Powder Mixtures Research Articles

The Influences of Agglomeration and Storage on the Thermal Properties and Stability of Fats in Infant Formulas

The Influences of Agglomeration and Storage on the Thermal Properties and Stability of Fats in Infant Formulas

Patterns of Synthesis of TiC–NiCr Cermets from Powder Mixtures: Influence of Nichrome Content and Titanium Particles Size

Patterns of Synthesis of TiC–NiCr Cermets from Powder Mixtures: Influence of Nichrome Content and Titanium Particles Size

Optimization of gluten- free semolina dessert (revani) formulation ıncluding different flours: response surface methodology

Celiac syndrome occurs as a result of the deterioration of the natural structure of the intestine due to the consumption of foods containing gluten. Since semolina dessert contains gluten protein, it cannot be consumed by celiac patients. The production of alternative gluten-free products shows that these products are of great importance for this patient group. In this study, gluten-free semolina dessert formulations using rice flour (RF) and buckwheat flour (BWF) and chestnut flour (CF) were optimized using Response Surface Methodology (RSM). Potato Starch (PS) was added to the samples containing BWF and CF. It was determined that the addition of PS increased the processibility of the flour of the semolina dessert prepared with chestnut flour and the consumability of the semolina dessert prepared with buckwheat flour. It was determined that the use of different grades of flour, potato starch/corn semolina mixture, egg white and yolk powder and drinking water increased the volume, symmetry index, chewiness and texture values of the sample (p<0.05). When all components are taken into account, in BWF formulation (62.5/37.5) % flour/corn semolina mixture, 75.85% drinking water 14.73 egg white and yolk powder (same amount) and (50/50) flour/corn semolina mixture in RF formulation, % 81.46, drinking water 14.91% yolk and egg white powder (same amount), in CF formulation (50/50) flour/corn semolina mixture, 60.30% water when drinking, 14.95% egg white and yolk It was possible to produce gluten-free semolina, which is the closest dessert to the control sample semolina dessert by using powdered semolina. As a result of the sensory scores of the prepared revanis (with different formulations), the control sample, rice, chestnut and buckwheat semolina dessert got the highest score, respectively.

Cr2AlC and metals reactivity: Sintering and oxidation

Cr2AlC-20 wt% (Sn; Cu; Co; Fe; Ag) powder mixtures were hot isostatically pressed at 1000 °C for 4 h under 150 MPa to investigate the possible alloying behaviour of the metals with the MAX phase. The as-synthesized bulk materials were further oxidized at 1000 and 1200 °C for 10 h under dry air flux to study the effect of the alloying on the oxidation performance of the MAX phase. The metallic elements did not dissolve into the MAX phase grains: they mainly acted as oxidizing agents on the MAX phase grains, draining the aluminum from it to form intermetallic phases. The oxidation tests resulted in the formation of an alumina scale for most of the samples. The oxidation kinetic study shows no improvement of the oxidation behaviour of the Cr2AlC-metal composites as compared to pure bulk Cr2AlC. Sn spheres embedded in an alumina layer and empty alumina shells are respectively observed on the surface of the oxidized Cr2AlC–Sn and Cr2AlC–Ag composites.

Surface Characteristics of Vacuum-Plasma-Sprayed Reinforced Stainless Steel Coatings with TiC Particles

Fe-based coatings reinforced with TiC particles exhibit outstanding properties and are widely recognized as highly promising coatings or components with superior performance. In the present study, composite materials using a powder mixture of AISI 316 stainless steel and TiC particles were deposited by vacuum plasma spraying onto a S235 low alloyed steel substrate. The coating and the base material were characterized in terms of microstructure and surface properties. The metallographic analysis of the deposited coating revealed the uniform distribution of the TiC into the stainless steel matrix. The results show that the presence of tungsten carbide particles improved the hardness and tribological properties of the composite coating compared with the S235 base material. The wear resistance of the coating was approximately seven times higher than that of the low alloyed steel substrate. The electrochemical corrosion resistance of the coating in chloride media was much higher than that of the base material.

Sintered Wick Heat Pipes with Excellent Heat Transfer Capabilities—Case Study

A sintered wick was formed in a heat pipe through the process of sintering a mixture of copper powder with particle sizes of 100 µm and 200 µm, mixed with a pore-forming agent. The heat pipe’s thermal resistance, which affects its heat transfer efficiency, is determined during manufacturing according to the powder type, thickness of the sintered wick, and filling rate of the working fluid. Heat transfer efficiency was then tested at various inclination angles (0°, 45°, and 90°) to evaluate the performance of heat pipes. Regardless of the filling amount and test angle, the 200 μm copper powder type exhibited superior heat transfer efficiency compared to the 100 μm type. After analyzing heat transfer performance at various filling rates between 20% and 50%, it was determined that the heat pipe’s optimal heat transfer capability occurred at a working fluid filling rate of 30%. The width of the wick was directly related to the heat transfer performance.

Exploring the impact of culture media on life history characteristics of the house fly, Musca domestica L. (Diptera: Muscidae)

Insects, particularly house fly pupae (M. domestica L.), are increasingly promoted as a rich and sustainable protein source, presenting a practical solution for organic waste management. These insects possess the capability to transform animal waste into valuable biomass, underscoring the necessity to evaluate housefly larval growth on diverse waste mixtures. The primary objective was to comprehend how different culture media influence the life history traits of this species. To address this, the research aimed to assess the growth and development performance of housefly larvae reared on various waste mixtures. Adult house flies (M. domestica) were sourced from meat and fish markets in Rajshahi city, Bangladesh, employing systematic sampling from different market sections for a representative selection. Experimental diets were formulated with combinations of cattle blood, cattle manure, rice bran, wheat bran, and kitchen waste, categorized into Diet-A (kitchen waste:cattle manure:wheat bran), Diet-B (cattle blood:rice bran), Diet-C (cattle manure:wheat bran), and Diet-D (cattle blood:kitchen waste:rice bran). Additionally, a control group comprised a mixture of waste materials, including yeast, egg white, milk powder, and wheat bran. The findings revealed that larvae, pupae, and adults reared on Diet-B, incorporating cattle blood and rice bran, demonstrated increased length compared to other diets. This varied diet also produced the heaviest larvae, pupae, and adults, exhibiting the highest morphometric parameters. The moisture content of pupae varied across the different diets, ranging from 53.23±0.17 % to 65.47±1.32 %. The pupae reared on Diet-B had the highest levels of crude protein (53.44±0.05 %, p < 0.05), while those reared on Diet-C had the highest levels of fat (18.56±0.05 %, p < 0.05 except for diet A). The findings demonstrate that housefly larvae can be reared on diets containing rice bran and cattle blood, which have different nutritional profiles and biological capacities. However, the ideal rearing strategy should depend on how M. domestica will be utilized in the future. The study highlights insects, especially housefly pupae, as a sustainable protein source and an organic waste management solution. Therefore, the results of this study contribute to the broader understanding of Musca domestica and offer practical implications for both scientific research and pest management practices.

Hot Deformation Behavior of a Hot-Isostatically Pressed Ti-6Al-4V Alloy from Recycled Powder.

In this work, a new use of mixed Ti-6Al-4V powder, consisting of the retained powder after screening for additive manufacturing and the recycled powder after multiple printing, has been exploited. The powder mixture has been hot-isostatically-pressed (HIPed) at 930 °C/120 MPa for 3 h to reach full density. The hot deformation behavior of the as-HIPed powder compacts were investigated through isothermal compression tests, kinetic analyses, and hot processing maps. Finally, the optimized hot working parameters were validated using upsetting tests. The results show that the as-HIPed Ti-6Al-4V alloy has a fine and homogeneous microstructure. The activation energies were calculated to be 359 kJ/mol in the α + β phase regime and 463 kJ/mol in the β phase regime, respectively. The optimal hot working parameters are a deformation temperature above 950 °C and strain rate higher than 0.1 s-1. The hot workability of as-HIPed powder compacts is better than the as-cast billets. The deformed microstructure can be finer than that of as-HIPed state, and the mechanical performance can be further improved by the optimal thermo-mechanical processing treatment.

New spinel‐structured high‐entropy oxides with high‐ and stable‐infrared radiation properties

AbstractSpinel‐structured high‐entropy oxides (HEOs), the novel materials, have recently attracted great attention for their unexpected properties and extensive applications. In this work, employing a facile scalability process of solid‐state reaction method, we synthesized a new kind of non‐equimolar (Co2/11Mn2/11Fe2/11Cr2/11Ni2/11Cu1/11)3O4 HEOs powder. However, under the same condition, the raw mixed oxide powders, with equimolar cations and higher configuration entropy, cannot form single‐phase HEOs powder but with the mixture of (Co,Mn,Fe,Cr,Ni,Cu)3O4 and residual CuO powders, ruling out the crucial role of entropy effect in forming single‐phase spinel‐structured HEOs. In addition to (Co2/11Mn2/11Fe2/11Cr2/11Ni2/11Cu1/11)3O4 powder, various (Co,Mn,Fe,Cr,Ni,Cu)3O4 HEOs powders can be obtained by controlling the Cu cation content in an appropriate range. To explore the application of the spinel‐structured HEOs in high‐temperature infrared field, the infrared radiation properties of the (Co2/11Mn2/11Fe2/11Cr2/11Ni2/11Cu1/11)3O4 powder were evaluated and exhibited a high‐infrared radiation emissivity of 0.880 in the near‐infrared wavelength range (0.78–2.5 µm) and superior thermal stability. Notably, the infrared radiation emissivity of the HEOs powder was maintained at 0.855 with a slight loss of 2.8% after high‐temperature treatment. This work not only provides a valuable strategy for fabricating high‐ and stable‐infrared radiation properties materials but also expands the great potential application of spinel‐structured HEOs to high‐temperature infrared field, such as energy saving in industrial high‐temperature furnaces.

Study of Non-Transformable t’-YSZ by Addition of Niobia for TBC Application

The high toughness of zirconia is paving the way for the development of new materials for application in TBC for gas turbine blades. The main aim of this work was the obtainment of tetragonal zirconia polycrystalline (TZP) with high density, from mixtures of high-purity powder of zirconia, yttria, and niobia with different compositions (14.5 to 21 mol%), through the processes of cold pressing by uniaxial pressing and by isostatic pressing, followed by air sintering processes at 1550 °C for 1 h. The samples were characterized for phase composition by X-ray diffraction, Rietveld analysis, and morphology by transmission electron microscopy and energy dispersive spectroscopy analyses. Mechanical and tribological resistance was evaluated by fracture toughness and nanoindentation tests as well as Weibull statistics. The incorporation of yttria and niobia resulted in relatively denser ceramics with stabilization of the tetragonal phase which was confirmed by detailed X-ray diffraction analysis. Modified ceramics for TBC with 17.5 mol% of yttria and niobia showed higher hardness and fracture toughness, 16.16 GPa and 173.38 GPa, respectively. Through nano hardness measurements, it was possible to verify the effect of the samples’ ferroelasticity. Thus, the addition of niobia and yttria to zirconia represents an opportunity for the development of new materials with increasing mechanical and tribological resistance for TBC application.

Cermet Powders Based on TiAl Intermetallic for Thermal Spraying

The paper presents a study of the formation process of cermet powders based on TiAl intermetallic with the addition of non-metallic refractory compounds. Non-metallic refractory compounds B4C, BN, SiC, and Si3N4 were chosen as strengthening components, improving the mechanical properties and resistance to high-temperature oxidation of TiAl-type intermetallic coatings. The composition of the initial mixtures was selected based on thermodynamic analysis of the interaction between TiAl intermetallic and non-metallic refractory compounds. As a result of the mechanochemical synthesis of powder mixtures, 73TiAl-27B4C, 69TiAl-31BN, 88TiAl-12SiC, and 83TiAl-17Si3N4 (wt. %) cermet powders are formed, consisting of titanium aluminide (TiAl, Ti3Al) phases and refractory compounds of aluminium (AlB2 and AlN) and titanium (TiB2, TiC, TiN, Ti5Si3). The conglomeration technology of produced cermet powders has been developed to enhance fluidity. Using conglomerated powders will provide their constant feed to the high-temperature jet and the formation of dense coatings during thermal spraying.

Mirtazapine loaded polymeric micelles for rapid release tablet: A novel formulation-In vitro and in vivo studies.

Major depression is a prevalent disorder characterized by sadness, lack of interest or pleasure, interrupted sleep or food, and impaired concentration. Mirtazapine (MTZ), a tetracyclic antidepressant drug, is commonly used to treat moderate to severe depression. MTZ is classified as a BCS class II drug that has shown bioavailability of 50% due to extensive first-pass metabolism. The aim of this research is to develop a delivery platform with enhanced solubility and oral bioavailability of MTZ through formulating polymeric micelles modeled in a rapid release tablet. Mirtazapine loaded polymeric micelles (MTZ-PMs) were formulated to enhance the solubility. Solutol® HS 15 and Brij 58 were used as combined surfactants in a ratio of (20:1) to MTZ in addition to Transcutol® P as a penetration enhancer. The following in vitro tests were performed: particle size, PDI, zeta potential, solubility factor, stability index, and transmission electron microscopes. Afterward, MTZ-PMs were converted to dry free flowable powder through loading on the adsorptive surface of Aerosil 200; then, the powder mixture was directly compressed (MTZ-PMs-RRT) into 13 mm tablets. MTZ-PMs-RRT was further investigated using in vitro evaluation tests of the tablets, namely, weight variation, thickness, diameter, hardness, friability, disintegration time, drug content, and in vitro dissolution test, which complied with the pharmacopeial limits. The pharmacokinetic parameters of MTZ-PMs-RRT compared to Remeron® tablet were further investigated in rabbits. The results showed enhanced solubility of MTZ with improved percentage relative bioavailability to 153%. The formulation of MTZ in the form of MTZ-PMs-RRT successfully improved the solubility, stability, and bioavailability of MTZ using a simple and scalable manufacturing process.

WC-based cemented carbide with NiFeCrWMo high-entropy alloy binder as an alternative to cobalt

In the current work, a nanostructured NiFeCrWMo high entropy alloy (HEA), synthesized by mechanical alloying, was used as the alternative binder phase for substituting Co to fabricate WC–HEA cemented carbides by electron–beam sintering (EBS). The microstructure and mechanical properties of initial powder mixtures and sintered samples were studied using X-ray diffraction analysis, scanning electron microscopy, energy dispersive X-ray spectroscopy (EDS), indentation technique and compression tests. NiFeCrWMo HEA does not have direct interaction with WC, but at the boundaries between WC and HEA particles (Ni, Fe, Cr)xWyCz complex carbide is formed as result of reduction processes during sintering. The results show that WC–HEA cemented carbide has better performances than the commercial WC–8Co-cemented carbide prepared by EBS. The NiFeCrWMo HEA binder significantly slows down the growth of WC grains due to the sluggish diffusion effect and the formation of a small amount of complex carbide, and, compared to Co, improves the mechanical properties, provides an excellent combination of microhardness (18.9 ± 0.4 GPa) and fracture toughness (11.4 ± 0.3 MPa m1/2). Therefore, the NiFeCrWMo high entropy alloy can potentially become a binder for WC cemented carbides.

Fabrication of Sr-feldspar/cordierite and Sr-feldspar/Sr-osumilite composites through sintering of Mg–Sr-cordierite and borosilicate glass for electronic applications

The main objective of this study is to fabricate composite materials having excellent thermal, mechanical and electrical properties for thermal and electronic applications. In this work, strontium feldspar-containing composites (Sr-feldspar/cordierite and Sr-feldspar/Sr-osumilite) were prepared by solid-state sintering of SrO-containing cordierite (MgSrAl4Si5O18)/borosilicate glass powder mixtures. The phase composition, physical properties and microstructure of sintered composites were investigated by X-ray diffraction technique, water displacement method and scanning electron microscope, respectively. Moreover, the thermal expansion coefficient, hardness, and electrical properties were also measured. The results of X-ray patterns revealed the crystallization of Sr-feldspar and cordierite in the composites that contain up to 20% borosilicate glass. On the other hand, the composites that include more than 20% glass, displayed the crystallization of Sr-feldspar and Sr-osumilite with little amount of cristobalite. The bulk density values of sintered composites were decreased from 2.41 to 1.84 g/cm3 with increasing the amount of added glass. The microhardness values were increased from 519 to 710 kg/mm2 with increasing the glass content. Low thermal expansion coefficient (2.65 × 10−6, 2.22 × 10−6, 3.45 × 10−6 and 4.26 × 10−6 K-1 for C0, CG91, CG73, CG55, respectively) and low dialectic constant (7–8.5) were obtained for the prepared composites.

Zinc Ferrite Nanoparticle Coatings on Austenitic Alloy Steel.

The phase transition of austenitic stainless steel of commercial label CL20ES and zinc ferrite nanoparticles was studied in an oxidative atmosphere of dry air to develop a low-cost, effective technique for covering-layer fabrication. CL20ES powder and zinc ferrite powder were mechanically mixed. This mixture was studied in an atmosphere of dry air at different annealing temperatures from room temperature to 900 °C. The employed characterization techniques are X-ray powder diffraction, Mössbauer spectroscopy in the transmission geometry, and scanning electron microscopy with elemental mapping. The fabricated layers were also characterized by surface-specific techniques such as conversion electron Mössbauer spectroscopy and grazing incidence X-ray powder diffraction. The analyzed powder mixture shows resistance against oxidation in dry air and high temperatures. These results were employed to produce zinc ferrite covering layers on 3D-printed cylinders of CL20ES. The results show a predisposition of zinc ferrite to be recrystallized at temperatures above 350 °C without the production of corrosive substances on steel. The zinc ferrite layers were analyzed by an ultrasonic hardness tester as well, which proved the hardness enhancement.

Effect of Powdered Swarf on Self-Adhesive Moldings with Machining Center Extracted Bamboo Fiber

To address global environmental challenges and mitigate bamboo-related ecological damage, this study focuses on the development of self-adhesive molded products utilizing solely bamboo fibers and powder obtained through machining center extraction. However, the mechanical properties of these molded products remain inadequate. This study utilizes Scanning Electron Microscope (SEM) and Fourier transform infrared spectrometer (FTIR) analyses to explore the disparities associated with chip size as raw materials for molded products. Bamboo fiber, characterized by its substantial cellulose content and high strength, is contrasted with bamboo powder, which contains significant amounts of lignin and exhibits potential adhesive properties. Building upon these findings, the powder was added to the conventional fiber alone, with results demonstrating that a predetermined ratio (20%) of the powder yields optimal mechanical properties. Moreover, employing a parameter representing the degree of lignin flow utilized in previous molding studies, the study establishes the optimum molding conditions (PD'=1.031) to maximize tensile strength (37.8 MPa) when incorporating a 20% powder mixture.

Polymer Metallization by Cold Spray Deposition of Polyamide-Copper Composite Coatings

Cold spray metallization of polymers is a promising surface engineering technique that enables the deposition of metal coatings onto polymer substrates at low process temperatures, resulting in improved surface properties, thus enhanced functionality of the polymeric material. However, deposition of well-adhering metallic coatings without causing surface damage to the polymer substrate is still a challenge. In this work, copper-polyamide composite coatings with different copper concentrations between 30 and 75 vol.% in the starting powders were deposited on polyamide substrates using a low-pressure cold spray system with two nozzle geometries of short and long diverging sections. The spray parameters were first developed for the deposition of polyamide powder (at gas temperature of 260 °C and gas pressures ranging from 0.41 to 1.37 MPa), and then used to spray the composite powder mixtures where the polyamide particles were acting as a binder for copper particles. Inflight and impact particle characteristics (velocity and temperature) of the polyamide powder were simulated to better understand the deposition properties. Considering that the selected conditions were suboptimal for the deposition of copper particles, no surface damage was caused as no penetration of the copper particles into the polymer substrate occurred. The results show that increasing the copper content in the powder mixtures significantly improved the resulting coating uniformity and the retained copper content. In addition, the coating deposited by spraying the powder mixture with a higher copper content of 75 vol.% and using the longer nozzle yielded the highest cohesion strength. To further improve coatings cohesion, two post-spray processing methods of furnace heating and hot pressing were used, and the effect of each process on coatings properties was investigated.Please confirm if the author names are presented accurately and in the correct sequence (given name, middle name/initial, family name). Given name: [Kintak Raymond] Last name [Yu]. Also, kindly confirm the details in the metadata are correct.The author names are now correct: Kintak Raymond given name and Yu last nameAll other details are corrects

SYNTHESIS OF CALCIUM SILICATE MATERIALS FROM THE RESIDUAL WASTE SLUDGE OF A WATER-PURIFICATION PLANT

SYNTHESIS OF CALCIUM SILICATE MATERIALS FROM THE RESIDUAL WASTE SLUDGE OF A WATER-PURIFICATION PLANT

Enhanced performance and cycling behavior in symmetric supercapacitors developed by pure HfB2 and HfB2-SiC composites

Boron-based materials have attracted growing interest as promising candidates for energy storage applications. This study focuses on synthesizing pure HfB2 powders through a straightforward method involving the mechanical activation of a powder mixture comprising hafnium tetrachloride (HfCl4), boron (B), and magnesium (Mg). The HfB2 powders were mechanically alloyed with varying amounts of SiC powders to create HfB2-based composite structures. The chemical and microstructural properties of the synthesized samples were assessed using XRD, SEM/EDX, and DLS characterization techniques. Supercapacitor device performances of all resulting powders as symmetrical electrodes were systematically investigated. The test results revealed that the pure HfB2 electrode material exhibited a pseudocapacitor behavior, whereas composite powders exhibited battery-like behavior. Composite powders, demonstrated enhanced supercapacitor performance surpassing that of pure powder in terms of energy density and cycle efficiency. The pure HfB2 electrode displayed the highest power density (95 Wkg−1) among all samples: Its distinctive pseudocapacitor behavior results in the highest power density, providing valuable insights into the intricate relationship between composition and electrochemical performance in boron-based supercapacitor materials. Moreover, these results propose that by synthesizing composite powders, the charge storage mechanism can be altered and used to improve the energy density.

A sustainable packaging composite of waste paper and poly(butylene succinate-co-lactate) with high biodegradability

The challenge of global climate change has drawn people's attention to the issue of carbon emissions. Reducing the use of petroleum-derived materials and increasing the use of biodegradable materials is a current focus of research, especially in the packaging materials industry. This study focused on the use of environmentally friendly plastics and waste paper as the main materials for packaging films. Poly(butylene succinate-co-lactate) (PBSL) was modified with maleic anhydride (MA) to form a biobased compatibilizer (MPBSL), which was then blended with a mixture (WPS) of waste-paper powder (WP) and silica aerogel powder (SP) to form the designed composite (MPBSL/WPS). The modification of PBSL with MA improved interfacial adhesion between PBSL and WPS. The structure, thermal, and mechanical properties, water vapor/oxygen barrier, toxicity, freshness, and biodegradability of MPBSL/WPS films were evaluated. Compared with the PBSL/WP film, the MPBSL/WPS film exhibited increased tensile strength at break of 4–13.5 MPa, increased initial decomposition loss at 5 wt% of 14–35 °C, and decreased water/oxygen permeabilities of 18–105 cm3/m2·d·Pa. In the water absorption test, the MPBSL/WPS film displayed about 2–6 % lower water absorption than that of the PBSL/WP film. In the cytocompatibility test, both MPBSL/WPS and PBSL/WP membrane were nontoxic. In addition, compared with PBSL/WP film and the control, the MPBSL/WPS film significantly reduced moisture loss, extended the shelf life, and prevented microbial growth in vegetable and meat preservation tests. Both MPBSL/WPS and PBSL/WP films were biodegradable in a 60-day soil biodegradation test; the degradation rate was 50 % when the WP or WPS content was 40 wt%. Our findings indicate that the composites would be suitable for environmentally sustainable packaging materials.