The general behaviour of transitions from bound molecular surface states into dissipative gaseous states in an externally dc-field-free region is reviewed. Adiabatic and non-adiabatic processes have to be distinguished. It is shown that non-adiabatic interactions may be responsible for various phenomena of molecular ion formation by heavy ion induced desorption, in the inelastic as well as in the elastic primary ion energy loss regime. The implications of this non-adiabatic desorption model are compared with experimental data as primary ion energy loss dependence, secondary ion yields, and energy distributions. The organic ion types are shown to be representative for the condensed phase acidity or basicity, respectively, being desorbed by the very sudden process of ion impact.