The non-linearity (NL) of radiation thermometers is critically involved when realizing ITS-90 above the silver point. It has to be corrected for, and its uncertainty should be adequately specified. In this article, results are presented of NL measurements based upon the superposition method and involving light emitting diodes (LEDs) with high radiance output, peaked at a wavelength of 645 nm. To this end, the two LEDs in question have been operated in the pulse mode with a fixed phase shift. Their spectral radiances have been measured by the radiation thermometers to be tested, separately or superimposed by means of a beam splitter. Still the drift in the spectral radiance observed after switching on the LEDs has to be taken into account and corrected for, since this drift, interfering during the superposition procedure, could corrupt the sum rule for the fluxes involved, which is the crux of the superposition method. Therefore, experimental research has been carried out to characterize the drift of LEDs operated in the pulse mode with a fixed phase shift. The result indicated that the drift could be roughly specified in terms of characteristic time intervals: non-linear drift in the first tens of seconds followed by a quasi-linear drift in the subsequent time interval. The crossover time from non-linear to quasi-linear drift could be ascertained by experiment. In the course of the superposition process, switching of the LEDs was done in such a way that only the quasi-linear part of the drift was involved which allowed for the correction of the drift in the NL measurements, as will be reported. Two radiation thermometers were involved in the NL measurements at radiance temperatures between the silver point and 3153 K: an LP-4, with a central wavelength of 650 nm and 10 nm bandwidth, manufactured by KE-Technologie and the primary standard pyrometer PSP, with a central wavelength of 660 nm and 10 nm bandwidth, developed by NIM.