To investigate the static pressure distribution characteristics of a flying-wing model, an advanced binary pressure sensitive paint (PSP) technique is introduced. It has low-temperature sensitivity and can compensate the errors induced by temperature. The pressure measurement test was performed in 0.6 m trisonic wind tunnel at angles of attack ranging from 0[Formula: see text] to 12[Formula: see text] in supersonic condition, adopting a low-aspect-ratio flying wing model. The binary PSP is sprayed on the upper surface of the model while pressure taps are installed on the upper surface of the right wing. Luminescent images of two probes are acquired with a color charge-coupled-device camera system and processed with calibration results. During the test, the surface pressure is measured by PSP and transducer, respectively. The results obtained show that the binary paint is of advantage to the surface pressure measurement and flow characteristic analysis. The high-resolution pressure spectra at different angle of attack clearly reveal the impact of leading edge vortex on the upper surface pressure distributions. The pressure measured by PSP also agrees well with the pressure tap results. The root mean square error of pressure coefficient is 0.01 at [Formula: see text], [Formula: see text].