall cooling process,The gas at the top of the tank has the simplest and fastest physical field evolution. It has the most uneven distribution (average temperature variance of 4 °C2), the strongest flow (average flow velocity of 0.4 m/s), the highest cooling rate (0.632 °C/h), and the lowest temperature (14.84 °C at the end). Its physical field is influenced by both the atmosphere and crude oil. The evolution of the physical field of crude oil is the most complex. It lags behind the gas at the top of tank and is directly effectted by it. Based on the evolution characteristics of the flow field of crude oil, the cooling process is divided into three stages: Stage I (0–––10 h) is the stage of convection generation and evolution in the crude oil region; Stage II (10 h − 34 h) is the stage of convection stability in the crude oil region; Stage III (after 35 h) is the stage of flow field transformation of crude oil. In stages I and II, the flow and momentum exchange at the oil–gas interface are significant. Crude oil is jointly influenced by the natural convection of the gas at the top of the tank and its own natural convection, forming a counterclockwise large vortex structure. The low-temperature area is near the central axis boundary of storage tank, oil–gas interface, and tank wall. The high-temperature area is within a range of 0.1 m − 3.3 m from the tank wall. After entering stage III, the flow and momentum exchange at the oil–gas interface weaken. The flow field of crude oil is only controlled by its own natural convection and transforms into a clockwise large vortex dominated. The low-temperature area is concentrated in the enclosed area of “oil–gas interface − tank wall” and “oil–water interface − tank wall”. The temperature field changes accordingly. Eventually, the high-temperature area is concentrated in the area slightly above the center of the tank. The physical field evolution of bottom water lags behind crude oil and is most unstable. Its cooling rate is 0.164 °C/h, slightly higher than crude oil’s 0.157 °C/h. The temperature is always slightly lower (33.47 °C at the end), and the physical field is the most uniform (average temperature variance of 0.0003 °C2), affected by the tank bottom environment and liquid crude oil.

How do morphological characteristics affect tidal asymmetry in the Radial Sand Ridges?

While it is widely recognized that the Radial Sand Ridges (RSR) in the South Yellow Sea are predominantly shaped by tidal forces, there remains a limited understanding of how this distinctive morphological configuration—characterized by an interlaced channel-ridge system—can subsequently influence local tidal dynamics. This study examines the effects of morphological features on tidal asymmetry, taking into account seabed slope, relative depths between ridges and channels, and channel convergence. Three principal indices—namely tidal-duration-asymmetry (TDA), peak-current-asymmetry (PCA), and slack-water-asymmetry (SWA)—are employed to quantify various dimensions of tidal asymmetry. The findings indicate that SWA serves as the most morphology-sensitive indicator, whereas TDA exhibits minimal sensitivity to morphological changes. Furthermore, seabed steepness emerges as a critical factor influencing tidal asymmetry within the RSR; steeper slopes enhance intrinsic energy conversion processes, thereby inducing tidal asymmetries. Additional analysis reveals that streamwise advection accounts for an average of 88 % of total advection scale while controlling for spatial heterogeneity. Specifically, the average integral sum of advection terms along submerged sand ridges is 2.53 times greater than that along the deepest section of the tidal channel line—a significant contributor to spatial variability in SWA. With a positive seabed slope, the apex of the RSR acts as a source for overtides which interact with incoming astronomical tides, consequently generating tidal asymmetries. Moreover, this study illustrates varying dependencies of tidal asymmetry on bottom stress across channels and ridges, contributing to spatial variability in arc direction among RSRs. Ultimately, this research elucidates complex interactions between tidal flow and morphological characteristics within RSRs and provides insights into tide evolution in analogous ebb-shoal systems.

New insights on the petrogenesis of the Koktokay No.3 pegmatitic dyke: Petrological and zirconological evidence from the Aral granitic complex (Xinjiang, China)

The Koktokay No.3 pegmatite dyke (KPD), containing numerous Li–Be–Nb–Ta–Cs mineral resources, is among the world’s most famous rare-metal deposits, and attracted much attention. Up to now, over thirty geochronological data have been reported ranging from 332 Ma to 120 Ma for the KPD, which causes uncertainty about the origin and petrogenesis of the pegmatite. In this contribution, whole-rock geochemistry and zircon geochronology have been conducted on the Aral biotite monzogranite (BMG), the Koktokay muscovite alkali-feldspar granite (MAG), and the KPD. Petrological and whole-rock geochemistry results reveal that the BMG is normal granite with medium SiO2 (mean of 67.23 %), enriched in compatible trace elements such as Ba, Sr and Zr, and slight negative Eu anomalies, while the MAG belongs to highly-fractionated granite with high SiO2 (mean of 73.92 %) and extensive negative Eu anomalies, and enriched in incompatible trace elements such as Rb, Ta, and U. Zircon morphology and LA–ICPMS analysis reveal that magmatic zircons from the BMG, hydrothermal zircons from the MAG and KPD yield lower intercept ages at 217.3 ± 2.4 Ma, 197.8 ± 4.7 Ma, and 195.4 ± 2.0 Ma, respectively. Combining with tectonic information and geochronological data of granitic activity and its mineralization in the Altay, this study explains the petrogenetic mechanism of the KPD after Wang et al. (2021)‘s metallogenic model: (1) In late stage of Middle Triassic, the collision between the Siberian plate and the Kazakhstan–Junggar plate caused a large number of thrust nappe faults and crust thickening in the Altay orogenic belt; At ∼217 Ma, the compression reached its peak, the crustal anatexis produced syn-collisional BMG (i.e., the Aral BMG); After the compressive peak, huge amount of granitic magma in deep-seated magma chamber underwent over 20 Myr of fractional crystallization, and the residual magma enriched in ore-forming materials (rare metal elements, volatile components, and aqueous fluids) occurred at the top of the magma chamber; (2) When the regional stress converted from compression to extension, the highly-fractionated residual magma ascended rapidly from the long-lived magma chamber along extensional faults at ∼195 Ma; The huge amount of melt-bearing fluids were exsolved from the residual magma in the course of its emplacement due to sharply decreasing pressure, and intruded into a large cavity generated by extensional fault; Along with slowly decreasing temperature, the melt-enriched fluids crystallized outside-in as (quasi-) concentric pegmatitic zones (i.e., KPD); (3) The residual magma which lost huge amount of fluid filled the lower space of the extensional system, and crystallized as post-collisional MAG (i.e., the Koktokay MAG). Based on the genetic relationship among tectonics, petrogenesis, and metallogeny, the proposed model shows material and energetic conversion processes from syn-collisional granites to post-collisional granites with granitic–pegmatitic deposits

Biotransformation of ginsenoside compound K using β-glucosidase in deep eutectic solvents.

Ginsenoside compound K (CK) holds significant potential for application in the pharmaceutical industry, which exhibits numerous pharmacological activity such as cardioprotective and antidiabetic. However, the difficult separation technique and limited yield of CK hinder its widespread use. The study investigated the process of converting ginsenoside CK using β-glucosidase. It aimed to determine the specific site where the enzyme binds and the most favorable arrangement of the enzyme. Molecular docking was also employed to determine the interaction between β-glucosidase and ginsenosides, indicating a strong and spontaneous contact force between them. The effectiveness of the conversion process was further improved using a "green" deep eutectic solvent (DES). A univariate experimental design was used to determine the composition of DES and the optimal hydrolysis conditions for β-glucosidase to convert ginsenoside Rb1 into ginsenoside CK. The employment of β-glucosidase enzymatic hydrolysis in the synthesis of rare ginsenoside CK applying the environmentally friendly solvent DES is not only viable and effective but also appropriate for industrial use. The characterization methods confirmed that DES did not disrupt the structure and conformation of β-glucosidase. In ChCl:EG = 2:1 (30%, v/v), pH 5.0 of DES buffer, reaction temperature 50 ℃, enzyme substrate mass ratio 1:1, after 36h of reaction, the CK yield was 1.24 times that in acetate buffer, which can reach 86.2%. In this study, the process of using β-glucosidase enzymatic hydrolysis and producing rare ginsenoside CK in green solvent DES is feasible, efficient and suitable for industrial production and application.

Thermodynamic investigation of the efficiency of ammonia-powered marine solid oxide fuel cells with gas turbine

Improvement of marine power plants includes increasing their efficiency and drastically reducing emissions of pollutants, which involves transitioning to carbon-free fuels. This article discusses the evolution of a marine power system designed for decarbonization, utilizing ammonia and comprising solid oxide fuel cells with a gas turbine. To enhance efficiency, the system incorporates a steam supply into the fuel burning device of a gas turbine. By adding superheated steam, the system's performance improves significantly. Thermodynamic calculations identified optimal parameters for the gas turbine, which enhances efficiency by utilizing off-gases from the fuel cells. Key parameters include compressor and exhauster pressure ratios, which can be used to increase the specific power. A combined energy system with an overexpansion turbine achieves a total efficiency of 60.62 % at a fuel cell temperature of 1190 K during operation, with the SOFC efficiency being 43.76 %. These findings highlight potential improvements for marine power systems using ammonia and provide insights into the energy conversion processes within such hybrid systems.

Design and experimental study of solar-driven biomass gasification based on direct irradiation solar thermochemical reactor

Solar-driven biomass steam gasification is a promising technology to produce H2-rich syngas, meanwhile achieve flexible storage of renewable energy. However, the solar gasification application also faces numerous challenges, due to its involved complex chemical reaction characteristics and the inherent the multi-physics energy conversion processes. This work designs a novel direct irradiation solar gasification reactor, with the improved optical acceptance structure and reasonable test module, and the wheat straw particle is selected as experimental sample. Employing a 9 kWe high flux solar simulator, the maximum temperature of reaction bed in this prototype reactor reaches to 1260 °C, with the average solar flux of 1171.3 kW/m2. With adjustable radiation flux as experiment factor, under the highest total radiation of 3.35 kW, the molar fraction of H2 in the produced syngas is 47.1 % with the energy upgrade factor of 1.15, and the cellulose component completes decomposition. Increasing the mass flow rate of steam reduces the syngas output while raising the H2/CO ratio of the syngas. In addition, smaller biomass particle size facilitates the reaction, thereby improving the conversion efficiency of direct irradiation gasification. The investigation results provide a meaningful reference for the efficient utilization of abundant solar and biomass energy.

Experimental and modeling studies on char combustion under pressurized O2/H2O conditions

The desorption kinetic parameters for pressurized combustion and gasification reactions were determined based on a C++ program coupled with the Langmuir-Hinshelwood (L-H) kinetic model developed and experimental data from pressurized char combustion, and the established L-H kinetic model for pressurized char-O2/H2O combustion was refined in the current paper. The activation energy for desorption in reactions involving pressurized char-O2 and char-H2O was determined to be 250.8 kJ/mol, accompanied by a pre-exponential factor of 5.42×1010 g/(m2 s). Using this foundation, the current research conducted simulations to investigate the impacts of temperature, pressure, and H2O concentration on the oxidation adsorption rate (Rads,oxi), desorption rate (Rdes), gasification adsorption rate (Rads,gas), and the competitive influences of kinetics and diffusion processes within the pressurized char-O2/H2O combustion. The simulation results indicate a gradual increase in Rdes and Rads,gas with char conversion to reach a peak, followed by a gradual decline. Conversely, the Rads,oxi varies smoothly throughout the char conversion process. At 1673 K/1.0 MPa, the char-O2/H2O reaction rate is primarily constrained by Rads,oxi and Rads,gas, with the adsorption reaction serving as the rate-controlling step. Moreover, it was noted that a rise in pressure resulted in a linear increase in Rads,oxi, Rdes, and Rads,gas. At elevated temperatures, the impact of pressure on them becomes more noticeable. However, the introduction of H2O mitigates this effect. Elevated temperature and pressure facilitate the competition on the kinetics of char-O2 combustion for O2 diffusion, resulting in the conversion of char being more susceptible to O2 diffusion rate limitation. With the addition of 20% H2O, the competition effect was weakened. In the case of pressurized combustion involving char and O2/H2O, the char conversion is primarily constrained by the O2 diffusion rate and is scarcely influenced by the H2O diffusion rate.

ANALYSIS AND EVALUATION OF THE EFFECTIVENESS OF INNOVATIVE METHODS IN ENERGY

The global energy landscape is undergoing a transformative shift as the demand for energy continues to grow due to industrialization, urbanization, and population expansion. Traditional energy sources, particularly fossil fuels, have long dominated the energy sector, contributing to significant environmental challenges such as climate change, air pollution, and resource depletion. As a result, there is an urgent need to develop and implement innovative energy technologies that can meet growing energy demands while minimizing environmental impact. This paper presents a comprehensive analysis of contemporary innovations in the energy sector, with a focus on the integration of renewable energy sources, optimization of energy conversion processes, and the deployment of advanced energy management systems. These innovations are assessed in terms of their potential to enhance energy efficiency, sustainability, and reliability. By synthesizing the latest research findings and practical implementations, this study aims to identify key trends, challenges, and opportunities in the ongoing transition towards a more sustainable energy future. Keywords: renewable energy sources, energy efficiency, integration, energy consumption.

Dynamics of Religious Conversion from Islamic Education Perspective: Study at the Central Sulawesi Regional Center for Mualaf Foundation

This research aims to discuss the dynamics of religious conversion of converts to Islam and their coaching patterns at the Central Sulawesi Regional Mualaf Center Foundation. This study uses a qualitative method. Data was collected through in-depth interviews, direct field observations, and written document reviews. This research interview involved administrators of converting foundations, converts, and local religious department officials. This research shows that the conversion of converts to Islam at the Central Sulawesi Regional Mualaf Center Foundation occurred because of guidance and marriage. The purpose of receiving guidance is that the informants studied religion before taking the shahada because of God's guidance, while religious conversion was due to marriage, and the informants studied religion after marrying a Muslim partner. The religious conversion process occurs through seven stages: (1) Macro and micro context stages. In the macro context, informants experience pressure from family, the people closest to them, and the family's economic situation. There are two patterns of coaching for converts to Islam at the Central Sulawesi Regional Mualaf Center Foundation, namely: Pre-syahadat coaching, where the Mualaf Center Foundation programs pre-syahadat coaching or what is known as pre-syahadat discussions which are carried out through question and answer sessions about Christianization and the basics of Islam. After the discussion process, the individuals decide to embrace Islam, and then the foundation carries out the prayer process and indicates that the individual has officially converted to Islam.

Quantification of ocean microplastic fragmentation processes in the Sea of Japan using a combination of field observations and numerical particle tracking model experiments

This study estimated the fragmentation rate of microplastics (MiPs) in the Sea of Japan by analyzing MiP size over time following their generation from macroplastics (MaPs). A 5-year particle-tracking model was used to simulate the MaP and MiP motions driven by ocean currents, Stokes drift, the windage of MaPs, beaching, re-drifting, the conversion process from MaPs to MiPs, and the removal of MiPs from the upper ocean. MiP sizes decreased downstream in the Tsushima Current flowing northeastward. The highest correlation between MiP size and elapsed time occurred in the simulation where MiP fragmentation also occurred in the ocean, at 20 % of the rate on beaches. The apparent fragmentation rate in nature was estimated to approximately 1.0 mm/100 days. This study demonstrated that incorporating spatiotemporal information from the simulation into observed size results could further our understanding of fragmentation of MiPs degraded in marine environments.

Modulating Eco-friendly Colloidal AgGaS2 Quantum Dots for Highly Efficient Photodetection and Image Sensing via Direct Growth of Ternary AgInS2 Shell.

Tailoring the optoelectronic characteristics of colloidal quantum dots (QDs) by constructing a core/shell structure offers the potential to achieve high-performing solution-processed photoelectric conversion and information processing applications. In this work, the direct growth of wurtzite ternary AgInS2 (AIS) shell on eco-friendly AgGaS2 (AGS) core QDs is realized, giving rise to broadened visible light absorption, prolonged exciton lifetime and enhanced photoluminescence quantum yield (PLQY). Ultrafast transient absorption spectroscopy demonstrats that the photoinduced carrier separation and transfer kinetics of AGS QDs are significantly optimized following the AIS shell coating. As-synthesized environmentally benign AGS/AIS core/shell QDs are employed to fabricate photodetectors (PDs), showing a remarkable responsivity of 38.4 AW-1 and a detectivity of 2.4×1012 Jones under visible light illumination (405 nm). Moreover, the fabricated QDs-PDs exhibit superior image-sensing capability to record complex patterns with high resolution (160×160 pixels) under visible light illumination at 405 and 532 nm. The findings indicate that the direct growth of multinary narrow-band shell materials on eco-friendly QDs holds great promise to implement future "green", cost-effective and high-performance optoelectronic sensing/imaging systems.

Real-Time Simulation and Hardware-in-the-Loop Testing Based on OPAL-RT ePHASORSIM: A Review of Recent Advances and a Simple Validation in EV Charging Management Systems

Phasor-domain (RMS) simulations have become increasingly vital in modern power system analysis, particularly as the complexity and scale of these systems have expanded with the integration of renewable energy sources. ePHASORSIM, an advanced phasor-based simulation tool developed by OPAL-RT, plays a crucial role in this context by enabling real-time phasor-domain simulation and hardware-in-the-loop testing. To keep pace with these evolving needs, continuous efforts are being made to further improve the accuracy, efficiency, and reliability of ePHASORSIM-based simulations. These efforts include automating model conversion processes for enhanced integration with ePHASORSIM, extending ePHASORSIM’s simulation range with custom models, developing hybrid co-simulation techniques involving ePHASORSIM and an EMT simulator, enhancing simulation scalability, and refining HIL testing to achieve more precise validation of control and protection systems. This paper provides a comprehensive review of these recent advances. Additionally, the paper discusses the conversion of models from PowerFactory—a widely used and comprehensive modeling environment—to ePHASORSIM through both automated tools and manual methods using Excel workbooks, which has been discussed little in the literature. Furthermore, as ePHASORSIM is a relatively new tool with limited cross-validation studies, the paper aims to contribute to this area by presenting a comparative validation against DIgSILENT PowerFactory, with a specific emphasis on its application in electric vehicle charging management systems.

Fine Mapping Regulatory Variants by Characterizing Native CpG Methylation with Nanopore Long-Read Sequencing.

5-methylcytosine (5mC) is the most common chemical modification occurring on the CpG sites across the human genome. Bisulfite conversion combined with short-read whole genome sequencing can capture and quantify the modification at single nucleotide resolution. However, the PCR amplification process could lead to duplicative methylation patterns and introduce 5mC detection bias. Additionally, the limited read length also restricts co-methylation analysis between distant CpG sites. The bisulfite conversion process presents a significant challenge for detecting variant-specific methylation due to the destruction of allele information in the sequencing reads. To address these issues, we sought to characterize the human methylation profiling with the nanopore long-read sequencing, aiming to demonstrate its potential for long-range co-methylation analysis with native modification call and intact allele information retained. In this regard, we first analyzed the nanopore demo data in the adaptive sampling sequencing run targeting all human CpG islands. We applied the linkage disequilibrium (LD) R2 to calculate the co-methylation in nanopore data, and further identified 27,875, 50,481, 26,542 and 51,189 methylation haplotype blocks (MHB) in COLO829, COLO829BL, HCC1395 and HCC1395BL cell lines, respectively. Interestingly, while we found that majority of the co-methylation were in a short range (≤200bp), a small portion (1~3%) showed long distance (≥1,000bp), suggesting potential remote regulatory mechanisms across the genome. To further characterize the epigenetic changes related to transcription factor binding, we profiled the 5mC percentage changes surrounding various motif sites in JASPAR collection and found that CTCF and KLF5 binding sites showed reduced methylation, while FOXE1 and ZNF354A sites showed increased methylation. To further investigate the allele-specific 5mCG in the prostate genome, we designed a target region covering methylation quantitative trait loci (mQTL) and genome-wide association study (GWAS) risk germline variants and generated long reads with adaptive sampling run in the 22Rv1 cell line. To identify the allele-specific methylation in the 22Rv1 cell line, we performed long-read based phasing and compared the 5mCG signals between the two haplotypes. As a result, we identified 6,390 haplotype-specific methylated regions in the 22Rv1 cell line (p-MWU ≤ 1e-5 and delta ≥ 50%). By examining haplotype-specific methylated regions near the phasing variants, we identified examples of allele-specific methylated regions that showed allelespecific accessibility in the ATAC-seq data. By further integrating the ATAC-seq data of 22Rv1, we found that methylation levels were negatively correlated with chromatin accessibility at the genome-wide scale. Our study has revealed native methylome profiling while preserving haplotype information, offering a novel approach to uncovering the regulatory mechanisms of the human prostate genome.

The barriers, determinants, and willingness-to-pay in electric motorcycle conversion (EMC) adoption

The rise in motorcycle use in Southeast Asian countries like Indonesia has caused environmental issues and transitioning from fossil-fuel to electric motorcycles (EM) will reduce emissions and improve air quality. This study aims to investigate the barriers, determinants, and willingness-to-pay in electric motorcycle conversion (EMC). In a choice experiment, data from motorcycle users in Bali, Indonesia, was collected and analysed in this study using K-modes cluster analysis and the Mixed-Logit Model. The study identified different barriers to EMC among motorcyclist groups: mix-motor commuters and hardcore oldies concerned with financial challenges, all-day riders with mature motorcycles face a lack of information on EMC costs and procedures, and higher-power enthusiasts and newbies with light motorcycles concerned with daily travel disruptions during the conversion process. This study also found waiting and conversion time to play a role in EM adoption and travellers who use older motorcycles are the most likely to adopt EMC. Lower-income individuals tend to be more inclined towards EMC and younger demographics lean towards internal combustion engine (ICE) motorcycles. Moreover, the study indicates that EMC reduces the adoption of ICE motorcycles more than conventional EM. A 50% increase in conversion time lowers EMC adoption probability by 5.2%pts. and increases new ICE motorcycle adoption by 3%pts. and new EM adoption by 2.2%pts. Additionally, motorcyclists are more willing to invest in EMC if it means reducing conversion time/charging costs, particularly for older motorcycles. This study offers several policy recommendations for accelerating EMC adoption in Indonesia.

Deterministic Synthesis of a Two-Dimensional MAPbI3 Nanosheet and Twisted Structure with Moiré Superlattice.

The synthesis of extremely thin 2D halide perovskites and the exploration of their interlayer interactions have garnered significant attention in current research. A recent advancement we have made involves the development of a successful technique for generating ultrathin MAPbI3 nanosheets with controlled thickness and an exposed intrinsic surface. This innovative method relies on utilizing the Ruddlesden-Popper (RP) phase perovskite (BA2MAn-1PbnI3n+1) as a template. However, the precise reaction mechanism remains incompletely understood. In this work, we systematically examined the dynamic evolution of the phase conversion process, with a specific focus on the influence of inorganic slab (composed of [PbI6]4- octahedrons) numbers on regulating the thickness and quality of the resulting MAPbI3 nanosheets. Additionally, the atomic structure is directly visualized using the transmission electron microscopy (TEM) method, confirming its exceptional quality. To illustrate interfacial interactions in ultrathin structures, artificial moiré superlattices are constructed through a physical transfer approach, revealing multiple localized high-symmetry stacks within a distinctive square moiré pattern. These findings establish a novel framework for investigating the physics of interfacial interactions in ionic semiconducting crystals.

Metabolite and Transcriptomic Changes Reveal the Cold Stratification Process in Sinopodophyllum hexandrum Seeds.

Sinopodophyllum hexandrum (Royle) Ying, an endangered perennial medicinal herb, exhibits morpho-physiological dormancy in its seeds, requiring cold stratification for germination. However, the precise molecular mechanisms underlying this transition from dormancy to germination remain unclear. This study integrates transcriptome and plant hormone-targeted metabolomics techniques to unravel these intricate molecular regulatory mechanisms during cold stratification in S. hexandrum seeds. Significant alterations in the physicochemical properties (starch, soluble sugars, soluble proteins) and enzyme activities (PK, SDH, G-6-PDH) within the seeds occur during stratification. To characterize and monitor the formation and transformation of plant hormones throughout this process, extracts from S. hexandrum seeds at five stratification stages of 0 days (S0), 30 days (S1), 60 days (S2), 90 days (S3), and 120 days (S4) were analyzed using UPLC-MS/MS, revealing a total of 37 differential metabolites belonging to seven major classes of plant hormones. To investigate the biosynthetic and conversion processes of plant hormones related to seed dormancy and germination, the transcriptome of S. hexandrum seeds was monitored via RNA-seq, revealing 65,372 differentially expressed genes associated with plant hormone synthesis and signaling. Notably, cytokinins (CKs) and gibberellins (GAs) exhibited synergistic effects, while abscisic acid (ABA) displayed antagonistic effects. Furthermore, key hub genes were identified through integrated network analysis. In this rigorous scientific study, we systematically elucidate the intricate dynamic molecular regulatory mechanisms that govern the transition from dormancy to germination in S. hexandrum seeds during stratification. By meticulously examining these mechanisms, we establish a solid foundation of knowledge that serves as a scientific basis for facilitating large-scale breeding programs and advancing the artificial cultivation of this highly valued medicinal plant.

Efficient photocatalytic CO2 and Cr(VI) reduction on carbon quantum dots/carbon nitride heterojunctions

Carbon quantum dots (CQDs), known for their exceptional optical properties, hold the potential to enhance light absorption, charges separation and transfer in semiconductor materials. However, using cheap medicinal materials as precursors in the field of photocatalysis to obtain CQDs has seldom concerned. In this study, we utilized biomass-derived CQDs from carbon-rich licorice powder to improve photocatalytic CO2 and Cr(VI) reduction in polymer carbon nitride (PCN). The CQDs/g-C3N4 heterojunctions were synthesized via a hydrothermal method, and the successful fabrication and integration of CQDs on g-C3N4 surfaces were confirmed through detailed characterization. The optimal sample with a licorice powder to PCN mass ratio of 0.05:1 ((50CQDs/CN) demonstrates a tripling in CO2 conversion efficiency under simulated sunlight compared to the reference PCN. Under visible light irradiation, the 50CQDs/CN also performs superior photocatalytic Cr (VI) removal efficiency, which is 2.48 times of that of the reference PCN. This significant boost is attributable to the successful construction of the CQDs/CN heterojunction and the abundance of functional groups on the CQDs surface, which provide more active sites, improve light absorption and increase charges migration rates. The stability of these new photocatalysts was confirmed through repeated photocatalytic cycles, indicating their potential for practical applications. Mechanistic studies reveal insights into the enhanced photocatalytic pathways and intermediate conversion processes. Our findings present a novel, efficient and sustainable route to fabricate g-C3N4-based photocatalysts, offering a promising strategy for further mitigate the greenhouse gas crisis and environmental pollution.