This paper deals with the experimental research and verification of a passive cooling system operating on the principle of a loop gravity heat pipe designed for cooling electrical cabinets. This type of cooling works automatically by changing the state of the working substance and thus saves energy consumption. Since the designed cooling system ensures heat transfer from the interior cabinet to the outdoor space, where the heat can naturally dissipate to the surroundings, it is dustproof. The heat pipe consists of an innovative evaporator concept designed to minimize liquid and vapour phase interference in the refrigeration circuit. The aim of the research was to experimentally determine the limit performance parameters of the refrigeration system for different volumes of working medium in the evaporator and decrease heat loss in the cabinet interior. The designed device was verified experimentally and by mathematical calculations as well. The greatest benefit of the work is that the cooling device was able to ensure temperature conditions inside the electrical enclosure at a heat load of 2000 W under 60 °C, 1500 W under 55 °C, 1000 W under 50 °C, 750 W under 45 °C and 500 W under 40 °C.