Sludge Treatment Process Research Articles

Fractionation of wastewater characteristics for modelling of Firle Sewage Treatment Works, Harare, Zimbabwe

Varying conditions are required for different species of microorganisms for the complex biological processes taking place within the activated sludge treatment system. It is against the requirement to manage this complex dynamic system that computer simulators were developed to aid in optimising activated sludge treatment processes. These computer simulators require calibration with quality data input that include wastewater fractionation among others. Thus, this research fractionated raw sewage, at Firle Sewage Treatment Works (STW), for calibration of the BioWin simulation model. Firle STW is a 3-stage activated sludge system. Wastewater characteristics of importance for activated sludge process design can be grouped into carbonaceous, nitrogenous and phosphorus compounds. Division of the substrates and compounds into their constituent fractions is called fractionation and is a valuable tool for process assessment. Fractionation can be carried out using bioassay methods or much simpler physico-chemical methods. The bioassay methods require considerable experience with experimental activated sludge systems and associated measurement techniques while the physico-chemical methods are straight forward. Plant raw wastewater fractionation was carried out through two 14-day campaign periods, the first being from 3 to 16 July 2013 and the second was from 1 to 14 October 2013. According to the Zimbabwean Environmental Management Act, and based on the sensitivity of its catchment, Firle STW effluent discharge regulatory standards in mg/L are COD (<60), TN (<10), ammonia (<0.2), and TP (<1). On the other hand Firle STW Unit 4 effluent quality results based on City of Harare records in mg/L during the period of study were COD (90±35), TN (9.0±3.0), ammonia (0.2±0.4) and TP (3.0±1.0). The raw sewage parameter concentrations measured during the study in mg/L and fractions for raw sewage respectively were as follows total COD (680±37), slowly biodegradable COD (456±23), (0.7), readily biodegradable COD (131±11), (0.2), soluble unbiodegradable COD (40±3), (0.06), particulate unbiodegradable COD (53±3) (0.08), total TKN (40±4) mg/L, ammonia (28±6), (0.68), organically bound nitrogen (12±2), (0.32), TP (15±1.4), orthophosphates (9.6±1.4), (0.64), and organically bound TP (5.4±1.4), (0.36), soluble unbiodegradable TP (0.4±0), (0.03), particulate unbiodegradable TP (0.05±0), (0.003). Thus, wastewater at Firle STW was found to be highly biodegradable suggesting optimisation of biological nutrient removal process will generally achieve effluent regulatory standards compliance. Thus, opportunities for plant optimisation do exist of which modelling with the use of a simulator is recommended to achieve recommended effluent standards in addition to reduction of operating costs.

A rheological approach to analyze aerobic granular sludge

Aerobic granular sludge is one promising biotechnology in wastewater treatment. Despite intensive researches on granular architecture and strategies to improve treatment efficiency, there are still some elusive material parameters needed to stimulate the granulation process. The main aim of this study was to evaluate aerobic granular sludge innovatively using the universal rheology methodology, in terms of processability or quality and texture. Steady shear and oscillatory measurements were performed. Basic rheological characterization showed that aerobic granular sludge was a shear-thinning Herschel–Bulkley fluid with yield pseudoplasticity. Meanwhile, granular sludge presented characterized viscoelastic behaviors in dynamic sweeps highlighting its superiority to flocculent sludge. Furthermore, a Wagner-type constitutive model incorporating a relaxation and damping function was introduced and able to describe the time-dependent and non-linear viscoelastic behaviors. This study could make a further step on predicting rheological properties, helping improve the actual sludge treatment process and the operation of sludge dewatering.

Impact of wastewater treatment processes on antimicrobial resistance genes and their co-occurrence with virulence genes in Escherichia coli

An increase in the frequency of antimicrobial resistance genes (ARGs) in bacteria including Escherichia coli could be a threat to public health. This study investigated the impact of activated sludge and physicochemical wastewater treatment processes on the prevalence of ARGs in E. coli isolates. In total, 719 E. coli were isolated from the influent and effluent (prior to disinfection) of two activated sludge and two physicochemical municipal treatment plants, and genotyped using DNA microarrays. Changes in the abundance of ARGs in the E. coli population were different for the two treatment processes. Activated sludge treatment did not change the prevalence of ARG-possessing E. coli but increased the abundance of ARGs in the E. coli genome while physicochemical treatment reduced both the prevalence of ARG-carrying E. coli as well as the frequency of ARGs in the E. coli genome. Most E. coli isolates from the four treatment plants possessed ARGs of multiple antimicrobial classes, mainly aminoglycoside, β-lactams, quinolone and tetracyclines. In addition these isolates harboured DNA insertion sequence elements including integrase and transposase. A significant positive association was found between the occurrence of ARGs and virulence genotypes.

Seasonal variation in the occurrence and removal of pharmaceuticals and personal care products in a wastewater treatment plant in Xiamen, China

The occurrence and seasonal variation of 50 pharmaceuticals and personal care products (PPCPs) in a wastewater treatment plant (WWTP) in Xiamen, China was investigated over a period of one year. Among the targets, 39 PPCPs were detected in the influent. The highest concentration was observed for acetaminophen, with the average concentration in the influent of 2963.5ng/L. The seasonal variation of PPCPs in the influent was observed. For most pharmaceuticals, highest concentrations were in March 2013, followed by December 2012, while the concentrations were lower in August 2012 and May 2013. Among the detected PPCPs, 14 targets could be removed more than 50% in the WWTP. The activated sludge treatment process contributed to most of PPCP removal, while the adsorption to the particles in the primary treatment and the transformation under UV radiation in the disinfection treatment also contributed to the PPCP removal. Among the detected PPCPs in the influent, 36 PPCPs could be detected in the final effluent of the WWTP. Significantly higher concentrations of PPCPs were observed in effluent samples collected in March 2013 compared to other seasons, suggesting higher concentrations of PPCPs could be discharged into the surrounding seawater during this period.

REDUCTION IN AMMONIUM IONS IN SLUDGE LIQUOR / VIENAS IŠ BŪDŲ MAŽINTI AMONIO JONŲ KONCENTRACIJĄ DUMBLO VANDENYJE

Liquor rejected from the centrifugation of the digested sludge can contain the concentrations of ammonium ions up to 1750 mg/L. These loads are usually returned to the intake of wastewater treatment plants (WWTP) without additional treatment and can have a negative impact on biological wastewater and/or sludge treatment processes, e.g. phosphorus and nitrogen removal. This article deals with the use of naturally obtained sorbent, zeolite, in batch and column test procedure for removing ammonium from the rejected liquor. This research study was carried out using different sizes of zeolite particles: 0.8–1.6 mm and 1.6–2.5 mm. The highest efficiency of ammonium removal (up to 98 %) was achieved by applying the zeolite particles of 0.8–1.6 mm. Article in Lithuanian. Santrauka Sausinant pūdytą dumblą centrifugomis išsiskiria skystis, kuriame gali būti didelės amonio jonų koncentracijos (iki 1750 mg/l). Taip užterštas ir papildomai nevalytas dumblo vanduo, grąžinamas į nuotekų valymo įrenginių pradžią, gali trukdyti nuotekų ar dumblo valymo procesams, būtent, kai siekiama pašalinti azotą ir fosforą. Nagrinėjamas gamtinio sorbento ceolito panaudojimas amonio jonams šalinti iš dumblo vandens maišaluose ar skystį filtruojant pro ceolito užpildus. Tyrimams naudota 0,8–1,6 mm ir 1,6–2,5 mm dydžio ceolito grūdeliai. Didžiausias amonio jonų šalinimo iš skysčio efektyvumas (iki 98 %) buvo pasiektas, kai ceolito grūdeliai 0,8–1,6 mm dydžio.

Impact of secondary treatment types and sludge handling processes on estrogen concentration in wastewater sludge

Endocrine-disrupting compounds (EDCs), such as estrogen, are known to be present in the aquatic environment at concentrations that negatively affect fish and other wildlife. Wastewater treatment plants (WWTPs) are major contributors of EDCs into the environment. EDCs are released via effluent discharge and land application of biosolids. Estrogen removal in WWTPs has been studied in the aqueous phase; however, few researchers have determined estrogen concentration in sludge. This study focuses on estrogen concentration in wastewater sludge as a result of secondary treatment types and sludge handling processes. Grab samples were collected before and after multiple treatment steps at two WWTPs receiving wastewater from the same city. The samples were centrifuged into aqueous and solid phases and then processed using solid phase extraction. Combined natural estrogens (estrone, estradiol and estriol) were measured using an enzyme-linked immunosorbent assay (ELISA) purchased from a manufacturer. Results confirmed that activated sludge treatments demonstrate greater estrogen removal compared to trickling filters and mass concentration of estrogen was measured for the first time on trickling filter solids. Physical and mechanical sludge treatment processes, such as gravity thickeners and centrifuges, did not significantly affect estrogen removal based on mass balance calculations. Dissolved air flotation thickening demonstrated a slight decrease in estrogen concentration, while anaerobic digestion resulted in increased mass concentration of estrogen on the sludge and a high estrogen concentration in the supernatant. Although there are no state or federally mandated discharge effluent standards or sludge application standards for estrogen, implications from this study are that trickling filters would need to be exchanged for activated sludge treatment or followed by an aeration basin in order to improve estrogen removal. Also, anaerobic digestion may need to be replaced with aerobic digestion for sludge that is intended for land application.

A comprehensive substance flow analysis of a municipal wastewater and sludge treatment plant

The fate of total organic carbon, 32 elements (Al, Ag, As, Ba, Be, Br, Ca, Cd, Cl, Co, Cr, Cu, Fe, Hg, K, Li, Mg, Mn, Mo, N, Na, Ni, P, Pb, S, Sb, Se, Sn, Sr, Ti, V, and Zn) and 4 groups of organic pollutants (linear alkylbenzene sulfonates, bis(2-ethylhexyl)phthalate, polychlorinated biphenyl and polycyclic aromatic hydrocarbons) in a conventional wastewater treatment plant were assessed. Mass balances showed reasonable closures for most of the elements. However, gaseous emissions were accompanied by large uncertainties and show the limitation of mass balance based substance flow analysis.Based on the assessment, it is evident that both inorganic and organic elements accumulated in the sewage sludge, with the exception of elements that are highly soluble or degradable by wastewater and sludge treatment processes. The majority of metals and metalloids were further accumulated in the incineration ash, while the organic pollutants were effectively destroyed by both biological and thermal processes. Side streams from the sludge treatment process (dewatering and incineration) back to the wastewater treatment represented less than 1% of the total volume entering the wastewater treatment processes, but represented significant substance flows. In contrast, the contribution by spent water from the flue gas treatment process was almost negligible. Screening of human and eco-toxicity by applying the consensus-based environmental impact assessment method USEtox addressing 15 inorganic constituents showed that removal of inorganic constituents by the wastewater treatment plant reduced the toxic impact potential by 87–92%.

Study of Treatment Process and Development of Oily Sludge

Oily sludge is a mixture of oil and sludge, produced during the process of crude oil production and gathering, contains crude oil, heavy metal and organic toxic and harmful substances, and with the characteristics of high moisture content, poor liquidity and big volume. The recycling and disposal of it has been one of the most important aspects of enviromrntal protection in oil industry. In this paper the origin nature and hazards of oil sludge were described, the existing oily sludge treatment process from the aspects of quenched separation, heat treatment, extraction, biological treatment were introduced, and looks forward to the development of the oil sludge treatment technology.

Ultrasound sludge lysis: heavy metals stability enhancement

Heavy metals in sludge are of great concerns worldwide due to their high toxicity. The toxicity of heavy metals strongly depends on their stability in the sludge. This study investigated the stability of typical sludge heavy metals (As, Cd, Cr, Cu, Ni, Hg, and Pb) during ultrasonic sludge treatment process. Results showed that sonication enhanced the stability of sludge heavy metals, which was beneficial for sludge disposal and reclamation. Content of stable fractions increased and content of unsteady fractions decreased after 15-min sonication at 2.0 WmL−1. The stability of each heavy metal in sludge was significantly different during sonication. For arsenic, unsteady fractions decreased from 94 to 9% and stable fractions increased from 0 to 68% after 15-min sonication; for mercury and lead, stability showed little change due to the high residual fraction. Sonication changed the stability order of heavy metals in sludge. In the untreated sludge, the stability order was As < Ni < Cd < Cu < Cr < Pb < Hg; after 15-min sonication, the order was Cd < Ni < Cu < Cr < As < Pb < Hg.

Polyhydroxyalkanoate (PHA) production from sludge and municipal wastewater treatment

Polyhydroxyalkanoates (PHAs) are biodegradable polyesters with comparable properties to some petroleum-based polyolefins. PHA production can be achieved in open, mixed microbial cultures and thereby coupled to wastewater and solid residual treatment. In this context, waste organic matter is utilised as a carbon source in activated sludge biological treatment for biopolymer synthesis. Within the EU project Routes, the feasibility of PHA production has been evaluated in processes for sludge treatment and volatile fatty acid (VFA) production and municipal wastewater treatment. This PHA production process is being investigated in four units: (i) wastewater treatment with enrichment and production of a functional biomass sustaining PHA storage capacity, (ii) acidogenic fermentation of sludge for VFA production, (iii) PHA accumulation from VFA-rich streams, and (iv) PHA recovery and characterisation. Laboratory- and pilot-scale studies demonstrated the feasibility of municipal wastewater and solid waste treatment alongside production of PHA-rich biomass. The PHA storage capacity of biomass selected under feast-famine with municipal wastewater has been increased up to 34% (g PHA g VSS(-1)) in batch accumulations with acetate during 20 h. VFAs obtained from waste activated sludge fermentation were found to be a suitable feedstock for PHA production.

Life cycle assessment of sewage sludge management: A review

In this article, 35 published studies on life cycle assessment (LCA) of sewage sludge were reviewed for their methodological and technological assumptions. Overall, LCA has been providing a flexible framework to quantify environmental impacts of wastewater and sewage sludge treatment and disposal processes for multiple scales, ranging from process selection to policy evaluation. The results of LCA are, in principle, unique to the goal and scope of each study, reflecting its local conditions and comparison between different LCAs is not intended. Furthermore, the assessments are limited by the methodological development of the life cycle impact assessment (LCIA) and the advancement of research in quantifying environmental emissions associated with wastewater and sewage sludge treatment processes. Thus, large discrepancies were found in the selection of the environmental emissions to be included and how they were estimated in the analysis. In order to reduce these choice uncertainties, consolidation of the modelling approach in the following area are recommended: quantification of fugitive gas emissions and modelling of disposal practices. Besides harmonization of the key technical assumptions, clear documentation of the modelling approach and the uncertainties associating with each assumption is encouraged so as to improve the integrity and robustness of assessment.

Use of PCR-DGGE Based Molecular Methods to Analyse Microbial Community Diversity and Stability during the Thermophilic Stages of an ATAD Wastewater Sludge Treatment Process as an Aid to Performance Monitoring.

PCR and PCR-DGGE techniques have been evaluated to monitor biodiversity indexes within an ATAD (autothermal thermophilic aerobic digestion) system treating domestic sludge for land spread, by examining microbial dynamics in response to elevated temperatures during treatment. The ATAD process utilises a thermophilic population to generate heat and operates at elevated pH due to degradation of sludge solids, thus allowing pasteurisation and stabilisation of the sludge. Genera-specific PCR revealed that Archaea, Eukarya and Fungi decline when the temperature reaches 59°C, while the bacterial lineage constitutes the dominant group at this stage. The bacterial community at the thermophilic stage, its similarity index to the feed material, and the species richness present were evaluated by PCR-DGGE. Parameters such as choice of molecular target (16S rDNA or rpoB genes), and electrophoresis condition, were optimised to maximise the resolution of the method for ATAD. Dynamic analysis of microbial communities was best observed utilising PCR-DGGE analysis of the V6-V8 region of 16S rDNA, while rpoB gene profiles were less informative. Unique thermophilic communities were shown to quickly adapt to process changes, and shown to be quite stable during the process. Such techniques may be used as a monitoring technique for process health and efficiency.

Development of Resource Processing Technology for Heavy Oil Sludge

The process of oil extraction and processing produces large quantities of oily sludge, which is complex and unwieldy. It has become the main pollution factor of affecting oil production. So it is necessary to look for a reasonable treatment technology of oily sludge .This document introduces different sludge treatment methods and technological process, highlights the pyrolysis principle and test methods, and looking forward to the development of oily sludge treatment process.

Organic matter humification in vermifiltration process for domestic sewage sludge treatment by excitation–emission matrix fluorescence and Fourier transform infrared spectroscopy

Performance of a conventional biofilter (BF) and two vermifilters (VFs, different heights) containing earthworms was investigated for domestic sewage sludge (DWS) treatment. Humic-acid like (HAL) fraction isolated from the influent sludge (IS) and effluent sludge of BF (ESBF) and VFs (ESVFs) were determined the elemental and functional composition, and structural characteristics using various analytical approaches. Results showed that performance of DWS treatment in the VFs was preferable to that in the BF. With respect to IS-HAL and ESBF-HAL, ESVFs-HAL had low C, H and N contents and C/O ratio, and high O, carboxyl and phenolic OH group contents, and C/N, C/H and E4/E6 ratios, and large molecular weight. The excitation–emission (Ex/Em) matrix spectra revealed that an additional peak was found at Ex/Em wavelength pairs of 345/435nm in ESVFs-HAL. Further, Fourier transform infrared spectra showed that vermifiltration led to the loss of aliphatic materials and carbohydrates, and the enrichment of carbonyl and phenolic OH groups in HAL fractions. Additionally, the increase in VF height seemed to accelerate humification degree of organic matter in the effluent sludge. In summary, vermifiltration is alternate technology for transformation of organic matter into humic substances, and thus improves quality of DWS as soil organic fertilizer.

Ammonium recovery from reject water combined with hydrogen production in a bioelectrochemical reactor

In this study, a bioelectrochemical reactor was investigated for simultaneous hydrogen production and ammonium recovery from reject water, which is an ammonium-rich side-stream produced from sludge treatment processes at wastewater treatment plants. In the anode chamber of the reactor, microorganisms converted organic material into electrical current. The electrical current was used to generate hydrogen gas at the cathode with 96±6% efficiency. Real or synthetic reject water was fed to the cathode chamber where proton reduction into hydrogen gas resulted in a pH increase which led to ammonium being converted into volatile ammonia. The ammonia could be stripped from the solution and recovered in acid. Overall, ammonium recovery efficiencies reached 94% with synthetic reject water and 79% with real reject water. This process could potentially be used to make wastewater treatment plants more resource-efficient and further research is warranted.

Modelling the filling rate of pit latrines

Excreta (faeces and urine) that are deposited into a pit latrine are subject to biodegradation, which substantially reduces the volume that remains. On the other hand, other matter that is not biodegradable usually finds itsway into pit latrines. The net filling rate is thus dependent on both the rate of addition of material and its composition. A simple material balance model is presented which represents the faecal sludge as a mixture of biodegradable organic material, un-biodegradable organic material and inorganic material. Measurements made on 2 pits in eThekwini, South Africa, were used to determine parameters for the model. Model predictions were then compared with data from 15 other pits in the same area and filling rate data from previous South African studies, which exhibit a 20th to 80th percentile range of 200 to 453 ℓ∙pit−1∙yr−1. These comparisons indicated that the pits studied exhibited relatively low filling rates resulting from orderly disposal practices. The average composition of the pit (COD, biodegradable material and inorganic fraction) changes with age, which will impact on any subsequent sludge treatment process. Pit filling rates are greatly affected by the disposal of solid waste in addition to the faecal material. For the pits studied, the model predicts that the filling time could have been extended from 15 years to over 25 years if all solid waste had been excluded from the pit.Keywords: Pit latrine, filling rate, biodegradation, solid waste disposal

Sludge Retention Time as a Suitable Operational Parameter to Remove Both Estrogen and Nutrients in an Anaerobic–Anoxic–Aerobic Activated Sludge System

Estrogen in wastewater are responsible for a significant part of the endocrine-disrupting effects observed in the aquatic environment. The effect of sludge retention time (SRT) on the removal and fate of 17β-estradiol (E2) and 17α-ethinylestradiol (EE2) in an anaerobic-anoxic-oxic activated sludge system designed for nutrient removal was investigated by laboratory-scale experiments using synthetic wastewater. With a hydraulic retention time of 8 h, when SRT ranged 10-25 days, E2 was almost completely removed from water, and EE2 removal efficiency was 65%-81%. Both estrogens were easily sorbed onto activated sludge. Distribution coefficients (Kd) of estrogens on anaerobic sludge were greater than those on anoxic and aerobic sludges. Mass balance calculation indicated that 99% of influent E2 was degraded by the activated sludge process, and 1% remained in excess sludge; of influent EE2, 62.0%-80.1% was biodegraded; 18.9%-34.7% was released in effluent; and 0.88%-3.31% remained in excess sludge. Optimal SRT was 20 days for both estrogen and nutrient removal. E2 was almost completely degraded, and EE2 was only partly degraded in the activated sludge process. Residual estrogen on excess sludge must be considered in the sludge treatment and disposal processes. The originality of the work is that removal of nutrients and estrogens were linked, and optimal SRT for both estrogen and nutrient removal in an enhanced biological phosphorus removal system was determined. This has an important implication for the design and operation of full-scale wastewater treatment plants.

Occurrence and removal efficiencies of benzotriazoles and benzothiazoles in a wastewater treatment plant in Greece

Despite the widespread use of benzotriazoles and benzothiazoles and the occurrence of these compounds in wastewater treatment plants (WWTPs), no earlier study has comprehensively examined their fate in WWTPs. In this study, an integrated liquid chromatography–tandem mass spectrometry (LC–ESI(+)MS/MS) method was developed and validated for simultaneous determination of four benzotriazoles and four benzothiazoles in dissolved and particulate phases of wastewater (raw and treated), and in dewatered sewage sludge. The target benzotriazoles (BTRs) were 1H-benzotriazole, 1-hydroxy-benzotriazole, tolyltriazole, and xylyltriazole (or 5,6-dimethyl-1H-benzotriazole), and the target benzothiazoles (BTHs) were benzothiazole, 2-hydroxy-benzothiazole, 2-methylthio-benzothiazole, and 2-amino-benzothiazole. The limits of detection ranged from 0.08 (2-methylthio-benzothiazole) to 17ng/L (benzothiazole) for dissolved phase samples, and from 0.04 (2-methylthio-benzothiazole) to 13ng/g dry weight (dw) (benzothiazole) for particular matter and sludge samples. The method was applied in the analysis of wastewater and sludge samples from the WWTP in Athens, Greece. All target chemicals were detected in wastewater samples, and in some cases the concentrations were significant, on the order of a few μg/L. In sludge samples, benzothiazole and tolyltriazole were present at the highest concentrations (174 and 116ng/g dw, respectively). For benzotriazole and tolyltriazole, the removal efficiency was below 68%, and for benzothiazoles, the removal efficiency was greater than 64% in the activated sludge treatment process. Both BTRs and BTHs showed low solid–liquid distribution coefficients.

Environmental Effects of Sewage Sludge Carbonization and Other Treatment Alternatives

Carbonization is a newly developed process that converts sewage sludge to biocoal, a type of solid biomass that can partially substitute for coal during power generation. This study presents an assessment of the environmental effects of various sewage sludge treatment processes, including carbonization, direct landfills, co-incineration with municipal solid waste, and mono-incineration in Taiwan. This assessment was conducted using the life cycle assessment software SimaPro 7.2 and the IMPACT2002+ model. Results show that carbonization is the best approach for sewage sludge treatment, followed in descending order by co-incineration with municipal solid waste, direct landfills, and mono-incineration. The carbonization process has noticeable positive effects in the environmental impact categories of terrestrial ecotoxicity, aquatic ecotoxicity, land occupation, ionizing radiation, aquatic eutrophication, non-renewable energy, and mineral extraction. For the emission quantity of greenhouse gases, landfilling has the greatest impact (296.9 kg CO2 eq./t sludge), followed by mono-incineration (232.2 kg CO2 eq./t sludge) and carbonization (146.1 kg CO2 eq./t sludge). Co-incineration with municipal solid waste has the benefit of reducing green house gas emission (–15.4 kg CO2 eq./t sludge). In the aspect of energy recovery, sewerage sludge that has been pretreated by thickening, digestion, and dewatering still retains a high moisture content, and thus requires a significant amount of energy use when used as a substitute solid fuel. Therefore, the carbonization of sewage sludge would be a more sustainable option if the energy delivery and integration processes are made more efficient.

Comparative LCA of sewage sludge valorisation as both fuel and raw material substitute in clinker production

Abstract A life cycle assessment to evaluate the environmental impact of urban sewage sludge use as alternative fuel or raw material in clinker production was carried out. In order to quantify in detail the overall environmental impact of both scenarios, the sewage sludge treatment process and the transport to cement facilities for both alternatives were considered. The substitution ratio of fuel (petcoke) and raw material (limestone) was fixed between 5 and 15% according to the cement production plant limitations. Both scenarios show CO2 savings when compared to the clinker production without substitution. The mid-point and end-point analysis were favourable to the fuel substitution with savings ranging from 3 to 7% compared to the raw material substitution and also to base case without substitution. The influence of the amount of sewage sludge used for both scenarios indicates that fuel substitution reduced the CO2 emissions when the amount of substitution is increased, while other mid-point and end-point categories were proportionally favourable to the fuel substitution scenario. Additionally, the influence of the substituted material characteristics showed that low heating value (fuel substitution) and CaO addition in lime stabilized sludge (raw material substitution) are critical parameters in terms of environmental impact in clinker production. The fuel substitution represents a significant environmental improvement compared to the raw material substitution scenario and clinker production without substitution.