Output Power Density Research Articles

Extreme condition-tolerant stretchable flexible supercapacitor and triboelectric nanogenerator based on carrageenan-enhanced gel for energy storage, energy collection and self-powered sensing

As flexible electronics devices for energy storage, mechanical energy collection and self-powered sensing, stretchable flexible supercapacitor and triboelectric nanogenerator (TENG) have attracted extensive attention. However, it is difficult to satisfy the requirements of high safety and resistance to extreme conditions. Dual roles of mechanical and electrical enhancement of inorganic salt are put forward, and a carrageenan (CG) enhanced poly (N-hydroxyethyl acrylamide)/CG/lithium chloride/glycerol (PCLG) conductive gel is prepared by designing hydrogen bonding self-crosslinking and chain entanglement. A high concentration and rapid deposition strategy is proposed to prepare a PCLG gel-based stretchable flexible all-in-one supercapacitor for energy storage, and a single electrode PCLG gel-based TENG is designed for mechanical energy collection, self-powered strain and tactile sensing. The supercapacitor has high capacitance, excellent cycling stability. The TENG possesses efficient energy harvesting with high and stable output voltage and power density, and sensitive and stable self-powered strain and tactile sensing without external power supply. Even under extreme conditions such as low temperatures, self-healing after damage, prolonged placement, deformation, post-deformation, multiple continuous work, pinprick and burning, the supercapacitor and TENG still have excellent properties. Therefore, we provide novel ideas to design flexible supercapacitor and TENG used under extreme conditions for future wearable electronics.

Direct Current Triboelectric Nanogenerator Based on Contact Electrification, Air Breakdown, Electrostatic Induction, and Charge Leakage for Self‐powered Applications

AbstractDiverging from air breakdown‐based triboelectric nanogenerators (TENGs), recent TENG designs present high output power density without requiring precise control over discharge channels. However, existing researches predominantly ascribe its direct current output to electrostatic induction, disregarding the critical factor of charge leakage. This oversight hampers efforts to improve device performance, especially in material selection and optimization. Here, the generation of direct current signals ultimately stems from material charge leakage and spatial electrostatic induction is illustrated. Through theoretical analysis, visualization, and experimental measurement of four phenomena in the device, a quadruple‐effect mechanoelectrical conversion mechanism is established to refine the material selection rule. Under this guideline, the output power density is increased by 34.42% in contrast to the electrostatic induction direct current TENG. For practical applications, a power management circuit is utilized to boost the device's charging rate by up to 18 times. Furthermore, the high voltage of the device can activate discharge‐type UV tubes, demonstrating great potential in developing self‐powered wastewater treatment systems. The multiple charge behaviors proposed in this work, along with the material selection rule, lay a solid foundation for achieving high output power density in direct current TENGs.

Understanding of multiway heat extraction using peripheral diamond in an AlGaN/GaN high electron mobility transistor by electrothermal simulations

High-power operation of high electron mobility transistors (HEMTs) is limited due to a variety of thermal resistances in HEMT devices that cause self-heating effects (SHEs). To reduce SHEs, diamond heat spreaders integrated in the device have proven efficient in extracting heat from the device. In this report, we use electrothermal technology computer-aided design simulations to demonstrate a qualitative understanding of multiway heat extraction utilizing diamond heat spreaders to improve HEMT thermal performance at high DC output power densities (∼40 W mm−1). The impact of each heat extraction pathway is understood while considering the thermal boundary resistance between the diamond/GaN heterointerface and optimization of the GaN buffer layer thickness. Using these findings, we simulate an AlGaN/GaN HEMT device operating at 40 W mm−1 DC output power and demonstrate significant reduction in the temperature.

TRPM4-Inspired Polymeric Nanochannels with Preferential Cation Transport for High-Efficiency Salinity-Gradient Energy Conversion.

Biological ion channels exhibit switchable cation transport with ultrahigh selectivity for efficient energy conversion, such as Ca2+-activated TRPM4 channels tuned by cation-π interactions, but achieving an analogous highly selective function is challenging in artificial nanochannels. Here, we design a TRPM4-inspired cation-selective nanochannel (CN) assembled by two poly(ether sulfone)s, respectively, with sulfonate acid and indole moieties, which act as cation-selective activators to manage Na+/Cl- selectivity via ionic and cation-π interactions. The cation selectivity of CNs can be activated by Na+, and thereby the Na+ transference number significantly improves from 0.720 to 0.982 (Na+/Cl- selectivity ratio from 2.6 to 54.6) under a 50-fold salinity gradient, surpassing the K+ transference number (0.886) and Li+ transference number (0.900). The TRPM4-inspired nanochannel membrane enabled a maximum output power density of 5.7 W m-2 for salinity-gradient power harvesting. Moreover, a record energy conversion efficiency of up to 46.5% is provided, superior to most nanochannel membranes (below 30%). This work proposes a novel strategy to biomimetic nanochannels for highly selective cation transport and high-efficiency salinity-gradient energy conversion.

Optimization of baffle and tapering integration in the PEM fuel cell flow field employing artificial intelligence

In this study, two surrogate models are developed to investigate and enhance the performance of parallel flow field Proton Exchange Membrane Fuel Cells (PEMFCs) with two modifications. The main channels are tapered, and baffles are inserted to enhance the mass transfer. A data set is generated by the multi-phase, three-dimensional CFD model. Two different data-driven models based on Artificial Intelligence (AI) and Modified Response Surface Methodology (MRSM) provide surrogate models. Subsequently, two multi-objective optimization methods are employed to reveal the optimum case. The results show that the AI model achieves superior accuracy, whereas the MRSM model has greater simplicity. An increased number of baffles and an optimal tapering ratio contribute to higher mass flux and improved uniformity in reactant distribution. The insertion of baffles and the tapering of main channels result in a remarkable 67 % increase in output power density. Optimum tapering also reduces pressure drop, whereas baffles, while improving performance, contribute to increased pressure drop and potential PEMFC degradation. The identified optimum configuration of baffles and tapering, along with the optimum values for voltage, pressure, and anode and cathode stoichiometries, results in an impressive output power density of 0.93 W cm−2 and a parasitic power ratio of 0.17, respectively.

Recess-free enhancement-mode AlGaN/GaN RF HEMTs on Si substrate

Enhancement-mode (E-mode) GaN-on-Si radio-frequency (RF) high-electron-mobility transistors (HEMTs) were fabricated on an ultrathin-barrier (UTB) AlGaN (<6 nm)/GaN heterostructure featuring a naturally depleted 2-D electron gas (2DEG) channel. The fabricated E-mode HEMTs exhibit a relatively high threshold voltage (V TH) of +1.1 V with good uniformity. A maximum current/power gain cut-off frequency (f T/f MAX) of 31.3/99.6 GHz with a power added efficiency (PAE) of 52.47% and an output power density (P out) of 1.0 W/mm at 3.5 GHz were achieved on the fabricated E-mode HEMTs with 1-µm gate and Au-free ohmic contact.

Calcium-doped double perovskite PrBaFe2O5+δ as a high-performance cathode for solid oxide fuel cells

Fe-based double perovskites represent a significant category of cobalt-free materials and exhibit promise as cathodes for solid oxide fuel cells (SOFCs) because of their lower thermal expansivity and reduced cost. However, they often encounter challenges associated with poor oxygen reduction reactivity stemming from intrinsic low electronic and oxygen-ion conductivity. In this investigation, Ca was introduced as a dopant for the first time to improve the electrochemical properties of PrBaFe2O5+δ (PBFO). The findings unveiled effective adjustments in the formation of oxygen vacancy by introducing Ca into PBFO. Therefore, the oxygen adsorption, dissociation, and charge transfer processes were modulated considerably. At 800 °C, PrBa0.9Ca0.1Fe2O5+δ (PBCFO) exhibited a Rp of 0.027 Ω cm2, representing a 78.1 % reduction in comparison with PBFO. Concurrently, the output power density of the PBCFO increased by 17.3 %. These results underscore the potential of Ca doping to elevate the ORR kinetics and CO2 tolerance of PBFO.

Accelerating cell division of Shewanella oneidensis to promote extracellular electron transfer rate for efficient pollution treatment

The slow rate of extracellular electron transfer (EET) of electroactive microorganisms (EAMs) remains a predominate bottleneck that restricts practical applications of bio-electrochemical systems. Cell division has significant effects on cell cycle, morphology, growth and metabolism. However, the relation between cell division and the EET rate of Shewanella oneidensis has not been established. Here, we employed modular engineering strategy to accelerate DNA replication in the C period and divisome formation in the D period of cell cycle, which decreased cellular volume and enhanced the EET efficiency. Assembly of the C and D period modules further decreased the cell volume by 82.0 % and enhanced power density by 3.12-fold. Electrophysiological and transcriptomic analyses synergistically revealed that the programmed cell volume decrease facilitated lactate uptake and cellular metabolism due to the increased specific surface area (SSA), which consequently reinforced intracellular electron generation. Moreover, the reduced cell size facilitated electroactive biofilm formation. Finally, programmed increase in riboflavin biosynthesis and transport further strengthened indirect EET and boosted output power density to 1537.8 ± 116.9 mW m−2, 21.1-fold of that of the WT. The engineered strains exhibited superior abilities for Cr6+ reduction and azo dyes degradation. This study shed light on the underlying mechanism how reduced cell size impacts electrophysiology of EAMs, and indicated accelerating cell division is a promising avenue to increase the EET of EAMs for efficient environmental pollution treatment.

Enhancing Osmotic Energy Harvesting Through Supramolecular Design of Oxygen‐Functionalized MXene with Biomimetic Ion Channels

AbstractReverse electrodialysis (RED) technology, relying on ion‐selective permeability membranes (ISPM), offers a direct means of harnessing osmotic energy from the salinity difference between seawater and freshwater. Critical technical challenges include limitations in ISPM's immobile charge carriers, transmembrane ionic internal resistance, and durability in water. Drawing inspiration from the subunit structure of the epithelial sodium channel (ENaC), an ISPM assembled using a supramolecular engineering strategy is introduced. This innovative approach enables the synergistic action of multiple molecular building blocks to mimic the distribution of ENaC subunit structures, strategically planning the placement of immobile charge carriers on nanofluidic channels. The design incorporates nano‐confined oxygen‐rich functionalized MXene (O‐MXene) and high‐strength polymer backbone aramid fibers to construct 3D nanofluidic channels with a high surface charge density. Enhanced by a bonding network of sodium carboxymethylcellulose, the ISPM achieved an exceptional output power density of 21.7 W m−2 and 46.0% energy conversion efficiency in a RED half‐cell system using natural seawater and river water, surpassing current technologies. This research not only advances RED technology but also provides biomimetic customization concepts for ISPM design across various applications, including flow batteries, fuel cells, and related fields.

B4C/PVDF-based triboelectric nanogenerator: Achieving high wear-resistance and thermal conductivity

Triboelectric active composites that are built with high thermal conductivity and wear-resistance are of prime importance for the long-term operation of triboelectric nanogenerators (TENGs) in harsh environments. In this paper, it’s demonstrated that the introduction of B4C particles into poly(vinylidene fluoride) (PVDF) leads to a thermal conductivity of 0.727 W/(m·k), which is 600 % higher than that of pure PVDF film, and a significant reduction of 39.7 % in the average friction mass loss of the B4C/PVDF. Enhanced anti-corrosion and electrical output performance are also observed, including an open-circuit voltage of 155.4 V, a short-circuit current of 7.9 μA, as well as a maximum output power density of 0.33 W/m2, which are 2.6, 6, and 12 times higher than those of pure PVDF devices, respectively. Interestingly, such a performance grows steadily, rather than degrades, with the operation time, which is sharply differentiated from that observed from other common composites and may be partly ascribed to the roughened surface of the composite film. This work demonstrates an effective strategy for improving the wear resistance and thermal conductivity of the triboelectric material for high-performance energy harvesting and self-powered sensing that are based on BP-TENG for long-term operation.

Comparison of SiNx Dielectric Layer Grown by Plasma‐Enhanced Chemical Vapor Deposition, Low‐Pressure Chemical Vapor Deposition, and Metal‐Organic Chemical Vapor Deposition in Diamond‐ and GaN‐Based Integrated Devices

To address the issue of heat dissipation caused by the high output power density of gallium nitride (GaN) devices, using diamond‐integrated devices is an effective solution. Recent studies have suggested that incorporating a dielectric layer, such as silicon nitride (SiNx), between diamond and GaN can improve adhesion while also reducing thermal boundary resistance (TBR). In this study, plasma‐enhanced chemical vapor deposition (CVD), low‐pressure CVD, and metal‐organic CVD (MOCVD) techniques are utilized to grow the SiNx layer. The interface behavior of diamond/SiNx/GaN is analyzed through scanning electron microscopy, transmission electron microscopy (TEM), scanning TEM, and energy‐dispersive X‐ray spectroscopy, while time‐domain thermoreflectance measurement is used to characterize thermal properties. After analyzing the impact of the growth dielectric layer on the interface thermal resistance of the three growth modes, it is concluded that the dielectric layer produced by the MOCVD technique exhibits a smoother surface and lower TBR compared to the other two methods. Therefore, the use of the MOCVD technique is recommended to achieve optimal thermal performance in diamond/SiNx/GaN systems.

Highly electronegative borophene/PVDF composite hybrid nanofibers based triboelectric nanogenerator for self-powered sensor for human motion monitoring and energy harvesting from rain

In recent advancements in energy harvesting, triboelectric nanogenerators(TENG) have emerged as promising candidates for powering various sensors and small electronic devices autonomously. So, this work focuses on the development of a novel TENG utilizing borophene/PVDF hybrid nanofibers and Al as tribo-materials. Sono-chemically synthesized borophene and PVDF hybrid nanofibers are fabricated by electrospinning method. The formation of borophene/PVDF hybrid nanofibers is confirmed by different physiochemical characterization like Transmission Electron microscopy (TEM), X-Ray diffractometer (XRD), and Raman spectroscopy. The as-fabricated TENG is used as mechanical energy harvester to generate open circuit voltage (Voc) of 102.5 V and short circuit current (Isc) of 0.80 μA. Furthermore, the power density of the as-fabricated TENG is 0.08 W/m2 at an external resistance load of 200 MΩ. For practical applications, TENG is used to power small electronics like LED, watch, and calculator. Further, borophene/PVDF hybrid nanofibers is used to fabricate single electrode based TENG (SE-TENG) to harvest energy from the rain drops, which generates Voc of 13 V and Isc of 0.10 μA. Integrating energy harvesting from different medium represents a significant advancement, as it provides higher output power density. This approach holds great promise for enhancing energy conversion efficiency of TENG technology and for exploring its applications in healthcare and consumer electronics.

Tuning ZnO-based piezoelectric nanogenerator efficiency through n-ZnO/p-NiO bulk interfacing

ZnO based piezoelectric nanogenerators (PENG) hold immense potential for harvesting ambient vibrational mechanical energy into electrical energy, offering sustainable solutions in the field of self-powered sensors, wearable electronics, human–machine interactions etc. In this study, we have developed flexible ZnO-based PENGs by incorporating ZnO microparticles into PDMS matrix, with ZnO concentration ranging from 5 to 25 wt%. Among these, the PENG containing 15 wt% ZnO exhibited the best performance with an open-circuit output voltage/short-circuit current of ~ 42.4 V/2.4 µA. To further enhance the output performance of PENG, p-type NiO was interfaced with ZnO in a bulk hetero-junction geometry. The concentration of NiO was varied from 5 to 20 wt% with respect to ZnO and incorporated into the PDMS matrix to fabricate the PENGs. The PENG containing 10 wt% NiO exhibits the best performance with an open-circuit output voltage/short-circuit current of ~ 65 V/4.1 µA under loading conditions of 30 N and 4 Hz. The PENG exhibiting the best performance demonstrates a maximum instantaneous output power density ~ 37.9 µW/cm2 across a load resistance of 20 MΩ under loading conditions of 30 N and 4 Hz, with a power density per unit force and Hertz of about ~ 0.32 µW/cm2·N·Hz. The enhanced output performance of the PENG is attributed to the reduction in free electron concentration, which suppresses the internal screening effect of the piezopotential. To assess the practical utility of the optimized PENG, we tested the powering capability by charging various commercial capacitors and used the stored energy to illuminate 10 LEDs and to power a stopwatch displays. This work not only presents a straightforward, cost-effective, and scalable technique for enhancing the output performance of ZnO-based PENGs but also sheds light on its underlying mechanism.

A novel layered cobalt oxide Ba2Co9O14 as an efficient and durable bifunctional oxygen electrocatalyst for rechargeable zinc-air batteries

In this work, a layered cobalt oxide Ba2Co9O14 (BCO), belongs to a Ban+1ConO3n+3(Co8O8) family composed by alternating CdI2 based layers (Co8O8) with n (111) perovskite blocks (Ban+1ConO3n+3), has been developed as a potential bifunctional oxygen electrocatalyst candidate for efficient and durable rechargeable zinc-air battery (ZAB) application. Because of the greatly increased the specific surface area caused by ball-milling, the as-milled BCO material exhibits strongly enhanced bifunctional electrocatalytic activity towards oxygen reduction and oxygen evolution reaction in alkaline medium. Moreover, the assembled BCO-based ZAB yields an effectively improved maximum output power density of 166 mW cm−2, a considerable specific capacity of 789 mAh g−1, and excellent charge-discharge cycle stability of over 250 h at 10 mA cm−2 with over 1500 cycles.

Boron-doped reduced graphene oxide as an efficient cathode in microbial fuel cells for biological toxicity detection

Electrodes with superior stability and sensitivity are highly desirable in advancing the toxicity detection efficiency of microbial fuel cells (MFCs). Herein, boron-doped reduced graphene oxide (B-rGO) was synthesized and utilized as an efficient cathode candidate in an MFCs system for sensitive sodium dodecylbenzene sulfonate (SDBS) detection. Boron doping introduces additional defects and improves the dispersibility and oxygen permeability, thereby enhancing the oxygen reduction reaction (ORR) efficiency. The B-rGO-based cathode has demonstrated significantly improved output voltage and power density, marking improvements of 75 % and 58 % over their undoped counterparts, respectively. Furthermore, it also exhibited remarkable linear sensitivity to SDBS concentrations across a broad range (0.2–15 mg/L). Notably, the cathode maintained excellent stability within the test range and showed significant reversibility for SDBS concentrations between 0.2 and 3 mg/L. The highly sensitive and stable B-rGO-based cathode is inspiring for developing more practical and cost-effective toxicant sensing devices.

Supercapacitors and triboelectric nanogenerators based on electrodes of greener iron nanoparticles/carbon nanotubes composites

The development of supporting materials based on carbon nanotubes (CNTs) impregnated with iron nanoparticles via a sustainable and green synthesis employing plant extract of Punica granatum L. leaves was carried out for the iron nanoparticle modification and the following impregnation into the carbon nanotubes composites (CNT-Fe) that were also coated with polypyrrole (CNT-Fe + PPy) for use as electrode for supercapacitor and triboelectric nanogenerators. The electrochemical characterization of the materials by cyclic voltammetry (CV) and galvanostatic charge–discharge (GCD) assays revealed that the CNT-Fe + PPy gave rise to better performance due to the association of double-layer capacitance behavior of carbon derivative in association with the pseudocapacitance contribution of PPy resulting in an areal capacitance value 202 mF/ cm2 for the overall composite. In terms of the application of electrodes in triboelectric nanogenerators, the best performance for the composite of CNT-Fe + PPy was 60 V for output voltage and power density of 6 μW/cm2. The integrated system showed that the supercapacitors can be charged directly by the nanogenerator from 0 to 42 mV in 300 s. The successful green synthesis of iron nanoparticles on CNT and further PPy coating provides a feasible method for the design and synthesis of high-performance SCs and TENGs electrode materials. This work provides a systematic approach that moves the research front forward by generating data that underpins further research in self-powered electronic devices.

Photothermal conversion-enhanced thermoelectric generators combined with supercapacitors: An efficacious approach to integrated power generation and storage

Thermoelectric generators (TEGs), which harness and convert solar-thermal energy into electrical energy, possess immense potential within the field of photothermal conversion (PTC). However, the widespread adoption of conventional TEGs in PTC domain has encountered some obstacles, which represent that TEGs have poor inherent PTC performance, resulting in low solar-thermoelectric conversion efficiency, and this solar-thermal-electric conversion method lacks the capability of electrical energy storage. Hence, an urgent imperative exists to develop integrated and synergistic energy technologies that can respond to these underlying challenges. Herein, we reported a novel strategy for employing spinel-type Cu1.5Mn1.5O4 PTC coating to adorn conventional TEG to construct the solar-thermoelectric generator (STEG) which exhibited excellent solar-thermoelectric conversion capability, and then integrating the STEG in series with a supercapacitor composed of synthetic ionic liquid electrolytes and carbon electrodes to fulfill the conversion and storage of solar-thermal energy into electrical energy. The results indicated that, when compared to a conventional TEG, the STEG attained a drastically elevated internal temperature difference due to the excellent PTC capability of spinel-type coating. As a result, remarkable enhancements were observed in both the steady-state voltages (Voc) and maximum output power density (Pmax) of the STEG, exceeding a 6-fold and 40-fold increase, respectively. Furthermore, we conducted experimental validation to ascertain the viability of the solar-driven STEG to charge a supercapacitor, thereby achieving the conversion and storage of solar-thermal energy into electrical energy, and the working mechanism of this integrated system has been revealed. This study offers invaluable insights into the development of highly efficient solar-thermal energy conversion and storage methods.

Polyoxometalate-based plasmonic electron sponge membrane for nanofluidic osmotic energy conversion.

Nanofluidic membranes have demonstrated great potential in harvesting osmotic energy. However, the output power densities are usually hampered by insufficient membrane permselectivity. Herein, we design a polyoxometalates (POMs)-based nanofluidic plasmonic electron sponge membrane (PESM) for highly efficient osmotic energy conversion. Under light irradiation, hot electrons are generated on Au NPs surface and then transferred and stored in POMs electron sponges, while hot holes are consumed by water. The stored hot electrons in POMs increase the charge density and hydrophilicity of PESM, resulting in significantly improved permselectivity for high-performance osmotic energy conversion. In addition, the unique ionic current rectification (ICR) property of the prepared nanofluidic PESM inhibits ion concentration polarization effectively, which could further improve its permselectivity. Under light with 500-fold NaCl gradient, the maximum output power density of the prepared PESM reaches 70.4 W m-2, which is further enhanced even to 102.1 W m-2 by changing the ligand to P5W30. This work highlights the crucial roles of plasmonic electron sponge for tailoring the surface charge, modulating ion transport dynamics, and improving the performance of nanofluidic osmotic energy conversion.

Sodium alginate/carbon nanotube energy harvesting fibers: Axial functional group gradient and moist-electric performance

Moist-electric generation, a green and environmentally friendly energy harvesting technology, is undoubtedly one of the effective methods to alleviate energy shortages and environmental damage. However, the lack of fiber-like moist-electric generators (MEGs) that combine continuous power generation and high electrical output performance has constrained the development of moist-electric in the fields of flexible wearable and self-power supplies. In this work, sodium alginate (SA)/multi-walled carbon nanotubes (MWCNT) fibers with axial heterogeneous (axi-he) of oxygen-containing functional groups (Ocfgs) are prepared through a mold forming method in assistance with the coagulation process. The interaction between axi-he MEG and moisture is investigated by analyzing the electrical signal changes of dried MEG under moisture stimulation. The maximum output voltage and current of axi-he MEG can reach 0.35 V and 1.92 μA under the stimulation of moisture. Based on the regulation of Ocfgs, axi-he MEG has a continuous high moist-electric performance and environmental adaptability. The maximum output power density (Pmo) of axi-he MEG with a length of only 2 cm can reach 27.37 μW cm–2 at RH = 90 %, which exceeds most of the MEGs reported in literature. Meanwhile, a continuous output voltage of 0.33–0.37 V for more than 15 h can be obtained from this axi-he MEG. Thus, the axi-he MEG from Ocfg distribution design and mold forming method provides a new way of clean energy generation using moisture from the ambient environment, exhibiting enormous potential in energy supply for Internet of Things (IoT) devices.

High-performance piezoelectric energy harvesting in amorphous perovskite thin films deposited directly on a plastic substrate

Most reported thin-film piezoelectric energy harvesters have been based on cantilever-type crystalline ferroelectric oxide thin films deposited on rigid substrates, which utilize vibrational input sources. Herein, we introduce flexible amorphous thin-film energy harvesters based on perovskite CaCu3Ti4O12 (CCTO) thin films on a plastic substrate for highly competitive electromechanical energy harvesting. The room-temperature sputtering of CCTO thin films enable the use of plastic substrates to secure reliable flexibility, which has not been available thus far. Surprisingly, the resultant amorphous nature of the films results in an output voltage and power density of ~38.7 V and ~2.8 × 106 μW cm−3, respectively, which break the previously reported record for typical polycrystalline ferroelectric oxide thin-film cantilevers. The origin of this excellent electromechanical energy conversion is systematically explored as being related to the localized permanent dipoles of TiO6 octahedra and lowered dielectric constant in the amorphous state, depending on the stoichiometry and defect states. This is the leading example of a high-performance flexible piezoelectric energy harvester based on perovskite oxides not requiring a complex process for transferring films onto a plastic substrate.