Environmental energy harvesting technology has achieved great success in remote sensor power supply applications. However, existing technologies in the power grid neglect the potential of weak energy sources. This study aims to optimize the most reasonable array configurations and create hybrid energy fusion schemes for different weak energy environments. Taking thermal and electromagnetic energy harvesting from cable surfaces and currents in coaxial cables as an example, this paper introduces a genetic algorithm-based optimization method of harvester array configuration under multiple constraints and a dual-source energy fusion system. First, a vector impedance parameter identification method based on the equivalent circuit model of current transformer (CT) is proposed. Later, an optimization model for harvester array is established. Then, a genetic algorithm is used to optimize array combinations. And, a dual-source energy fusion system is proposed. Finally, thermal and electromagnetic energy harvesting and fusion are performed using 3 × 1 TEGs array and 6 × 1CT array. Under the specified conditions of a hot end temperature of 50 ℃ and an effective current value of 2 A, the power supply for the Zigbee wireless sensing system is realized to monitor the temperature of the cable core.