Chemisorption studies have progressively shown the importance of having available truly clean surfaces to obtain valuable results. To this end in the past few years extensive use has been made of evaporated films: however, recent trends seem to prefer the use of bulk materials (filaments, foils, tips) which can be degassed at high temperature. Such materials are much more versatile than films, and give a useful basis to the development of new techniques for the study of surface phenomena. These surfaces can be used any number of times; they further permit the elimination of secondary phenomena, not strictly related to the surface, such as diffusion within the discontinuous structure of evaporated films. Techniques employing bulk materials are necessarily restricted to those metals which do not possess an appreciable vapour pressure at the degassing temperatures required. However, the results which have recently been obtained with this type of sorbent, by field emission microscopy, field ion microscopy and flash filament technique, are of great theoretical interest and can be applied to most of the other metals. We limit ourselves to quote the information obtained about the existence of: (a) various types of atoms on the metal surface, characterized by different sorption properties; (b) different coefficients of surface diffusion for the different crystal faces; (c) different states of the gas adsorbed on the metal. Concerning this latter point, useful information can be obtained from infrared spectroscopy of the adsorbed molecules. This complex picture of the observed phenomena is confirmed by our results for the adsorption of nitrogen and carbon monoxide on tungsten. The technique used to measure the velocity of adsorption, based on the flow of gas through a capillary of known conductance, is similar to that used in the field of getters; the adsorbent is a tungsten lamina having a thickness of 0.0025 cm and a surface area of 27.5 cm 2; the measurements have been carried out in the pressure range of 10 -7 to 10 -8 Torr, and in the temperature interval between 90 and 480°K. A problem of particular interest arises from the immeasurably low temperature coefficients and from the fact that the velocity of adsorption is initially independent of the surface coverage. The theoretical hypotheses put forward concerning this problem are briefly examined. The correct interpretation of such complex surface phenomena seems to be necessary even for the study of gas sorption by evaporated metal films.