Prior Austenite Grain Research Articles

Effect of N Content on the Microstructure and Impact Properties of Normalized Vanadium Micro-Alloyed P460NL1 Steel

In this work, the effect of nitrogen doping on vanadium micro-alloyed P460NL1 steel is studied in terms of microstructures and impact toughness. As the nitrogen content increased from 0.0036% to 0.0165%, the number of V (C,N) particles increased. The fine precipitates of V (C,N) effectively pin the prior austenite grain boundary, resulting in the refinement of the austenite grain. The intragranular and intergranular V-containing coarse particles enhanced the nucleation of intragranular ferrite and the grain boundaries of polygonal ferrite during air cooling. Accordingly, the proportion of heterogeneously nucleated ferrite increased, and the grain size of ferrite decreased. Notably, the size of the pearlite microstructure decreased, and the bainite microstructure appeared with a high doping of N. With the increase in N content, the impact toughness of vanadium micro-alloyed P460NL1 steel was enhanced. This can be attributed to the refinement of ferrite and the reduction in pearlite, which, in turn, was ascribed to the increase in nitrogen.

Crystallographic characteristics and mechanical behavior of laser welded joints of hot roll bending parts

In this work, laser welding was performed on the hot roll bending parts obtained by local-induction-heating bending forming. The influence of the crystallographic characteristics of the phase transformation products in different regions of the laser welded joint on the mechanical properties was systematically studied, and the reasons for the performance degradation were discussed in detail. The results show that upper-critical HAZ (UCHAZ) forms coarse prior austenite grain (PAG) and bainite, resulting in the lowest dislocation density of 2.5 × 1014 m−2 and the lowest impact toughness value of 46 J/cm2. Sub-critical HAZ (SCHAZ) forms tempered martensite, causing the joint to soften and the tensile strength to decrease by 18%. The number of variants in SCHAZ is the lowest, where short laths with smaller misorientations merge into long laths, and precipitates nucleation and growth occurs. The uniform orientation of the variants in SCHAZ forms low-angle grain boundaries (LAGBs), which reduces the hindrance to crack propagation, so the mechanical properties of SCHAZ decrease. In addition, the texture analysis found that UCHAZ has the highest 〈001〉//RD orientation volume fraction, indicating that UCHAZ is most prone to rapid expansion of brittle cracks on the {001} cleavage plane, so the toughness of UCHAZ is reduced. SCHAZ has the highest {001}〈110〉 texture volume fraction and the lowest proportion of high-angle grain boundaries (HAGB), indicating that the deformed grain structure with the {001} cleavage planes distributed along the LAGB after welding heat tempering is the main reasons for the delamination of SCHAZ.

Characterization of the Microstructure of A Breakout Steel Sample

The microstructure of a continuously cast break out of low carbon steel has been studied using optical microscopy; SEM/EDS and EBSD analysis techniques. SEM and EBSD studies were carried out on two different locations on one sample piece and the resulting room temperature grains were found to be mostly BCC α- ferrite phase. Their orientations (using Euler angles) were determined. No meaningful amount of FCC phase was indexed after two patterns indexed on the two locations of the sample piece. The FCC comprised only 0.02% to 0.08% of the total patterns indexed. EBSD maps for the two locations, along with pole figures and grain size charts were deduced for the BCC phase. Volume fraction of the phase was estimated. Reconstruction of the Prior Austenite Grain Boundary was made from the alpha grains data using AztecWave software (AZtecCrystal). Only a small amount of the prior austenite grain boundaries was determined suggesting that the size of the parent grains were significantly larger than the map area in each case.

Quantitative analysis of local plasticity accompanying hydrogen-related fracture in low-carbon martensitic steel

In this study, the local plasticity accompanying hydrogen-related fracture in a low-carbon martensitic steel was quantitatively investigated by correlative microscopy analysis combining digital image correlation technique and electron backscatter diffraction. The results revealed that strain localization occurred mainly in the bulk of martensite blocks and at prior austenite grain boundaries, both with and without the presence of hydrogen. Moreover, hydrogen enhanced strain localization during deformation and facilitated crack nucleation and propagation. The quantitative analysis showed that the hydrogen-related quasi-cleavage cracking was closely related to the local plastic deformation, and increasing hydrogen content decreased the local strain level required for quasi-cleavage cracking. It was found that strain localization also occurred around the intergranular cracks, suggesting that hydrogen-induced intergranular cracking was not a classical simple decohesion process and strain localization was involved in the sequence of hydrogen-induced intergranular cracking. These findings shed light on the understanding of the intrinsic nature of hydrogen embrittlement.

Analysis of phase transformation thermodynamics and kinetics and its relationship to structure-mechanical properties in a medium-Mn high strength steel

The difference in transformation mechanisms between the normal and reverse phase transformation in medium Mn steel was revealed using thermodynamic and kinetic analysis. The results indicate that the austenite formation during the reverse phase transformation is a fast reaction, significant amount of 46.9 vol% retained austenite is obtained after subjected partial reversion at 650 °C × 1 h. At the nucleation stage, the lath-like structure, dislocations, martensitic packet boundaries, and grain boundaries provide high-density nucleation sites for austenite formation. The critical temperature of austenite formation is reduced by the enrichment of Mn and C. However, no ferrite transformation occurred during the normal phase transformation (650 °C × 6 h isothermal treatment and subsequent furnace-cooling process). At the nucleation stage, the undersaturated Mn and C in the prior austenite grain interior provide insufficient concentration fluctuation, leading to a low nucleation rate. At the phase growth stage, the atomic mobility of Mn and C in the parent austenite (control the ferrite growth) is 1/69 and 1/282 than that in ferrite (control the austenite growth) at 650 °C. The differences in nucleation site density, driving force, and element diffusion rate lead to significant variations in phase transformation behaviors. The excellent mechanical property with the product of strength and elongation (PSE) exceeding 20 GPa % is achieved via the sustained transformation-induced plasticity (TRIP) effect by metastable retained austenite over a large strain range.

Microstructural inhomogeneity and associated hetero mechanical behavior in advanced bainitic weathering steel weldments

A new filler metal was developed to join the new generation weathering steel Q690qNH. Microstructural evolutions and the associated mechanical behavior of weldments were comparatively studied in hot rolled and tempered thick Q690qNH plates with initial microstructure of lath bainite and granular bainite respectively. Phase transformations in the HAZ promote the work hardening capacity of the weld jointed tempered Q690qNH (Q690T) plate and enable the joints to exhibit a different mechanical response upon the tensile loading in comparison to the weld jointed hot rolled Q690qNH (Q690R) plate. Prior austenite reconstruction was carried out to understand the crack nucleation behavior in HAZ. The plastic incompatibility between martensitic-austenitic (M-A) and bainitic ferrite leads to the nucleation of plastic micro-voids from the prior austenite grain boundary or M-A boundary. The fracture of Q690R joint is caused by coalescing micro-voids in HAZ with a strength reduction of 10%–14% that caused by the welding process. The continuous yielding behavior regarding the retained austinite in HAZ results in a competition of the plastic deformation in each subzone of the Q690T joint, of which the catastrophic fracture is dominated by the initial microstructure comprising the ferrite and the granular bainite.

Study on the materials flow, microstructure and mechanical properties of ultrasonic vibration-assisted friction stir weld of 1500 MPa martensitic steel

In this study, friction stir welding (FSW) was conducted on 1500 MPa martensitic steel with a thickness of 2.3 mm at 500 rpm and 60 mm/min with and without the application of ultrasonic vibration. The utilization of pure nickel as a marker material could help to visualize the material flow behavior throughout the whole FSW process. In addition, the width change of the marker material was used to distinguish the welding stages. At the same time, the microstructure was also characterized to study the effect of ultrasonic vibration on the welding process. The conventional FSW (C-FSW) joint had tunnel defects due to poor material flow, while the ultrasonic vibration-assisted FSW (U-FSW) joint was defect-free. To study the microstructure and texture evolution during the process, a fully austenitized welding zone was reconstructed from martensite to prior austenite grain (PAG) based on the Kurdjumov-Sachs orientation relationship. The strain rate increased in U-FSW compared to that in C-FSW, resulting in a reduction of the PAG size and an alteration of its shear texture components from type-A to type-B. The uniaxial tensile tests showed that the ultimate tensile strength (UTS) of the stir zone (SZ) of U-FSW was significantly increased compared with that of C-FSW.

An integrated experimental-numerical study of martensite/ferrite interface damage initiation in dual-phase steels

Martensite/ferrite (M/F) interface damage is relevant to failure of many dual-phase (DP) steels, but the underlying microscale mechanisms remain unclear. Through an integrated experimental-numerical study, this work examines the recent hypothesis that (lath) martensite substructure boundary sliding triggers and dominates M/F interface damage initiation accompanied by apparent martensite plasticity. The mesoscale morphology and prior austenite grain reconstruction are used as modelling inputs. A multi-scale framework is adopted to predict the interface damage initiation. The M/F interface damage initiation sites predicted by the model based on a sliding-triggered interface damage mechanism adequately agree with those identified from in-situ experiments, confirming the key role of substructure boundary sliding. Moreover, the M/F interface damage initiation strongly correlates with a low M/F strain partitioning rather than the commonly accepted strong M/F strain partitioning. This fundamental understanding is instrumental for the future optimization of DP steel microstructures.

Effect of paint baking on the fusion boundary softening and fracture behavior of Q&P 980 steel resistance spot welds

During automotive assembly, vehicles undergo low-temperature heat treatment (paint baking) to harden the paint. Although paint baking occurs at a relatively low temperature, it can remarkably affect the weld's mechanical and fracture behavior. This work studies how paint baking improving the strength and fracture behavior of Q&P 980 spot welds exhibiting a halo ring; a low carbon enriched zone in the weld nugget. The mechanical behavior of the paint-baked welds reveals an increase in cross-tensile strength and absorbed energy when baked at 180 °C for 27 min. Microstructural observation showed that the martensite present in the as-welded conditions started to decompose into tempered martensite with ε-carbide in the martensitic matrix. Gleeble thermo-mechanical simulations of the upper-critical heat-affected zone (UCHAZ) were produced to understand the mechanical and fracture micro-and macro-mechanisms, before and after the paint baking process, by widening the regions of UCHAZ. The transmission electron microscopic analysis of the Gleeble simulated sample reveals the segregation of C, Mn, Al, and Cr along the prior austenitic grain boundary which will change the nature of bonding at these boundaries. Nevertheless, paint baking treatment helps to redistribute the segregated elements from the grain boundary to the grain interior and to eliminate the solidified liquation formed at the grain boundaries during welding. The transformation of martensite to decomposed martensite, elimination of solidified liquation due to the enhanced atomic mobility and growth of surrounding grains, and the redistribution of C, Mn, Al, and Cr from the grain boundary to interior regions of grains, are the main reasons for the improvement of mechanical properties and fracture behavior of the spot welds.

Continuous Heating/Cooling Transformation Kinetics of a Novel CrNiMoV Steel for Large Structural Parts

Continuous heating transformation (CHT) and continuous cooling transformation (CCT) characteristics as well as phase transformation kinetics of a novel Cr–Ni–Mo–V steel for large structural parts are studied using a Gleeble‐3500 thermal–mechanical simulator. CCT curves are obtained. The results show that carbides in initial structure can be completely dissolved during CHT as the heating rates are not greater than 0.2 °C s−1. The final microstructure exhibits obvious sensitivity to cooling rate. It contains martensite with or without bainite. Besides, kinetic models of austenitization are established, and it is confirmed that diffusion is the major mechanism of austenitic transformation in steel during CHT. Meanwhile, bainitic phase transformations kinetic model is developed based on the J–M–A model. The fitted Avrami indexes n combined with transmission electron microscope reveal that the bainite nucleation sites of the steel are mainly located at the prior austenite grain boundaries, and the growth of bainite grains mainly follows a 2D mode. The kinetics of martensitic transformation is better modeled based on the K–M equation. A deep understanding of kinetics and microstructure characteristics during CHT and CCT is of great significance to regulate the final performance of the novel steel under development.

Initiation of high-temperature fatigue cracks at the most tip of fractured grain boundaries

Two 2.2Cr heat resistant steel samples that had been fatigue tested respectively at 550 °C and 650 °C are analyzed on the atomic scale to reveal the different crack initiation mechanisms. Cracks formed along prior austenite grain boundaries (PAGBs) are selected and manufactured into foil specimens with the aid of focused ion beam (FIB). Hence the interior crack progressing routes are illustrated and the atomic structure particularly at the most tip of cracks are characterized by using the high resolution TEM. It is revealed that the cracks mainly progress within a spinel phase (Cr2MnO4) while not its interface with neighbouring martensitic matrix. Moreover, geometric phase analysis (GPA) and lattice misfit at the most tip of cracks further manifest a elastic dominated and a plastic dominated mechanism corresponding to the two specimens, respectively. Cracking of the 650 °C specimen is mainly attributes to the accumulation of plastic strain that caused by the viscoelastic transformation of PAGBs, which causes intriguing periodic grain boundary sliding (GBS) waves ahead of the crack tip.

Effects of Intercritical Heat Treatment on the Temper Embrittlement of SA508 Gr.4N Ni-Cr-Mo High Strength Low Alloy Steels for Reactor Pressure Vessels

To analyze the effects of intercritical heat treatment on the temper embrittlement of SA508 Gr.4N steels, two model alloys with different phosphorus (P) contents were fabricated. Each sample was heat treated by applying a conventional heat treatment process (quenching-tempering) with/without an intercritical heat treatment process (IHT) and a step-cooling heat treatment for temper embrittlement. Then their microstructure and mechanical properties were evaluated. The microstructure of the SA508 Gr.4N model alloy was composed of tempered lower bainite and martensite, and nano-sized precipitates formed both inside and at boundaries. The grain size was reduced when IHT was applied. There was a small difference in tensile properties according to the heat-treatment conditions and P contents, but the difference in Charpy impact properties was large. The heat treatment for temper embrittlement (TE) increased the impact transition temperature, and a very significant increase was observed in steels with a high P content. The increase in transition temperature owing to TE was reduced when IHT was applied. The fractograph analysis of Charpy fractured specimens at transition temperatures showed that an increase in intergranular fracture was main reason for the TE, and that IHT reduced the formation of intergranular fracture. The AES results showed that P-Ni was segregated at grain boundaries, and the level of segregation was reduced by applying IHT. This occurred because the formation of prior austenite grain boundaries by IHT dispersed the P at grain boundaries, and reduced the amount of P segregation.

Microstructural Evolution of a Re-Containing 10% Cr-3Co-3W Steel during Creep at Elevated Temperature

Ten percent Cr steels are considered to be prospective materials for the production of pipes, tubes, and blades in coal-fired power plants, which are able to operate within ultra-supercritical steam parameters. The microstructural evolution of a Re-containing 10% Cr-3Co-3W steel with low N and high B content during creep was investigated at different strains at 923 K and under an applied stress of 120 MPa using TEM and EBSD analyses. The studied steel had been previously normalized at 1323 K and tempered at 1043 K for 3 h. In the initial state, the tempered martensite lath structure with high dislocation density was stabilized by M23C6 carbides, NbX carbonitrides, and M6C carbides. At the end of the primary creep stage, the main microstructural change was found to be the precipitation of the fine Laves phase particles along the boundaries of the prior austenite grains, packets, blocks, and martensitic laths. The remarkable microstructural degradation processes, such as the significant growth of martensitic laths, the reduction in dislocation density within the lath interiors, and the growth of the grain boundary Laves phase particles, occurred during the steady-state and tertiary creep stages. Moreover, during the steady-state creep stage, the precipitation of the V-rich phase was revealed. Softening was in accordance with the dramatic reduction in hardness during the transition from the primary creep stage to the steady-state creep stage. The reasons for the softening were considered to be due to the change in the strengthening mechanisms and the interactions of the grain boundary M23C6 carbides and Laves phase with the low-angle boundaries of the martensitic laths and free dislocations.

Acceleration of bainitic transformation in 0.28C-3.8Mn-1.5Si steel utilizing chemical heterogeneity

This study proposes a novel method for accelerating bainitic transformation by utilizing Mn heterogeneity. The process involves intercritical annealing to create a heterogeneous distribution of Mn prior to full austenitizing. Heterogeneous Mn distribution leads to the rapid nucleation of bainitic ferrite in the Mn-depleted austenite region, and the rapidly formed bainitic ferrite acts as a nucleation site for Mn-enriched austenite region. Consequently, the required austempering time to achieve a similar fraction of bainitic ferrite is nearly halved compared to conventional process. The effectiveness of Mn heterogeneity in accelerating the transformation is comparable to other acceleration methods, such as prior austenite grain refinement and introducing prior martensite. Moreover, the proposed method has an additional advantage in increasing the fraction of retained austenite. The retained austenite is stabilized not only by C partitioning during austempering but also by pre-partitioned Mn during intercritical annealing.

Mesoscale quantification of grain boundary character and local plasticity in hydrogen-assisted intergranular and intergranular-like cracking paths in tempered martensitic steel

The effects of the misorientation of prior austenite grain boundary (PAGB) segments on the local plasticity evolution in intergranular (IG) and IG-like fractures were investigated using a tempered martensitic steel. When a diffusible hydrogen content of 6.3 mass ppm was introduced, IG fractures with smooth fracture surfaces occurred in the elastic regime of the tensile test. According to the grain orientation spread (GOS) distribution, local plasticity did not contribute to the mesoscopic (block size) scale, irrespective of the PAGB segment misorientation. With a relatively low hydrogen content (4.0 mass ppm), an IG-like feature appeared on the fracture surface, which included plasticity-related traces such as tear ridges or nanovoids. The GOS values near the IG-like cracks were higher than those near the IG cracks and exhibited significant misorientation dependence. Specifically, at the low-angle PAGB segments, the GOS values of the grains neighboring the IG-like cracks increased with a decreasing misorientation. On the other hand, most of the cracked high-angle PAGB segments exhibited nearly constant GOS values. Remarkably, a Σ3 PAGB segment exhibited an abnormally high GOS value. These facts and corresponding microstructural observation results indicate that the low angle and Σ3 PAGB segments allow crack-tip blunting before crack growth.

Superior mechanical properties of M35 high-speed steel obtained by controlling carbide precipitation and distribution via electropulsing treatment

Carbide precipitation and distribution always significantly affect the mechanical properties of High-speed Steel (HSS). Thus, the effect of electropulsing treatment (EPT) on the microstructure and mechanical properties of M35 HSS was investigated in this paper. The results show that the electropulsing austenitising then quenched, followed by electropulsing tempered (EQ + ET) samples, showed a 2.3% increase in Rockwell hardness, a 9.7% increase in the bending strength, and the impact toughness increased by 10.3% compared with the conventional heat treatment (CQ + CT) samples. The superior mechanical properties were attributed to the reduction of retained austenite (RA), the uniform distribution of the carbide, and the refinement of the prior austenite grains. Under the action of the current, Ms increased in response to various combinations of alloying elements, thereby reducing the content of RA. Compared to conventional heat treatments, the electropulsing treatment provides additional Gibbs free energy, as well as a large number of dislocations generated by the thermo-compressive stresses, which increase the carbide nucleation sites, resulting in a large number of small-sized carbides precipitating and uniformly distributed in the matrix. The fracture morphology indicates that micro-cracks arise between the carbide and martensite, and the larger carbide provides a preferential path for crack initiation.

Dual grain size-effects on hydrogen-assisted fatigue crack growth in 1 GPa-class medium-carbon martensitic steel

The influence of prior austenite grain (PAG) size ranging from 6 to 90 μm on the fatigue crack growth (FCG) of a tempered 0.41%C lath martensitic steel was investigated in a 90 MPa H2 gas environment at ambient temperature. Under the presence of H, severe FCG accelerations accompanying intergranular (IG) cracking along PAG boundaries as well as quasi-cleavage (QC) fracture along martensite block boundaries and {011} crystallographic planes were systematically found. Smaller PAG mitigated the acceleration at a relatively high-stress intensity via suppressing IG cracking. However, PAG refinement instead escalated the acceleration at a low-stress intensity factor where QC facture prevailed. This inverse grain size effect was discussed in terms of the plasticity criterion in triggering QC and its possible dependence on the microstructural length scale.

Machine learning assisted materials design of high-speed railway wheel with better fatigue performance

To improve the fatigue fracture resistance of high-speed railway wheels, this paper studies the matching optimization design of microscopic crystal parameters of wheel materials based on machine learning methods. The microscopic crystal parameters of a pearlitic steel of high-speed railway wheel are collected, the relationship between microscopic crystal parameters and material properties of wheel material is studied. Based on machine learning methods including artificial neural network, random forest, support vector machine and K-nearest neighbor, the influence of the microscopic crystal parameters on the material properties of wheel steel is studied. The results show that the artificial neural network has a higher prediction accuracy, the microstructure parameters have a complex effect on fatigue performance of the wheel. When the prior austenite grain size of the structure is 55–65 μm, the pearlite colony size is 27–29 μm, and the pearlite interlamellar spacing is 95–105 nm, the fatigue resistance of the wheel steel is the best, and the fatigue strength is 528 MPa. The optimization result meets the requirements of high-speed railway wheel strength evaluation standard with a higher safetyfactor by finite element simulation.

Influence of boron segregation on the hot ductility of T23 steel CGHAZ

Boron segregates in a non-equilibrium segregation mode at lath, packet, block boundaries as well as prior austenite grain boundaries (PAGBs) in 2.25Cr1.6WVNb steel coarse grain heat-affected zone (CGHAZ) during the thermal cycle, and tends to segregate only at PAGBs in the same mode during the high-temperature tensile test. Boron segregation along PAGB increases GB plasticity but not inter-granular strength. This is because the boron segregation at PAGBs occupies the vacancies and other defect positions, which inhibits the nucleation and growth of micro-voids, and reduces plasticity consumption. As a result, the hot ductility of CGHAZ is enhanced.

Temperature dependence of hydrogen-assisted damage evolution and fracture behavior in TRIP-aided bainitic ferrite steel

We systematically investigated the effects of hydrogen and deformation temperature on the micro-damage evolution and fracture behavior of the TRIP-aided bainitic ferrite steel using slow strain rate tensile tests and microstructure examinations. For hydrogen-uncharged condition, the micro-damage evolution behavior was not dependent on temperature, except for −100 °C. The exceptional behavior at −100 °C was attributed to the occurrence of brittle fracture. Hydrogen uptake significantly increased the number density of micro-damage in all deformation temperatures. The fracture mode of hydrogen-charged specimens changed from quasi-cleavage and ductile fractures to cleavage, quasi-cleavage, and intergranular fractures with decreasing deformation temperature. Quasi-cleavage fracture features were attributed to the crack growth process consisting of repetition of small crack initiation/blunting (or void initiation) and crack coalescence, whereas the cleavage and intergranular surfaces with smooth facets were due to the occurrence of hydrogen-reduction cohesive strength of cleavage planes and prior austenite grain boundaries.