Ferrite Powders Research Articles

Magnetic Properties of a Nickel–Zinc Ferrite Powder with Different Degrees of Dispersion

The influence of the degree of dispersion of a nickel–zinc ferrite powder of a Ni0.7Zn0.3Fe2O4 composition on its magnetic properties has been considered. The material has been synthesized using the ceramic technology with preliminary mechanical activation of precursors. The degree of dispersion has been varied using different modes of its dry grinding in a ball mill. The patterns of the changes in saturation magnetization and the coercive force as a function of grinding modes and a specific surface area of the ferrite powder have been established. The changes in the pattern of the magnetic phase transition in the region of the Curie temperature of materials with different degrees of dispersion have been determined.

Enhancing optical properties of Ba-Ni ferrite through nonmagnetic ion doping for sustainable green technologies and renewable energy applications

Barium ferrite powder was produced using a standard ceramic procedure, and its structure and optical properties were investigated. X-ray diffraction analysis (XRD) showed that the powder had a w-type hexagonal structure. The crystallite size was at approximately 35–36 nm, with bulk density and lattice constants increasing as zinc concentration rose. Conversely, X-ray density and porosity decreased with the increasing zinc concentration. This material has useful optical properties, as well as the standard ferrimagnetic properties of barium ferrite, which make it suitable for use in recording media. Ferrimagnetic behavior, which is useful for recording media, occurs because the powder's crystallites have their unit cell axes aligned. Up to the near-infrared part of the spectrum, the powder was found to have a very low absorption coefficient. Both of these properties—an arrangement that gives rise to ferrimagnetism and a corresponding low optical density—make barium ferrite very attractive for high-density recording and microwave applications. Fourier transform infrared spectra of the samples were recorded in the wavenumber range of 400–4000 cm−1 and supported the X-ray diffraction findings by confirming the idea of the formation of W-type hexagonal ferrite by the presence of two prominent peaks at 454 and 591 cm−1 in the FTIR spectra. Zinc addition was also found to enhance the optical properties of the material. The UV–VIS analysis confirms that the band gap energy of Ba-Ni ferrite was indeed reduced by zinc doping. Values decrease from 3.34 eV to 3.20 eV for direct transitions and from 2.96 eV to 2.79 eV for indirect transitions, using Tauc equation. That means that zinc doping enhances the optical properties of Ba ferrite without affecting the hexagonal structure of Ba-Ni ferrite. Moreover, key parameters of optical performance such as the dielectric constant, the extinction coefficient, the penetration depth, and the refractive index show a dramatic increase with a rise in zinc concentration. These attributes make zinc-doped Ba-Ni ferrite a promising optoelectronic material. The material also showed high absorbance in the wavelengths ranging from 334 to 338 nm, which makes it good for the solar cell applications. Overall, zinc-doped Ba-Ni ferrite is a good candidate for sustainable and renewable energy applications. Our study of the optical properties of barium ferrite up to the near-infrared part of the spectrum demonstrated that the powdered material has a very low absorption coefficient. Indeed, the combination of ferrimagnetism and low optical density makes barium ferrite particularly appealing for use in high-density recording and microwave technology applications.

Binder jet 3D printing of Mn–Zn ferrite soft magnet toroidal cores

Traditional powder processing methods for Mn–Zn ferrites limits design freedom and scalability of producing customized soft magnetic cores. In this work, binder jet 3D printing techniques were applied to commercially available Mn–Zn ferrite powders and toroidal cores were successfully fabricated. As-printed Mn–Zn ferrite powders were sintered at different temperatures between 1300 and 1400 °C, resulted in an optimized single-phase spinel at 1350 °C. Microstructural characterization revealed high porosity remained for binder jetted materials and various magnetic property measurements were performed on sintered cores. Despite high porosity, the saturation moments normalized by mass remained similar between binder jetted and traditionally compacted samples. Two-winding method measurements indicated a large demagnetizing field for binder jetted samples. Effective medium theory model was used to estimate the effect of remnant porosity on measured magnetic permeabilities. Importance of novel concepts to successfully realize dense cores through additive manufacturing pathways such as binder jetting is highlighted.

Durably Superhydrophobic Magnetic Cobalt Ferrites for Highly Efficient Oil-Water Separation and Fast Microplastic Removal.

Microplastic pollution has become a primary global concern in the 21st century. Recyclable magnetic particles with micro-nanostructures are considered an efficient and economical way to remove microplastics from water. In this study, superhydrophobic magnetic cobalt ferrite particles were prepared by using a simple coprecipitation method combined with surface functionalization. The micromorphology, chemical composition, hysteresis loop, and surface contact angle of the functionalized cobalt ferrite were characterized. The separation efficiency and absorption capacity of cobalt ferrite particles in water-oil separation and microplastic removal were investigated. The results showed that the saturation magnetic field intensity of cobalt ferrite was 65.52 emu/g, the residual magnetization intensity (Mr) was 18.79 emu/g, and the low coercivity was 799.83 Oe. Cobalt ferrites had stable superhydrophobicity in the pH range of 1-13. The separation efficiency of cobalt ferrite powder for four oil-water mixture separations was higher than 94.2%. The separation efficiency was as high as 99.6% in the separation of the hexane and water mixtures. Due to the synergistic effect of the hydrophobic effect and van der Waals force, the functionalized magnetic cobalt ferrite had a high and stable microplastic removal efficiency and capture capacity. The removal efficiency of microplastics was close to 100%, and the capture capacity was 2.56 g/g. After ten microplastic removal cycles, the removal efficiency reached more than 98%, and the surface contact angle was still greater than 150°.

Structural and electromagnetic properties of 3D printed and electron beam sintered lithium ferrite ceramic

In this work, the structures and electromagnetic properties of lithium ferrite ceramics manufactured by the additive method, based on the extrusion deposition of ferrite samples with a binder and their subsequent heating with high-energy electron beam, were studied. Preliminary synthesis of ferrite powder was carried out by a solid-phase method using iron oxide and lithium carbonate. To prepare ferrite paste, a binder based on ethylcellulose and terpineol was used. The printed samples were sintered by heating with 1.4 MeV electron beam using an ELV-6 accelerator. Using X-ray phase analysis, it was established that the sintered ceramic consists mainly of an ordered α−Li0.5Fe2.5O4 phase and a certain amount of disordered β−Li0.5Fe2.5O4 phase. Ferrite ceramics are characterized by a relative density of 72.6–92.1%, specific saturation magnetization of 63–65 emu/g, Curie temperature of 628–630 °C, electrical resistivity of 108–106 Ω cm, depending on the thickness of the printed sample (200 and 400 μm) and sintering temperature (1100 and 1200 °С).

The Effect of the Calcination Time on the Microstructure and Properties of MnZn Ferrite Powders

MnZn ferrite powders were prepared based on the novel nano in situ composite method and through chemical sol-spray drying–calcination technology. The precursor powders were calcined at 1060 °C at different calcination times (1–9 h) to research the influences of the calcination time on MnZn ferrite powders. The research results revealed that all samples had similar morphologies composed of fine particles. The pure MnZn ferrite spinel phase can only be obtained when the calcination time does not exceed 3 h. Otherwise, some α-Fe2O3 or γ-Fe2O3 impurities will appear. The particle size descended with an increasing calcination time and then ascended. After 3 h of preservation, the smallest particle size was obtained, and it exhibited a unimodal distribution. The saturation magnetization (Ms) increased at first and decreased later with an increasing calcination time, and the optimal value (53.4 emu/g) was reached after holding for 3 h. In view of this work, the optimal calcination time is 3 h.

Study of the magnetic and structural properties of BaFe12 – xCuxO19 ferrites obtained by hydrothermal synthesis

Hexagonal ferrites of M-type (in particular, BaFe12O19) are magnetic materials with functional characteristics affected both by chemical composition and technology of their synthesis. We present the results of studying the magnetic and structural properties of BaFe12 – xCuxO19 hexaferrites (x = 0, 0.1, 0.2, 0.3, 0.4) obtained by hydrothermal synthesis with partial substitution of copper for iron. The composition of the synthesized samples was analyzed using X-ray diffraction, and the magnetic characteristics were measured using a vibration magnetometer. It has been revealed that the coercivity of the ferrite powders depends non-monotonically on the copper concentration and reaches the maximum (5629 Oe) and minimum (4698 Oe) values at x = 0 and x = 0.2. The presence of copper reduces the coercive force, but at the same time the values remain rather high compared to the results of similar studies. The saturation magnetization of the obtained ferrites gradually decreases (from 65.88 to 60.75 A · m2/kg at x = 0 and x = 0.4, respectively) with increasing. The distribution of Cu over ferrite sublattices was studied using Mössbauer spectroscopy. It is shown that in the hexaferrite structure, copper ions preferentially occupy 12k and 4f1 sites. Hence, a decrease in the saturation magnetization with increasing x is most likely attributed to the presence of side non-magnetic phases observed on X-ray diffraction patterns. It is also revealed that during synthesis, copper participates in the formation of low-melting phases on the surface of hexaferrite grains which promotes agglomeration of the particles. Thus, the resulting powders can potentially be sintered at lower temperatures and, therefore, without a significant increase in the size of crystallites. Herewith, the coercivity retains its original high values. The results obtained can be used in developing ferrite permanent magnets with improved characteristics.

4D printing of the ferrite permanent magnet BaFe12O19 and its intelligent shape memory effect

4D printing of the barium ferrite permanent magnets provides new opportunities for intelligent structure and process innovation of permanent magnets. In this paper, the preparation, filament manufacture, and intelligent printing methods with shape memory/recovery effect are studied for the barium ferrite permanent magnet. Firstly, the PLA/TPU/BaFe12O19 composite materials are developed by adding different contents of ferrite permanent magnet BaFe12O19 powders into the PLA/TPU (polylactic acid/thermoplastic polyurethane) matrix. The weight percentage of the BaFe12O19 is 10–40 wt% with an interval of 10 wt%. Secondly, the composites are pelletized and further extruded to manufacture composite filaments with different BaFe12O19 contents. Scanning electron microscope (SEM) is used for the microstructural analysis. The BaFe12O19 particles are uniformly distributed in the PLA/TPU matrix, and the slight particle agglomeration phenomenon occurs in the composite filaments with 30 and 40 wt% BaFe12O19. The thermal properties of PLA/TPU/BaFe12O19 composite filaments are analyzed by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). After adding the barium ferrite particles, the glass transition temperature of the composite filaments changes within a small range from 53.5 °C to 55 °C. Thirdly, the filaments are successfully manufactured to magnet parts by the fused deposition modeling (FDM) 3D printing for the tests of mechanical, magnetic, and shape recovery properties. With the increase of the barium ferrite content, the magnetic properties show a rising trend, proving the feasibility of using 3D printing technology to make magnets. The shape memory effects of the printed parts are excellent and the shape recovery ratios show a rising trend, from 85.6 % to 88.9 % under heat contact stimulus and from 88.9 % to 97.8 % under electromagnetic induction non-contact stimulus. Relatively, the parts hold fast response speed due to direct contact with the heat source under the heat stimulus, and the parts hold higher shape recovery ratios due to more heats produced under the electromagnetic induction stimulus. The addition of magnetic particles is helpful to improve the heat transfer ability and provide the possibility of non-contact heat transfer. The magnetic parts with complex structure and intelligent shape memory/recovery effect can be achieved for special application requirements. As a result, the research of this paper expands preparation methods of new magnetic composite materials, explores the manufacture process for intelligent magnets and lays a solid foundation for the development of new permanent magnet devices.

Influence of synthesis methods on the structural, dielectric and magnetic properties of cobalt ferrites

A systematic study comprising structural, magnetic and dielectric properties of the cobalt ferrite (CoFe2O4) powders at first is carried out by way of synthesizing the materials using different preparatory methods, such as conventional solid-state method, wet chemical sol-gel autocombustion method using citric acid as well as glycine, separately as fuels. X-ray diffraction (XRD) studies reveal the formation of spinel phase with clear variations of peak intensities in all the samples. Morphology studies using scanning electron microscopy (SEM) reveal well grown grains in solid state synthesized sample compared to sol-gel autocombustion samples. The variations observed in the grain growth as well as densities (porosity) were attributed to typical temperature treatment conducted on the samples. Dielectric tests provide the evidence of space charge polarization in all the samples. Magnetic studies using vibrating sample magnetometry (VSM) provide the values of saturation magnetization and coercivity of the samples explored. The sol-gel autocombustion sample using glycine matrix (Cogly) shows higher saturation magnetization (Ms = 59.2 emu/gm) comparing to other samples whereas, sample with citric acid matrix results with lower Ms value as 36.5 emu/gm. The typical reasons for the observed variations in structural, microstructural, magnetic, dielectric and impedance properties of these materials were well addressed in terms of theoretical aspects and presented in this paper.

Tuning structural and electrical properties of Co-precipitated and Cu-incorporated nickel ferrite for energy applications

Abstract The Ni1−x Cu x Fe2O4 (where x = 0, 0.05, 0.10, 0.15) nano ferrite powder was synthesized through chemical co-precipitation method, NaOH and acid oleic as raw materials. The XRD patterns confirmed the spinal structure phase purity of materials. XRD results showed that lattice parameter decreases with the increase of copper concentration by increasing copper concentration in the parent material. Scanning electron microscopy (SEM) was used to determine the morphology and particle size. SEM analysis indicated that all the samples are in nano size and homogeneous. AC electrical properties of nanoparticles were investigated by employing impedance spectroscopy. The real and the imaginary parts of impedance, permittivity, modulus along with the real part of ac conductivity, and tan delta were measured and analyzed for all synthesized samples in 1 Hz to 7 MHz for different voltages at 300 K.

Influence of plasma synthesis parameters on the magnetic, structural and photocatalytic properties of copper ferrite

CuFe2O4 cubic copper ferrite nanoparticles were synthesized by a new plasma method, the advantage of which is the short duration of processing and cost-effectiveness. To select optimal synthesis conditions, central compositional rotatable experimental planning was used. Using the methods of X-ray phase analysis, vibration magnetometry, electron microscopy, and UV spectroscopy, the sizes of crystallites, the intensity of peaks in X-ray diffraction patterns, dislocation density, saturation magnetization, coercive force, and the degree of degradation of 4-nitrophenol were determined. To study the effect of pH on the composition of the resulting copper ferrites, cyclic voltammetry was used. The kinetics of the ferritization process under the influence of a plasma discharge has also been studied. A mechanism for ferritization in the Cu2+-Fe2+-SO42--OH- system has been proposed.It was found that single-phase nanodispersed powders of cubic copper ferrites with a saturation magnetization Ms 78–93 Emu/g can be obtained by plasma treatment at 300 s and pH 12. Copper ferrite with an admixture of Cu2O is formed at pH = 8.The maximum values of the coercive force correspond to regimes in which the minimum dislocation density is observed. The saturation magnetization depends on the crystallite size. The crystallite size of the resulting powders is in the range of 225–500 A. The results showed that the processing time is the parameter that has the greatest impact on the structural and magnetic characteristics of copper ferrite; the pH of the reaction medium affects them to a lesser extent.

Influence of calcination temperature and particle size distribution on the physical properties of SrFe12O19 and BaFe12O19 hexaferrite powders

The paper deals with the economic optimisation of ferrite powder preparation during producing hard ferrite magnets. The magnetic properties of ferrites are investigated by replacing feedstock and reducing calcination temperature and particles in the order of tens of microns. The granulates about 8–10 mm in size were calcined for 2 h in the temperature range from 1100 °C to 1300 °C and additionally crushed and milled to an average particle size of about 80–90 µm. The scanning electron microscopy images confirmed the agglomerates of particles with different shapes and sizes in tens of µm. The X-ray diffraction measurements revealed that, besides the SrFe12O19 and BaFe12O19 phases, there was also the presence of 2–39% hematite. The highest values of maximum energy product (BH)max = 930 J/m3 and remanent magnetic induction Br = 72.8 mT were obtained at a calcination temperature of 1300 °C. The Henkel plots confirmed the presence of exchange-coupling and dipolar magnetic interactions at lower and higher magnetic fields, respectively. The strength of interactions was also dependent on the calcination temperature. Replacing strontium with barium led to a deterioration of the magnetic parameters, which were optimal at a lower calcination temperature (1100 °C). This phenomenon was partly overcome by reducing the mean particle size of Ba-based hexaferrites to 45–50 µm.

Characterization of Some Functional Polymeric Composites in a Synergistic Regime of Protection at Electromagnetic Shielding and Electrostatic Transfer

The paper presents the characterization of 5 polymer composite materials with a poly-propylene (PP) matrix obtained with different (mass) concentrations of strontium ferrite (Fe12SrO19) reinforcement that have synergistic protective properties against electrostatic discharges (ESD) and electromagnetic impulses (EMI). These types of composites can be used to protect electronic equipment. To this purpose, suitable polymer composites were developed using SrFe12O19 type filler in two forms (powder and concentrate). The weight ratio of the PP/SrFe12O19 composites obtained by the extrusion process and injection from the melt is 75/25 and 70/30. The characterization of these composite materials consisted of carrying out some physico-chemical tests to determine the hydrostatic density and the resistance to the action of water, as well as FTIR, UV-Vis analyzes and dielectric, magnetic and functional tests to identify the simultaneous protection performance at electromagnetic shielding and electrostatic discharges, which can occur in the electro-technical, electronics and automotive industries. It is also found that all composite materials presented reflection shielding properties (SER) in the range: -71.5 dB...to -56.7 dB, indicating very low absorption shielding. The best performing material was the PP/SrFe12O19 powder composite with a weight ratio of 70/30. At the same time, EDS tests were also carried out on these materials. For these applications, the surface resistance Rs and the point-to-point resistance Rp were tested. Recommended composites for simultaneous EMI and sensitivity to electrostatic discharges (ESD) functionality, in order of their performance, are M2 (with 30% ferrite powder) and M1 (with 25% ferrite powder). M4 composite (with 30% ferrite powder concentrate) can also be used at the limit. Following the research carried out, the obtained results recommend the composite with promising simultaneous operations as M2 (with 30% ferrite powder). The element of originality consists of obtaining polymer composites with simultaneous properties of protection against electromagnetic impulses and electrostatic discharges.

Synthesis and structural, morphological, and chimico-optical properties of Sr2FeO4 Ruddlesden-Popper oxide

The citrate sol-gel process was used to produce Sr2FeO4 strontium ferrite powder. The method involves metallic nitrates, citric acid and distilled water as a solvent, followed by calcination. The Ruddlesden-Popper structure of the resulting compound was identified by XRD analysis. The different molecular structures and vibration bands were studied by FTIR. The morphology of the powder was analysed using SEM. Samples appear of good crystalline quality and with interesting nanostructure. We studied optical properties and determined the band gap energy to lie about 2.8 eV, Sr2FeO4 can thus absorb photons having a wavelength less than 444 nm, approximately, making this compound potentially interesting for applications.

Manufacturing and performances of MnZn ferrite cores with thin walls prepared by paste material extrusion 3D printing

The 3D printing technique using material extrusion of a paste filled with ferrite powder (Mn,Zn)Fe2O4 and organic additives has been successfully improved to produce sintered samples for studying their magnetic and structural properties. The rheological behaviour of the pastes and the printing parameters have been optimised to obtain parts with regular geometries, in particular by minimising sagging effect during filament deposition. Printing is followed by a debinding and sintering stage, for which the temperature and oxygen partial pressure conditions were adjusted. These conditions enable the densification of the (Mn,Zn)Fe2O4 material in the spinel structure without parasitic phases, with a low grain size dispersion and a relative density of 91 %. The core loss has been measured on the 3D printed samples to be 144 mW/cm3 at a frequency of 500 kHz and an induction of 50 mT. This performance is comparable to the nominal value of a part produced by the conventional process. This work paves the way for an advantageous manufacturing method in terms of accessible geometries, while maintaining satisfactory magnetic characteristics.

Investigating the adsorption of Malachite green and Methyl green onto synthesized Ni0.5Zn0.5Fe2O4 spinel ferrites

Nano-sized Ni0.5Zn0.5Fe2O4 spinel ferrites were synthesized at the nanoscale by the co-precipitation method via a sonochemical approach. High-intensity ultrasonic radiation treated the hydroxide suspension at 90 °C for 2 hours. Both the X-ray diffraction analysis (XRD) and the Fourier transform infrared spectra (FT-IR) analysis confirm the presence of the cubic spinel phase with a grain size of 15 – 25 nm. The vapor adsorption experiments confirmed that the pore surface area was found to be 95.34 m2/g by N2 adsorption desorption isotherm, and the material was mesoporous. The saturation magnetization of ferrite powders was investigated using a vibrating sample magnetometer (VSM). This work mainly focuses on the removal of Malachite green (MaG) and Methyl green (MG) with the help of adsorption technology from water using Ni0.5Zn0.5Fe2O4 spinel ferrites. The adsorption studies examined the impact of mass and pH, revealing that both factors influence adsorption. The optimum conditions for Malachite green and Methyl green adsorption onto the spinel Ni-Zn ferrites were 0.02 g for spinel mass, pH values (6−8). At 328 K, the maximum capacity for Ni0.5Zn0.5Fe2O4 spinel adsorbents was 82 and 180 mg/g MaG and MG, respectively. The removal efficiency for MaG and MG dye was respectively 95 % in 420 and 180 minutes. According to the kinetic studies, a pseudo-second-order model is the most suitable model for the adsorption process. The adsorption mechanism was examined by fitting the adsorption data to Langmuir, Freundlich, Radushkevich, and Temkin adsorption models. The Langmuir model can adequately describe results.

Enhanced room temperature ferromagnetism and versatile optical properties in MgFe2O4 spinel ferrite prepared under different calcination temperatures

This study employs the sol-gel auto combustion technique fueled by diethanolamine (DEA) to synthesize nanocrystalline magnesium ferrite (MgFe2O4) powders. During the study, X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), transmission electron microscopy (TEM), UV–visible diffuse reflectance spectroscopy (UV-DRS), photoluminescence spectroscopy (PL), and vibrating sample magnetometry (VSM) were then used in order to determine how differing calcination temperatures influence the structure, chemical bonding, surface texture, morphology, optical, fluorescence, and magnetic properties of the resulting MgFe2O4 powders. The findings from the XRD and FT-IR analysis indicate that a single-phase spinel structure is formed in each of the MgFe2O4 samples. According to UV-DRS analysis, optimal calcination improved sample reflection levels in comparison to the visible and infrared spectral findings for the as-synthesized sample. The calcined samples exhibited bandgap energy (Eg) ranging from 2.11 eV to 2.14 eV, which was greater than the 2.02 eV of the as-synthesized sample. Examination of the PL spectra in the range of 380–700 nm revealed various light emission bands for the samples, which increased significantly in intensity at higher calcination temperatures. Furthermore, higher calcination temperatures also increased the magnetization of the MgFe2O4 spinel powders, while coercivity dropped significantly.

Microwave-Assisted Hydrothermal Synthesis of Nanosheet Layered Hexagonal Spinel Ferrites for Efficient Electromagnetic Wave Absorbing.

A microwave-induced combustion method has been utilized to prepare nanosized powders of hexagonal spinel ferrites using urea and glycine as fuel. The structural and electromagnetic absorption of these products was investigated using X-ray diffraction (XRD). From the (3,1,1) and (1013) peaks in XRD measurements, it was seen that the samples we synthesized were nanosized spinel and y-phase hexagonal ferrite. In addition, Fourier-transform infrared measurements showed that the synthesized samples had high absorption values showing Fe-O, which is between 878 to 4000 cm-1, and metal-oxygen transitions, which are between the 700 and 2500-3000 cm-1 in the spinel and hexagonal phases. From the scanning electron microscope image of the particles, it is seen that they are homogeneous, filled structures with ∼35-40 nm. It appears from vector network analyzer measurements that the synthesized 1.5 mm thick composite materials have very high electromagnetic absorption properties and that these composites can also be used in electromagnetic interference, Wi-Fi applications, and health.

A remarkable permeability enhancement of Ni1−xZnxFe2O4 (x = 0.65 and 0.70), using a multi-compound calcined additive

In this study, entanglement of composition, additive and/or sintering conditions and their effects on magnetic properties of soft ferrites, nickel zinc spinel ferrites (Ni1−xZnxFe2O4, x = 0.65 and 0.70) which were prepared via conventional solid-state reaction method investigated. Also an equiponderant calcined mixture of Bi2O3, CaO, CeO2, SiO2, Al2O3, Y2O3 and nanotitania was mixed thoroughly and used as a multi-compound calcined additive (MCCA). Calcined ferrite powders were crushed, dry and wet milled, dried, mixed with different amounts of MCCA (0.0, 0.5, 1.0, 1.5 and 2.0 wt%), formed in toroidal shapes and finally sintered at different temperatures, from 1150 up to 1360 °C for 3 h. X-ray diffraction assessment confirmed formation of the single phase cubic spinel structures. Initial permeability and Q-factor spectra of the toroids were obtained from 0.1 to 1000 kHz, using an LCR meter. The results show that initial permeability of each sample has a maximum and addition of MCCA to the ferrites leads to a marvelous increase in permeabilities. Additionally, MCCA decreases the optimum sintering temperature too. The optimum amounts of additive were 1.0 and 0.5 wt% for the x = 0.65 (μ′ = 492, Ts = 1280 °C) and x = 0.70 (μ′ = 478, Ts = 1320 °C), respectively. Permeability spectra illustrate that utility zone of the Ni0.35Zn0.65Fe2O4 and Ni0.3Zn0.7Fe2O4 are both less than 100 and 10 kHz, respectively. The results represent that there is a strong entanglement between composition, additive and/or sintering conditions. It can be concluded the MCCA added Ni0.35Zn0.65Fe2O4, is suitable for application in the switching power supplies.

Development of soft magnetic composites for magnetized pavement to improve the efficiency of electric vehicle's wireless power transfer

Integrating the wireless power transfer (WPT) system into the pavement is an effective way to solve the inconvenience of electric vehicles (EVs)’ charging, accelerating the growth of ownership of EVs to achieve net carbon zero in transportation. However, the existence of a cement paving layer between coils was a negative impact factor. Here, two types of ferrite powders were separately mixed into the cement to prepare soft magnetic composite (SMC) material to enhance the coupling degree of coils. The magnetic and mechanical performance of the composite were tested by a vibrating sample magnetometer and compressive and flexural strength tester. Furthermore, to explore the optimal layout of the magnetized pavement structure, nine pavement layouts were designed based on the distribution of magnetic flux. Finally, the effect of SMC material on improving the charging performance was verified by WPT system test platform. Results showed that the Ni–Zn ferrite powder exhibited superior magnetic permeability due to its stronger magnetic moments and lower magnetic domain wall energy compared to Mn–Zn ferrite powder. The peak relative permeability of SMC materials reached 14.370 with an equal mass ratio of Ni–Zn ferrite powder to cement. Conversely, optimal strength was attained with a Mn–Zn ferrite to cement ratio of 0.2, resulting in a compressive strength of 36.0 MPa and a flexural strength of 4.0 MPa. Strategically placing SMC within the pavement, both in the core's interior and exterior to the coil, enhanced the coupling coefficient of coils, thereby improving the transmission efficiency of the WPT system. The incorporation of Ni–Zn ferrite powder in a 1:1 mass ratio to cement materialized the highest efficiency. Nonetheless, considering the mechanical performance, the SMC material with a 0.6 mass ratio of Mn–Zn ferrite powder to cement was recommended for magnetized pavements. The WPT system test results showed a transmission efficiency of 89.78% when utilizing magnetized pavement, surpassing the efficiency with the whole pavement material by 1.36%, which indicated great value and potential in energy conservation and carbon reduction of employing magnetized pavement in WPT technology.