Printable Polymer Research Articles

3D‐Printable Polymer Filters for the Selective Complexation of Silver Ions

ABSTRACTThis study presents the fabrication of polymeric filters, which are able to selectively bind silver ions from aqueous solution. Those filters are fabricated within an easy approach via 3D‐digital light processing (DLP)‐printing enabling a tailor‐made design. In first order, an acrylamide containing a benzo‐trithiacrown‐ether (BTCE) functionality is synthesized. This monomer is further 3D‐printed via layer by layer photo‐polymerization together with commercially available comonomers, resulting in polymer networks containing the BTCE‐groups in their side chains as selective binding moiety for silver ions. Within isothermal‐titration calorimetry (ITC) measurements, the complexation abilities of the BTCE to bind the Ag+ ions are determined. Furthermore, the resulting 3D‐printed filters are investigated regarding their complexation behavior, in a detailed fashion applying inductively coupled plasma optical emission spectroscopy (ICP‐OES).

Influence of Recycling and UV Exposure on the Properties of 3D Printing Polymer Materials.

The use of polymer materials in various fields has increased significantly due to their ease of thermoforming and relatively low production costs. The production volume of these materials is extremely high, and according to forecasts from global statistical centers, it is expected to continue rising in the future. However, the extensive use and easy availability of polymeric materials have caused significant ecological problems. The world faces large amounts of polymer waste and environmental pollution. Plastic recycling remains challenging due to issues related to sorting polymer waste and separating it according to polymer types. Recycling certain plastics requires only a quarter of the energy needed to produce new plastic. To address this, circular economy principles should be applied to 3D printing products made from polymeric materials. A particularly wide application of these technologies is found when polymeric materials are used due to their low cost, low melting temperatures, and other advantageous properties. This paper investigates the impact of plastic recycling on the quality of 3D-printed products. During the research, samples were 3D printed and tested using both virgin and recycled PLA, ABS, and PET-G materials. The samples underwent static and dynamic tests to determine their mechanical properties, such as tensile strength, elongation, and impact resistance. The research results showed that the properties of recycled polymer materials deteriorate, with relative elongation of recycled and 3D-printed materials decreased by 16-45%. Despite this, recycled polymer materials can still be used, but it is necessary to account for the reduction in plasticity when creating products that will be exposed to dynamic loads. The impact strength is reduced by 6% for PLA, 54% for ABS, and 58% for PET-G. Additionally, the research included tests on samples printed with 3D printing technology that were exposed to UV irradiation. The results indicated similar dependences, as UV exposure also affects the reduction of material plasticity. After 66 Wh/m2 of UV radiation, the tensile strength of PET-G and PLA decreased by 17%, while ABS showed a reduction of about 5%.

3D Printable Polymer Electrolytes for Ionic Conduction based on Protic Ionic Liquids.

A range of protic ionic liquids (PILs) based on tri-n-alkylammonium cations and mesylate/triflate anions were incorporated into a polymer matrix to form ionogels (IGs). These systems were investigated for their thermal and electrochemical behaviour, as well as under the aspect of ion motion via PFG-NMR. The ionic conductivities of the ILs/IGs are in the range of 10‑4-10-3Scm-1 at elevated temperatures and the diffusion coefficients were around 10‑11m2s-1. Successful 3D printing of an IG with 70wt% of IL is possible via stereolithography approaches, opening up applications in, e.g., structured ion-conductive membranes.

Impact of Porosity and Stiffness of 3D Printed Polycaprolactone Scaffolds on Osteogenic Differentiation of Human Mesenchymal Stromal Cells and Activation of Dendritic Cells.

Despite the potential of extrusion-based printing of thermoplastic polymers in bone tissue engineering, the inherent nonporous stiff nature of the printed filaments may elicit immune responses that influence bone regeneration. In this study, bone scaffolds made of polycaprolactone (PCL) filaments with different internal microporosity and stiffness was 3D-printed. It was achieved by combining three fabrication techniques, salt leaching and 3D printing at either low or high temperatures (LT/HT) with or without nonsolvent induced phase separation (NIPS). Printing PCL at HT resulted in stiff scaffolds (modulus of elasticity (E): 403 ± 19 MPa and strain: 6.6 ± 0.1%), while NIPS-based printing at LT produced less stiff and highly flexible scaffolds (E: 53 ± 10 MPa and strain: 435 ± 105%). Moreover, the introduction of porosity by salt leaching in the printed filaments significantly changed the mechanical properties and degradation rate of the scaffolds. Furthermore, this study aimed to show how these variations influence proliferation and osteogenic differentiation of human bone marrow-derived mesenchymal stromal cells (hBMSC) and the maturation and activation of human monocyte-derived dendritic cells (Mo-DC). The cytocompatibility of the printed scaffolds was confirmed by live-dead imaging, metabolic activity measurement, and the continuous proliferation of hBMSC over 14 days. While all scaffolds facilitated the expression of osteogenic markers (RUNX2 and Collagen I) from hBMSC as detected through immunofluorescence staining, the variation in porosity and stiffness notably influenced the early and late mineralization. Furthermore, the flexible LT scaffolds, with porosity induced by NIPS and salt leaching, stimulated Mo-DC to adopt a pro-inflammatory phenotype marked by a significant increase in the expression of IL1B and TNF genes, alongside decreased expression of anti-inflammatory markers, IL10 and TGF1B. Altogether, the results of the current study demonstrate the importance of tailoring porosity and stiffness of PCL scaffolds to direct their biological performance toward a more immune-mediated bone healing process.

3D printing of aligned silk fibroin microfibers covered with nitrogen-doped carbon dots for anti-counterfeiting

Counterfeiting has serious economic and social consequences, prompting researchers worldwide to develop innovative and highly secure anti-counterfeiting methods, including the use of various polymer printing techniques and the integration of functional materials to create patterns with customized designs that are easy to detect and cannot be falsified. Composite inks made of silk fibroin microfibers and polyvinyl alcohol or polyethylene glycol were developed to produce patterns with the microstructures aligned in the direction of extrusion during the 3D printing process. Fibroin microfibers were obtained via high temperature treatment and used as a precursor for carbon dot synthesis. This approach allowed the microfiber structure to be maintained and be amenable to the synthesis of carbon dots doped with N-heteroatom on its surface, resulting in a material that fluoresces bright blue when irradiated at 365 nm but remains invisible in normal lighting conditions.

Energy-efficient FDM printing of sustainable polymers: Optimization strategies for material and process performance

The integration of sustainable polymers in fused deposition modeling (FDM) 3D printing offers a promising pathway toward reducing the environmental impact of additive manufacturing. However, the energy-intensive nature of FDM processes presents a significant challenge to the overall sustainability of this technology. In this study, we explore the use of bio-based and recycled polymers in FDM printing and develop optimization strategies to reduce energy consumption without compromising material and print performance. Our results demonstrate that by systematically optimizing key printing parameters such as extrusion temperature, print speed, and layer height it is possible to achieve up to 20% energy savings. Additionally, we find that novel material formulations and advanced thermal management techniques enhance the mechanical properties of printed objects by up to 15%, all while minimizing energy use. This research not only advances the field of sustainable 3D printing but also provides a framework for the development of next-generation materials and processes that align with the principles of a circular economy.

Surface‐Functionalization of Oleate‐Capped Nano‐Emitters for Stable Dispersion in 3D‐Printable Polymers

AbstractTwo‐photon polymerization 3D‐printing is a well‐known technique for fabricating passive micro/nanoscale structures, such as microlenses and inversely designed polarization splitters. The integration of light emitting nanoparticle (NP) dopants, such as quantum dots (QDs) and rare‐earth doped nanoparticles (RENPs), into a polymer resist would enable 3D printing of active polymer micro‐photonic devices, including sensors, lasers, and solid‐state displays. Many NPs contain oleic acid ligands to prevent degradation, but oleate‐capped NPs (oc‐NPs) tend to agglomerate in nonpolar media despite the hydrophobicity of the ligand. This results in an uneven nanoparticle distribution and increased optical extinction. In this work, a general approach is proposed for dispersing oc‐NPs in commercial 3D printable polymers. Controlled growth of small carbon chains around the oc‐NPs is achieved by functionalizing them with methyl‐methacrylate monomers. The proposed approach is validated on RENPs (≈65 nm) and CdSe/ZnS quantum dots (≈12 nm) using commercial polymer resists (IP‐Dip and IP‐Visio). Dispersions of functionalized NPs (f‐NPs) have improved the NP density by an order of magnitude and are shown to be stable for several weeks with minimal impact on printing quality. The approach is generalizable to other oc‐NPs, enabling synthesis of functional resins for high‐quality polymer‐based optical and electronic devices.

3D printed polymers for transseptal puncture simulation

PurposeThis study aims to examine the efficacy of 3D printing polymers to realistically mimic the fossa ovalis (FO) – a cardiac structure that is positioned in the interatrial septum – for simulating transseptal puncture (TP) procedures.Design/methodology/approachSpecimen of different materials and thicknesses were prepared and tested simulating the puncturing of the FO using a 12F ID/14F OD TP catheter. Force and tenting length results were compared with literature references. Scanning electron microscope images of the specimen were acquired to observe the perforated region as well as the structure of the specimen in the unaffected area.FindingsSignificant changes in the properties of interest were registered for the same material on specimens tested at different moments after fabrication. Suturable vessel wall polyjet material offers the best characteristics to replicate FO anatomy and mimic its behavior to puncturing.Originality/valueThe originality of the work lies in the test of different commercial materials. Similar works are already present in literature but specifically designed materials are used. Demonstrating that off-the-shelf materials could be viable for FO specimens would simplify the design of realistic TP simulators in the future.

The Influence of Thickness and Spectral Properties of Green Color-Emitting Polymer Thin Films on Their Implementation in Wearable PLED Applications.

A systematic investigation of optical, electrochemical, photophysical, and electrooptical properties of printable green color-emitting polymer (poly(9,9-dioctylfluorene-alt-bithiophene)) (F8T2) and spiro-copolymer (SPG-01T) was conducted to explore their potentiality as an emissive layer for wearable polymer light-emitting diode (PLED) applications. We compared the two photoactive polymers in terms of their spectral characteristics and color purity, as these are the most critical factors for wearable lighting sources and optical sensors. Low-cost, solution-based methods and facile architecture were applied to produce rigid and flexible light-emitting devices with high luminance efficiencies. Emission bandwidths, color coordinates, operational characteristics, and luminance were also derived to evaluate the device's stability. The tuning of emission's spectral features by layer thickness variation was realized and was correlated with the interplay between H-aggregates and J-aggregates formations for both conjugated polymers. Finally, we applied the functional green light-emitting PLED devices based on the two studied materials for the detection of Rhodamine 6G. It was determined that the optical detection of the R6G photoluminescence is heavily influenced by the emission spectrum characteristics of the PLED and changes in the thickness of the active layer.

Fabrication of GelMA - Agarose Based 3D Bioprinted Photocurable Hydrogel with In Vitro Cytocompatibility and Cells Mirroring Natural Keratocytes for Corneal Stromal Regeneration.

The complex anatomy of the cornea and the subsequent keratocyte-fibroblast transition have always made corneal stromal regeneration difficult. Recently, 3D printing has received considerable attentionin terms of fabrication of scaffoldswith precise dimension and pattern. In the current work, 3D printable polymer hydrogels made of GelMA/agarose are formulated and its rheological properties are evaluated. Despite the variation in agarose content, both the hydrogels exhibited G'>G'' modulus. A prototype for 3D stromal model is created using Solid Works software, mimicking the anatomy of an adult cornea. The fabrication of 3D-printed hydrogels is performed using pneumatic extrusion. The FTIR analysis speculated that the hydrogel is well crosslinked and established strong hydrogen bonding with each other, thus contributing to improved thermal and structural stability. The MTT analysis revealed a higher rate of cell proliferation on the hydrogels. The optical analysis carried out on the 14th day of incubation revealed that the hydrogels exhibit transparency matching with natural corneal stromal tissue. Specific protein marker expression confirmed the keratocyte phenotype and showed that the cells do not undergo terminal differentiation into stromal fibroblasts. The findings of this work point to the potential of GelMA/A hydrogels as a novel biomaterial for corneal stromal tissue engineering.

4D Printing Hybrid Soft Robots Enabled by Shape-Transformable Liquid Metal Nanoparticles.

In recent years, soft robotics has emerged as a rapidly expanding frontier research field that draws inspiration from the locomotion mechanisms of soft-bodied creatures in nature to achieve smooth and complex motion for diverse applications. However, the fabrication of soft robots with hybrid structures remains challenging due to limitations in material selection and the complex, multi-step processes involved in traditional manufacturing methods. Herein, a novel direct one-step additive manufacturing (3D printing) approach is introduced for the fabrication of hybrid robots composed of soft and rigid components for sophisticated tasks. Inspired by the shape-transformable liquid metal nanoparticles (LMNPs), a functional material toolkit with tuneable mechanical properties and deformability is developed by integrating differently shaped gallium-based nanoparticles (GNPs) into the 3D printing polymers. Then the direct printing of assembled or one-piece hybrid soft-rigid robots is presented through a single recipe of GNPs-integrated inks. This fabrication method enables precise control of the mechanical properties and shape memory properties within the hybrid structures of robot body with a customized structure design. Their capabilities are further demonstrated through the design and fabrication of hybrid robots as high-precision gripper, bioinspired motor, and hand rehabilitation device.

Iterative printing of bulk metal and polymer for additive manufacturing of multi-layer electronic circuits

In pursuing advancing additive manufacturing (AM) techniques for 3D objects, this study combines AM techniques for bulk metal and polymer on a single platform for one-stop printing of multilayer 3D electronic circuits with two novel aspects. The first innovation involves the embedded integration of electronic circuits by printing low-resistance electrical traces from bulk metal into polymer channels. Cross-section grinding results reveal (92 ± 5)% occupancy of electrically conductive traces in polymer channels despite the different thermal properties of the two materials. The second aspect encompasses the possibility of printing vertical bulk metal vias up to 10 mm in height with the potential for expansion, interconnecting electrically conductive traces embedded in different layers of the 3D object. The work provides comprehensive 3D printing design guidelines for successfully integrating fully embedded electrically conductive traces and the interconnecting vertical bulk metal vias. A smooth and continuous workflow is also introduced, enabling a single-run print of functional multilayer embedded 3D electronics. The design rules and the workflow facilitate the iterative printing of two distinct materials, each defined by unique printing temperatures and techniques. Observations indicate that conductive traces using molten metal microdroplets show a 12-fold reduction in resistance compared to nanoparticle ink-based methods, meaning this technique greatly complements multi-material additive manufacturing (MM-AM). The work presents insights into the behavior of molten metal microdroplets on a polymer substrate when printed through the MM-AM process. It explores their characteristics in two scenarios: When they are deposited side-by-side to form conductive traces and when they are deposited out-of-plane to create vertical bulk metal vias. The innovative application of MM-AM to produce multilayer embedded 3D electronics with bulk metal and polymer demonstrates significant potential for realizing the fabrication of free-form 3D electronics.

Elevating mechanical performance of cementitious composites with surface-modified 3D-Printed polymeric reinforcements

3D printed polymeric reinforcement has been found able to improve the ductility of cementitious materials. However, due to the hydrophobic nature of commonly used 3D printing polymers, the bonding strength between the 3D printed polymers and cementitious matrix is extremely weak, which potentially hinders the mechanical performance of the reinforced composites. This work aims to improve the bonding properties by applying surface modifications on the 3D printed reinforcement, and eventually enhance the mechanical performance of the reinforced cementitious composites. Three types of surface coatings ingredients: epoxy resin (EP), sand sprinkled epoxy (SA) and short steel fibers sprinkled epoxy (SF) were used. Pull-out experiments are performed to study the bonding properties of the 3D printed reinforcement with different coatings. Then, uniaxial tensile and four-point-bending experiments are used to investigate the mechanical performance of the reinforced cementitious composites. A lattice type numerical model is applied to simulate the pull-out and tensile tests. The pull-out experiments indicate that the SA and SF reinforcement achieved approximately two times higher bonding strength than the uncoated and EP reinforcement. The tensile and flexural results suggest that the cementitious composites with SA and SF reinforcement achieved significantly better ductility (manifested by strain-hardening and deflection-hardening behavior) than the composites with uncoated and EP reinforcement. The numerical simulation results highly agree with the experimental findings, and further confirmed that the improved reinforcement-mortar bonding strength is the determinative factor that enhanced the composites mechanical performance. The findings of this work suggest that the sand and steel fiber surface coatings can effectively enhance the ductility of cementitious composites reinforced by 3D printed polymers.

Printed polymer platform empowering machine-assisted chemical synthesis in stacked droplets

Efficiently exploring organic molecules through multi-step processes demands a transition from conventional laboratory synthesis to automated systems. Existing platforms for machine-assistant synthetic workflows compatible with multiple liquid-phases require substantial engineering investments for setup, thereby hindering quick customization and throughput increasement. Here we present a droplet-based chip that facilitates the self-organization of various liquid phases into stacked layers for conducting chemical transformations. The chip’s precision polymer printing capability, enabled by digital micromirror device (DMD)-maskless photolithography and dual post-chemical modifications, allows it to create customized, sub-10 µm featured patterns to confine diverse liquids, regardless of density, within each droplet. The robustness and open design of surface-templated liquid layers actualize machine-assistant droplet manipulation, synchronous reaction triggering, local oscillation, and real-time monitoring of individual layers into a reality. We propose that, with further integration of machine operation line and self-learning, this droplet-based platform holds the potential to become a valuable addition to the toolkit of chemistry process, operating autonomously and with high-throughput.

Volume-Metallization 3D-Printed Polymer Composites.

3D printing polymer or metal can achieve complicated structures while lacking multifunctional performance. Combined printing of polymer and metal is desirable and challenging due to their insurmountable mismatch in melting-point temperatures. Here, a novel volume-metallization 3D-printed polymer composite (VMPC) with bicontinuous phases for enabling coupled structure and function, which are prepared by infilling low-melting-point metal (LM) to controllable porous configuration is reported. Based on vacuum-assisted low-pressure conditions, LM is guided by atmospheric pressure action and overcomes surface tension to spread along the printed polymer pore channel, enabling the complete filling saturation of porous structures for enhanced tensile strength (up to 35.41MPa), thermal (up to 25.29Wm-1K-1) and electrical (>106Sm-1) conductivities. The designed 3D-printed microstructure-oriented can achieve synergistic anisotropy in mechanics (1.67), thermal (27.2), and electrical (>1012) conductivities. VMPC multifunction is demonstrated, including customized 3D electronics with elevated strength, electromagnetic wave-guided transport and signal amplification, heat dissipation device for chip temperature control, and storage components for thermoelectric generator energy conversion with light-heat-electricity.

Manufacturing fused silica hemispherical resonators using polymer glass suspension and replication molding

This work introduces a new method for manufacturing fused silica (FS)-based hemispherical resonators (HSRs) using a printable polymer glass mixture and replication molding. This process involves 3D printing to create the mold, followed by the casting of a photo-reactive pre-polymer glass mixture. This technique allows us to produce complex 3D geometries and offers faster production of resonators compared to other traditional methods. In this study, we manufactured three devices and successfully identified resonance modes with two (N = 2), three (N = 3) and four (N = 4) nodes/antinodes in all three HSRs, demonstrating the repeatability of our new manufacturing method. The highest quality factor of 482 k was achieved for the N = 3 resonance mode using the ring-down method. Some of the key advantages of our method include producing multiple devices efficiently with relatively good surface quality, making it a viable option for producing high-precision devices in the future. Our new fabrication technique results in a device surface roughness of ∼100 nm (measured over an area of 250 μm × 250 μm) and manufacturing yield of over 90%. Moreover, all the steps involved in this method can be completed outside of a specialized cleanroom environment.

Fabricating Multiphasic Angiogenic Scaffolds Using Amyloid/Roxadustat-Assisted High-Temperature Protein Printing.

Repairing multiphasic defects is cumbersome. This study presents new soft and hard scaffold designs aimed at facilitating the regeneration of multiphasic defects by enhancing angiogenesis and improving cell attachment. Here, the nonimmunogenic, nontoxic, and cost-effective human serum albumin (HSA) fibril (HSA-F) was used to fabricate thermostable (up to 90 °C) and hard printable polymers. Additionally, using a 10.0 mg/mL HSA-F, an innovative hydrogel was synthesized in a mixture with 2.0% chitosan-conjugated arginine, which can gel in a cell-friendly and pH physiological environment (pH 7.4). The presence of HSA-F in both hard and soft scaffolds led to an increase in significant attachment of the scaffolds to the human periodontal ligament fibroblast (PDLF), human umbilical vein endothelial cell (HUVEC), and human osteoblast. Further studies showed that migration (up to 157%), proliferation (up to 400%), and metabolism (up to 210%) of these cells have also improved in the direction of tissue repair. By examining different in vitro and ex ovo experiments, we observed that the final multiphasic scaffold can increase blood vessel density in the process of per-vascularization as well as angiogenesis. By providing a coculture environment including PDLF and HUVEC, important cross-talk between these two cells prevails in the presence of roxadustat drug, a proangiogenic in this study. In vitro and ex ovo results demonstrated significant enhancements in the angiogenic response and cell attachment, indicating the effectiveness of the proposed design. This approach holds promise for the regeneration of complex tissue defects by providing a conducive environment for vascularization and cellular integration, thus promoting tissue healing.

Electroplating Additively Manufactured Honeycomb Structures to Increase Energy Absorption Under Quasi-Static Crush

Honeycomb (HC) has been used in energy absorption applications due to its high stiffness and low density. Metallic HC are used for energy absorption applications, however, these metallic structures can be challenging to manufacture if complex geometric features designed to improve energy absorption are used, which motivates the use of additive manufacturing (AM). Metal AM methods include powder bed fusion (PBF) and direct energy deposition (DED). In addition to capital equipment cost, these processes possess challenges that include a required inert environment, powder handling, final part porosity, residual stresses, and nonuniform surface finish. These concerns can be alleviated through the use of polymer AM, however, polymeric parts exhibit brittle failure and have a lower stiffness than metallic HC structures. In this study, a low-cost 3D polymer printing method, stereolithography (SLA), is combined with a conventional electroplating process to fabricate a metal-plastic composite HC structure with energy absorption capability much greater than of a plastic HC structures of the same nominal volume. SLA parts have a smooth surface, so that the surface finish is at least as uniform after electroplating as the SLA part. The energy absorption characteristics of the electroplated HC is studied to determine how these energy absorbing materials can be manufactured at reduced cost. Our study confirms that the metal-plastic composite HC increases both the crush strain range and the mean crush stress of these samples, resulting in metal-plastic composite HC structures with substantially increased energy absorption. This study also examines how buckling initiators (BIs), or diamond shaped holes located at 50, 75, and 100% of the height of the hexagonal cell vertices, can influence energy absorption performance. This study shows that it is feasible to fabricate electroplated HCs, using an SLA preform, to achieve a substantial increase in energy absorption over using SLA alone.

Photoinduced double hydrogen-atom transfer for polymerization and 3D printing of conductive polymer

Photoinduced double hydrogen-atom transfer for polymerization and 3D printing of conductive polymer

Effect of thickness on the translucency of machinable and printable ceramic-glass polymer materials

ObjectivesTo assess the translucency of machinable and printable ceramic-glass polymer materials with different thicknesses. MethodsFive ceramic-glass polymer materials were tested: one 3D-printable material, Permanent Crown resin (3D), two machinable materials available at low translucency (LT) and high translucency (HT) levels, VITA Enamic (VE) HT/LT, and Cerasmart 270 (CS) HT/LT. A total of 100 specimens were produced across 10 subgroups (n = 10) with thicknesses of 1 mm and 1.5 mm. The colour coordinates of the specimens were measured against black and white backgrounds using a spectrophotometer. Translucency was quantified using the Relative Translucency Parameter (RTP), calculated via the CIEDE2000 formula. A two-way ANOVA followed by post-hoc tests with Bonferroni correction (α = 0.05) was used for statistical analysis. ResultsThe RTP for both thicknesses were ranked as follows: CSHT > VEHT > CSLT > 3D > VELT. The RTP of the 3D was lower than that of the HT machinable materials (CSHT and VEHT) for both thicknesses (p < 0.05). No significant difference was observed between the RTP of 3D and CSLT at 1.5 mm (p = 1.000); however, at 1 mm, the RTP of the 3D was lower than that of the CSLT (p < 0.05). Notably, the 3D showed the least translucency difference with a 0.5 mm increase in thickness. ConclusionsPrintable ceramic-glass polymer materials demonstrated lower translucency than HT machinable ceramic-glass polymer materials. Both the thickness and type significantly influenced the translucency of the LT machinable counterparts compared to the printable ceramic-glass polymer material. Clinical significancePrintable ceramic-glass polymer resins may be a suitable option for minimally invasive procedures, especially when attempting to mask undesirable-coloured abutments. When selecting HT machinable ceramic-glass polymers, clinicians should pay greater attention to the abutment colour and thickness of the restorative material.