Preservation Of Organic Matter Research Articles

Sequence Stratigraphy Variation and Its Implication in Shale Oil Exploration: A Case Study of the Eocene Dongying Depression, Eastern China

Organic matter (OM) and carbonate are the important organic and inorganic components, respectively, in the shales of the upper fourth member of the Eocene Shahejie Formation, Dongying Depression, Eastern China. Their enrichment affects the hydrocarbon generation capacity and reservoir development of shales. The development mechanism of sequence stratigraphy and the influence of sequence stratigraphy on OM enrichment and carbonate deposition are investigated in this study. Based on the petrological, mineralogical, and geochemical analyses, a third-order sequence is recognized, including the lowstand systems tract (LST), transgressive systems tract (TST), and highstand systems tract (HST). The total organic carbon (TOC) content is 0.11–9.05 wt% (average 2.2 wt%), and the carbonate content is 3–95 wt% (average 51 wt%). Organic matter and carbonate are enriched in TST and gradually reduced in HST and LST. The decrease in the relative lake level in LST results in the deposition of abundant siltstone, leading to both poor OM preservation and carbonate precipitation. The rapid rise in the relative lake level in TST may be triggered by marine transgression, promoting OM enrichment in terms of both production and preservation. Seawater input brought abundant Ca2+ and Mg2+, which facilitated the precipitation of carbonates. The enrichment of OM and carbonate improves the capacity of hydrocarbon generation and reservoir performance of shales in the TST. The decrease in the relative lake level in HST causes a slight increase in the terrigenous clastic content, which, on the one hand, accelerates the sedimentation rate and OM deposition and, on the other hand, reduces carbonate precipitation. This study not only explains the differential distribution of OM and carbonate but also helps to improve the accuracy of the evaluation of shale oil sweet spots.

Onset of the Messinian Salinity Crisis: Sedimentological, petrographic and geochemical characterization of the pre-salt sediments from a new core (Caltanissetta Basin, Sicily)

The present study aims to reconstruct the environmental changes leading to the Messinian Salinity Crisis during the transition from the Tortonian-Messinian marine conditions to the Messinian evaporitic environments. The core 3AGN2S04, recently drilled in the Caltanissetta Basin (Sicily), was analyzed to reveal the petrographic, mineralogical and geochemical characteristics of the late Tortonian – early Messinian pre-salt sediments. In particular, the facies characterization of the carbonates and organic-rich shales of the Calcare di Base (CdB) member allowed to understand its significance in the paleoenvironmental evolution towards salt deposition and to the reconstruct the brecciation processes inside the CdB. The sedimentological and mineralogical analyzes revealed that core 3AGN2S04 consists of the inner shelf facies of the Tripoli Formation passing to the typical carbonate platform facies of the CdB. The local transition between the upper part of the Tripoli Formation and the CdB member indicates that stressful environmental conditions were constant in the central Mediterranean shelf zones during the late Messinian. The CdB carbonates indicate the occurrence of a carbonate platform characterized by peritidal environments rich in different microbial communities and evaporitic deposits, whereas the embedded organic-rich shales suggest a confined, low energy, anoxic and stratified saline system with high productivity and good preservation of organic matter. A complex set of syndiagenetic brecciation processes, interpreted as in situ brecciation, have profoundly marked the CdB deposits.

Inorganic geochemistry and hydrocarbon potential of the Voltaian Basin of Ghana, West Africa

Interest in hydrocarbon prospects of Neoproterozoic sedimentary basins is on the rise, globally. This follows significant oil and gas discoveries from these basins in Asia, North America, the Middle East, and North Africa. The Voltaian Basin of Ghana covers significant parts of the country and is largely accepted as a Neoproterozoic basin, however, unlike other Neoproterozoic basins, the Voltaian Basin has little information on its hydrocarbon prospects. The current study seeks to provide an insight into the hydrocarbon potential of the basin leveraging on the inorganic geochemistry of outcrop samples of shales obtained using the Inductive Coupled Plasma Mass Spectrometry (ICP-MS) analytical method. The paleoclimatic conditions were warm – humid and arid allowing for a weak to moderate weathering of the studied samples from Sr/Cu, and C-values, also with ICV values of >1 suggesting a probable single recycling event. The sedimentation rate was somewhat rapid in an oxic depositional environment, an inference from Ce/Tm and V/(V + Ni), V/Ni, Ni/Co, U/Th, Th/U, V/Cr values. Restricted conditions prevailed in the basin and appear to have favored primary organic matter production considering Ni/Al, and Cu/Al proxies. The organic matter preservation, however, appears not to have been favored in the oxic conditions. The proxies on paleoredox conditions, upwelling and sedimentation rate, terrestrial material input, and water depth all correlated positively with TOC, suggesting their positive effect on the TOC content on the Voltaian Basin of Ghana. Detrital material input did not necessarily affect the TOC content.

Fundamental controls on organic matter preservation in organic- and sulfur-rich hydrocarbon source rocks

Incorporation of reduced inorganic sulfur (S) into organic matter (OM) in euxinic environments is considered a vital route through which OM is preserved for millions of years. However, precipitation of iron sulfides is believed to compete with OM preservation via sulfurisation. High resolution geochemical, petrographic, and electron microprobe (EMPA) analyses were employed to better understand S controls on OM preservation with particular focus on iron sulfides precipitation in organic S-rich mudstones from the Kimmeridge Clay (KCF), Monterey (MF), and Whitby Mudstone [Grey Shale (GS) and Jet Rock (JR) Members] Formations. Analyses indicated that S in the KCF and MF is mostly bound to OM as shown by the relatively high abundance of organic sulfur compounds (OSCs) in their pyrolysates. The relatively low amounts of iron (Fe) in these mudstones permitted extensive reaction of S and OM to occur efficiently, promoting preservation of high amounts OM through sulfurisation. State-of-the-art EMPA imaging of total S and Fe indicated that the S was mainly bound to organics, supporting the geochemical analyses. In contrast, S in the GS and JR was predominantly sequestered as pyrite (FeS2) rather than organically bound, as indicated by the relatively low quantity/absence of OSCs in their pyrolysates, hence, preservation through sulfurisation was less significant in these settings. EMPA imaging of S in these mudstones shows discrete shapes ranging in geometry and size and in most cases correlated with Fe in the corresponding Fe EMPA images, confirming that the S exists in discrete authigenic FeS2. Overall, in line with previous research, this study indicates that preservation of OM through sulfurisation is an important pathway for sequestration of OM. However, an abundance of reactive Fe could hinder this process by preferentially reacting with reduced S, to form iron sulfides (mainly FeS2), thus impeding reactions between OM and S to occur efficiently.

Spatial distribution, compositional pattern and source apportionment of n-alkanes in surface sediments of the Bohai Sea, Yellow Sea, and East China Sea and implications of carbon sink

China's marginal seas (CMSs, including the Bohai Sea, Yellow Sea, East China Sea) are a significant sink for both terrestrial organic matter (OM) and marine OM, and they play an important role in the global biogeochemical carbon cycle. The spatial distribution and origin of organic matter based on n-alkanes in the surface sediments of CMSs and the implications of carbon sinks were comparatively analyzed. The n-alkane content in surface sediment from the Bohai Sea was higher than that of the Yellow Sea and the East China Sea. The spatial distribution trends of marine and terrestrial organic matter are obviously different in the surface sediments of China's marginal seas. The n-alkanes in the sediments of the Yellow Sea and the East China Sea were mainly derived from terrestrial higher plants, and land-based influence gradually decreased from the near shore to the open sea. Higher concentration of terrigenous OM are concentrated nearshore, especially near estuaries, such as the Yellow River Estuary, the Old Yellow River Estuary and the Yangtze River Estuary. The input of n-alkanes from woody plants in the Bohai Sea area was slightly higher than that of herbaceous plants, and the input of herbaceous plants in the Yellow Sea and East China Sea was slightly dominant. The distribution of marine organic matter is controlled by marine productivity and the sedimentary environment. Due to climate change, the decomposition and enrichment of organic matter also show the climate effect of carbon molecular combinations. As a semiclosed sea area, the Bohai Sea was beneficial to the growth and reproduction of marine phytoplankton. From the perspective of petroleum pollution, the Bohai Sea was the most serious, followed by the Yellow Sea, and the East China Sea was the lightest. The carbon burial amount of terrestrial organic matter accounts for approximately 7% of the terrestrial organic matter burial amount of global marginal sea sediments, indicating that China's marginal sea plays an important role in the global carbon cycle. The result provide a basis for further understanding the source pattern and burial preservation of sedimentary organic matter in this sea area.

Mineral Protection and Resource Limitations Combine to Explain Profile‐Scale Soil Carbon Persistence

AbstractThe fate of soil carbon (C) is largely controlled by microbial oxidation of organic matter (OM), which is constrained by a variety of mechanisms. OM association with soil minerals provides pronounced protection against microbial decomposition. However, factors such as climate, occlusion, and resource limitations also contribute to OM preservation. We explore the factors explaining C distribution and age within an upland rainforest soil in Hawaiʻi, a site with abundant preferential flow paths (PFPs) and high short‐range order (SRO) mineral content. We characterized lateral and vertical changes in ∆14C, SRO mineral content, C‐functional group chemistry, and microbial community composition to elucidate the contributions of multiple protection mechanisms to OM preservation. Consistent with our expectation, SRO mineral content and ∆14C were strongly correlated (R2 = 0.95), indicating strong mineral protection of OM throughout the profile. Surprisingly, distance from PFP was also a significant predictor of ∆14C and improved model fit, particularly in the shallow horizons (R2 = 0.97). Elevated C/N ratios, decreased microbial abundance, and greater SRO mineral content suggest nitrogen limitations and enhanced mineral protection constrain OM turnover with distance from PFPs in deep, subsurface mineral horizons. Steady microbial abundance, increasing putative anaerobe abundance, and changes in C‐functional group chemistry indicate oxygen limitations constrain OM turnover in the matrix of shallow mineral horizons. Given that oxygen and nutrient limitations contribute to OM preservation in this high SRO system—an exemplar of mineral protection—resource limitations may play an even more important role in OM preservation in other well‐structured soils.

Lateral changes of organic matter preservation in the lacustrine Qingshankou Formation (Cretaceous Songliao Basin, NE China): Evidence for basin segmentation

Organic matter-rich intervals in the Cretaceous succession of the large non-marine Songliao Basin in northeastern China (covered area ~ 87 × 103 km2), including the Turonian–Coniacian Qingshankou Formation (K2qn), offer unique records to study the role of global (e.g., climate, “limno-eustasy”) and regional (tectonics, basin geometry) controls on organic matter accumulation. A wealth of scientific papers concentrate on the vertical variations in organic matter (OM) preservation along the Southeastern Uplift of the basin, which hosts its most prolific source rock intervals. However, the corresponding K2qn interval in the Central Depression is less well studied, and no lateral correlation between both parts of the basin based on direct information from well logs and drill cores exists to date. Hence, the dominant influencing factors causing lateral changes organic-richness and source potential are not yet fully understood. Basin geometry effects in particular could not be evaluated in detail, as highly resolved seismic data is lacking for the transitional zone between the Southeastern Uplift and Central Depression. This paper uses Integrated Prediction Error Filter Analysis of wireline logs together with petrographical and geochemical data from drill cores of two key wells in the Central Depression and Southeastern Uplift areas for a detailed correlation of the K2qn1 interval and its three sub-units (Sq1 to Sq3). Bulk geochemical (e.g., total organic carbon vs. total sulphur), biomarker (ratios of pristane vs. phytane, dibenzothiophene vs. phenanthrene, and total steroid vs. hopanoid compounds; Gammacerane Index; abundance of 4-methylsteranes and C29 steranes), and petrographical (e.g., maceral composition; framboidal pyrite size) data to trace changes in the depositional conditions. All data sources support a higher degree of salinity stratification and more intense anoxia at the Southeastern Uplift compared to the Central Depression particularly during accumulation of the lowermost and most organic-rich Sq1 sub-unit. These observations indicate that two depocenters may have existed during times of Sq1 deposition, and that the pronounced basin separation inhibited marine incursions from the Southeastern Uplift to the Central Depression. During deposition of the overlying Sq2 and Sq3 sub-units, a low relative lake level and dry climatic conditions likely prevailed. The geochemical data suggest similar dysoxic brackish-fresh water conditions in both depocenters. Moreover, the well log correlation indicates that a gradually connected basin may have formed at this time, reducing the effects of two separate depocenters on sediment accumulation and organic matter preservation. Thus, this study provides the first direct evidence that apart from global factors, basin segmentation strongly controlled the distribution of organic matter-rich rocks within the Qingshankou Formation.

Mechanism of Organic Matter Accumulation in Black Shales of the Yuertusi Formation in the Tarim Basin: Insights From Paleoenvironmental Variation During the Early Cambrian

The paleoenvironment during the Early Cambrian is closely related to the accumulation mechanism of organic matter (OM) from the Lower Cambrian black shales. However, paleoenvironment remains a controversial issue. Here, we reported a lot of detailed data of sedimentary stratigraphy and geochemistry of the Lower Cambrian Yuertusi Formation in the Aksu area, Tarim Basin. The Yuertusi Formation from the Yutixi outcrop consists mainly of silicalite at the base, two sets of black shales, and crystalline dolostone. Based on the redox conditions traced by U/Th, V/Cr, Ni/Co, and V/Sc, the hydrothermal activity traced by Ce/Ce*, Cr/Zr, U/Th, Fe/Ti, and (Fe + Mn)/Ti ratios, as well as paleo-productivity traced by Ba, Cu, Rb/Sr, and other parameters, variations were observed in the depositional environments of the Yuertusi Formation: 1) the silicalite at the base was deposited under an euxinic condition and intense hydrothermal activity. Mo-U co-variation analysis revealed that the north margin of Tarim Basin belonged to the unrestricted marine during the Early Cambrian, 2) the lower black shales were deposited under an oxygen-poor condition and weak hydrothermal activity, and 3) the upper black shales were deposited under oxygen-poor, sub-oxic conditions and almost no hydrothermal activity. Although the hydrothermal activity improved paleo-productivity, the TOC values were low on the whole, which may be due to the intense hydrothermal activity that damaged the formation of source rocks. Comprehensive studies showed a gradually oxidizing environment and weakening paleo-productivity during the Yuertusi Formation deposited. The anoxic conditions were conducive to the preservation of OM, and the high-quality source rocks represented by the black shales of the Yuertusi Formation were formed, especially the first set of black shales. However, the enrichment of OM may be affected by the intense hydrothermal activity.

Carbon isotopic constraints on the degradation and sequestration of organic matter in river‐influenced marginal sea sediments

AbstractOrganic matter degradation and sequestration in marine sediments are important processes involved in carbon cycling in the ocean. Here, we present the results of carbon isotope (14C and 13C) and concentration measurements of sedimentary organic carbon (SOC), pore‐water dissolved organic carbon (DOC), and dissolved inorganic carbon (DIC) in sediments collected from the East China Sea, Yellow/Bohai Sea, and South China Sea. Our results indicated that selective degradation and preservation of organic matter occurred in these sediments, and marine‐derived young organic carbon degraded preferentially and rapidly, resulting in high concentrations of pore‐water DOC and DIC with distinct carbon isotopic signatures. The average 14C age of pore‐water DOC was thousands of years younger than that of SOC in the sediment, suggesting that DOC was newly produced and cycled much faster than SOC. Aged SOC was refractory and preserved in sediments. Using a dual‐isotope three‐end‐member model, the contributions of potential sources to SOC, DOC, and DIC were estimated. Marine‐derived biomass organic carbon contributed the most to DOC, and dissolution of biogenic carbonate contributed the most to DIC. Riverine inputs of pre‐aged soil and fossil organic carbon dominated the SOC pool. Our study demonstrated that marginal sea sediments are important sites of young DOC and DIC fluxes into the water column, thus acting as a major pathway for carbon and nutrient cycling in the ocean.

Trace fossil characterization during Termination V and MIS 11 at the western Mediterranean: Connection between surface conditions and deep environment

Trace fossil assemblages are studied at Ocean Discovery Program (ODP) Site 977 to characterize the response of the macrobenthic trace maker community to deep paleoenvironmental conditions during the Termination V (TV) and interglacial Marine Isotope Stage (MIS) 11 at the western Mediterranean Alboran Sea. An assemblage composed of Chondrites, Planolites, Scolicia, Thalassinoides and Zoophycos is identified, showing notable variations in ichnodiversity, abundance and Bioturbation Index, that were analyzed in detail. The integration of ichnological information with sediment color and high-resolution coccolithophore records from Site 977, evidenced that variations in macrobenthic trace maker community are primarily controlled by oxygen availability and surface organic productivity patterns. During TV, high surface organic productivity by intense Alboran Upwelling System enhanced the deep organic accumulation that, together with reduced deep-water removal, resulted in a decrease of bioturbation and the formation of an Organic Rich Layer. Moderate and stable surface production through MIS 11c reduced deep food availability, resulting in an oligotrophic and stable deep environment. This is reflected by relatively abundant trace fossils in lighter sediments. Intra-interglacial increase in surface organic production at ~405 ka is evidenced by increased organic matter preservation. Minor impact of western Mediterranean circulation on deep-water removal, but a plausible stronger control by Bernoulli aspiration intensities in the region, is, in overall, observed during these intervals. During the Heinrich-type (Ht) events 3 and 2, increased trace fossil diversity and ameliorated oxygenation is driven by limited surface organic production, but intense western Mediterranean deep-water circulation and enhanced regional deep-water removal.

Depositional and diagenetic constraints on the quality of shale‐gas reservoirs: A case study from the Late Palaeocene of the Potwar Basin (Pakistan, Eastern Tethys)

Unconventional shale‐gas reservoir assessment concurs numerous exploration challenges, often related to their complex lithology, which reflects secular changes in depositional environment(s) as well as spatially variable diagenetic overprinting. This study combines a range of methods (sedimentological, petrographical, CL‐microscopy, X‐ray diffraction, TOC (total organic carbon), TON (total organic nitrogen) and δ13Corg and δ15Norg stable isotopes) to address the controls of lithofacies, palaeo‐depositional environment(s) and diagenesis on the shale‐gas reservoir potential of the Late Palaeocene Patala Formation in the Potwar Basin of Pakistan. This formation records sediment accumulation in a shallow, mixed siliciclastic‐carbonate shelf environment. Sedimentological and X‐ray diffraction (XRD) analyses show that the formation is primarily composed of an alternation of carbonaceous, siliceous, calcareous and argillaceous mudstone lithofacies. Detrital assemblages, including grains of quartz, apatite, calcite, chlorite, as well as organic matter (OM) and clay minerals with auxiliary (authigenic) pyrite, dominate the formation. High terrigenous influx is represented by the abundance of siliciclastics and terrigenous OM. The δ13Corg and δ15Norg proxies reflect dysoxic to anoxic palaeo‐environmental conditions, which promoted preservation of mixed marine and terrigenous OM, a setting considered to be indicative for high shale‐gas potential. The organic‐rich siliceous and carbonaceous mudstone lithofacies are considered to be the most prospective intervals, while calcareous and argillaceous mudstones are considered least promising in terms of reservoir quality. Spatially variable eo‐, meso‐ and telo‐diagenetic features such as compaction, cementation, stylolitization, dissolution and re‐precipitation are superimposed upon the depositional fabric, which locally affected the reservoir quality of the Patala Formation. The results of this study strongly suggest that the organic‐ and quartz‐rich mudstone lithofacies constitute “sweet spots” whose occurrence in space and time may be traced to design a strategy for shale‐gas exploration in the Potwar Basin of Pakistan and in analogous settings elsewhere.

The Shahejie Formation in the Dongpu Depression, Bohai Bay Basin, China: Geochemical investigation of the origin, deposition and preservation of organic matter in a saline lacustrine environment during the Middle Eocene

The Eocene Shahejie Formation in the Bohai Bay, Eastern China is known to contain important petroleum source rocks. Here, a new, large set of geochemical, petrographical and mineralogical data obtained on 41 samples from 9 wells within the North Dongpu Depression is presented in order to investigate organic matter precursor material, thermal maturity as well as paleoenvironment during deposition of the Es3U, Es3L, Es3M and Es4U members within the Eocene Shahejie Formation. These shales and marlstones from the four sub-members show low to moderate TOC contents (up to 5%) with highest values in the Es3U member; quartz content is at about 10% and carbonate content is variable, partly reaching more than 40%. A range of different maturity parameters was determined indicating early mature to peak oil mature stages, and maturity increase with burial depth. Throughout, alginite is the predominant maceral, whereas both vitrinite and inertinite are rare. Hydrogen index values are highly variable, ranging from about 100 to 700. Distinctly different biomarker assemblages indicate variable depositional environments and organic matter inputs between the four intervals. The Eocene Shahejie shales and marlstones in the study area were deposited under episodic photic zone anoxia as revealed by the presence of aryl isoprenoids. Bottom water conditions were anoxic during most of the time, except for Es3M, as indicated by several parameters, e.g. low pristane/phytane ratios. In north Dongpu Depression Es4U displays a fairly uniform biomarker composition, which indicates relatively stable hypersaline lake conditions with a shallow chemocline based on the high Gammacerane Index > 0.6 and abundant aryl isoprenoids. Water salinity changed during deposition of Es3L according to variable C24 tetracyclic terpanes related parameters and evaporite minerals content. The aquatic algal organisms, i.e. haptophyte algae, diatoms and bryophytes which are reflected by abundant nC37–39 alkanes, a variable sterane pattern and other biomarkers, were flourishing during Es3L. Additionally, specific PAHs, i.e. retene, cadalene, fluoranthene, indeno[1,2,3-cd]pyrene and benzo[ghi]perylene also have been identified in small concentration in Es3L, which may be attributed to limited terrigenous organic matter input. Es3M was deposited in a normal lacustrine environment under rather low salinity conditions with substantial input of organic matter derived from algae. During Es3U, saline lake conditions were re-established accompanied by input of both algal and microbial organic matter, especially cyanobacteria as deduced from MMAs and 2α-MeHs, methanogens as deduced from abnormally abundant phytane, PMI, squalane, and methanotrophs from 3β-MeHs.

The formation of early Eocene organic-rich mudstone in the western Pearl River Mouth Basin, South China: Insight from paleoclimate and hydrothermal activity

Following the collapse of the Yanshanian orogenic belt, mantle magma uplift, crustal stretching and thinning, and multiperiod strong magmatic hydrothermal activities occurred during the Eocene in South China. As a complete early Eocene sedimentary record, the lacustrine organic-rich mudstone of the Wenchang Formation in the western Pearl River Mouth Basin (PRMB) provides an excellent opportunity to understand the early Eocene paleoclimate, paleoenvironment, and hydrothermal activities in southern China. By analyzing the organic petrology and geochemistry, the effects of paleoclimate and hydrothermal activity on organic matter (OM) accumulation in organic-rich mudstone in the early Eocene Wenchang Formation were revealed. The bulk geochemical analyses showed that these mudstones are characterized by high OM abundances (1.73–3.20 wt%), dominated by kerogen type II and in the early oil maturity window. Additionally, maceral analyses indicated that the OM sources were mainly lacustrine algae and terrestrial higher plants. The element ratios ((Fe + Mn)/Ti), rare earth element anomalies (δEu* and δCe*) and hydrothermal indicator discrimination diagrams (Zn-Ni-Co and (Cu + Ni + Co) × 10-Fe-Mn triangular plot, etc.) jointly revealed three episodes of hydrothermal activity during early Eocene Wenchang Formation deposition. Intense hydrothermal activity not only brought abundant nutrients and improved the primary productivity of the lake but also released reducing gas via hydrothermal eruption, which further aggravated the hypoxic bottom water conditions, thus promoting the accumulation and preservation of organic matter. In addition, the elemental ratios (Sr/Cu, Rb/Sr, and SiO2/Al2O3) indicated a warm paleoclimate in the early Eocene Wenchang Formation. In the period without hydrothermal activity, the humid paleoclimate promoted the prosperity of lake algae and peripheral terrestrial plants, and the high lake level provided excellent organic matter preservation conditions. Therefore, the warm and humid paleoclimate and intermittent hydrothermal activity jointly controlled the formation of lacustrine organic-rich mudstone in the early Eocene Wenchang Formation.

Petrological and organic geochemical characteristics of the Permian Lucaogou Formation in the Jimsar Sag, Junggar Basin, NW China: Implications on the relationship between hydrocarbon accumulation and volcanic-hydrothermal activities

The coupling relationship between volcanic-hydrothermal activities and hydrocarbon generation has been a common understanding in recent years. However, there is a lack of theoretical and practical guidance in the application hydrocarbon production. The fine-grained sedimentary rocks of the middle Permian Lucaogou Formation in the Jimsar Sag in the Junggar Basin, NW China, are critical source rocks and have been simplify regarded as a mudrocks for target for tight oil exploration. Recently studies show that rocks were deposited in an intracontinental lacustrine environment with multiple volcanic-hydrothermal activities. Their complex micro-scale lithological characteristics restrict the understanding and further exploration and development of tight oil. Hence, this study focuses on the detailed lithological and their organic geochemical characteristics of the Lucaogou Formation using microscopic thin-section observation, scanning electron microscopy, X-ray diffraction, Rock-Eval, saturated hydrocarbon chromatography and mass spectrometry. The following key conclusions were obtained. First, the massive mudrocks are sub-divided into lithofacies for hydrocarbon generation, including tuffaceous shale, calcareous shale and dolomitic shale, and, microinterval reservoirs, including dolostone and sedimentary tuff. Second, the origins of organic matter in Lucaogou Formation were mainly plankton, bacteria with minor of land plants. The depositional environment is high salinity and anoxic conditions. Materials derived from volcanic-hydrothermal activities, lacustrine precipitation, and terrestrial transportation mixed with various proportions to form this formation. Third, a mixture of carbonate minerals, felsic minerals and clay minerals is the best source rock, and the higher the mixture, the better. This research not only provides insight into the influence of volcanic-hydrothermal activities on lithology and organic matter enrichment, but also providing a potential scheme for the tight oil exploration and development in similar rifted geological settings. • A mixture lithology of carbonate minerals, felsic minerals and clay minerals is the best source rock. • The better the mixture of carbonate minerals, feldspar minerals and clay minerals, the better the quality of hydrocarbon source rock. • Volcanic-hydrothermal activities are favorable to the enrichment and preservation of organic matter. • The Lucaogou formation was formed in a high salinity and anoxic condition, and the biological source was mainly plankton.

Mechanisms for the anisotropic enrichment of organic matter in saline lake basin: A case study of the Early Eocene Dongpu Depression, eastern China

Organic-rich terrestrial shales, the most promising shale oil production layer, are widely distributed in major basins in China, and they are usually interbedded salt rocks. Understanding the role of salt rocks in the organic matter (OM) enrichment in shale sediments has important enlightenment for shale oil exploration. The shale of the third member of the Eocene Shahejie Formation (Es3 shales) in the Dongpu depression of the Bohai Bay Basin is dominated by clay minerals, with a non-negligible proportion of gypsum, anhydrite, and halite. They contain abundant OM with a mean total organic carbon content of 1.26 wt %. The development of salt rocks revealed the arid and transiently humid climate during the Es3 period and an evaporating environment with a shallow lake level at the Dongpu Ancient Lake Basin. OM enrichment was synthetically affected by the palaeoenvironment during the Es3 period. The paleolake with a paleosalinity as high as 23.43‰ was nutritious and promoted the prosperity of salt loving organisms causing high paleoproductivity. The Es3 shales were deposited under anoxic and dysoxic conditions in a deep lake, which provided good conditions for OM preservation. In addition, salt rocks itself are good caprocks to prevent the loss of shale oil. Under the dual guarantee of high productivity and good preservation conditions, OM is much enriched in the Es3 shales. OM enrichment was synthetically affected by the palaeoenvironment during the Es3 period. The horizontal difference of paleoclimate controlled the discrepancy of salinastones distribution, OM enrichment, paleosalinity, andpaleoproductivity in different saline surroundings of Dongpu Depression. The composite patterns of palaeoenvironmental variation affected the vertical anisotropic enrichment of OM. Seven stages were divided for the Es3 period to reflect the effects of vertical anisotropy on OM enrichment. Stages I, V, and, VII deposited thick salt under an arid climate and provided a good seal-capping and preservation condition for the OM enriched in stages II, III, IV, and VI. The shale reservoirs deposited in stages III and IV were favorable for shale oil exploration.

Sedimentology and Geochemistry of the Lower Permian Shanxi Formation Shan 23 Submember Transitional Shale, Eastern Ordos Basin, North China

Shanxi Formation Shan 23 Submember transitional shale in Eastern Ordos Basin is characterized by high TOC value, wide distribution, and large single-layer/cumulative thickness. In this study, based on section division of Shan 23 Submember, petrographic, mineralogical, and high-resolution geochemical analyses were integrated to reveal sedimentary environment, detrital influx, paleoclimate, paleosalinity, and paleoredox conditions. Results indicate that Shan 23 Submember is divided into four sections (Shan 23-1, Shan 23-2, Shan 23-3, and Shan 23-4). The upper part of the Shan 23-1 section is dominated by bay facies, which is characterized by high TOC value (2.75%–10.96%, avg. 6.98%), low detrital influx proxies (Zr, 97–527 ppm, avg. 310 ppm; Ti, 1985–7591 ppm, avg. 3938 ppm), relatively dry paleoclimate condition (CIA*, 41.96–92.58, avg. 75.55; Sr/Cu, 6.23–14.49, avg. 8.87), high paleosalinity proxies (Sr/Ba, 0.39–1.29, avg. 0.62), and relatively anoxic reduction condition (UEF, 0.83–3.00, avg. 1.67; MoEF, 3.95–27.00, avg. 15.56). By comparison, the other three sections are dominated by a combination of transitional facies, including barrier island, lagoon, tidal flat, and swamp. In this interval, shale is deposited in lagoon facies. The paleoclimate gradually tends to be warm and humid, which results in increasing the chemical weathering intensity. Meanwhile, the detrital influx increases, and the paleoredox condition tends to be oxic. The above conditions are not conducive to the preservation of organic matter in lagoon facies shale.

Contrasting Modes of Carbonate Precipitation in a Hypersaline Microbial Mat and Their Influence on Biomarker Preservation (Kiritimati, Central Pacific)

Microbial mats represented the earliest complex ecosystems on Earth, since fossil mineralized examples (i.e., microbialites) date back to the Archean Eon. Some microbialites contain putative remains of organic matter (OM), however the processes and pathways that lead to the preservation of OM within microbialite minerals are still poorly understood. Here, a multidisciplinary study is presented (including petrographic, mineralogical and organic geochemical analyses), focusing on a modern calcifying mat from a hypersaline lake in the Kiritimati atoll (Central Pacific). The results show that this mat has a complex history, with two main growth phases under hypersaline conditions, separated by an interruption caused by desiccation and/or freshening of the lake. The mineral precipitates of the mat are predominantly aragonitic and two contrasting precipitation modes are observed: the main growth phases of the mat were characterized by the slow formation of irregular micritic particles with micropeloidal textures and subspherical particles, linked to the degradation of the exopolymer (EPS) matrix of the mat; whereas the interruption period was characterized by the rapid development of a thin but laterally continuous crust composed of superposed fibrous aragonite botryoids that entombed their contemporaneous benthic microbial community. These two precipitation modes triggered different preservation pathways for the OM of the mat as the thin crust shows a particular lipid biomarker signature, different from that of other layers and the relatively rapid precipitation of the crust protecting the underlying lipids from degradation, causing them to show a preservation equivalent to that of a modern active microbial community, despite them being >1100 years old. Equivalent thin mineral crusts occur in other microbialite examples and, thus, this study highlights them as excellent targets for the search of well-preserved biomarker signatures in fossil microbialites. Nevertheless, the results of this work warn for extreme caution when interpreting complex microbialite biomarker signatures, advising combined petrographic, mineralogical and geochemical investigations for the different microbialite layers and mineral microfabrics.

The sedimentation, bioturbation and organic matter degradation as revealed by excess 230Th and 210Pb in the Cosmonaut Sea

Sedimentation and bioturbation (the activity of benthic organisms) play an important role in organic matter degradation. The excess 230Th and 210Pb in a sediment core were used to evaluate the sedimentation, bioturbation and organic degradation processes in the Cosmonaut Sea, East Antarctica. Our results show that the sedimentation rate estimated from excess 230Th through the Constant Flux (CF) and Constant Flux and Constant Sedimentation (CFCS) models has changed in the past 200 ka. The mass accumulation and the linear sedimentation rates vary from 0.36 to 0.76 kg m-2 ka-1 and from 0.6 to 1.3 mm ka-1, which are significantly lower than the rates in other Antarctic seas. The stage III (120–202 ka), which corresponds to Marine Isotope Stage (MIS) 6 (glacial period), had the lowest sedimentation rate, indicating less sediment input by sea ice expansion. The bioturbation coefficient estimated by excess 210Pb is as low as 0.023 ± 0.003 cm2 a-1, showing inactive benthic activities. The average C/N ratio of organic matter is 7.2 ± 0.4, which is close to that of fresh organic matter and lower than the typical value of deep-sea sediments, indicating that organic matter is less degraded. The degradation rates of organic carbon and organic nitrogen estimated by the bio-diffusion model are 0.61 ka-1 and 0.29 ka-1, respectively, which are significantly lower than previously reported values for Southern Ocean sites. Despite the low sedimentation rate, low rates of bioturbation and inefficient organic matter degradation are conducive to the preservation of organic matter in sediments of the Cosmonaut Sea.

Hydrocarbon source potential and paleodepositional environment of the (Devonian) Barreirinha formation on the south edge of the Amazonas basin border, Brazil

The present work aims to study the depositional paleoenvironment and the hydrocarbon source potential of the (Devonian) Barreirinha Formation, in the southern portion of the Amazonas basin. To accomplish this task, the geochemical parameters (total organic carbon, Rock-Eval pyrolysis, total sulfur and total nitrogen, whole oil hydrocarbons, and biomarkers) and palynofacies of 22 samples distributed in three outcrops are studied. Total organic carbon (TOC) values in the collected samples vary between 1.42% and 5.56%, indicating great variation in the production and preservation of organic matter. The sulfur content, ranging from 0.05 to 2.90%, indicates deposition in a marine environment. Rock-Eval pyrolysis parameters also reflect variations in the depositional conditions of this formation. The potential for hydrocarbon generation varies from low to excellent, noting that the samples that have the highest values of generation potential (S2) have higher TOC levels. This characteristic is justified by the good quality of the organic matter, since such samples have high hydrogen index (HI) values and low oxygen index (OI) values, indicating type I/II kerogen. The low free hydrocarbon (S1) values present in the samples (<0.5 mg HC/g rock) indicate immaturity, as shown by the Tmax (<440 °C) and by the production index (PI < 0.1). For total oil hydrocarbon chromatographic analysis, the largest contribution of algal organic matter is explicit for terrestrial-aquatic reasons (TAR <1). Furthermore, the pristane and phytane isoprenoid ratios (Pr/Phy) indicate differences between anoxic and oxic environments. Saturated biomarkers allow us to state that the organic matter present in the samples has a marine origin with terrestrial contributions and low thermal maturation. Palynofacies analysis shows that there is a predominance of amorphous organic matter (AOM), with a moderate amount of palynomorphs and subordinate amounts of phytoclasts. In the ternary diagram, these percentages allow us to infer that the depositional paleoenvironment was a distal platform with oxic-anoxic variation.

Sedimentary environment and organic matter enrichment of black mudstones from the upper Triassic Chang-7 member in the Ordos Basin, Northern China

The black mudstone of the Chang-7 Member is the most important source rock in the Ordos Basin. In order to understand the paleo-climate, weathering, redox conditions, salinity, water temperature, water depth, and primary productivity under which black mudstone of the Chang-7 Member was deposited, we have analyzed total organic carbon (TOC), rock pyrolysis parameters, major elements, and trace elements of 60 black mudstone samples from the Chang-7 Member of the Yanchang Formation in the Ordos Basin. Geochemical indicators such as TOC, volatile hydrocarbon and residual hydrocarbon (S1 + S2), hydrogen index (HI), chloroform asphalt “A”, maximum pyrolysis peak temperature (Tmax), Vitrinite reflectance (Ro), kerogen macerals, and other organic indicators, show that the kerogen type of the Chang-7 Member was type I–II1, the thermal evolution of organic matter was in the mature stage, and it has good hydrocarbon generation potential. The major and trace element characteristics, such as C-value, Sr/Cu, Rb/Sr and Mg/Ca ratios, chemical alteration index(CIA), Sr/Ba, B, Ga-B-Rb trace element triangle, B/Ga, 1000 × Rb/K2O, V/(V + Ni), pristane/phytane ratio (Pr/Ph), foraminiferal Mg/Ca, and Co values indicate that the sedimentary environment of the Chang-7 Member was semi-arid and semi-humid, with continental freshwater, a reductive sedimentary environment, and an average paleotemperature of 16 °C. Based on the analysis of Baxs and Ba/Al ratio, the Chang-7 Member has medium–high primary productivity, which together with the sedimentary environment, played an important role in the enrichment and preservation of organic matter.