In the past 20 years polymer electrolyzer membrane fuel cells (PEMFCs) received great attention as a clean alternative for powering mobility and stationary applications. Resultingly, there has been a rich amount of research by public, private and university investigators particularly focusing on membranes, catalysts, transport and cost. Yields of great advances were made, though scant attention was given to the generation of this hydrogen and polymer electrolyte membrane water electrolysis (PEMWE) was the neglected stepsister, sentenced to back chapters, footnotes, and small conference rooms. Now however the opportunity for hydrogen generated from renewables, "green hydrogen" has been widely seen as an opportunity to not only provide hydrogen for these PEMFC applications, but also seemingly intractable CO2 emitters as ammonia generation and steel and petroleum refining. As numerous government agencies have announced eye-popping targets for green electrolysis and the complementary research funding, the temptation is to take the beautiful evening gown woven of PEMFC research and adorn the overlooked stepsister. .Zealous PEMFC researchers have not surprisingly reversed course and focused attention on making, rather than consuming hydrogen. Exploitation of the PEMFC and PEMWE analogy is tempting, as many of the materials and reactions are the same or similar. Noteworthy, there are the polymer electrolyte membrane, expensive PGM catalysts, a very fast hydrogen reaction and very slow oxygen reaction. Yearning for faster kinetics and facile heat management, both also have pushed operation to higher temperatures and suffer the accelerated degradation that goes with it. Using these analogies has has generated some benefits, particularly in lower catalyst loading and conductive membrane resistance. Keeping in mind the differences is key however, as PEMWE will generally need to operate at much higher currents, under higher pressures, for far longer durations.This talk will look at what PEMWE has and has the potential to learn from PEMFC research. We will look at materials, their key aspects and how optimizing for each is different, with a focus on costs, the use of hydrocarbon materials, chemical and mechanical durability strategies and recycling. Use cases will also be explored, particularly how the need for high hydrogen production pressures (>30 bar) changes the electrode assembly as well as the balance of stack.
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