Primitive Mantle-normalized Trace Element Diagrams Research Articles

Apatite and pyroxene as records of magmatic–hydrothermal processes and platinum-group mineral (PGM) formation in the Wengeqi mafic–ultramafic intrusion, Inner Mongolia, China: The role of oxidized, H2O-rich magmas

The Devonian Wengeqi mafic–ultramafic intrusion, situated on the northern margin of the North China Craton (NCC) — an Andean-style convergent margin during the Paleozoic — hosts many platinum-group minerals (PGMs), especially within the S-deficient, magnetite-rich clinopyroxenite zones. These PGMs occur in two distinct associations: Pt-rich PGMs (e.g., sperrylite) closely associated with primary magnetite and Pd-rich PGMs (e.g., sudburyite, kotuskite, arsenopalladinite) associated with secondary minerals (e.g., actinolite, pyrite). The mechanisms underlying the formation of PGMs in S-deficient rocks and the spatial decoupling of various PGM types remain elusive. The relationship of PGM formation and characteristics of magmas at convergent margins is also not well understood. In this contribution, we utilized apatite and clinopyroxene textures and chemistry alongside whole-rock SrNd isotopes to characterize i) the nature of the parental magma from which the Wengeqi intrusion crystallized, and ii) the magmatic–hydrothermal processes that operated to generate the Pt- and Pd-rich PGM. Based on the composition of clinopyroxene and clinopyroxene–melt partition coefficients, the parental magma of the Wengeqi intrusion is estimated to have an arc-like affinity on a primitive mantle-normalized trace-element diagram. This, together with the EMI-like SrNd isotope signature, implies that the Wengeqi magma was sourced from metasomatized SCLM beneath the NCC with an EMI-like composition. Three types of apatite (Ap1, Ap2, and Ap3) were identified within the intrusion. Ap1 and Ap2 are magmatic in origin, and appear as isolated grains, whereas Ap3 occurs as stringers or heterogeneous domains within Ap1 and Ap2, and likely resulted from hydrothermal modification of magmatic apatite. Notably, the abundant Ap2 exhibits higher VS contents and Eu/Eu* ratios than the less common Ap1, and contains S predominantly in the form of S6+, suggesting that the Wengeqi magma was relatively oxidized, with fO2 > FMQ + 1.2. Based on the chemistry of magmatic apatite, the Wengeqi magma had ∼5 wt% H2O, which, together with its high fO2, facilitated crystallization of magnetite, causing reduction of the magma by removal of Fe3+. This reduction process promoted PGM nucleation by decreasing PGE solubility in the magma, leading to the association of PGM with magnetite. Additionally, the oxidized, H2O-rich magma likely released oxidizing fluids, selectively mobilizing Pd rather than Pt, separating Pt-rich PGMs from Pd-rich PGMs. The budget of PGE in the parental magma could have been increased by i) metasomatism of the SCLM source (e.g., by carbonatitic fluids), which would have elevated the concentration of PGE in the mantle source, and ii) the high fO2 and H2O levels of the magma, which would have delayed sulfide saturation. Accordingly, mantle metasomatism and high fO2–H2O are deemed favorable for enrichment of PGE in magmas within convergent margins.

Picture Gorge Basalt: Internal stratigraphy, eruptive patterns, and its importance for understanding Columbia River Basalt Group magmatism

AbstractThe Picture Gorge Basalt (PGB) of the Columbia River Basalt Group (CRBG) has been previously thought to be limited in its eruptive volume (<3000 km3) and thought to not extend far from its type locality. At present, PGB represents only 1.1 vol% of the CRBG with a relatively limited spatial distribution of ~10,000 km2. New age data illustrate that the PGB is the earliest and longest eruptive unit compared to other main-phase CRBG formations and that some dated basaltic flows reach far (~100 km) beyond the previously mapped extent. This study focuses on extensive outcrops of basaltic lavas and dikes south of the type locality at Picture Gorge, in order to reassess the spatial distribution and eruptive volume of the PGB. Field observations coupled with geochemical data indicate that PGB lava flows and mafic dikes covered a significantly greater area than shown on the published geologic maps. We find that additional mafic dikes located farther south of the original mapped distribution have geochemical compositions and northwest-trending orientations comparable to the dikes of the Monument dike swarm. We also identify new lava flows that can be correlated where stratigraphic control is well defined toward the original mapped PGB distribution. Our analyses and correlations are facilitated by comparison of 20 major- and trace-element abundances via a principal component analysis. This statistical comparison provides a new detailed distribution of PGB with stratigraphic significance that more than doubles the total distribution of PGB lavas and dikes and brings the eruptive volume to a new minimum of at least ~4200 km3. Geochemically correlated basaltic lavas and dikes in the extended distribution of PGB represent the earlier and later sections of the internal PGB stratigraphy. This is an intriguing observation as new geochronological data suggest an eruptive hiatus of ~400 k.y. during PGB volcanic activity, which occurred from 17.23 Ma to 15.76 Ma.The geochemical identifiers used to differentiate PGB from other main-phase CRBG formations include lower TiO2 (<2 wt%) concentrations, lower incompatible trace-element (i.e., La, Th, and Y) abundances, and a more pronounced enrichment in large- ion- lithophile elements (LILEs) on a primitive mantle–normalized trace-element diagram (Sun and McDonough, 1989). Geochemical characteristics of PGB are interpreted to represent a magmatic source component distinct from the other main-phase CRBG units, possibly a localized backarc-sourced mantle melt. However, this source cannot be spatially restricted as there are observed PGB lava flows and dikes extending as far east as Lake Owyhee and as far south as Hart Mountain, covering at least 15,000 km2. In context with the existing stratigraphy and the new extent of PGB lavas and dikes, these ages and coupled geochemical signatures demonstrate this mantle component was not spatially localized but rather tapped across a wide region.

Pressure-temperature evolution of the Qingshuiquan mafic granulite: Implications for Proto-Tethys subduction in the East Kunlun orogenic belt, northern Tibetan Plateau

AbstractGranulite is in general a key metamorphic rock that can be used to understand the tectonic architecture and evolutionary history of an orogenic belt. The Qingshuiquan mafic granulite in the East Kunlun orogenic belt, northern Tibetan Plateau, occurs as tectonic boudins together with lower-grade ophiolitic mélange assemblages within an amphibolite-facies crystalline basement. In this study, we investigated the geochemistry, geochronology, mineralogy, and phase modeling of the Qingshuiquan mafic granulite. Based on mineralogical observations and microstructures, three mineral assemblage generations were distinguished: an assemblage found as inclusions within garnet and amphibole comprising clinopyroxene + plagioclase + amphibole + quartz + ilmenite + rutile (M1); an inferred peak assemblage of garnet + clinopyroxene + plagioclase + amphibole + quartz + ilmenite ± orthopyroxene (M2) in the matrix; and a retrograde assemblage of amphibole and biotite coronae (M3) around clinopyroxene or orthopyroxene. Thermobarometric calculations and phase equilibrium modeling constrained a clockwise pressure-temperature (P-T) path for the Qingshuiquan mafic granulite with peak T conditions of 830–860 °C at 8.0–9.5 kbar. Prior to the peak T conditions, a pressure maximum of ~11 kbar at ~800 °C was recorded by rutile, ilmenite, and clinopyroxene inclusions in garnet and amphibole. The retrograde path was defined by a decompression segment followed by final cooling. The whole-rock geochemical results indicated that the protolith of the Qingshuiquan mafic granulite was similar to present-day enriched mid-ocean-ridge basalt (E-MORB) displaying low total rare earth element (REE) concentrations and a slight enrichment of light REEs, as well as flat high field strength element patterns in the primitive mantle–normalized trace-element diagram. Geochronologic results revealed that the protolith crystallization age of the mafic granulite is 507 ± 3 Ma, and the timing of granulite-facies metamorphic overprint is 457–455 Ma. This evidence, taken together with results from previous studies, indicates that the protolith of the Qingshuiquan mafic granulite can be interpreted as basaltic rocks of Proto-Tethys oceanic crust that experienced a first high-pressure granulite-facies imprint followed by subsequent decompression and granulite-facies overprint at slightly lower P and slightly higher T. This granulitefacies metamorphism can be attributed to the subduction of Proto-Tethys oceanic crust, which also generated numerous contemporaneous subduction-related magmatic rocks in the East Kunlun orogenic belt.

Petrogenesis, tectonic setting and geodynamic implications of Ouaden, Doumba Bello, and Ngoura granitic plutons (Eastern Cameroon): Constraints from elemental and Sr−Nd−Hf isotopic data and zircon U−Pb ages

The Ouaden, Doumba Bello, and Ngoura granitic plutons, eastern Cameroon, comprise segments of the Central African Fold Belt (CAFB) situated along the northern edge of the Congo craton. A geochemical, isotopic and geochronological study was carried out on these three plutons to determine their petrogenesis and tectonic environment of formation. Granodiorites and granites (SiO2 of 65–73 wt%, Mg# of 14–46) of these plutons are potassic and weakly peraluminous with A/CNK ratios of 0.99–1.10. On primitive-mantle normalized trace element diagrams, all intrusives are depleted in Nb, Ta, and Ti. LA-ICP-MS zircon U − Pb dating indicate that the Ouaden, Doumba Bello and Ngoura granitic plutons were emplaced coevally at 640 ± 3 Ma, 641 ± 3 Ma, and 638 ± 4 Ma, respectively. The granodiorites and granites have variable 87Sr/86Sr(i) ratios of 0.71117–0.71831, relatively unradiogenic whole-rock εNd(t) values of −9.6 to −6.3, and zircon εHf(t) values ranging from −10.1 to −2.1; the occurrence of mafic microgranular enclaves suggests mixing with mantle-derived magmas, and such mixing possibly resulted in the scattering of zircon Hf data. Two-stage Nd-Hf model ages of 2115–1856 Ma and 2218–1708 Ma, and ΔFMQ of +5.3 − +2.1 indicate that the studied granitoids were derived from partial melting of Paleoproterozoic crust under variable oxidizing conditions. All granitoids yield inherited zircon ages (736–685 Ma), indicating contamination of Early Neoproterozoic crust during ascent. A combined examination of the geological record, bulk rock chemistry and isotope signatures suggests that the granodiorites and granites formed by mixing of mantle-and crust-derived melts during a late-subduction early-collision setting between the Metacraton and the Congo craton.

Tectonic settings of formation of volcanic and sedimentary rocks of the Itmurundy zone, central Kazakhstan

The paper presents new petrographic and geochemical data from volcanic and sedimentary rocks and first U-Pb ages of detrital zircons from sandstones of the Itmurundy zone of central Kazakhstan. The volcanic rocks are aphyric and porphyric basalts, andesibasalt and andesite. The major element composition of tuff and sandstone are close to that of andesite. The poorly sorted greenish grey sandstones carry numerous fragments of volcanic and sedimentary rocks suggesting its greywacke nature which is probably due to. The greywacke probably formed by the destruction of undissected arc. The distribution of U-Pb ages of detrital zircons spanning 505 to 432 Ma has unimodal character peaked at 445 Ma suggesting formation of the sandstones by the destruction and subsequent transportation of clastic material from a late Ordovician intra-oceanic arc. In geochemical diagrams, the tuffs and sandstone plot close to the volcanic rocks. All chondrite-normalized REE spectra show enrichment in LREE (LaN=38–367, La/YbN=4.0–16.9, La/SmN=2.1–3.3) and moderate to weakly differentiated HREE (Gd/YbN=1.4–4.0). However, the level of REE concentrations in the volcanic rocks, in particular, in basalts, is significantly higher than that in the sandstone and andesite. The primitive mantle normalized trace-element diagrams show peaks at Nb (Nb/Lapm=0.9–1.6, Nb/Thpm=0.8–1.6) in most basaltoids, but troughs at Nb for andesite, tuff and sandstone (Nb/Lapm=0.25–0.31, Nb/Thpm=0.17). The previous and new geochronological, petrographic and geochemical data show that the volcanic and sedimentary rocks of the Itmurundy zone formed in Ordovician time in an intra-plate oceanic setting and in a supra-subduction setting at a Pacific-type convergent margin.

Geochemistry and tectonic setting of Middle Ordovician MORB-like basalts in the Kunlun Orogen: implications for a back-arc environment

The Central Kunlun ophiolitic melange zone, northern Tibetan Plateau, represents a remnant of the Early Paleozoic oceanic lithosphere. The Middle Ordovician Longshigeng basalts (LBs) are located in south of this melange zone and have important significance for reconstructing the opening and subduction processes of the Proto-Tethys Ocean. This study presents petrological, whole-rock geochemical, and zircon U-Pb data for these basalts. LA-ICP-MS U-Pb zircon data indicate that these basalts formed ca. 463 Ma. Geochemically, the basalts are characterized by low SiO2 (47.00–50.63 wt%) and K2O (0.22–1.05 wt%), intermediate Mg# (47–57) and high TiO2 (1.51–2.72 wt%), and are identified as tholeiitic basalts. Their chondrite-normalized REE patterns feature slight enrichments in LREEs (LREE/HREE = 2.11–3.08) with mild Eu anomalies (δEu = 0.89–1.06), and their patterns are similar to the reference line of enriched mid-ocean ridge basalt (EMORB). The primitive mantle-normalized trace element diagrams also show similarities with EMORB and are characterized by overall enrichments in large ion lithophile and high field strength elements, without notable Nb, Ta, and Ti depletions. Combining these data with the tectonic discrimination diagrams, we infer that these rocks formed in a back-arc environment in response to the northward subduction of the Proto-Tethys Ocean (South Kunlun Ocean) in the East Kunlun region, northern Tibetan Plateau.

Geochemistry of late paleoproterozoic Anjana and Amet granites of the Aravalli craton with affinities to sanukitoid series granitoids: Implications for petrogenetic and geodynamic processes

The Mangalwar Complex of the Aravalli craton is marked by the presence of late Paleoproterozoic granites referred to as Anjana Granite and Amet Granite. These granites occur as 1.64 Ga old plutons intruding greenstone sequences and migmatitic gneisses of Mangalwar Complex which comprises parts of BGC of the Aravalli craton. In the present contribution major, trace and REE data of these granites along with associated microgranular mafic enclaves (MMEs) are presented and discussed. Geochemically these granites are quartz monzonite, metaluminous, sub-alkaline and high-K calc-alkaline rocks. The most important characteristics of Anjana and Amet granites are low SiO2, high MgO, Mg#, K2O, Ba, and low Na2O/K2O ratios. In addition, the REEs show moderate to high fractionation, with (La/Yb) ratios up to 22 and 23 of the Anjana and Amet granites respectively, with no or positive europium anomalies. In the primitive mantle-normalized trace element diagrams both granites show depletion in high-field strength elements (HFSE) such as Nb, Ta, P, Ti and enrichment in LILEs. Most of these features are comparable to those of sanukitoid series rocks. Geochemically both granites are distinguished as high-Ti sanukitoids. Geochemical characteristics of MMEs suggest that they are similar to Anjana and Amet granites and in turn to sanukitoids with lower SiO2 content. They display LREE enriched patterns with low values (avg. 13) of (La/Yb)N, negative Eu anomalies and high HREE contents (58 ppm). It is suggested that the parental magma of Anjana and Amet granitic plutons originated through a four stage process (1) Generation of magmatic melts produced by partial melting of terrigeneous sediments of subducting slab in an arc setting; (2) interaction of those melts with the overlying mantle wedge, and total consumption of slab-derived melts during the reaction resulting in production of a metasomatized mantle; (3) tectonothermal event, possibly related to the slab break-off, causing asthenospheric mantle upwelling. This may have induced the melting of the metasomatized mantle and the generation of sanukitoid magmas. The parental magmas of Anjana and Amet granites and their mafic enclaves were generated at lower and higher lithospheric levels respectively (4) Granitic magma ascended due to viscosity and gravity instabilities and interacted with enclave magma at higher mantle level. Both magmas ascended towards upper crust and evolved through fractional crystallisation. Existing data suggest that in the Mangalwar Complex, the formation of sanukitoid magma started even during Mesoarchaean times and continued till late Paleoproterozoic. Formation of sanukitoid magma during this time indicates that in northern Indian shield the multi-stage subduction- accretionary orogenic processes continued for a protracted geological period and played a major role in the origin and evolution of early continental crust.

Geology and geochronology of the Jurassic magmatic arc in the Magdalena quadrangle, north-central Sonora, Mexico

This work reports on the geology and U–Pb LA-ICPMS zircon geochronology of a crustal section that is part of the Jurassic magmatic arc in the Magdalena quadrangle of north-central Sonora, Mexico. This rock succession is variably metamorphosed and strained as it was affected by Late Cretaceous shortening, intruded by early Tertiary granitoids, and further exhumed in the lower plate of the early Miocene Magdalena metamorphic core complex. The older and more extensively exposed Jurassic unit is the >3.5 km thick Sierra Guacomea rhyolite that is composed of massive to poorly bedded rhyolite, bedded quartz-phyric rhyolitic ignimbrite and interbedded ash-fall tuffs and quartz-rich sandstone beds. Three rhyolite samples collected at different localities of its outcrops yielded concordia ages of 175.2 ± 0.9, 171.7 ± 0.6, and 171.4 ± 0.7 Ma. The quartz-phyric Rancho La Víbora, Los Vallecitos, and the Agua Caliente rhyolitic domes that are associated with the Sierra Guacomea rhyolite yield concordia ages of 176 ± 0.8, 174.4 ± 0.9 and 173.1 ± 0.8 Ma, respectively. The Rancho Los Pozos unit composed of interbedded rhyolitic ash-fall tuff and flows, sandstone, siltstone and subordinate limestone beds has an estimated thickness of 600 m and yielded a crystallization concordia age of 170.7 ± 0.6 Ma from a rhyolite bed. The porphyritic El Rincón granite that intrudes into the Sierra Guacomea rhyolite yields crystallization ages of 167.43 ± 0.42 and 164.4 ± 0.7 in samples from different localities. The La Jojoba metasandstone that consists of foliated, quartz-rich to arkosic strata of fluvial origin is at least 900 m thick; detrital zircon grains dated from three sandstone samples yielded dominantly Jurassic ages with peaks at 172, 170, and 163.7 Ma, and a combined maximum depositional age of ca. 163 Ma.The younger plutons are the porphyritic El Nopalito granite that has an interpreted crystallization age of 160.8 ± 0.6 Ma, and the leucocratic, two-mica, garnet-bearing La Cebolla granite that yielded a concordia age of 158.1 ± 1 Ma. These granitic intrusions record the waning magmatic pulses of the arc, in the study quadrangle, but their volcanic equivalents were not identified. Inherited zircon grains in the reported volcanic and plutonic units are only of Jurassic age, except by two Proterozoic zircon grains yielded by the El Nopalito granite. The El Salto granite augen gneiss is a xenolith dated at 1071.9 ± 5 Ma that indicates the presence of Grenvillian basement in the study area.Major- and trace-element geochemical data indicate that the volcanic and plutonic units are silica-rich, mostly high K calc-alkaline to shoshonitic rocks associated with a continental margin arc setting. The plutons are mostly peraluminous, and in conjunction with trace element geochemistry data, they suggest crustal assimilation of magmas emplaced in a probably thickened continental crust. Chondrite-normalized REE patterns and primitive mantle-normalized trace element diagrams also suggest partial melting and fractional crystallization processes.The ages obtained indicate that the arc in the study area developed from ca. 176 to 158 Ma, encompassing a 17 m.y. interval of magmatism and associated sedimentation. Regional correlation and geochronologic published data indicate that the arc crustal section of the Magdalena quadrangle is part of the Jurassic magmatic arc that regionally lasted from ca. 190 to 158 Ma.

Late Silurian to Early Devonian volcanics in the East Kunlun orogen, northern Tibetan Plateau: Record of postcollisional magmatism related to the evolution of the Proto-Tethys Ocean

The late Early Paleozoic volcanic rocks in the East Kunlun orogen are crucial to determining collisional processes related to the evolution of the Proto-Tethys Ocean. We report new zircon U-Pb ages, whole-rock geochemistry and Sr-Nd isotopes from these volcanic rocks and constrain their tectonic setting and magmatic processes. This volcanic suite consists mainly of foliated metarhyolites and minor metabasalts. Zircon U-Pb ages indicate that the bimodal volcanic rocks formed from Late Silurian to Early Devonian (ca. 420−409 Ma). The basalts show tholeiitic geochemical signatures characterized by low contents of SiO2 (47.19–54.83 %), MgO (2.21–7.52 %), and K2O/Na2O ratios (0.32−0.77%) and high contents of TiO2 (1.80–2.91 %). Their chondrite-normalized REE patterns are characterized by enrichments in LREEs (LREE/HREE = 3.68–6.09) with slight Eu anomalies (δEu = 0.67–1.00); their patterns are similar to the reference line of oceanic island basalt (OIB). The primitive mantle-normalized trace element diagram also shows similarities with OIBs and features overall enrichments in large ion lithophile and high field strength elements, except for Nb and Ta. The εNd(t = 422 Ma) values range narrowly from −1.79 to +1.32. These features suggest that the basalts were most likely derived from an asthenospheric mantle that was contaminated by small volumes of subcontinental lithospheric mantle (SCLM)/crust. The variations in major and trace elements show that the basalts experienced fractional crystallization of olivine, pyroxene and plagioclase. In contrast, the metarhyolites have high SiO2 (65.85–70.83 %), Na2O + K2O (6.71–10.09 %), K2O/Na2O ratios (1.69–2.80 %) and low MgO, Ni, and Cr contents. Their trace element signatures show enrichments in LILEs and LREEs (e.g. Cs, Rb, Ba), depletion of HFSEs (e.g. Nb, Ti, Ta) and high negative Eu anomalies. These features suggest a crustal origin lacking interactions with mantle melts. Considering all the geochemical and tectonic events of this area, it is concluded that the Maoniushan Formation volcanic rocks in EKOB formed in a postcollisional extensional setting related to asthenospheric mantle upwelling and continental delamination processes during the Late Silurian to Early Devonian. These tectonic-magmatic events, together with previous data, suggest that the Proto-Tethys Ocean had closed and evolved to postcollisional collapse stage since the Late Silurian.

Early Cretaceous bimodal volcanic rocks in the Yinshan belt, North China Craton: age, petrogenesis, and geological significance

Determining the age and petrogenesis of the Mesozoic magmatic rocks may provide crucial evidence regarding the tectonic setting and evolution of the North China Craton (NCC). In this paper, we present new zircon U–Pb ages and geochemical data for bimodal volcanic rocks from Zhuozi area in the eastern Yinshan belt, NCC, to discuss their petrogenesis and tectonic implications. The volcanic rock suite consists of basalts, rhyolites, and trachytes. According to the results of laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), the rhyolitic and trachytic rocks have zircon U–Pb ages of 136.9 ± 0.8 Ma and 134.0 ± 1.7 Ma, respectively, representing their eruption ages. The basalts are enriched in large-ion lithophile elements (LILE; Ba, Rb, Sr, and Th) and light rare-earth elements (LREE), and are relatively depleted in high field strength elements (HFSE; Nb, Ta, and Ti). In addition, the basalts are characterized by high fractionations of rare-earth elements (REE), with (La/Yb)N = 24.87–42.85. These features suggest that they were derived from low-degree partial melting of enriched lithospheric mantle metasomatized by subduction-related components. The rhyolitic rocks have low mean Al2O3 (12.26 wt%) and TiO2 (0.14 wt%) contents and Mg# (14.92) values, with relatively low total REE abundances. They have high alkali and Zr, Ce, Y, and Nb contents and high Ga/Al ratios, with notably positive Pb and negative Sr, Ba, and Eu anomalies observed in the primitive mantle-normalized trace element diagram. These features indicate that the rocks exhibit characteristics of A1-type granite and likely derived from the partial melting of a crustal source. The trachytic rocks are show moderate trace elements and SiO2, MgO, Fe2O3T, and TiO2 contents. They were possibly generated by fractional crystallization of the underplating basaltic magmas and assimilated minor crustal materials. The geochemical characteristics, in combination with the regional geology, suggest that the bimodal volcanic rocks formed in an intraplate extensional setting likely associated with the retreat of the subducted Paleo-Pacific plate.

Petrogenesis and tectonic implications of the Neoproterozoic adakitic and A-type granitoids in the southern Arabian-Nubian shield

Both adakitic and A-type granitoid have been recently identified in the southern ANS. The Emba-Derho and Koka granitoids yielded the same zircon U–Pb ages of 851 ± 14 Ma and 851 ± 2 Ma, respectively. The Emba-Derho granitoids show high and a narrow range of SiO2 (71.3–73.6 wt.%) and Al2O3 (14.9–15.9 wt.%) contents, but relatively lower K2O + Na2O (4.8–5.5 wt.%). They are characterized by high Sr (306–367 ppm) and very low Y (3.57–6.03 ppm) and Yb (0.38–0.61 ppm), and high Sr/Y (42–70) ratios, implying they have adakitic signatures. Their chondrite-normalized REE patterns are highly fractionated with high La/YbN (14.03 to 29.82) ratio without significant Eu anomalies (Eu/Eu* = 0.89–1.07). Their primitive mantle-normalized trace element diagram is characterized by enrichment of LILE and depletion of HREE (Ta, Nb, and Ti). The samples have low initial 87Sr/86Sr (0.70084 to 0.70263), higher positive ƐNd (+ 5.0 to + 8.2), and more radiogenic Pb isotopes. These lines of geochemical evidence indicate that the Emba-Derho granitoids were generated by partial melting of a subducted oceanic slab at the stability field of garnet. In contrast, the Koka granitoids display wide range of SiO2 (67.9–78.4 wt.%), Al2O3 (11.05–16.51 wt.%), and K2O + Na2O (5.86–8.76%) contents. The rocks have extremely low initial 87Sr/86Sr (0.68685 to 0.70099) and high ƐNd (+ 5.43 to + 5.78) and relatively less radiogenic Pb isotopic compositions compared with the Emba-Derho granitoids. They also show A2-type geochemical characteristics, suggesting that the Koka granitoids were originated from the juvenile continental crust. Both the adakitic and A-type granitoids in this study may have been formed in an arc-back-arc setting resulted from NW dipping subduction of the oceanic slab.

Nature and Thermal State of the Lithosphere beneath the Western Margin of the Yangtze Block in South China during the Neoproterozoic

The western margin of the Yangtze Block is characterized by numerous felsic intrusions and many mafic-ultramafic plutons that record the lithospheric thermal state of South China during the Neoproterozoic. Numerous ∼800 Ma mafic dikes, intruded into the Neoproterozoic Dengxiangying Group, consist of fine- to medium-grained diabase and have variable SiO2 (42.80–57.20 wt%), MgO (5.16–13.15 wt%), and total alkalis (0.05–4.41 wt%). They show light rare earth element–enriched patterns with negative to slightly positive Eu anomalies (Eu/Eu*=0.67–1.09) and display enrichment of Pb and depletion of Nb, Ta, and Sr in the primitive mantle–normalized trace-element diagram. Rocks from the Dengxiangying mafic dikes have variable initial 87Sr/86Sr ratios (0.652431–0.730039) but relatively constant εNd values (−2.5 to +2.6) and Pb isotope ratios (Pb206/Pb204=17.53–17.88, Pb207/Pb204=15.60–15.63, Pb208/Pb204=37.66–38.38). These geochemical features suggest that the mafic dikes were derived from a lithospheric mantle enriched by slab-derived materials. PRIMELT3 modeling for the Neoproterozoic mafic rocks in the western margin of the Yangtze Block reveals that their primary magmas were in equilibrium with harzburgite and spinel peridotite with potential temperatures of 1377°–1498°C. They have high primary magmatic water contents (1900–72,000 ppm) that are similar to those of other arc basalts. These lines of evidences confirm that the Neoproterozoic mafic and ultramafic rocks were formed in an active continental setting.

Post-collisional ultrapotassic rocks and mantle xenoliths in the Sailipu volcanic field of Lhasa terrane, south Tibet: Petrological and geochemical constraints on mantle source and geodynamic setting

Post-collisional ultrapotassic magmatic rocks (15.2–18.8Ma), containing mantle xenoliths, are extensively distributed in the Sailipu volcanic field of the Lhasa terrane in south Tibet. They could be subdivided into high-MgO and low-MgO subgroups based on their petrological and geochemical characteristics. The high-MgO subgroup has olivine-I (Fo87–92), phlogopite and clinopyroxene as phenocryst phases, while the low-MgO subgroup consists mainly of phlogopite, clinopyroxene and olivine-II (Fo77–89). These ultrapotassic magmatic rocks have high MgO (4.6–14.5wt%), Ni (145–346ppm), Cr (289–610ppm) contents, and display enrichment in light rare earth element (REE) over heavy REE and enriched large ion lithophile elements (LILE) relative to high field strength elements (HFSE) with strongly negative Nb-Ta-Ti anomalies in primitive mantle-normalized trace element diagrams. They have extremely radiogenic (87Sr/86Sr)i (0.7167–0.7274) and unradiogenic (143Nd/144Nd)i (0.5118–0.5120), high (207Pb/204Pb)i (15.740–15.816) and (208Pb/204Pb)i (39.661–39.827) at a given (206Pb/204Pb)i (18.363–18.790) with high δ18O values (7.3–9.7‰). Strongly linear correlations between depleted mid-ocean ridge basalt-source mantle (DMM) and the Indian continental crust (HHCS) in Sr-Nd-Pb-O isotopic diagrams indicate that the geochemical features could result from reaction between mantle peridotite and enriched components (fluids and melts) released by the eclogitized Indian continental crust (HHCS) in the mantle wedge. The high-MgO (13.7–14.5wt%) subgroup displays higher (143Nd/144Nd)i, lower (87Sr/86Sr)i and (206Pb/204Pb)i ratios and lower δ18O values compared with the low-MgO (4.6–8.8wt%) subgroup. High Ni (850–4862ppm) contents of olivine phenocrysts and high whole-rock SiO2, NiO, low CaO contents indicate that the low-MgO ultrapotassic magmatic rocks are derived from partial melting of olivine-poor mantle pyroxenite. However, lower Ni concentrations of olivine phenocryst and lower whole-rock SiO2, NiO, higher CaO contents of the high-MgO ultrapotassic rocks may indicate their peridotite mantle source. This could be attributed to different amounts of silicate-rich components added into the mantle sources of the parental magmas in the mantle wedge caused by the northward subduction of the Indian continental lithosphere. The reaction-formed websterite xenoliths, reported for the first time in this study, are made up of anhedral and interlocking clinopyroxene (45–65vol%) and orthopyroxene (30–50vol%) with minor phlogopite (<3vol%) and quartz (<2vol%) and are suggested to be formed by silicate metasomatism of the mantle peridotite. The harzburgites, another major type of mantle xenolith in south Tibet, have a mineral assemblage of olivine (60–75vol%), orthopyroxene (20–35vol%), clinopyroxene (<3vol%), phlogopite (<2vol%) and spinel (<2vol%) and may have experienced subduction-related metasomatism. Combined with two types of ultrapotassic magmas, we propose that compositions of mantle wedge beneath south Tibet may gradually evolve from harzburgite through lherzolite to websterite with strong metasomatism of silicate-rich components in their mantle source region. Partial melting of the enriched mantle sources could be triggered by rollback of Indian continental slab during 25–8Ma in south Tibet.

Mid-Neoproterozoic Tadong amphibolites at the junction of the East Kunlun and Western Qinling Orogens – a record of continental rifting during the break-up of Rodinia

ABSTRACTMid-Neoproterozoic rift-related Tadong amphibolites (TDA) are situated in the junction of the East Kunlun Orogen (EKO) and the West Qinling Orogen (WQO) in western China, and have important significance in the break-up of the Supercontinent Rodinia. The mineral assemblage of the TDA exhibits amphibolite facies metamorphism, and the protolith is basic volcanic rocks. Here, we present a detailed laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) zircon U–Pb age and geochemical data of TDA. LA-ICP-MS U–Pb zircon age determination indicates that the basic volcanics formed at ca. 743–711 Ma. Geochemically, TDAs are characterized by low SiO2 (46.06–50.18%), K2O (0.66–1.86%), and Mg# (40–45) and high TiO2 (1.9–3.5%), and are attributed to tholeiite basalts. Their chondrite-normalized REE patterns are characterized by moderate enrichments in LREEs (LREE/HREE = 4.98–5.51) with insignificant Eu anomalies (δEu = 0.99–1.12). The primitive mantle-normalized trace element diagrams are characterized by pronounced enrichment of high-field-strength elements (HFSEs, e.g. REE, Nb, Ta, Zr, Hf) with slightly positive anomalies of Ti, which is different from the subduction zone basalts and normal mid-ocean ridge basalts (NMORBs), but similar to the ocean-island basalts (OIBs) and Emeishan continental flood basalts (ECFBs), resembling the features of an OIB-like mantle source. Most samples exhibit high Nb/Ta (16.6–17.4), Nb/La (0.70–0.94), and positive ΔNb (ΔNb = 1.74 + log (Nb/Y) − 1.92*log (Zr/Y)) values. These geochemical features suggest that the Tadong basaltic rocks were most likely derived from an OIB-like mantle source and were the products of a lower degree partial melting of garnet lherzolite. Along with the tectonic discrimination diagrams, it is further inferred that these rocks were formed in a continental rifting setting. These results from our research confirm the existence of continental rifting in the junction of the EKO and the WQO in the mid-late Neoproterozoic, implying that the rifting is a response to the break-up of the Supercontinent Rodinia.

Zircon U–Pb age and Sr–Nd–Hf–O isotope geochemistry of the Paleocene–Eocene igneous rocks in western Gangdese: Evidence for the timing of Neo-Tethyan slab breakoff

Northward Neo-Tethyan oceanic lithosphere subduction beneath southern Tibet in the Mesozoic–Early Cenozoic produced continental arc magmas in the ~1600km-long Gangdese belt. The most voluminous magmatism occurred in the Paleocene–Eocene, and is characterized by extensive I-type calc-alkaline to high-K calc-alkaline Linzizong volcanic rocks, and coeval plutons. These rocks have been extensively studied in the eastern Gangdese belt (east of ∼89°E), but few data exist from the western Gangdese belt. New data for eleven samples of these rocks, combined with existing data from the literature, show that they are similar to the eastern Gangdese belt rocks, with relative depletions in Nb, Ta, P, and Ti, and enrichments in Rb, Ba, Th, U, K, Pb, Zr, and Hf on a primitive mantle-normalized trace element diagrams, typical of continental arc-related igneous rocks. However, compared to the east, western Gangdese igneous rocks range to higher K2O contents (up to 6.1wt.%), higher (87Sr/86Sr)i ratios (up to 0.7151), and lower εNdi values (down to −8.1), suggesting that an evolved crustal source was involved in arc magmatism.The Gangdese arc magmatism lasted to ~80Ma, and has a gap or quiescent period afterwards. Starting at ~69Ma, the arc magmatism initiated and shifted southward from ~30.5°N to ~29.5°N in southern Tibet with an abrupt change of India-Asia convergence rate. The magmas through the whole Gangdese belt at ~69–53Ma are characterized by intermediate εNdi values (−0.6 to +4.0), positive εHfi values (+3.8 to +7.1), intermediate δ18O values (+5.0‰ to +6.5‰), and low Th/Y and La/Yb ratios (<20). These magmas were likely derived from the mantle with crustal contamination by MASH process in response to Neo-Tethyan slab rollback as proposed by previous studies.The Sr–Nd–Hf–O isotopic compositions of Linzizong volcanic rocks and coeval intrusions are relatively homogeneous during ~69–53Ma, but show a wide range at ~53–50Ma. Zircon temperature values from these rocks are distinctively high during the latter period and whole rock Th/Y and La/Yb ratios increased significantly after ~50Ma. We suggest that the high temperature and heterogeneous geochemistry of these magmas at ~53–50Ma reflect Neo-Tethyan slab breakoff during India-Asia collision, which triggered asthenospheric mantle upwelling. Mantle derived magmas resulted in extensive heating, induced crustal melting, and generated magmas with variable isotopic compositions. Tibetan crust was significantly thickened after ~50Ma.

Plume-lithosphere interaction in the generation of the Tarim large igneous province, NW China: Geochronological and geochemical constraints

The magmatism in the early Permian Tarim large igneous province (TLIP) in NW China is represented by basaltic lava flows in Keping and ultramafic-mafic-felsic intrusions and mafic dikes in Bachu, northwestern Tarim Craton. This paper reports new Ar-Ar dating results and chemical compositions of Keping basalts and Bachu dikes, with aims of better characterizing the timing of and mantle/crustal contribution to the TLIP. The Keping basalts yield two well-defined ⁴⁰Ar/³⁹Ar plateau ages of 287.3 ± 4.0 Ma and 287.9 ± 4.1 Ma, which, together with age data from the literature, define a magmatic event at ∼289 Ma. The intrusions and dikes in Bachu are believed to have formed at ∼279 Ma based on screened literature data. Thus, they together define two magmatic episodes. The Keping basalts, representing the earlier episode, have alkaline affinity (SiO₂ = 44.0-47.9 wt.%, Na₂O + K₂O = 3.7-4.9 wt.%), low MgO (4.3-5.9 wt.%) and high TiO₂ (3.8-5.1 wt.%) contents, showing fractionated chondrite-normalized LREE and nearly flat HREE patterns [(La/Yb)_N = 6.27-7.71; (Dy/Yb)_N = 1.36-1.48] with noticeable negative Nb and Ta anomalies in the primitive mantle-normalized trace element diagram. They have negative and relatively uniform ε_Nd(t) (−2.3 to −3.8) and low (²⁰⁶Pb/²⁰⁴Pb)_i (17.43-17.57). We argue that these “crustal signatures” cannot be attributed to crustal assimilation because neither ε_Nd(t) nor (²⁰⁶Pb/²⁰⁴Pb)_i correlates with SiO₂; rather they are more likely derived from a sub-continental lithospheric mantle (SCLM) source metasomatized by subduction-related processes. The Bachu dikes, representing the later episode and confined to the margins of the Tarim Craton, have similar MgO (3.6-5.4 wt.%) and TiO₂ (3.1-4.7 wt.%) contents to the Keping basalts, and display more fractionated REE patterns [(La/Yb)_N = 10.1-14.0; (Dy/Yb)_N = 1.79-1.99]. They have variable isotope compositions [ε_Nd(t) = −0.3-4.8, (²⁰⁶Pb/²⁰⁴Pb)_i = 17.50-18.11] and display OIB-like trace element signatures. Correlations between isotopic and trace element ratios indicate that some dikes with low ε_Nd(t) and low initial Pb isotope ratios could have been subjected to crustal assimilation. We propose a model involving plume-lithosphere interaction to account for the two discrete magmatic episodes with distinct mantle sources in the TLIP. The earlier episode was formed in response to the impact of a sub-lithospheric mantle plume at the base of the SCLM. Partial melting of the metasomatized lithospheric mantle was triggered by temperature increase due to conductive heating of the impregnating mantle plume. The later episode was generated by decompression melting of the mantle plume, as a result of deflection of the plume towards the margins of the Tarim Craton with thinner lithosphere.

Genesis of the Chehugou Mo-bearing granitic complex on the northern margin of the North China Craton: geochemistry, zircon U–Pb age and Sr–Nd–Pb isotopes

AbstractThe Chehugou granite-hosted molybdenum deposit is typical of the Xilamulun metallogenic belt, which is an important Mo–Ag–Pb–Zn producer in China. A combination of major and trace element, Sr and Nd isotope, and zircon U–Pb isotopic data are reported for the Chehugou batholith to constrain its petrogenesis and Mo mineralization. The zircon SIMS U–Pb dating yields mean ages of 384.7 ± 4.0 Ma and 373.1 ± 5.9 Ma for monzogranite and syenogranite and 265.6 ± 3.5 Ma and 245.1 ± 4.4 Ma for syenogranite porphyry and granite porphyry, respectively. The Devonian granites are calc-alkaline with K2O/Na2O ratios of 0.44–0.52, the Permian granites are alkali-calcic with K2O/Na2O ratios of 1.13–1.25, and the Triassic granites are calc-alkaline and alkali-calcic rocks with K2O/Na2O ratios of 0.78–1.63. They are all enriched in large-ion lithophile elements (LILEs) and depleted in high-field-strength elements (HFSEs) with negative Nb and Ta anomalies in primitive mantle-normalized trace element diagrams. They have relatively high Sr (189–1256 ppm) and low Y (3.87–5.43 ppm) concentrations. The Devonian granites have relatively high initial Sr isotope ratios of 0.7100–0.7126, negative ɛNd(t) values of −12.3 to −12.4 and 206Pb/204Pb ratios of 16.46–17.50. In contrast, the Permian and Triassic granitoids have relatively low initial 87Sr/86Sr ratios (0.7048–0.7074), negative ɛNd(t) values of −10.1 to −13.1 and 206Pb/204Pb ratios of 17.23–17.51. These geochemical features suggest that the Devonian, Permian and Triassic Chehugou granitoids were derived from ancient, garnet-bearing crustal rocks related to subduction of the Palaeo-Asian Ocean and subsequent continent–continent collision between the North China and Siberian plates.

Petrologic, chemical, and isotopic evaluation of pitchstones in the Samho area, southwestern Okcheon Belt, South Korea

The Samho area in the southwestern Okcheon Belt, Korean Peninsula, contains spatially related eruptions of lapilli tuff, rhyolite, and pitchstone, considered to be of Late Cretaceous age. The pitchstones, which are the youngest rocks in this volcanic suite, are chemically highly evolved, strongly metaluminous to weakly peraluminous, and calc-alkaline. They have moderately fractionated chondrite-normalized rare earth element (REE) patterns, with relative enrichment of light REEs and Eu/Eu* values of 0.53–0.57. A distinct negative Nb anomaly is observed on a primitive mantlenormalized trace element diagram. These chemical features correspond to an I-type granite derived from a continental/oceanic arc. The pitchstones have Zr contents of 45–92 ppm, and zircon thermometry yields temperatures of 650–743 °C (mean value, 722 °C). The pitchstones have an initial 87Sr/86Sr isotopic ratio of 0.712, an initial 143Nd/144Nd ratio of 0.5120, and aNd(t) values of −10.6 to −12.0. The mean K-Ar whole-rock ages of the lapilli tuff, rhyolite, and pitchstone are 81.9 ± 2.4 Ma, 65.5 ± 1.9 Ma, and 12.7 ± 0.9 Ma, respectively. The depleted mantle model ages (TDM) range from 1.46 to 1.58 Ga. The 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb isotopic ratios are 18.477–18.569, 15.672–15.702, and 38.889–38.999, respectively. The Sr and Nd isotopic compositions of the pitchstones are relatively enriched compared with depleted MORB mantle (DMM), indicating the involvement of lower crustal components in their source. We conclude that the pitchstones in the Samho area formed in a continental arc setting by partial melting of a probable Mesoproterozoic parental source. The magma series, petrogenesis, and tectonic setting of Late Cretaceous magmatism in the Samho area can be correlated with those of the Haenam volcanic fields located east of the present study area.

Late Paleozoic volcanic record of the Eastern Junggar terrane, Xinjiang, Northwestern China: Major and trace element characteristics, Sr–Nd isotopic systematics and implications for tectonic evolution

The Eastern Junggar terrane of the Central Asian Orogenic Belt includes a Late Paleozoic assemblage of volcanic rocks of mixed oceanic and arc affinity, located in a structurally complex belt between the Siberian plate, the Kazakhstan block, and the Tianshan Range. The early history of these rocks is not well constrained, but the Junggar terrane was part of a Cordilleran-style accreted arc assemblage by the Late Carboniferous. Late Paleozoic volcanic rocks of the northern part of the east Junggar terrane are divided, from base to top, into the Early Devonian Tuoranggekuduke Formation (Fm.), Middle Devonian Beitashan Fm., Middle Devonian Yundukala Fm., Late Devonian Jiangzierkuduke Fm., Early Carboniferous Nanmingshui Fm. and Late Carboniferous Batamayineishan Fm. We present major element, trace element and Sr–Nd isotopic analyses of 64 (ultra)mafic to intermediate volcanic rock samples of these formations. All Devonian volcanic rocks exhibit remarkably negative Nb, Ta and Ti anomalies on the primitive mantle-normalized trace element diagrams, and are enriched in more highly incompatible elements relative to moderately incompatible ones. Furthermore, they have subchondritic Nb/Ta ratios, and their Zr/Nb and Sm/Nd ratios resemble those of MORBs, characteristics of arc-related volcanic rocks. The Early Devonian Tuoranggekuduke Fm., Middle Devonian Beitashan Fm., and Middle Devonian Yundukala Fm. are characterized by tholeiitic and calc-alkaline affinities. In contrast, the Late Devonian Jiangzierkuduke Fm. contains a large amount of tuff and sandstone, and its volcanic rocks have dominantly calc-alkaline affinities. We therefore propose that the Jiangzierkuduke Fm. formed in a mature island arc setting, and other Devonian Fms. formed in an immature island arc setting. The basalts from the Nanmingshui Fm. have geochemical signatures between N-MORB and island arcs, indicating that they formed in a back-arc setting. In contrast, the volcanic rocks from the Batamayineishan Fm. display geochemical characteristics of continental intraplate volcanic rocks formed in an extensional setting after collision. Thus, we propose a model that involves a volcanic arc formed by northward subduction of the ancient Junggar ocean and amalgamation of different terranes during the Late Paleozoic to interpret the formation of the Late Paleozoic volcanic rocks in the Eastern Junggar terrane, and the Altai and Junggar terranes fully amalgamated into a Cordilleran-type orogen during the end of Early Carboniferous to the Middle–Late Carboniferous.

Geochronology and geochemistry of the c. 80 Ma Rutog granitic pluton, northwestern Tibet: implications for the tectonic evolution of the Lhasa Terrane

AbstractThe Rutog granitic pluton lies in the Gangdese magmatic arc in the westernmost part of the Lhasa Terrane, NW Tibet, and has SHRIMP zircon U–Pb ages of c. 80 Ma. The pluton consists of granodiorite and monzogranite with SiO2 ranging from 62 to 72 wt% and Al2 O3 from 15 to 17 wt%. The rocks contain 2.33–4.93 wt% K2O and 3.42–5.52 wt% Na2O and have Na2O/K2O ratios of 0.74–2.00. Their chondrite-normalized rare earth element (REE) patterns are enriched in LREE ((La/Yb)n = 15 to 26) and do not show significant Eu anomalies (δEu = 0.68–1.15). On a primitive mantle-normalized trace element diagram, the rocks are rich in large ion lithophile elements (LILE) and poor in high field strength elements (HFSE), HREE and Y. Their Sr/Y ratios range from 15 to 78 with an average of 30. The rocks have constant initial 87Sr/86Sr ratios (0.7045 to 0.7049) and slightly positive ɛNd(t) values (+0.1 to +2.3), similar to I-type granites generated in an arc setting. The geochemistry of the Rutog pluton is best explained by partial melting of a thickened continental crust, triggered by underplating of basaltic magmas in a mantle wedge. The formation of the Rutog pluton suggests flat subduction of the Neo-Tethyan oceanic lithosphere from the south. Crustal thickening may have occurred in the Late Cretaceous prior to the India–Asia collision.