The occurrence of grain boundary damage and stress-relief cracking within heat-affected zones of pressure vessel weldments and claddings has led to numerous investigations. The metallographic and fractographic as well as microanalytical methods used are reported in respect of the results obtained and the given limits. Within the range of microanalysis the application of the electron beam microprobe is described for the detection of micro segregations as well as companion elements and trace elements, Auger spectroscopy for the investigation of thin grain boundary films, transmission electron microscopy especially for the identification of precipitations, and the photoemission electron microscope for the analysis of transformation and precipitation behaviour, as well as the so-called phase analysis for better knowledge in the field of kinetics of phases. Using the results of these methods, which were applied on real welded joints as well as on weld simulation tests, it was possible to prove the validity of the chosen parameters for the welding simulation. Further efforts will be made to find more clear correlations between the contents of alloying elements in the base material and the precipitation or crack behaviour in the coarse grain zone of the HAZ.
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