Pressure Liquid Research Articles

Vapor pressure to Boltzmann distribution law connection and its empirical corrections

Vapor pressure (P) data of pure substances in gas/solid-liquid equilibrium is important for scientific research and practical applications. Due to the large temperature range going from melting point to critical point, it is an impossible task to determine the P of a pure substance at each temperature point. Up to now, there is no general equation that can accurately describe the relation between temperature (T) and P for all pure substances. Utilizing Boltzmann distribution, we presented a general expression, ln P = a + bT + cln(T) + d(1/T), for the P of pure substances, that is, the P-T dependence is nearly exponential over the entire range of liquid and solid existence. Furthermore, on the base of above equation, we established a corrected general equation to express the liquid vapor pressure within temperature in going from melting point to critical point.lnP=a+bT+cTT/Tb+d(ln(T))+f(ln(T))T/Tb+g(1/T)The results show that the corrected equation has the advantages of universality, simplicity, and high calculation accuracy for the vapor pressure involving liquid simple substances, liquid inorganic and liquid organic compounds.

Determination of sprayer parameters for fruit nurseries

The paper highlights that in industrial plantings, pests and weeds control is conducted using sprayers. To establish the required liquid fl ow rate, it is necessary to use calculations for sprayer adjustment. A small-sized, remotely controlled «GNOM» unit, developed at Gorsk Agrarian University, is designed for various tasks, including herbicidal spraying in fruit nurseries. (Research purpose) The research aims to substantiate the optimal parameters of the spraying unit in the herbicide treatment module. It also seeks to investigate the dependence of the flow rate of the working fluid and quality of liquid spray on the pressure in the system. (Materials and methods) A laboratory installation was developed to study the spray characteristics. Nylon threads with diameters of 100 and 250 micrometers were placed within the spray zone, and the resulting liquid spray was captured using a Nikon COOLPIX 58100 digital camera. Each subsequent experiment was carried out at a liquid pressure of 0.05 megapascals more than the previous one. (Results and discussion) The experiments resulted in obtaining images of the spray swath for a small-sized self-propelled unit, allowing for the categorization of the spray based on droplet sizes. The theoretical analysis demonstrated how changes in the air volume within the tank influence both the pressure and quality of the liquid spray. Additionally, it showed how the dispersion depends on the pressure of the working fluid. (Conclusions) The analysis of the working fluid spray showed that at a pressure in the hydraulic system in the range from 0.65 to 0.75 megapascals and a spray angle of 90 degrees, the highest quality fine spray is observed, the flow rate of the working fluid is in the range of 0.4-0.6 liters per minute, which very signifi cantly affects the size of the treated area in the direction of its increase at one tank refueling unit.

Research on design technology of fiber optic fuel level sensor with novel structure

Traditional aircraft fuel level sensors, represented by capacitive fuel level sensors, have inherent shortcomings, making it difficult to meet the increasing aviation needs in terms of intrinsic safety and electromagnetic interference resistance. Therefore, this article studies the design technology of fiber optic fuel level sensors. By analyzing various optical fiber liquid level measurement methods, the fiber Bragg grating method that best meets practical needs is selected, and a novel and reasonable sensor structure design is achieved. Specifically, in order to improve the measurement accuracy, a lever-type sensitivity enhancing structure based on flexure hinge is studied in this paper. Combined with the metal diaphragm, it can generate higher axial strain on the fiber grating under a given liquid pressure. In order to ensure the practicality of the sensor, this paper analyzes the interference factors that may cause the measurement error in the actual fuel tank. Correspondingly, this paper proposes a design of fixed distance double measuring points to compensate the influence of posture, uses the reference fiber grating method to compensate the influence of temperature, and designs a reasonable assembly and sealing scheme. To verify the rationality of the design, the sensor test platform is built and the sensor function is tested comprehensively. The results show that the sensor has good precision and can achieve expected compensation effect.

Capture and Detection of Aerosolized Fentanyl in a Suspended Electrochemical Cell.

Fentanyl is an extremely potent opioid that is commonly laced into other drugs. Fentanyl poses a danger to users but also to responders or bystanders who may unknowingly ingest a lethal dose (∼2 mg) of fentanyl from aerosolized powder or vapor. Electrochemistry offers a small, simple, and affordable platform for the direct detection of illicit substances; however, it is largely limited to solution-phase measurements. Here, we demonstrate the hands-free capture and electroanalyzation of aerosols containing fentanyl. A novel electrochemical cell is constructed by a microwire (cylindrical working electrode) traversing an ionic liquid film that is suspended within a conductive loop (reference/counter electrode). We provide a quantitative finite element simulation of the resulting electrochemical system. The suspended film maintains a high-surface area:volume, allowing the electrochemical cell to act as an effective aerosol collector. The low vapor pressure (negligible evaporation) of ionic liquid makes it a robust candidate for in-field applications, and the use of a hydrophobic ionic liquid allows for the extraction of fentanyl from solids and sprayed aqueous aerosols.

Separation of full, empty, and partial adeno-associated virus capsids via anion-exchange chromatography with continuous recycling and accumulation

The field of recombinant adeno-associated virus (rAAV) gene therapy has attracted increasing attention over decades. Within the ongoing challenges of rAAV manufacturing, the co-production of impurities, such as empty and partial capsids containing no or truncated transgenes, poses a significant challenge. Due to their potential impact on drug efficacy and clinical safety, it is imperative to conduct comprehensive monitoring and characterization of these impurities prior to the release of the final gene therapy product. Nevertheless, existing analytical techniques encounter notable limitations, encompassing low throughput, long turnaround times, high sample consumption, and/or complicated data analysis. Chromatography-based analytical methods are recognized for their current Good Manufacturing Practice (cGMP) alignment, high repeatability, reproducibility, low limit of detection, and rapid turnaround times. Despite these advantages, current anion exchange high pressure liquid chromatography (AEX-HPLC) methods struggle with baseline separation of partial capsids from full and empty capsids, resulting in inaccurate full-to-empty capsid ratio, as partial capsids are obscured within peaks corresponding to empty and full capsids. In this study, we present a unique analytical AEX method designed to characterize not only empty and full capsids but also partial capsids. This method utilizes continuous N-Rich chromatography with recycling between two identical AEX columns for the accumulation and isolation of partial capsids. The development process is comprehensively discussed, covering the preparation of reference materials representing full (rAAV-LacZ), partial (rAAV-GFP), and empty (rAAV-empty) capsids, N-rich method development, fraction analysis, determination of fluorescence response factors between capsid variants, and validation through comparison with other comparative techniques.

Fractionation and characterization of Dunaliella microalgal biomass and extraction of carotenoids

This paper presents findings on the application of two fractionation protocols of Dunaliella microalgal biomass with the aim to separate and recover the lipid, pigment and protein fraction, leaving as “residue” the fraction that contains carbohydrates. The first protocol (LPC) is based on the initial extraction of lipids, followed by extraction of proteins, while in the second protocol (CLP), the pigments are first extracted followed by lipids extraction. With the LPC protocol the recovered lipid fraction was 34 and 32 wt%, while the recovered proteinic fraction was 46 and 50 wt% for the two samples under study, i.e. 1120 (D. granulata) and 1220 (D. minutissima). The CLP protocol led to the initial extraction of the pigment fraction with a percentage of 10–15 wt% while the subsequently recovered lipidic fraction was 16–24 wt%. The initial biomass was characterized for its moisture (<0.7 wt% for both samples), ash (approx. 45 wt% for both samples), organic matter, elemental composition and higher heating value (HHV) which was 23 and 30 MJ/kg (organic matter based-OMB). The composition of the lipid fraction was analyzed via esterification and gas chromatography (GC-FID) showing C16 and C18 as the predominant acids in the samples. The residue/carbohydrate fraction was analyzed via acid hydrolysis and analysis by high pressure liquid chromatography (HPLC) showing about 20 wt% (-OMB) content of carbohydrates. The high ash content of the biomass was found to be co-extracted during the fractionation protocols at a percentage of ≈49 % in the lipidic fraction and 45 % in the proteinic fraction. Furthermore, emphasis was given on pigment extraction and recovery using various solvents and quantification methods. Measurements of β-carotene, carotenoids, and chlorophyll content through UV and HPLC analyses is presented with chlorophyl and carotenoid content being ≈12 wt% and ≈9 wt% for samples 1120 and 1220 (-OMB). Additionally, a comparison between three solvents (THF, dichloromethane, acetone) was performed regarding their ability to extract the pigments from the microalgal biomass showing that acetone is capable of extracting pigments when concentration of the pigments is not high. The comparison of the HPLC with the UV method, suggested that UV spectroscopy is a reliable and rapid alternative for pigments determination, while HPLC enables identification and quantitative determination of specific pigments and chlorophyll species. The study provides insights for different fractionation protocols applied in two not yet fully studied Dunaliella species as well as the chlorophyl and carotenoid content.

Electrospun bio-polymeric nanofibrous membrane for membrane distillation desalination application

Polylactic acid (PLA) has been explored as a sustainable material for membrane distillation (MD) membranes using electrospinning for the first time. Adjusting the electrospinning parameters of PLA nanofiber, such as concentration, voltage, collector distance, humidity, and flow rate, resulted in uniformly distributed and smaller nanofibrous structures. Heat treatments were also performed to enhance the tackiness and fusibility of the fibers within the nanofibrous structure, optimizing the pore size, hydrophobicity, and surface roughness of the PLA membranes. The hierarchical structure of the PLA membranes improved the liquid entry pressure (LEP) and mechanical strength by 320 % and 230 %, respectively. The membrane characteristics were assessed in terms of porosity, pore size, surface roughness, and contact angle, which determined the impact of the wettability of the membrane under different conditions. The results showed that under certain constraints, PLA membranes could be effectively used in the air gap membrane distillation (AGMD) process, achieving a permeated flux of ~2 kg/m2h and a salt rejection of 99 %. However, PLA-based nanofibrous membranes are unsuitable for MD applications at feed temperatures above 60 °C and a flow rate of 60 LHP. This study provides a strong basis for developing and manufacturing eco-friendly bio-based nanofibers materials for desalinating saltwater.

Effect of tube bend angle on liquid propulsion system priming event pressures

Experimental work was performed to measure the priming event pressure transient levels in unrestricted liquid propulsion system tubing. An existing water hammer experimental setup was utilized, where system tubing diameter, length, and bend angle were examined. Experiments were performed under both atmospheric and low-pressure pre-test element conditions to understand any impact of tube bend angle on the mitigation of priming event pressure transients inside the liquid system. Experimental results showed pressure levels were influenced by a combination of tube diameter, length, and pre-test pressures; however, tube bend angle had minimal to no discernible change on the average peak pressure levels or rise times to peak pressure for all conditions examined.

Воздействие криогенных сред и струйного горения на эпоксидные интумесцентные композиции, предназначенные для защиты оборудования и строительных конструкций нефтегазового комплекса

The article discusses the studies of epoxy intumescent fire-protective coating of steel structures impacted by cryogenic media and jet fire, in accordance with the requirements of the methodology developed at the Orenburg branch of the Federal State Autonomous Educational Institution of Higher Education VNIIPO EMERCOM of Russia, and harmonized with the international standards ISO 22899-1:2021, ISO 20088-1:2016, and ISO 20088-3. The tests have been conducted with the epoxy fire- and cryogenic-protective intumescent composition «Plamkor-5» (produced by JSC Scientific and Production Holding «VMP», Yekaterinburg, Russia). According to the results of the test for resistance of a square-shaped sample with internal dimensions 1500×1500×500 mm and a central shelf made of 10 mm thick carbon steel coated with the fire-retardant composition «Plamkor-5» to cryogenic fluid spill, it has been established that the sample does not reach the critical temperature of minus 49 °C with an actual 22.37 mm dry layer thickness. The average sample temperature at the 60th minute of the test was minus 32.09 °C. The results of the test of a similar sample in order to determine the resistance of the fire-protective composition «Plamkor-5» to a jet fire with an actual 10,89 mm thickness of the protective dry layer have shown that the sample does not reach the critical temperature of 500 °С during 60-minute fire exposure, whereas the average temperature of the sample was only 37 % (184.84 ºС) of the temperature limit value. According to the results of the test for resistance of a steel column shape sample of I-section 25K2 coated with the fire-retardant composition «Plamkor-5» to spill under the pressure of the cryogenic liquid, it has been established that the sample does not reach the critical temperature of minus –49 °С with an actual 23.78 mm dry layer thickness, whereas the average temperature of the sample at the 60th minute of test was minus 48.38 °С. The obtained results are comparable with the effect of the best import analogs; therefore, «Plamkor-5»-based fire-protective coatings can be used for the design and development of fire protection of building structures, at the facilities of the oil and gas industry, in tunnel structures, and civil engineering.

Synthesis and gyromagnetic properties of highly-dense LiZnTi ferrite for microwave ferrite devices

LiZnTi ferrites with dense microstructure and excellent gyromagnetic properties are a critical class of materials for microwave ferrite devices. Many reported studies have demonstrated that grain refinement and good gyromagnetic properties is often contradictory. In this work, we have successfully prepared a highly-dense LiZnTi ferrite with small average grain size (<1.0μm) and good gyromagnetic properties by hot-pressure sintering (HPS) method. Interestingly, SEM images revealed that the hot-pressure sintering with zero holding time not only promoted densification of the LiZnTi ferrites, but also can realize their grain refinement, which effectively reduced porosity and improved gyromagnetic properties. Meanwhile, we found that the average grains size (GSave.) of the HPS950 sample is smaller than the TS950 and HPS900 samples due to the synergistic effect of applied pressure (zero holding time) and Bi2O3 liquid phase. Finally, a LiZnTi ferrite with uniform, dense grains (GSave. = 0.85 μm and ρr = 98.1 %) and good gyromagnetic properties (4πMs = 3859.6Gs and ΔH = 287.4 Oe) was obtained by hot-pressure sintering at ∼950 °C.

Eco-Friendly Superhydrophobic Modification of Low-Cost Multi-Layer Composite Mullite Base Tubular Ceramic Membrane for Water Desalination

This study aimed to investigate and develop a cost-effective and superhydrophobic ceramic membrane for direct contact membrane distillation (DCMD) applications. Two types of mullite-based composite membranes were prepared via extrusion and sintering techniques. To create a small and narrow pore diameter distribution on the membrane surface, the dip-coating technique with 1 µm alumina was employed. The hexadecyltrimethoxysilane eco-friendly grafting agent was adopted to modify low-cost multilayer mullite-based composite membranes, transforming them from hydrophilic to superhydrophobic. The prepared membranes were characterized via field emission scanning electron microscopy (FESEM), energy-dispersive spectrometry (EDS), Fourier Transform Infrared Spectroscopy (FT-IR), X-ray diffraction (XRD), liquid entire pressure (LEP), contact angle, atomic force microscopy (AFM), porosity, and membrane permeability. The results of the prepared membranes validate the appropriateness of the material for membrane distillation applications. The optimized membrane, with a contact angle of 160° and LEP = 1.5 bar, was tested under DCMD using a 3.5 wt.% sodium chloride (NaCl) synthetic solution and Persian Gulf seawater as a feed. Based on the acquired results, an average permeate flux of 3.15 kg/(m2·h) and salt rejection (R%) of 99.62% were found for the 3.5 wt.% NaCl solution. Moreover, seawater desalination showed an average permeate flux of 2.37 kg/(m2·h) and salt rejection of 99.81% for a 20-h test without any pore wetting. Membrane distillation with a hydrophobic membrane decreased the turbidity of seawater by 93.13%.

A new setup for measurements of absolute saturation vapor pressures using a dynamical method: Experimental concept and validation.

We describe a new experimental system for direct measurements of the absolute saturation vapor pressures of liquid or solid samples. The setup allows the isolation of the sample under steady conditions in an ultra-high vacuum chamber, where the measurement of the sample's vapor pressure as a function of its temperature can be performed in a range around room temperature and in a pressure range defined only by the applied absolute pressure sensor. We characterize the setup and illustrate its capability to measure saturation vapor pressures as well as enthalpies of evaporation around room temperature with explicit measurements on four liquid compounds (diethyl phthalate, 1-decanol, 1-heptanol, and 1-hexanol) for which accurate vapor pressures have previously been reported.

Surface modification for enhanced Anti‐Wetting properties of electrospun omniphobic membranes in membrane distillation

AbstractMembrane wetting caused by substances in the feed solution with low surface tension has posed serious issues for membrane distillation (MD). Omniphobic membranes could be helpful when dealing with this problem because they strongly repel liquids with a wide range of surface tensions. We fabricated electrospun omniphobic membranes containing PVDF‐TEOS‐PFDTMS, PVDF‐HFP‐TMOS‐PFDTMS, and PVDF‐HFP‐TEOS‐PFDTMS. All electrospun membranes have shown contact angles &gt;90°, but the electrospun membrane containing PVDF‐HFP‐TEOS‐PFDTMS has shown super repellence with a contact angle &gt;150° and maintains stable salt rejection and water flux in direct contact MD processes in the presence of sodium dodecyl sulfate surfactant (up to 0.3 mM). Furthermore, the morphology and crystallinity of the electrospun membranes were studied by scanning electron microscopy and Fourier‐transform infrared spectroscopy, and the percentage composition of elements was analyzed by x‐ray photoelectron spectroscopy. liquid entry pressure, mechanical strength, and the porosity of the electrospun omniphobic membranes were also studied.

VC ownership post‐IPO: When, why, and how do VCs exit?

AbstractWe examine the evolution of lead venture capital firm (VC) ownership after their portfolio companies (PCs) are publicly listed. We find that, on average, lead VCs retain their shares for three years post‐IPO. Higher liquidity pressure and better stock market performance lead to faster VC exits, while higher VC reputation, better VC monitoring, and higher quality PCs lead to slower exits. VCs mostly use sales in the open market, share distributions, and mergers and acquisitions to divest their shares. Higher liquidity pressure incentivizes VCs to use majority share distributions, while better stock market performance increases their preference for continuous sales.

Unraveling the multi-faceted role of Rosmarinus officinalis L. (rosemary) and diosmetin in managing gut motility

Ethnopharmacological relevanceRosmarinus officinalis L. (Rosemary) is a popular herb with reported effectiveness against diarrhea, anxiety and constipation, albeit with limited pharmacological evidence. Aim of the studyThe current study was aimed at evaluating the therapeutic potential, possible pharmacological mechanisms of action and active constituents of hydro-ethanolic extract of rosemary (Rs.Cr), as potential anti-diarrheal, laxative and anxiolytic agent. MethodRs.Cr was analyzed through reverse-phase high pressure liquid chromatography (RP-HPLC). Laxative, antidiarrheal, and anxiolytic activities were assessed using in vivo models. Spasmogenic and spasmolytic mechanisms were studied on isolated guinea pig ileum and rabbit jejunum tissues, respectively. Possible role of diosmetin, one of the active constituents of Rs.Cr was also evaluated. ResultsRP-HPLC analysis revealed presence of diosmetin, rutin and apigenin in Rs.Cr. Laxative effect was seen at low doses, which was partially reversed in atropinized mice. The spasmogenic mechanism was mediated by cholinergic and histaminergic receptors stimulation. At higher doses, antidiarrheal activity was evident, with reduction in gastrointestinal motility and secretions using charcoal meal and enteropooling assays, respectively. Rs.Cr also showed dose-dependent anxiolytic effect. The antispasmodic mechanisms were mediated by anti-muscarinic and K+ channel opening-like effect (predominant KATP-dependent). Diosmetin exhibited antidiarrheal and antispasmodic activities, but spasmogenic effect was not seen. ConclusionRosemary leaves have dual antidiarrheal and laxative effects, and as well as anxiolytic activity. In addition, the possible modulation of muscarinic and histaminergic receptors, and KATP channels show it as potential herb to be explored for irritable bowel syndrome. Diosmetin is possibly one of its constituents that contributes to its antidiarrheal activity.

Determination of Patulin in Apple Juice and Apple-Derived Products Using a Robotic Sample Preparation System and LC-APCI-MS/MS.

Patulin, a toxic mycotoxin, can contaminate apple-derived products. The FDA has established an action level of 50 ppb (ng/g) for patulin in apple juice and apple juice products. To effectively monitor this mycotoxin, there is a need for adequate analytical methods that can reliably and efficiently determine patulin levels. In this work, we developed an automated sample preparation workflow followed by liquid chromatography-atmospheric pressure chemical ionization tandem mass spectrometry (LC-APCI-MS/MS) detection to identify and quantify patulin in a single method, further expanding testing capabilities for monitoring patulin in foods compared to traditional optical methods. Using a robotic sample preparation system, apple juice, apple cider, apple puree, apple-based baby food, applesauce, fruit rolls, and fruit jam were fortified with 13C-patulin and extracted using dichloromethane (DCM) without human intervention, followed by an LC-APCI-MS/MS analysis in negative ionization mode. The method achieved a limit of quantification of 4.0 ng/g and linearity ranging from 2 to 1000 ng/mL (r2 > 0.99). Quantitation was performed with isotope dilution using 13C-patulin as an internal standard and solvent calibration standards. Average recoveries (relative standard deviations, RSD%) in seven spike matrices were 95% (9%) at 10 ng/g, 110% (5%) at 50 ng/g, 101% (7%) at 200 ng/g, and 104% (4%) at 1000 ng/g (n = 28). The ranges of within-matrix and between-matrix variability (RSD) were 3-8% and 4-9%, respectively. In incurred samples, the identity of patulin was further confirmed with a comparison of the information-dependent acquisition-enhanced product ion (IDA-EPI) MS/MS spectra to a reference standard. The metrological traceability of the patulin measurements in an incurred apple cider (21.1 ± 8.0 µg/g) and apple juice concentrate (56.6 ± 15.6 µg/g) was established using a certified reference material and calibration data to demonstrate data confidence intervals (k = 2, 95% confidence interval).

Prediction of liquid holdup and pressure drop in gas-liquid two-phase flow based on integrating mechanism analysis and data mining

Gas-liquid two-phase flow widely exists in gas transportation pipelines, and the prediction of liquid holdup and pressure drop is crucial for the safety and efficiency of pipelines. Due to the complexity of multiphase flow, the mechanism model is difficult to accurately and quickly predict the liquid holdup and pressure drop. Machine learning (ML) models have high accuracy, but the lack of physical meaning limits their application. In order to fully leverage the advantages of mechanism models and machine learning models, a new method using physically guided neural networks (PGNN) to predict pressure drop and liquid holdup is proposed. Based on the flow mechanism analysis of different flow patterns, the structure of PGNN is designed according to the calculation process of the mechanism model. Key physical intermediate variables such as shear stress and friction coefficient are added to the model as neurons. Physical constraints in gas-liquid two-phase flow are added to the loss function to give physical significance to neurons. 1390 publicly available experimental data are collected for model training and testing. Due to the uneven distribution of experimental data, the local outlier factor (LOF) algorithm is used to screen outlier of data. By comparing PGNN with other ML models, empirical models, and semi empirical models, it is proved that integrating mechanism into the ML model improves the accuracy and physical consistency. This research presents a fresh outlook on the investigation of the flow dynamics in gas-liquid two-phase systems.

Silicon Valley Bank Collapse: Causes &amp; Consequences

This paper discusses the concept of bank bankruptcy and highlights the recent failure of Silicon Valley Bank (SVB) as a significant case similar to the Lehman Brothers' collapse in 2008. Lehman's failure was attributed to the U.S. housing market collapse and internal risk management issues. SVB's failure, occurring in 2023, resulted from both internal factors (improper decisions, high-risk strategies, and poor financial management) and external factors (economic recession, Federal Reserve interest rate hikes, regulatory challenges, and changes in the tech industry). The bankruptcy of SVB has far-reaching economic impacts on depositors, borrowers, entrepreneurs, investors, and the banking industry. It triggers a crisis of confidence, liquidity pressure, and systemic risks. The Federal Reserve implements emergency measures to address the fallout, reflecting on regulatory approaches to mitigate threats to the banking system. The comparison with Lehman Brothers underscores similarities in improper development strategies, asset structures, risk management, and regulatory oversight, leading to systemic risks and undermining financial market confidence.

Feasibility of Different Methods for Separating n-Hexane and Ethanol

Conventional distillation methods cannot effectively separate the components of an azeotropic mixture since both phases have the same composition, thereby preventing further separation. Additional techniques such as pressure swing distillation or distillation with entrainers are often employed to overcome this limitation and achieve separation. The aim of this investigation was to select the most effective method for separating n-hexane and ethanol. The feasibility of three methods was analyzed: reduced pressure distillation, extractive distillation, and liquid–liquid extraction. The mutual solubility of n-hexane and prepared deep eutectic solvents (DESs) (nine hydrophilic: choline chloride with glycerol, ethylene glycol, or carboxylic acid (malic, citric, glycolic); tetramethylammonium chloride with glycolic acid; lactic acid with glycerol; K2CO3 with glycerol or ethylene glycol; two hydrophobic: menthol with decanoic or dodecanoic acid) was experimentally determined. Extraction experiments were conducted to test the solubility of DESs in the feed mixture. The effect of changing DES-to-feed mass ratio was further investigated with choline chloride–glycerol (1:2). The same DES and both hydrophobic DESs were able to increase the relative volatility and enhance the separation of ethanol and n-hexane. Based on the obtained results, extraction was selected as the most effective method for the separation of n-hexane and ethanol.

Finite element modeling of thermal‐hydro‐mechanical coupled processes in unsaturated freezing soils considering air‐water capillary pressure and cryosuction

AbstractThis paper presents a comprehensive computational model for analyzing thermo‐hydro‐mechanical coupled processes in unsaturated porous media under frost actions. The model employs the finite element method to simulate multiphase fluid flows, heat transfer, phase change, and deformation behaviors. A new soil freezing characteristic curve model is proposed to consider the suctions from air‐water capillary pressure and water‐ice cryosuction. A total pore pressure with components from liquid water pressure, air pressure, and ice pressure is used in the effective stress law. Vapor and dry air are considered miscible gases, utilizing the ideal gas law and Dalton's law. The governing equations encompass the linear momentum balance equation, the energy balance equation, and mass conservation equations for water species (ice, liquid, and vapor) and dry air. Weak forms are formulated based on primary variables of displacement, water pressure, air pressure, and temperature. The spatial discretization is achieved through the finite element method, while temporal discretization employs the fully implicit finite difference method, resulting in a system of fully coupled nonlinear equations. To verify the proposed computational model, a numerical implementation is developed and validated against a set of experimental data from the literature. The successful verification demonstrates the robustness of the model. A detailed discussion of the contributions from phase change strain and different sources of pore pressure is also addressed.