Shale Gas Preservation Conditions Research Articles

A novel method for evaluating shale gas preservation conditions in an area on a regional scale

The Youjiang Basin is the main area of the Middle Devonian shale gas resources in southern China, with complex geological conditions, diverse stratigraphic structures, low level of exploration and limited hydrocarbon geological data. In this study, a method is proposed for evaluating the regional shale gas preservation conditions, by which it is easy to obtain information (using available data from regional geological maps) and to process data (processed by computer software). This method was applied to the evaluation of the preservation conditions of the Middle Devonian shale gas in the Youjiang Basin. Information extracted from geologic maps includes exposed stratum, magmatic rock distribution, stratigraphic occurrence and surface fracture distribution. Evaluation criteria for three indexes (stratigraphy index, dip angle index and fracture index) were established to classify the preservation conditions into five types from good to bad. Based on the calculated values of comprehensive index (CI), the comprehensive evaluation each area: 11621.23 km2 for CI of 0.7–1.0, 37162.67 km2 for CI of 0.5–0.7, 57784.43 km2 for CI of 0.3–0.5, 69303.77 km2 for CI of 0.1–0.3, and 69303.77 km2 for CI of 0.0–0.1, accounting for 3.19%, 10.19%, 15.84%, 18.99% and 51.80% of the whole area, respectively. These results are highly consistent with the actual exploration discoveries, showing that in the northern and central parts of the Guizhong Basin, the southern part of the Xidamingshan Uplift, and the northern part of the Qiannan Basin, there are large areas with good shale gas preservation conditions.

Contrasting fracturing and cementation timings during shale gas accumulation and preservation: An example from the Wufeng-Longmaxi shales in the Fuling shale gas field, Sichuan Basin, China

The marine shales in southern China are characterized by high thermal evolution and intensive deformation during multistage burial and uplift. Fracturing and cementation, associated with tectonic activity, diagenesis, hydrocarbon generation and migration processes, are widely and variably distributed in shale reservoirs experiencing different tectonic evolution. In this study, we utilized cross-cutting relationships, fluid inclusion microthermometry, and laser Raman spectroscopy of fluid inclusions, along with U-Pb dating of fracture-filling calcite veins, integrated with burial history modeling, to elucidate the timing and mechanism of fracturing in the Paleozoic Wufeng-Longmaxi shale reservoir, as well as regional variations in the Fuling shale gas field. Bedding-parallel fractures (BFs) in shale reservoirs are filled with calcite and quartz veins. The timing of fracturing, as determined by minimum homogenization temperatures and U-Pb dating, is estimated to have occurred during ca. 191 -122 Ma, during which some short vertical (or high-angle) fractures (VFs) opened around 163.4 Ma and 137 Ma, subsequently sealed by calcite veins, respectively. All calcite and quartz veins within these fractures contain high-density methane inclusions, while shale reservoirs were in a high-over-mature evolutionary stage. This suggests that fracturing was primarily driven by gas generation overpressure during deep burial. In shale reservoirs near fault belt folds, multistage fractures developed, including three stages of intersecting fractures (IFs) and one-stage of long VFs. The timing of fracturing and cementation corresponds to the Yanshanian tectonic uplift (ca. 83 - 69 Ma) with intense tectonic movement likely being the direct cause of fracture opening. The presence of abundant gas inclusions in veins recorded shale gas expulsion during rapid tectonic uplift, reflecting the destruction of shale gas preservation conditions. In contrast, no significant fracturing or cementation processes have been observed in the tectonically gentle zones. The different fracturing and cementation processes indicated that preservation conditions declined with increased fracture openings during uplift, correlating with the gas enrichment.

The effect of structural preservation conditions on pore structure of marine shale reservoir: a case study of the Wufeng-Longmaxi Formation shale, Southern Sichuan Basin, China

The marine shale within the Sichuan Basin constitutes China’s significant shale gas production, featuring old formation age, high degree of thermal evolution, multiple tectonic movements, and complex structural conditions. However, there are significant differences in the shale gas preservation conditions and reservoir quality in different areas, limiting future large-scale exploration and development. Pore structure significantly influences shale reservoir quality, gas content, and exploration of shale gas occurrence, migration, and enrichment mechanisms. The influence of structural-dominated preservation conditions on shale pore structures is essential to comprehend for effective shale gas exploitation. This study employs field-emission scanning electron microscopy in conjunction with other techniques (low-temperature N2 adsorption, low-temperature CO2 adsorption, and nuclear magnetic resonance) for detailed analyses of the pore structure across varied structural zones, revealing the influence of structural attributes, fault systems, depth of burial, and formation pressure on pore architecture, and examining the relationship between pore structure and shale gas preservation conditions. The results show that stable structural condition is conducive to the development and preservation of shale pores. Structural compression causes inorganic and organic pores to become narrow and elongated due to shrinkage, with a significant increase in microfractures. The porosity of shale with stable structural conditions exhibits markedly increased porosity compared to samples under structural compressions. Under conditions of similar TOC and mineral composition, the pore size distribution (PSD), pore volume (PV), and specific surface area (SSA) of shale after structural compression are significantly lower than those of samples with stable structural conditions. As the burial depth increases, the shale porosity shows a decreasing trend, but the decrease is limited. Burial depth significantly impacts the SSA and PV of high-TOC samples (3%–6%). As the burial depth increases, both SSA and PV show a significant decreasing trend. When the burial depth reaches 4000 m, SSA and PV tend to concentrate. The formation pressure coefficient is an important factor for the development and preservation of shale pores, and porosity is positively correlated with the formation pressure coefficient. Increased formation pressure coefficient indicates superior preservation conditions and enhanced pore development.

Implications of multi-stage deformation on the differential preservation of Lower Paleozoic shale gas in tectonically complex regions: New structural and kinematic constraints from the Upper Yangtze Platform, South China

The strength of tectonic deformation in tectonically complex regions, particularly multi-stage superimposed tectonic regions, can have a significant impact on shale gas preservation conditions. However, differential tectonic deformation has still not been quantitatively constrained, and its impact on the preservation conditions of shale gas is thus poorly understood in the northern Guizhou Province, southwest China. This study investigates the differential preservation conditions of marine shale gas in four eroded synclines (including Shixi, Daozhen, Zhongguan, and Fuyan Synclines) of the northern Guizhou Province. Interpretation of structures in field outcrops, geometry and kinematic analysis, and typical gas reservoir anatomy are combined to quantitatively explore the effect of superimposed deformation on the preservation conditions of shale gas. According to a set of new structural and kinematic constraints, the Riedel shear model for strike-slip faults is firstly conducted in the eroded synclines in the northern Guizhou Province, which innovatively established a linkage between detailed structural analysis and evaluation of shale-gas preservation conditions. We demonstrate that superimposing of deformations plays a role in differential accumulation in eroded synclines. The results indicate that (1) fault strike in the Shixi Syncline is more concentrated than Zhongguan and Fuyan Synclines, whereas fault strikes in the Zhongguan and Fuyan Synclines are more scattered. There is only one direction of maximum principal stress (σ1) in the Shixi and Daozhen Synclines. There are two maximum principal stress directions (σ1) in the Zhongguan and Fuyan Synclines. The Zhongguan and the Fuyan Synclines have tensional environments, whereas the Shixi and the Daozhen Syncline have compressional settings; (2) the formation dip angle, distance to a class II fracture, average detachment layer thickness, intensity of superimposed modifications, and interlimb angle may be positively correlated with gas content; (3) the progressive transformation pattern is established. These findings lay the foundation for the future research on the differential preservation mechanism of eroded synclines and may be useful for enhancing research on worldwide strike-slip faults controlling hydrocarbon accumulation.

Quantifying the Widths of Fault Damage Zones Based on the Fault Likelihood: A Case Study of Faults in the Fuji Syncline of the Luzhou Block, Sichuan Basin, China

Faults are critical to the preservation or destruction of shale gas concentration. The Lower Silurian Longmaxi Formation in the southern Sichuan Basin hosts relatively developed faults, which pose a huge challenge to the exploration and exploitation of shale gas. An urgent need to quickly determine the widths of fault damage zones (FDZs) arises in locating horizontal shale gas wells. In this study, FDZs were estimated using the fault likelihood. The results are as follows: (1) It is rational to constrain the FDZ width using a fault likelihood greater than 0.2. The six major NEE-trending faults in the Fuji syncline of the Luzhou block have complex structures and varying FDZ widths from about 240–1220 m. (2) The degree of influence of FDZs is negatively correlated with their distance from the faults. In other words, a greater distance from a fault is associated with a weaker influence and a smaller fault likelihood. (3) Based on the ratio of the fault throw to the FDZ width, we propose that the width of seismic-scale fault damages can be directly constrained using a ratio value of 3.5. This method is fast and accurate and can provide support for the evaluation of the shale gas preservation conditions and well placement in the Longmaxi Formation of the southern Sichuan Basin.

Carbon isotope evidence for shale gas preservation conditions and large methane release over million years: A case study of shale gas reservoirs of Wufeng and Longmaxi Formations in the Sichuan Basin

Although carbon isotope reversal and its reasons in shale gas reservoirs have been widely recognized, the application of the reversal is yet to be investigated. A study on high-maturity shale from Wufeng and Longmaxi Formations in the Sichuan Basin not only reveals the relationship between the degree of isotopes inversion and the production capacity (e.g., estimated ultimate recovery (EUR)) of the gas well but also indicates the preservation conditions of shale gas reservoirs. (1) Although there are differences in gas isotopes in different shale gas reservoirs, the isotope fractionation of shale gas is small during the production stage of gas wells, even when the wellbore pressure drops to zero. The main cause of the difference in carbon isotopes and their inversion degree can be the uplift time during the Yanshan period and the formation pressure relief degree of shale gas reservoirs in distinct structural positions. Thus, carbon isotope inversion is a good indicator of shale gas preservation condition and EUR of shale gas wells. (2) The degree of carbon isotope inversion correlates strongly with shale gas content and EUR. The calculation formula of shale-gas recoverable reserves was established using Δδ13C (δC1-δC2) and EUR. (3) The gas loss rate and total loss amount can be estimated using the dynamic reserves and isotopic difference values of gas wells in various shale gas fields, which also reflects the current methane loss, thereby demonstrating great potential for evaluating global methane loss in shales.

Structural deformation characteristics and its influence on shale gas preservation of the Wufeng−Longmaxi Formation in the Wuxi area, Chongqing, China

The Upper Ordovician Wufeng to Lower Silurian Longmaxi Formation has a good material basis for marine shale gas development, and the structural preservation condition is the key factor to control the rich and integrated shale gas reservoirs in the Wuxi area of Chongqing City, China. Based on the seismic-structural interpretation data, combined with the regional structural background and drilling effect, the structural deformation characteristics and shale gas structural preservation conditions are comprehensively analyzed in the study area. The Wuxi area is located at the structural junction of the Sichuan Basin and southern Dabashan along with strong structural deformations. Seven rows of NW to near EW structural belts are mainly developed. The fold styles and fault development degrees of different structural belts are different, and the difference in the structural preservation conditions of shale gas is also obvious. The study results reveal that the shale gas structure preservation conditions of the Wufeng−Longmaxi Formation in the Wuxi area are overall poor and only locally better. The structure preservation conditions for shale gas enrichment and accumulation are divided into four grades, such as the good Class I area, the general Class II area, the poor Class III area, and the very poor Class IV area. Among them, the Heiloumen structural zone and Huangcaoping buried structural zone nearby the Sichuan Basin have good preservation conditions and are classified as the good Class I preservation area. The macroscopic preservation type of shale gas in the Wufeng−Longmaxi Formation of the Wuxi area belongs to the complex structural preservation of the basin margin. Three structural preservation modes of shale gas in the study area have also been confirmed, including the lost destruction type, lost residual type, and trap preservation type. The trap preservation type is more conducive to the preservation of shale gas, which is the most favorable structural mode for shale gas exploration.

A Technique to Determine the Breakthrough Pressure of Shale Gas Reservoir by Low-Field Nuclear Magnetic Resonance

The porous and low-permeability characteristics of a shale gas reservoir determine its high gas storage efficiency, which is manifested in the extremely high breakthrough pressure of shale. Therefore, the accurate calculation of breakthrough pressure is of great significance to the study of shale gas preservation conditions. Based on a systematic analysis of a low-field NMR experiment on marine shales of the Longmaxi Formation in the Sichuan Basin, a shale gas breakthrough pressure determination technique different from conventional methods is proposed. The conventional methods have low calculation accuracy and are a tedious and time-consuming process, while low-field NMR technique is less time-consuming and of high accuracy. Firstly, the NMR T2 spectrum of shale core sample in different states is measured through low-field NMR experiment. The NMR T2 spectra of sample in water-saturated state and dry state are combined to model the mathematical relationship between shale gas breakthrough pressure and NMR T2 spectrum. It is found that the gas breakthrough pressure is power-exponentially related to the geometric mean of NMR T2 spectrum and positively related to the proportion of micropores. Accordingly, the shale gas breakthrough pressure is quickly and accurately calculated using continuous NMR logging data and then the sealing capacity of the shale caprocks is evaluated, providing basic parameters for analyzing unconventional hydrocarbon accumulation, preservation and migration. This technique has been successfully applied with actual data to evaluate the sealing capacity of shale caprock in a shale gas well in the Sichuan Basin. It can provide a good basis for the evaluation and characterization of shale oil and gas reservoirs.

Simulation of tectonic stress field and prediction of tectonic fracture distribution in Longmaxi Formation in Lintanchang area of eastern Sichuan Basin

Shale is a low-porosity and low-permeability reservoir, and structural fractures are the main controlling factor for the migration and accumulation of shale gas. Moreover, tectonic fractures are controlled by the paleo-tectonic stress field. In this paper, taking the Longmaxi Formation of the Lintanchang area as an example, the finite element numerical simulation technology is used to analyze the distribution law of the paleo-tectonic stress field, and further, the fracture development areas under the superposition of two periods of tectonic stress are predicted using seismic, rock mechanics, and field data. The results show that the tectonic fractures developed in the Lintanchang area are mainly EW- and NNW-striking conjugate shear fractures formed in the Mid-Yanshanian period, followed by the NWW- and SWW-striking conjugate shear fractures formed in the late Yanshanian period. The distribution of tectonic fractures is affected by faults, folds, rock physical parameters and tectonic stresses. It is found that the comprehensive fracture coefficients of the anticline core and fault areas are both greater than 1.1, which are the areas with the most developed structural fractures, and these areas have poor shale gas preservation conditions. However, the comprehensive fracture coefficients of the western flanks of the anticline and the eastern and western dipping ends are between 1.0 and 1.1, which are areas with better shale gas preservation conditions. In addition, the development degree of tectonic fractures in the east and northwest areas of the Lintanchang anticline is lower than that in other areas. The comprehensive fracture coefficients of shale in these areas are between 0.9 and 1.0. The shale is in a state of “breaking without cracking”, and shale gas can be well preserved.

Complicated Fault Characterization and Its Influence on Shale Gas Preservation in the Southern Margin of the Sichuan Basin, China

Abstract The southern margin of the Sichuan Basin is characterized by strong structural deformation, complex fault structure styles and scales, and multistaged geological evolution stages, which together have created various shale gas preservation conditions. Taking Jianwu (JW)–Luochang (LC)–Shuanglong (SL) synclines as an example, the fault development characteristics and structural styles of the Longmaxi Formation were studied based on fine seismic interpretation and microscopic tests (rock acoustic emission experiments and fracture-filling inclusion tests), and the effects of the fault stage, fault class and scale, and fracture development degree on shale gas preservation conditions were analysed. Basement-involved faults, detachment faults, and intraformational microfaults are mainly developed from southeast to northwest. These fault structural types have affected the JW Syncline in the southeastern part, where faults are developed from the bottom of the Cambrian to the Wufeng–Longmaxi Formation and from the Wufeng–Longmaxi Formation to the Permian (Triassic). The SL-LC region in the northwestern part is dominated by the faults from the Wufeng–Longmaxi Formation to the Permian (Triassic). This region is dominated by NE-trending main control faults, supplemented by NW-trending, approximately EW-trending, SN-trending, and other small-scale regulating faults. Fault development can be divided into three stages, corresponding to the early, middle, and late Himalayan tectonic movements. In the early stage, a few small-scale approximately EW-trending faults had little impact on shale gas preservation. In the intermediate stage, the large number of large-scale NE-trending main control faults significantly impacted shale gas preservation. The JW Syncline mainly developed three types of faults with a high-filling degree, weak upwards penetration, and small-scale relevant fractures, which together created favourable conditions for shale gas preservation. The western and northern parts are dominated by I and II faults with large structural deformation, a low-filling degree, a large-scale, and strong penetration of related fractures, which have created unfavourable conditions for shale gas preservation. During the late stage, approximately SN- and NW-trending strike-slip reverse faults developed, and strong shear and fracture zones formed near the faults, producing unfavourable conditions for shale gas preservation. This research has clarified the characterization method of fault characteristics and stages and has established the influence of complex faults on shale gas preservation, which has an important reference value for the exploration and evaluation of shale gas reserves in complex tectonic regions.

Effects of Fracture Formation Stage on Shale Gas Preservation Conditions and Enrichment in Complex Structural Areas in the Southern Sichuan Basin, China

Fractures have significantly impacted the preservation, enrichment, and productivity of shale gas in the Longmaxi Formation in the complex structural area of the southern Sichuan Basin. Based on outcrop, core, imaging logging, inclusion analysis, acoustic emission experiments, and burial and thermal evolution history data, the formation stage, evolution and preservation conditions of structural fractures were comprehensively studied. Shear fractures are the main features of tectonic origin and are characterized by small widths, wide spacing, and high filling degrees. The structural fractures of the Longmaxi Formation can be divided into three groups in terms of their formation stage. The first-stage fractures were formed in the middle-late period of the Yanshanian tectonic movement (86.2–68.5 Ma), when the palaeotectonic stress was 68.33–71.82 MPa; and the homogenization temperature of the fluid inclusions in the corresponding fracture fillings is 150–178°C. The second-stage fractures were formed at the end of the Yanshanian -early Himalayan tectonic movement (68.5–35.2 Ma), when the palaeotectonic stress was 85.2–100.5 MPa; the homogenization temperature of the corresponding fluid inclusions is 123–148°C. The third-stage tectonic fractures formed during the middle-late period of the Himalayan tectonic movement (35.2–0 Ma), when the palaeotectonic stress was 55.6–63.8 MPa; fillings are scarce in these fractures, but the measured homogenization temperature of the corresponding fluid inclusions is 90–110°C. Shale gas preservation conditions were affected by the fracture formation stage, maximum horizontal crustal stress, fault scale, structural burial depth, formation pressure coefficient, etc. Three types of favourable preservation conditions were identified. The Type I target area is the low slope area in the middle of the syncline, which occurs more than 2.0 km from the fault. The research results have guiding significance for the evaluation of the preservation conditions of deep shale gas in the study area and similar areas.

Normal Pressure Shale Gas Preservation Conditions in the Transition Zone of the Southeast Basin Margin of Sichuan Basin

Shale in the Wufeng Formation of the upper Ordovician and Longmaxi Formation of lower Silurian in the Sichuan Basin and its surrounding area is widespread. Shale gas resources are abundant. Shale gas in the Wufeng Formation and the Longmaxi Formation in the basin has been a major breakthrough. The basin margin transition zone in southeastern Chongqing is in an intense tectonic activity area, which is more complicated and special than the stable stratum in the basin. Therefore, it is necessary to put forward higher requirements for preservation conditions and enrichment pattern evaluation of shale gas. Therefore, in view of the complicated structural pattern of the basin margin transition zone in southeastern Chongqing, the preservation conditions and reservoir forming patterns are analyzed through structural evolution, uplift and denudation, fault development, structural styles, roof and floor conditions, and formation pressure. The results show that the main reason for the formation of normal pressure is the late uplift, denudation and fault development. The pressure coefficient from the basin to the outer layer is changed from overpressure to normal pressure, and structural transformation forms the preservation form of shale gas with narrow and steep residual anticline, wide residual syncline and residual slope. The preservation condition evaluation of normal shale gas should be based on structural factors such as structural evolution, structural style, uplift and denudation degree and fault development degree, with formation pressure coefficient as reference condition, combined with material basic conditions such as roof and floor conditions and formation thickness. The findings of this study can help for better understanding of the “sweet spot” prediction of normal pressure shale gas in complex structural area.

Characteristics and Dominant Factors for Natural Fractures in Deep Shale Gas Reservoirs: A Case Study of the Wufeng-Longmaxi Formations in Luzhou Block, Southern China

Abstract In southern Sichuan Basin, the main production layers are characterized by deeply buried, high stress difference, and complex structural conditions. The Luzhou area is far from large faults, and natural fractures are greatly important for shale gas storage and production. Multi-scale natural fractures control the migration, enrichment, and preservation conditions of shale gas, and facilitate the formation of complex fracture network under the action of hydraulic fracturing. In this study, based on the outcrops, drilling cores, geochemical tests, thin section, and other experiments, the development characteristics of the Wufeng-Longmaxi shale in the Luzhou block, Southern China, are statistically analyzed, and the controlling factors (e.g., tectonic factors, organic matter, mineral components, mechanical properties) are discussed in details. Fractures observed in the outcrops are mainly regional fractures with two groups of orthogonal joints. Similarly, fractures observed in the core are also mainly joints fractures perpendicular to the laminae with three typical features (high-density, high-angle, and unfilled). In detail, steeply dipping fractures (75-90°) account for 78.1% of all fractures, with 85.1% being unfilled, 78.1% having a longitudinal extension less than 4 cm, and 65.1% having a spacing less than 2 cm. In brief, there exist cross-scale similarity among outcrops, cores, and microscopic thin sections, which is critical to the shale gas preservation conditions. Based on this understanding, further research is conducted on the relationship between the fracture density and gas content, which shows that (i) when the fracture density is less than 122 number/m, TOC content and fracture density together positively dominate gas content; (ii) when fracture density exceeds 122 number/m, gas content appears negative with fracture density, and TOC content is not the critical factor anymore. The above study establishes quantitative limits for shale gas preservation in the study block. It may assist in providing references for determining the sweet spot area and further deep shale gas exploration and development in the southern Sichuan Basin.

Structural Analysis and Evolution Model of the Longmaxi Formation in the Yanjin–Junlian Area of the Southern Sichuan Basin, China

The Longmaxi Formation in the southern Sichuan Basin is an important target for shale gas exploration and development. The characteristics and stages of structural development significantly impact shale gas preservation and enrichment. Taking the Longmaxi Formation in the Yanjin–Junlian area of the southern Sichuan Basin as an example and based on the results of surface and underground structural analysis, fluid inclusion tests, apatite fission track experiments, and burial-thermal evolution history analysis, a comprehensive study of the development characteristics and structural stages of the Longmaxi Formation was carried out, and an evolution model was developed. (1) The Longmaxi Formation of the Yanjin–Junlian area has been affected by multistage structural movements and exhibits structural compounding and superposition corresponding to different stages. The formation of surface tracks of the folds and faults has been affected by multidirectional extrusion stresses of the near SN, NE, and near EW. There are three stages of underground faults in the Longmaxi Formation, and the strikes are nearly EW, NE, and nearly SN. (2) Three distribution intervals for the homogenization temperature ranges of fracture fillings are 161–195°C, 121–143°C, and 74–105°C. The apatite thermal history simulation reveals that the Longmaxi Formation experienced three stages of tectonic movement after its formation. (3) There were clearly three stages in the structural development of the Longmaxi Formation in this area: the late Jurassic–Palaeocene (55 ± 5–38 ± 2 Ma), Eocene–early Miocene (38 ± 2–15.5 ± 3.5 Ma), and late Miocene-present (15.5 ± 3.5 Ma–present). Thus, a compound fracture system with superimposed structural deformations in different directions and at different stages formed in the study area. (4) A model for the stages and development of structural tracks in the Longmaxi Formation was established in conjunction with structural analysis and geomechanical theory. The results have guiding significance for the evaluation of shale gas preservation conditions and accumulation in the study area.

Shale gas preservation conditions of Lower Paleozoic Niutitang formation in southeastern Chongqing, China: Evidence from formation water and shale gas components

To quantitatively characterize the preservation conditions of shale gas in different wells, the formation water and gas composition characteristics of five wells (YC1, YY6, YY1, YK1, and QQ1) in southeastern Chongqing were analyzed. The formation water type of QQ1 and YK1 is CaCl2, and CY1 includes CaCl2 and NaHCO3 types. The CNa/Cl and Cd are low, while CCa/Mg and CCl/Mg are high, indicating that the retention degree of formation water is high. The formation water of YY6 and YY1 is NaHCO3 type, the CNa/Cl and Cd are high, while the CCa/Mg and CCl/Mg are low, indicating the strong connectivity of formation water. The N2 content of wells QQ1 and YK1 is below 32%, and 15N is between −7.33‰ and −1.98‰, the source of nitrogen is ammoniated in the process of organic matter pyrolysis and hydrocarbon generation, and the preservation conditions are relatively good. Therefore, the preservation conditions combined with the metamorphic degree of formation water and gas composition can be judged.

Composition of Formation Water and Natural Gas as an Indicator of Shale Gas Preservation Conditions: A Case Study of the Marine Shale of the Niutitang Formation in the Cengong Block in Northern Guizhou, China.

Shale gas (SG) wells in the Wufeng–Longmaxi Formation in northern Guizhou differ considerably in their production capacities. Preservation conditions are a crucial factor affecting the formation of SG reservoirs. In this study, the formation water (FW) in four wells in northern Guizhou was analyzed to determine the type; the Cl/Mg, Ca/Mg, and Na/Cl coefficients (CCl/Mg, CCa/Mg, and CNa/Cl, respectively), and the coefficient of desulfurization (Cd); the SG in these wells was tested to identify its composition and the sources of its components. The results show the following: wells TX1 and CY1 contain two types (CaCl2 and NaHCO3) of FW, each with low CNa/Cl, low Cd, high CCa/Mg, and high CCl/Mg, suggesting a high level of FW retention. The FW in wells TM1 and CD1 is of NaHCO3 type and is characterized by high CNa/Cl, high Cd, low CCa/Mg, and low CCl/Mg, indicating a high level of connectivity between the FW and surface water. Nonhydrocarbon gases account for a high proportion of SG in composition; with a 15N value between −8.7 and −4.2‰, N2 accounts for approximately 20% of SG in wells TX1 and CY1, respectively. This result indicates the ammonification of organic matter (OM) during pyrolysis and hydrocarbon generation as sources of N2. In contrast, with a 15N value between −3.6 and 0‰, N2 accounts for over 70% of SG in wells TM1 and CD1, respectively, indicating the atmosphere, the ammonification of OM, and the presence of poor preservation conditions due to a high level of connectivity between the shale bed and the atmosphere acted as the sources of N2. The metamorphism coefficients of FW in conjunction with the SG composition and the sources of nonhydrocarbon gases can serve as auxiliary indicators of the quality of SG preservation conditions.

Key geological factors for shale gas accumulation in the Wufeng–Longmaxi Fms in the central Yangtze area

The Upper Ordovician Wufeng Formation and the Lower Silurian Longmaxi Formation in the central Yangtze area of southern China has a good prospect of shale gas exploration. So far, however, its complicated geological conditions and shale gas exploration and development potentials have not been understood completely, which affects its exploration achievements. In order to determine the main factors controlling shale gas enrichment in the Wufeng–Longmaxi Fms in this area, this paper studied the key shale gas enrichment conditions in the black shale there (e.g. sedimentary environments, reservoir development characteristics and preservation conditions) based on single-well comprehensive reservoir evaluation, combined with drilling, logging, core, outcrop and test data. In addition, it was compared with the main shale gas blocks in the Sichuan Basin, such as Jiaoshiba and Changning. And the following research results are obtained. First, the organic-rich shale section in this area was formed during the sedimentation from Wufeng Formation to the third submember of the first member of Longmaxi Formation. It is the deposit of deepwater continental facies, and its thickness is in a range of 15–39 m, presenting a trend of increasing from south to north. Second, the reservoir rocks in the high-quality shale sections are dominated by siliceous shale, and the reservoir porosity is in a range of 1.60–7.44%. The reservoir spaces are dominated by organic pores with good connectivity and high total organic carbon (TOC) content. The organic matter is of a sapropel–sapropel prone hybrid type, with a high thermal evolution degree, better gas bearing property and good fracturability. Third, the Dangyang synclinorium is characterized by better strata preservation, rock occurrence flat, less developed faults and thick and stable roofs and floors, so its shale gas preservation conditions are better. Fourth, different from the Changning and Jiaoshiba Blocks, the central Yangtze area is characterized by great burial depth, large bidirectional stress difference, and low formation pressure coefficient. In conclusion, the Wufeng–Longmaxi Fms is better in shale gas enrichment conditions and has a potential of further exploration. However, its commercial shale gas development and scale production increase in the future face challenges due to its large stress difference, great burial depth, and lower pressure coefficient.

Relationship between geological structure and marine shale gas preservation conditions in the western Middle Yangtze Block

Lower Paleozoic dark shale is developed in the western Middle Yangtze Block, which lays a material foundation for the enrichment and accumulation of marine shale gas. In order to ascertain the control action of geological structures on the differential preservation of shale gas and reveal the key factors in shale gas preservation, this paper firstly analyzed the structure characteristics of this area, carried out structure pattern recognition and structural belt division, and studied structural deformation mode and intensity. Based on this, the relationships between different structure styles and shale gas preservation conditions were analyzed. Finally, combined with the structural deformation and the lithofacies paleogeographic characteristics of marine shale, the favorable exploration zones of shale gas were proposed. And the following research results were obtained. First, the western Middle Yangtze Block can be divided into four structural deformation belts, and three types of piggyback structural patterns have been identified, including restricted type, weakly reformed type and strongly reformed type. Second, the restricted type is located in the northwestern part of Hunan and Hubei Provinces. In this pattern, piggyback structure is incomplete and thrust belt and Compressive fold belt are developed. Third, the weakly and strongly reformed types are located in the western parts of Hunan and Hubei, and Wulingshan area, respectively. They both have complete piggyback structures, but the former has lower deformation intensity and has never undergone the late superimposed reformation. Fourth, there are three structural transfer belts in the western Middle Yangtze Block, i.e. the structural transfer belt between the East Sichuan fault–fold belt and West Hunan–Hubei fault–fold belt, the structural transfer belt between West Hunan–Hubei fault–fold belt and Wulingshan fault–fold belt, and the structural transfer belt between the outcrop and the hinterland of Middle Yangtze Block. The first one is structurally transformed at the Qiyueshan fault. The East Sichuan fault–fold belt on the west is an ejective fold with low fault density and formation denudation intensity, where shale gas is enriched in anticlines and slopes; while the West Hunan–Hubei fault–fold belt on the east is a trough-like fold with strong faulting and high formation denudation intensity, where shale gas is enriched in residual synclines. In conclusion, shale gas preservation conditions of Upper Ordovician Wufeng Formation–Lower Silurian Longmaxi Formation in this area are the best in Zigui syncline, thrust–detachment zone and western margin of Qiyueshan fault. The favorable exploration areas of shale gas of Lower Cambrian Niutitang Formation are distributed in the western flank of Yichang Slope, Kaixian thrust zone, compressive fold zone and thrust–detachment zone.

Quantitative evaluation of geological conditions for shale gas preservation based on vertical and lateral constraints in the Songkan area, Northern Guizhou, southern China

Organic rich Wufeng-Longmaxi shales (WLS) occur widely in the Upper Ordovician–Lower Silurian strata in southeastern Sichuan Basin, SW China. However, complex structural deformation and faulting activity in this area since the Mesozoic time has had significant impact on shale gas preservation. Thus, difference in the structural deformation strength is an important constraint for differential shale enrichment in a shale reservoir. Fracture analysis and bedding surface normal stress data obtained from the outcrop, core and fluid inclusion samples were used to determine the vertical and lateral constraints on shale gas preservation conditions. Using the finite element method, 2D mechanical models were established in the Songkan area, based on seismic inversion, rock mechanics and acoustic emission tests. Paleotectonic stress fields were estimated for the Middle Yanshanian (K11/K12), Late Yanshanian (K22/K23) and Himalayan （E-N）times. Fracture type distribution was determined from the rock failure criterion, and the shale bedding surface normal stress calculated by dip angle and burial depth. The results indicate that optimal conditions for shale gas preservation occur where the maximum principal stress values reach the fracture development stage (around 63.96–73.8 MPa). When the value increases to over 65 MPa, shale bedding surface closure favors the shale gas preservation. Based the vertical and lateral constraints, the best preservation area occurs where fracture development coincides with the shale bedding closure.

Influence of differential structural deformation on shale reservoirs: a case study of the lower Silurian Longmaxi Shale in north Guizhou, Southern China

AbstractSouthern China is affected by multi-stage tectonic activities, with strong fold deformation, complex fault systems and poor shale gas preservation conditions. Here, we used shale samples from the lower Silurian Longmaxi shale in the complex tectonic area of Southern China, to study the relationship between differential structural deformation, and pore structure and adsorption capacity. According to the deformation mechanism of the shale, it is further divided into brittle-slip rheological deformation (BD) and ductile-slip rheological deformation (DD). The results show that all micro-fractures can be observed under scanning electron microscopy in deformed shale samples, but in shale samples with different types of rheological deformation, the micro-fractures have large differences in scale, fracture length and lateral connectivity. The micro-fractures developed in DD shales are small in scale and short in fracture length, but have strong local connectivity. In contrast, brittle minerals are more developed in BD shales, and interlayer shearing has formed micro-fractures with large fracture length and good lateral connectivity, which is beneficial for later fracturing. In these two types of deformed shales, pores in organic matter are rare, and sporadic organic pores have small pore size and poor connectivity. The total pore volume (1.8–2.4 × 10−2 cm3 g–1) of BD shale samples is higher than that of DD shale samples (0.8–1.6 × 10−2 cm3 g–1). There is a positive correlation between total pore volume and quartz content. In addition, the specific surface area (12–18 m2 g–1) of DD shale samples is larger than that of BD shale samples (6–12 m2 g–1).