Hydrothermal carbonization (HTC) of untreated sewage sludge with high water content was evaluated as an alternative to usual wastewater treatment. This bold approach allowed bioproducts useful as biofuel and nutrient sources to be obtained directly from raw sludge. HTC experiments were performed in a scalable arrangement (technology readiness level >4) composed of a 10-liter high-pressure reactor. The influence of the experimental conditions, including temperature (180-220°C), reaction time (60-120min), and pH (6.5-12.0), was evaluated on nutrients and heavy metal distribution through the liquid phase by a 23 central composite design with a triple central point. The bioproducts were characterized by a set of six analytical techniques, and the results were refined by statistical procedures (Principal Component Analysis and Response Surface Methodology). pH is a variable that impacts bioproducts’ characteristics, making it a guiding factor for application. Basic pH promotes transfer of components from solid to liquid phase, while natural pH favors the heating value of hydrochars. Liquid phase is a carbon- and nitrogen-rich source that can be useful for plant nutrition, mainly due to the increase of ammonia nitrogen from 20.6 to 51.7wt.% under pH 6.5, and an expressive decrease of chemical oxygen demand from 32 to 6-16 mgO2L-1. The hydrochar can be considered a renewable solid fuel, reaching up to 12.43 MJ kg-1 under pH 6.5; the basic pH favored an increase in the O/C ratio and lower HHV values. HTC of primary sewage sludge can replace steps of a conventional treatment station and promotes treated wastewater reuse.
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