In this paper, the intricate problem of optimizing power metering within an intelligent energy system, utilizing a multi-objective optimization decision-making algorithm, is thoroughly explored. Given the current energy landscape, achieving efficient energy utilization and environmental sustainability has become a focal point of research. As a pivotal aspect of future energy management, the precision and optimization of power metering in intelligent energy systems directly influence the effectiveness and cost of energy consumption. To begin, this paper delves into the fundamental principles and application backdrop of intelligent energy systems, highlighting the significance of power metering in such systems. Subsequently, addressing the multi-objective optimization challenges in power metering, a novel optimization method based on a multi-objective optimization decision algorithm is introduced. This algorithm achieves comprehensive optimization of power metering, encompassing multiple objectives such as power cost reduction, enhanced energy efficiency, and environmental protection. The experimental results underscore the remarkable performance of this algorithm, which not only elevates the precision of power metering but also achieves substantial savings in energy costs and significantly boosts energy efficiency. Furthermore, the algorithm exhibits robust adaptability, making it capable of addressing power metering optimization challenges across diverse scenarios. Finally, this paper discusses the practical application prospects of the optimization algorithm in intelligent energy systems, and points out the direction of future research. The research in this paper provides new ideas and methods for the optimization of power metering in intelligent energy systems, and has important theoretical and practical significance for promoting the intelligence and refinement of energy management.