Burial Processes Research Articles

A Multi-Analytical Study on Characteristics and Formation Mechanisms of Corrosion on Bronze Sheets from the Chu Culture Tombs in Dangyang, China

ABSTRACT Bronze sheets from the Spring and Autumn periods (approximately fifth century BCE), which were excavated from Chu culture tombs located in Dangyang, Hubei Province, China, were analyzed in this study. The objective was to explore and elucidate the correlation between the alloy composition, corrosion products, and the surrounding burial environment, while also offering insights into the underlying corrosion mechanisms. A combination of techniques including optical microscopy (OM), SEM–EDX, XRD, micro-Raman spectroscopy, and ion chromatography (IC) were employed to examine these samples. The analysis revealed that the bronze sheets consisted primarily of Cu-Sn-Pb alloys. Metallographic examination showed that the artifacts were initially hot forged and later subjected to partial cold working; some of the samples exhibited sulfide inclusions. XRD and Raman spectroscopy results indicated that the primary corrosion products were SnO2, copper sulfates, and various copper sulfides. Additionally, CuO was identified. Raman spectra of the black-gray corrosion products showed two broad peaks at approximately 1360 and 1580 cm−1. Further analysis of the Raman parameters suggested the presence of soot or humic substances. Based on these findings, it was hypothesized that the sulfide inclusions within the metal's microstructure, the presence of SO 4 2 − , and the activity of sulfate-reducing bacteria in the surrounding soil, combined with the sealed and anaerobic conditions of the tomb, could account for the observed sulfide corrosion products on the bronze artifacts. Moreover, the detection of tenorite and soot points to the possibility that the tombs experienced a fire during the burial process.

Climatic and tectonic controls on ferroan dolomite formation – insights on Early Miocene Mediterranean anoxia (il-Blata, Malta)

Records from the Miocene il-Blata section in Malta offer insights into the Central Mediterranean's depositional environments following an Early Miocene restriction of the Mesopotamian Seaway (∼20 Ma). Inorganic and organic stable carbon isotope values suggest relatively steady depositional environments, whereas authigenic Fe-dolomite abundances exhibiting substantial δ 18 O and δ 13 C variations at a sequence-scale indicate dynamic sedimentation conditions leading to differential diagenesis. Petrographically, the dolomitic levels exhibit matrix-selective dolomitisation, occasional silicification and phosphatisation, and textural indicators pointing to subsurface microbial influence which collectively point to complex shallow burial diagenesis. In addition, the presence of framboidal pyrite and gypsum infilling foraminiferal chambers along with the absence of large planktonic foraminifera, suggests the development of paleoenvironmental stress imposed by a density-stratified water column affecting pore waters. Towards the top of the studied succession, a shift from organic to siliceous deposits reflects water column perturbations possibly linked to changes in oceanic circulation associated with a temporary re-opening of the Mesopotamian Seaway. This study not only underscores hydrochemical controls exerted by North African terrigenous fluxes over the Mediterranean, but also highlights the intricate interplay between shifting depositional environments and shallow burial diagenetic processes in shaping the geochemical and textural fabrics of authigenic mineral assemblages.

Geological structure and faunistic characteristics of the Mansurovo unique locality of early triassic tetrapods and ichnofossils, Orenburg Region

The geological features of the Mansurovo unique locality of the remains of tetrapods and ichnofossils, Orenburg Region (Gostevskaya Formation, Lower Olenekian Substage, Ustmylian Horizon) are considered. A layer-by-layer description cross-section of 16 ditchs and their correlation with the section construction along the line of ditchs are provided. The Mansurovo section, based on biostratigraphic (Wetlugasaurus malachovi grouping of the Wetlugasaurus Fauna) and lithologic-facies data, correlates with the middle part of the stratotype section of the Gostevskaya Formation (Buzuluk Depression of the East European Platform). The geological features of the locality indicate a heterogeneous structure of the identified four geological units of channel-floodplain genesis within the study area, which correspond to alternating sedimentation cycles. The genesis of deposits was clarified using structural-textural analysis and microlithological analysis of rocks in thin sections. The faunistic complex of tetrapods and macroflora, as well as unique complex of ichnofossils were also characterized. Based on the data of lithological-facial analysis, a sedimentation model of the genesis of the locality is presented, showing the uneven nature of sedimentation pattern due to the wandering of river branches and their periodic drying out in a hot and arid climate during the Early Olenekian. Taking into account paleontological data, taphonomy was analyzed, indicating the burial process in the river setting in strong current condition and the possible death of Temnospondyli in subaquatic conditions.

Reservoir Regulation Changed Terrestrial Particulate Organic Carbon Transport and Burial Processes off the Yellow River Mouth

AbstractThe dynamic behavior of particulate organic carbon (POC) is crucial for understanding biogeochemical carbon cycling in coastal and oceanic environments. However, intense watershed human activities have significantly altered the POC transport and burial in the estuary‐coast continuum. Here, we developed a novel parameterization scheme that incorporates grain‐size constraints to investigate the dispersal and accumulation processes of POC off the Yellow River mouth during the water‐sediment regulation scheme (WSRS) using a three‐dimensional hydrodynamic model (FVCOM). The result shows that the model successfully captures the offshore transport and hydrodynamic sorting of POC, which leads to a progressive increase in POC content with offshore dispersion and significant variations in POC and sediment deposition across different isobaths. Rapid fluctuations in river discharge and sediment composition during WSRS stages result in noticeable differences in sedimentation patterns for sediment and POC. At the Water‐regulation stage, distinct differences are observed in the distribution of riverine POC and sediment across various isobaths. In contrast, during the Sediment‐regulation stage, these differences are significantly reduced due to the finer riverine sediment. Compared to the sediment‐regulation, the Water‐regulation plays a crucial role in enhancing the effective burial of POC. Coarse‐grained sediment can form an armored layer that protects OC from disturbance. Additionally, increased runoff during this stage promotes the offshore transport of POC to a less energetic environment (>10 m in depth). This study provides valuable insights into POC dynamics in high‐turbidity estuarine and coastal environments. It underscores the importance of employing comprehensive modeling approaches to elucidate these complex processes.

Influence of tectonic evolution processes on burial, thermal maturation and gas generation histories of the Wufeng-Longmaxi shale in the Sichuan Basin and adjacent areas

The Wufeng-Longmaxi (WL) shale is widely distributed in the Sichuan Basin and adjacent areas in southwest China. The basin experienced multiple-stage complex tectonic movements, whose influences on burial, thermal maturation and gas generation histories in different areas are poorly understood. Based on a detailed study of the denudation stages, strata thickness, and thermal history of the basin, burial and thermal maturation histories of seven wells in different areas were modelled using PetroMod software. Due to the high maturity of the WL shale, a low-maturity Silurian Polish Llandovery shale was used for gold tube closed-system pyrolysis experiments to obtain kinetic parameters for evaluating methane generation history. The Polish shale was selected due to its depositional age, sedimentary environment and organic type, which are similar to the WL shale. The burial history of the WL shale can be divided into five stages: I. Early to Middle Silurian rapid burial; II. Caledonian uplift and denudation; III. Permian to Triassic sustained burial and denudation; IV. sustained burial since the Late Triassic; and V. Late Cretaceous to present sustained uplift and denudation. The thermal maturity of the WL shale in all wells increased with burial depth during stage IV. In addition, high calculated reflectance increments in wells JY1 and N201 during stage III occurred due to the relatively high basal heat flow and deep burial depth, resulting in higher current thermal maturities than in the other wells. The late Permian–Early Triassic and the Middle Jurassic–Early (or Late) Cretaceous were the key methane generation periods for wells JY1 and N201. In contrast, the other five wells had a single methane generation stage, mainly determined by burial and thermal maturation processes. The time of uplift and the amount of denudation during stage V, the current burial depth, the development of faults and fractures, high proportion of retention and the seal capacity of the overlying caprock are key factors for shale gas preservation. Hence, this study will help guide future shale gas development in the Sichuan Basin.

Quantitative characterization of porosity evolution in the Triassic Chang 8 tight sandstone reservoir during hydrocarbon accumulation in the Maling area, Ordos Basin, China

The Maling area in the Ordos Basin is characterized by delta front deposits. The principal oil-bearing layer, Chang 8 Member (the 8th member of the Triassic Yanchang Formation), manifests low-to-ultra-low porosity and permeability due to the interplay of depositional, diagenetic, and burial processes. The reservoir exhibits pronounced heterogeneity and diagenetic alterations, which limit the efficacy of hydrocarbon exploration. Methodologies employed for this research encompass grain size imaging, physical property assays, petrographic thin sections, scanning electron microscopy, high-pressure mercury intrusion, and X-ray diffraction. These techniques facilitated a comprehensive investigation into the diagenetic attributes and compaction mechanisms of the reservoir. A porosity evolution simulation equation tailored to the Chang 8 tight sandstone reservoir was formulated based on diagenetic evolution traits and geological influences. Interdependencies and correlations among various diagenetic processes were analyzed. During diagenesis, compaction, cementation, and replacement led to a reduction in primary porosity, whereas dissolution-induced secondary pores served as high-permeability channels. A quantitative model for porosity evolution was developed alongside qualitative assessments, achieving a deviation of 3.18% when compared to gas porosity measurements. Evaluation of four representative samples revealed that compaction-induced diagenetic alteration predominates, with burial depth, formation age, and cement types playing critical roles in the evolution of reservoir porosity. This differential diagenetic evolution elucidates the underlying causes of variability in reservoir properties and heterogeneity in pore structure, providing valuable insights for future exploration strategies.

Examining the effect of post-depositional processes on the preservation and identification of stone tool residues from temperate environments: An experimental approach.

Studying taphonomy is crucial for understanding how post-depositional processes impact archaeological remains. This knowledge is pivotal for accurately interpreting the archaeological record. Although taphonomy has a long tradition in archaeology, it is less developed in the analysis of stone tool residues compared to other subdisciplines. To address this gap, our study aims to further develop our understanding of the preservation potential of stone tool residues in temperate environments through actualist experiments. To achieve this, we develop a multidimensional experimental program that features the first biweekly monitoring of weathering processes on residues over a one-year cycle, aiming to understand the short-term effects of weathering immediately after tool discard. Additionally, the program involves the study of longer-term burial and weathering visual effects on different residue types within various previously unexplored depositional environments. This approach allows us to observe the visual effects of both weathering and burial processes and to improve our understanding of the different mechanisms involved in the diagenesis of stone tool residues. While known factors such as microbial activity and soil acidity play a primary role in residue decay, specific stone tool-related factors also prove important, underscoring the need to develop further a specific branch of taphonomy related to stone tool residues. Moreover, our results show that certain residue types may survive within these environments that are often considered as being hostile. A residue analysis of stone tools from temperate contexts may thus contribute unique data that can improve our understanding of past human behaviour. Future research with more diverse residue types and depositional conditions will permit further refinement of our understanding of how taphonomy affects residue preservation and enhance the reliability of residue identifications. As such, stone tool residue analysis will become firmly rooted within broader functional approaches to address how humans use stone tools and how this affects stone tool variability.

Depositional and diagenetic controls on the reservoir quality of marginal marine sandstones: An example from the Early Devonian subbat member, jauf formation, northwest Saudi Arabia

The reservoir quality of marginal marine sandstones can vary significantly across different depositional lithofacies. This variation is primarily due to differences in depositional processes and subsequent diagenetic alterations occurring during various stages of burial. To address this issue, this study focuses on the Early Devonian Subbat sandstones of the Jauf Formation, which serve as an important analogue for subsurface gas reservoirs and have potential for CO2 sequestration. An integrated approach was employed, including field observations, petrography, geochemical analyses, and petrophysical analyses, to investigate the impact of depositional and diagenetic processes on reservoir quality. The findings indicate that the sandstones range from poorly to well sorted, very fine to medium-grained arkosic and quartz arenites that were deposited in a range of environments including shoreface-to-offshore transition zones, wave-dominated deltas, fluvial and tidal estuarine channels. The sandstones experienced both shallow and deep burial diagenesis, while key diagenetic events affecting reservoir quality include compaction, carbonate cementation, the formation of authigenic clays (kaolinite, illite, and chlorite), quartz overgrowth, and the dissolution of unstable feldspar and mica grains. Authigenic pore-filling cements and grain-coating clays significantly influence reservoir quality. The effect of quartz cementation was minimal where illite and/or chlorite coatings are well-developed. Mechanical compaction is more pronounced in the shoreface-to-offshore transition compared to the estuarine channels likely due to the higher detrital matrix content (21.7–35%, avg. 26.7%). The well-sorted fluvial to estuarine channel sandstones exhibit the best reservoir quality, with porosity ranging from 15.9% to 25.5% (average 20.4%) and permeability between 433.8 mD and 1261.2 mD (average 720 mD). This high reservoir quality is attributed to the low detrital matrix content (0–1%, average 0.2%) and limited pore-filling cements. In comparison, the moderately sorted, wave-dominated delta sandstones have lower porosity (5.3–11.2%, average 8.2%) and permeability (17.8–80 mD, average 42.8 mD), despite a relatively higher detrital matrix content (0–11.5%, average 2.8%). The poorly sorted shoreface-to-offshore transition sandstones exhibit the lowest reservoir quality, with porosity ranging from 1% to 2% (average 1.5%) and permeability between 0.3 and 1.1 mD (average 0.7 mD). These variations in reservoir quality among different depositional facies are primarily linked to depositional factors (sorting and detrital clay matrix) and shallow to deep burial diagenetic processes (compaction and cementation). A comprehensive understanding of these processes can enhance reservoir quality prediction in the Jauf Formation and similar reservoirs elsewhere.

Silicon balance in an integrated multi-tropical aquaculture ecosystem, Sanggou Bay, China

Farmed aquaculture species play an important role in regulating nutrient cycles in farming systems. Compared with nitrogen and phosphorus, the role of farmed species in the silicon (Si) cycle remains poorly understood. To help reduce this uncertainty, we clarified the sources and sinks of silicate and quantified the Si pools in an aquaculture system in Sanggou Bay (SGB). The results showed that dissolved inorganic nutrient levels were significantly lower during the dry season than during the wet. Dissolved silicate (DSi) is a potential limiting factor for phytoplankton growth during spring, and phosphorus limitation occurs during summer. The budget results indicated that large amounts of nitrogen, phosphate (DIP), and DSi were buried in the sediment or transformed into other forms during both the wet and dry seasons. The nitrogen and DIP cycles were strongly influenced by bivalve excretion and farmed species harvesting; however, these processes had little impact on the Si cycle. Si availability depends on both external inputs and internal recycling. DSi was primarily supplied from the Yellow Sea, with a minor contribution from the river due to river discharge during spring. However, during summer, riverine inflow (accounting for 83% of the total influx) was the major DSi source followed by benthic flux (12%). Biogenic silica (BSi) burial efficiency in the sediment was estimated to be 78% during spring and 23% during summer. The BSi preservation efficiency in bivalves during spring was high (53%), leading to a higher Si retention than in river discharge. Bivalves biodeposition plays an important role in the Si burial process. We suggest that this high retention is essentially controlled by the biodeposition mechanism, which is directly controlled by the exotic suspension feeders. Bivalves have the potential to alter Si retention in the bay by producing large amounts of biodeposits and accelerating the silica cycle, which may lead to more carbon dioxide being absorbed by diatoms.

Controls of tectonics and paleoclimate on depositional–diagenetic evolution and pore types of Upper Cretaceous successions (Sarvak Formation) in the Abadan plain, Iran

This study examines the influence of tectonics and paleoclimate on the diagenetic evolution of Upper Cretaceous carbonate reservoirs (Sarvak Formation) in the Abadan Plain, Zagros Basin, Iran. Through petrographic analysis and scanning electron microscopy, the sedimentary facies, diagenetic processes, and pore system within the Sarvak Formation were analyzed. Facies analysis identified eight microfacies, which were deposited in shallow to deep settings of a carbonate ramp. Among these, the grain-dominated facies (packstone and grainstone) of shoal complexes and reef-talus settings were identified as the most important reservoir facies. The formation's complex diagenetic history includes marine, meteoric, and burial diagenetic processes, with meteoric diagenesis playing a significant role beneath paleoexposure surfaces. The Sarvak Formation was categorized into eight flow units, seven pore size classes, eleven electrofacies, eight velocity deviation zones, and thirteen Lorenz zones. The study's findings indicate that the most favorable reservoir units are located beneath the Cenomanian–Turonian exposure surface, characterized by significant dissolution of rudist-dominated facies due to meteoric processes and karstification. Tectonic uplift, along with weathering and erosion within a warm and humid (tropical) paleoclimate, significantly impacts the diagenetic evolution, pore types, and petrophysical properties of the Sarvak Formation. This research underscores the complex interplay between tectonics, paleoclimate, and petrophysical properties in the Abadan Plain, enhancing our understanding of carbonate systems in tectonically active and paleoclimatically dynamic regions.

Diagenetic evolution and cementation mechanism in deep Carbonate reservoirs: A case study of Dengying Fm. 2 in Penglai, Sichuan Basin, China

The Dengying Formation in the Penglai region of the Sichuan Basin is renowned for hosting high-quality dolomite reservoirs. However, the understanding of their formation mechanisms and spatial distribution patterns remains enigmatic. This study undertakes a comprehensive petrographic analysis of the second member of the Dengying Formation, primarily focusing on its burial history, reservoir characteristics, and an examination of the types, stages, and developmental patterns of cementation within the dolomite reservoir. This is achieved through the application of isotopic geochemistry, inclusion temperature analysis, and laser U-Pb dating. The findings reveal that cements within the second member of the Dengying Formation predominantly occur in pores and fractures, often exhibiting euhedral and subhedral morphologies. These cements also exhibit evidence of replacing original non-skeletal grains and micrites in semi-euhedral and other forms. Broadly, the cements can be classified into four types: calcium cement (the most abundant), dolomite cement, quartz, and pyrite. The formation of calcareous and siliceous cements closely aligns with the sedimentation and burial processes of the Dengying Formation as a whole. The early to late stages of early-middle diagenesis play a crucial role in the formation of dolomite within the second member. Notably, the degree of euhedral dolomite formation directly correlates with the specific diagenetic stage. Our research indicates that the development of high-quality reservoirs in deep-to-ultra-deep microbial dolomites is a result of complex multi-factor interactions and multi-stage discontinuous modifications, leading to strong heterogeneity within the reservoirs. Microbial dolomite carbonates inherently exhibit high initial porosity, with the favorable sedimentary facies serving as the fundamental basis for reservoir development. Dissolution processes during the syngenetic and quasi-syngenetic periods, in conjunction with epigenetic karstification, further augment porosity and expand the reservoir's capacity. During burial and deep burial stages, various acidic fluids play a pivotal role in preserving and modifying the early-formed pores. In the deep environment characterized by high temperature and pressure, microbial dolomite reservoirs undergo intricate diagenetic evolution and possess complex pore preservation mechanisms. Remarkably, even under exceptional ultra-deep conditions, high-quality microbial dolomite carbonate reservoirs can still develop and be preserved, presenting significant potential for oil and gas exploration.

A review of flash flood hazards influenced by various solid material sources in mountain environment

Solid material sources, such as sediment, large wood, and vehicles, intensify flash flood hazards. This paper provides a detailed review of processes involving the recruitment, entrainment, transport, and blockage dynamics of various solid material sources. Results indicate that sediment supplied by processes like landslides and debris flows can obstruct river channels, leading to a sudden increase in flash flood levels. The failure of a barrier dam results in an expansion of downstream inundation areas. Large wood and floating vehicles transported by flash floods and debris flows may directly impact and destroy built structures or form blockages at built structures. Blockages lead to a backwater rise, and the sudden amplification of flow during the failure of these blockages causes more severe disasters. Based on these analyses, the paper proposes future research directions primarily focusing on the changes in sediment burial processes caused by the sheltering effects of building groups. Furthermore, the study aims to investigate the flow amplification effects of large wood and vehicle blockage.

Both nutrients and macrophytes regulate organic carbon burial: Insights from high-resolution spatiotemporal records of a large shallow lake (Baiyangdian) in eastern China

Both ecological regime shifts and carbon cycling in lakes have been the subject of global debates in recent years. However, the direct linkage between them is poorly understood. Lake Baiyangdian, a representative large shallow lake with the coexistence of a macrophyte-dominated area (MDA) and an algae-dominated area (ADA) in eastern China, allowing better understanding of the relationship between regime shifts and organic carbon (OC) burial in lakes. On the basis of Bayesian isotopic mixing modelling of C/N ratios and δ13C values, the sediment OC is primarily of autochthonous origin. The mean OC burial rate (OCBR) was 39 g C m−2 yr−1 before eutrophication occurred in 1990 and increased approximately 2.7-fold to 106 g C m−2 yr−1 after eutrophication. Partial least squares path modelling revealed that this change can be largely attributed to enhanced primary productivity and rapid burial as a result of intensified human perturbation. In terms of spatial patterns, the OCBR was greater in the MDA than in the ADA, which may be related to the different burial and mineralization processes of debris from macrophytes and algae. It then deduced that a decrease in the OCBR and an increase in the mineralization rate might have occurred after a shift from a macrophyte-dominated state to an algae-dominated state. Our findings highlight that eutrophication generally increases OC burial by enhancing lake primary productivity. However, once nutrient levels reach a critical range, lake ecosystems may shift from a macrophyte-dominated state to an algae-dominated state, which can lead to a significant reduction in the carbon burial capacity of lakes. Therefore, more attention should be given to avoiding shifts in eutrophic lakes, as such shifts can alter carbon cycling.

Different pacemakers of marine organic carbon burial in the North Yellow Sea from the early to late Holocene

Marginal seas play a crucial role in the global carbon cycle, contributing approximately 20% of the net CO2 uptake by the world's oceans. The North Yellow Sea (NYS), a semi-enclosed marginal sea in the western Pacific Ocean, serves as a significant carbon sink influenced by factors such as sea level changes, monsoon dynamics, ocean currents, and El Niño-Southern Oscillation (ENSO) activity. This study examines a 538 cm-long sediment core W03 from the NYS (10.3 kyr BP to present). We analyzed Organic Carbon (OC) proxies, including total organic carbon (TOC), the stable carbon isotope (δ13C) of TOC, total nitrogen (TN) and marine-produced lipid biomarkers. Our findings demonstrate a strong correlation between OC burial and sea-level fluctuations during the early Holocene, driven by the exposure of the continental shelf. During the mid-Holocene, the intrusion of the Yellow Sea Warm Current increased salinity and temperature conditions and nutrient levels of sea water, thereby enhancing marine OC burial. Over the last 3.3 kyr BP, ENSO variability and intensified East Asian Winter Monsoon (EAWM) strengthened the coastal currents, contributing to better OC preservation. Additionally, human activities on the surrounding mainland increased terrestrial input, altering the OC burial. The heightened activity of the Kuroshio Current also introduced more saline and warm water masses into the NYS, impacting phytoplankton productivity and community structure, as indicated by increased C37 alkenones. This study highlights the complex interplay of geological factors in OC burial processes within the NYS, providing valuable insights into OC dynamics in marginal seas under the impact of global change.

Vertical distribution of microplastics in sediment columns along the coastline of China

At present, there has been relatively less coverage of microplastics (MPs) pollution in sediment columns, especially across a large geographical span. This study collected sediment columns across 11 provinces along the coastline of China for MPs pollution investigation. The study found higher MPs diversity (Simpson diversity index) in sediment columns than in surface sediments, mostly comprising fiber MPs with dominant transparent and blue colors. Lower MPs pollution was noted in mangrove reserves, while estuarine and coastal areas showed higher pollution levels. Spearman correlation analysis shows that vertical of MPs abundance significantly decreased with depth at 6 of 11 sites. Large-sized MPs with diverse colors in deeper sediments (>40 cm) suggests that burial processes may render MPs more resistant to degradation. Our research highlights varied MPs distribution in coastal sediment, aiding future marine MPs pollution prediction and assessment.

Multicriteria Model for Prospective Locations for Sediment Dump Sites Coastal Dunes Management: Case Study from Barroquinha City, Northeast Brazil

Coastal zones are attractive for the development of economic interests (real estate and tourism) and are intensely occupied in a disorderly manner. Development in areas with available sediments can lead to conflicts between the natural movement of dunes and cities and communities and may result in burial processes. In addition, natural structures, such as dunes, play key roles in protecting against coastal erosion by balancing the beach-dune system with the sediment input, thus slowing the erosion process. This study aims to determine suitable areas for creating dune field dump sites in Barroquinha, Ceará, northeastern Brazil. The results showed that along the study area, the places with the greatest viability for creating dump sites were those furthest from the urban and permanent protection areas. In the stretch connecting Barroquinha City to the Bitupitá community on the CE-187 highway, 45 deposition points were monitored across five sectors under different environmental conditions. Sectors 2, 3, and 4 showed good responses to sediment fixation, in agreement with what was presented in the locational feasibility model. These results add to the discussion on urban infrastructure burying processes, making important contributions to urban planning and management in coastal areas. The results of this study will form an integral part of the Regional Contingency Plan for Incidents and/or situations of risk of environmental impacts in the coastal and/or oceanic zones of Ceará, which was conceived by the Chief Environment Scientist Program of Ceará State and contributes to the Action Plan against burying infrastructure by dune fields.

Dynamic 3D model for decoding archaeological complexity of funerary contexts. Phenomena of collapse and fragmentation in an Iron Age burial of Padua (Italy)

Archaeological settings are intrinsically dynamic, undergoing transformations over time that significantly impact the archaeological record. These changes result from both deliberate human interventions and natural degradation processes. Post-depositional phenomena often distort our understanding of ancient contexts, complicating the identification of the original arrangement and hindering the interpretation of archaeological findings. This issue is particularly pronounced in funerary contexts, such as burials, which are susceptible to various natural and human-induced alterations. This study shows the potential of analysing funerary contexts within a processual framework and reconstructing them in a dynamic 3D environment. By employing metrically and morphologically accurate 3D reconstructions, it becomes possible to simulate, isolate, and analyze post-depositional phenomena. The precision of 3D simulation increases significantly when considering factors such as gravity. The goal of this study is to assess changes resulting from transformative phenomena, with a specific focus on creating a sequential representation that elucidates the burial's transformation processes, spanning from deposition to excavation phases.

Diagenetic history and porosity evolution of the Middle Permian clastic-carbonate mixed system, Indus Basin, Pakistan: Implications for reservoir development

This study deals with unraveling the diagenesis-induced porosity evolution in a mixed clastic-carbonate sequence of the Middle Permian Indus Basin, Pakistan. Multiple data sets including outcrop, petrography, cathodoluminescence, scanning electron microscopy (SEM), mineralogy, and geochemical isotopic compositions were integrated to establish a link between porosity evolution and diagenesis. The spatial thickness and facies variations of the strata at outcrop scale are inherently controlled by the underlying bathymetry of the basin with deepening westward trend. The low values of δ18O of the target strata, relative to average values of the Permian carbonate, hints to diagenetic alteration in the strata. The data sets used in this study reveal modification of the strata in four environments, that is, i) early marine diagenesis indicated by micritization, pervasive dolomitization and isopachous fibrous cements, followed by ii) meteoric dissolution, and iii) shallow burial diagenetic processes including the precipitation of blocky cement, compaction of skeletal and non-skeletal allochems, and stylolites, and iv) a deep burial environment, characterized by pressure solution, and micro-fractures. The clastic intervals host subangular to subrounded quartz grains, floating textures, and almost complete absence of deleterious clay minerals, consequently resulting in the preservation of primary porosity. The primary porosity of carbonate intervals is preserved in the form of intercrystalline and intracrystalline porosity. The secondary porosity evolved through various diagenetic phases in the form of fractures and dissolution. The diagenetic solution mediated by organic matter in carbonates may have experienced both bacterial decomposition and thermochemical sulfate reduction, precipitating sulfides within the pores. The plug porosity/permeability analyses generally suggest high porosity in the siliciclastic unit, and carbonates with wackestone fabric while lower values were observed for the inner shelf pure carbonate facies. However, both intervals show very low permeability values probably due to isolated moldic pores and intense micritization. Therefore, clastic intervals may provide an opportunity to serve as a moderate reservoir; however, the carbonate intervals possess very low permeability values and could generally be considered as low-moderate reservoir potential.

Tectono-metamorphic evolution of the Central Bundelkhand Craton, India from geochemistry and bulk composition modelling of amphibolite enclaves

The Bundelkhand Craton (BuC) represents a significant Archean terrane within the northern Indian Craton and yet its tectono-metamorphic evolutionary history remains relatively understudied. Our investigation involves detailed petrography, geochemistry, and bulk composition modeling of both garnet-bearing and garnet-absent amphibolites with a two-fold objective: (i) to constrain the protolithic nature and tectonic settings involved in the genesis of these rocks, and (ii) to propose a tectono-metamorphic evolutionary history for the BuC. The BuC amphibolites originate from basalt and andesitic-basalt protoliths. Their trace element compositions reveal negative anomalies in Nb, Ta, and Ti, while their rare earth element (REE) normalized patterns indicate enrichment in light REEs over heavy REEs. The basaltic protolith is interpreted to have formed during orogeny in a compressional tectonic regime at the active margins of island arcs in a subduction-related setting. This interpretation is supported by various discrimination plots for amphibolites, such as Nb/Th vs Zr/Nb, Zr vs Zr/Y, and Th/Nb vs Ce/Nb, as well as high Th/Yb and low Nb/Yb contents— all of which suggest an island arc setting influenced by subduction. These amphibolites have undergone three distinct phases of metamorphism, as evidenced by petrography, mineral chemistry, and bulk composition modeling. This interpretation is further supported by geochemical discrimination diagrams which indicate that a subduction tectonic setting was active during peak metamorphism. During the pre-peak phase, the garnet-bearing amphibolites experienced pressure and temperature conditions ranging from 6.25 to 6.5 kbar and 580 to 590ºC, while the garnet-absent amphibolites underwent conditions from 5.0 to 5.8 kbar and 400 to 450ºC. Peak metamorphism was observed at pressures ranging from 6.8 to 7.4 kbar and temperatures from 760 to 805ºC for the garnet-bearing amphibolites, and at pressures from 7.0 to 7.4 kbar and temperatures from 785 to 810ºC for the garnet-absent amphibolites. The metamorphic retrograde conditions for the garnet-bearing amphibolites are defined by P-T conditions ranging from 4.45 to 4.75 kbar and 585 to 615ºC, while for the garnet-absent amphibolites, it ranges from 3.1 to 4.0 kbar and 620 to 710ºC. The mineral assemblages and P-T conditions delineate a clockwise P-T path for both, garnet-bearing and garnet-absent amphibolites from the Babina and Mauranipur regions. This suggests that the rocks underwent a burial process amid subduction tectonic settings in an arc-related environment, followed by a decompression stage that brought them to the surface.

Robust sulfur and oxygen isotope evidence for a highly anoxic paleoenvironment in Late Devonian seawater: Insights from marine anhydrites in the Zaige Formation, South China

A global-scale mass extinction event occurred in the Late Devonian, and its triggering mechanisms have remained a subject of controversy. The key to resolving this controversy lies in elucidating paleoenvironmental characteristics and their coupling relationship with the mass extinction. Marine evaporites serve as sensitive indicators that can be used for reconstructing the geochemical history of ancient oceans. In this study, we present a dual sulfur and oxygen isotopic dataset of marine anhydrites in the Lunatian gypsum deposit (Yunnan, China), and investigate its paleoenvironmental significance within the framework of the Late Devonian mass extinction. These anhydrites originate in arid and hot continental margin seas near convergent plate boundaries, forming as a result of the dehydration of marine gypsums during burial processes. Anhydrites exhibit a conspicuous positive anomaly in δ34S values (23.6–25.1‰, averaging 24.3‰), primarily attributed to bacteria-mediated sulfate reduction. The δ18O values of the Lunatian anhydrites (12.2–15.2‰, averaging 14.0‰) indicate a slightly higher oxygen isotope composition for Late Devonian seawater (8.7–11.7‰, averaging 10.5‰) compared to those of contemporary seawater (9.5–10.1‰). Such an oxygen isotopic characteristic for the Lunatian anhydrites is intricately associated with the chemical processes that occur during the diffusion of sulfides into the upper seawater. The anhydrite-forming evaporating system has a noticeable brine layering where the surface seawater is less dense than the deeper brine, and bacterial processes gradually increase δ34S in the deep brine. When the deep brine and surface seawater rapidly mix, it leads to a significant positive shift in the sulfur isotope composition of the resulting evaporites. Our sulfur and oxygen isotope data from Lunatian anhydrites validate the existence of an exceedingly anoxic marine environment during the Late Devonian, potentially serving as a pivotal factor in the mass extinction event.