Zinbiel algebras were introduced by a way of Koszul dual to Leibniz algebras and connected with commutative associate algebras, pre-Lie algebras and dendriform algebras etc. In this article, the centroids of Zinbiel algebra are discussed. We study the proprieties of centroids and also determinate the centroids of Zinbiel algebras up to dimension ≤4. As consequent, we get the conclusion that the centroids of 2-dimensional Zinbiel algebras are not small and 3,4-dimensional Zinbiel algebras are almost small.