The relation to operands (RO) principles describe the relation between operands and answers in arithmetic problems (e.g., the sum is always larger than its positive addends). Despite being a fundamental property of arithmetic, its empirical relation with arithmetic/algebraic problem solving has seldom been investigated. The current longitudinal study aimed to address this issue. Two-hundred-and-two Chinese fifth graders (57% boys) were assessed on their RO understanding. Their arithmetic/algebraic problem solving were assessed multiple times over 2 years. Results from latent growth curve modeling showed that RO understanding predicted the growth in arithmetic/algebraic problem solving when other known predictors of arithmetic/algebraic problem solving were controlled. The findings highlight the role of RO understanding in children's mathematical development. Interventions should be developed to enhance children's RO understanding. (PsycInfo Database Record (c) 2023 APA, all rights reserved).