Changes in the morphology and structure of second phase particles, formed during isothermal ageing of rapidly quenched Al 6Ti 1.5Ni (wt.%) alloy at temperatures in the range 300–500°C, have been examined using a combination of conventional amplitude contrast imaging and electron microdiffraction. The precipitation-hardening response is initially attributable to a fine-scale distribution of coherent particles of metastable L1 2 phase and the orientation relationship between the metastable precipitate and α-aluminium matrix is such that (001) L1 2 //(001) α , [100] L1 2 //[100] α . During isothermal ageing, the metastable precipitates evolve with a transitional, three-dimensional cross-like morphology defined by three orthogonal sets of ellipsoidal elements forming in pairs. The precipitates comprise variants of a series of one-dimensional tetragonal superlattices that vary in structure from L1 2 to body-centred tetragonal D0 23; the c axis of the tetragonal cells is parallel to the major axis of each ellipsoidal segment and the orientation relationship is such that the principal axes of the ordered product superlattices are parallel to those of the matrix phase. The structural transformation from metastable L1 2 to equilibrium D0 22 phase, via an intermediate D0 23 structure can be modelled assuming aperiodic shear displacements of 1/2[110](001) within one-dimensional clusters of L1 2 unit cells, to create a range of one-dimensional tetragonal superlattices with differing c parameters.