Potential Sorbent Research Articles

Physicochemical, structural, and adsorption characteristics of DMSPS-co-DVB nanopolymers.

The aim of this work is the synthesis and characterization of the series of S,S'-thiodi-4,1-phenylene bis(thio-methacrylate)-co-divinylbenzene (DMSPS-co-DVB) nanomaterials. The series of new nanopolymers including three mixed systems with different ratios of DMSPS and DVB components, DMSPS-co-DVB = 1:1, DMSPS-co-DVB = 1:2, and DMSPS-co-DVB = 1:3, was synthesized in the polymerization reaction. The research task is to investigate the influence of the reaction mixture composition on morphological, textural, and structural properties of final nanosystems including size, shape, and agglomeration effect. The advanced biphasic nanomaterials enriched with thiol groups were successfully synthesized as potential sorbents for binding organic substances, heavy metals, or biomolecules. To determine the impact of the DMSPS monomer on the final properties of DMSPS-co-DVB nanocomposites, several techniques were applied to reveal the nano-dimensional structure (SAXS), texture (low-temperature nitrogen sorption), general morphology (SEM), acid-base properties (potentiometric titration), and surface chemistry and phase bonding effectiveness (FTIR/ATR spectroscopy). Finally, kinetic studies of aniline sorption on polymeric materials were performed.

Adsorption Behavior and Residue Degradation of Triazine Herbicides in Soil Amended with Rice Straw Biochar

The removal of or decrease in pesticide residues in soil has attracted considerable attention, due to the serious pollution of pesticides in soil. The purpose of the study was to explore the adsorption behavior of biochar on pesticides and the impact on the degradation of pesticide residues in soil, providing a basis for the remediation of soil by biochar. Biochars were prepared via pyrolysis of rice straw at a high temperature (300 °C, 400 °C, 500 °C, 600 °C). The individual and competitive adsorption of three triazine herbicides, prometryn, atrazine, and simazine, on biochar was investigated, and the degradation of the herbicide residues in biochar-added soil was determined. The selected herbicides presented similar adsorption characteristics to rice straw biochar, and the amount of herbicides adsorbed increased with higher preparation temperature and the amount of biochar. The rice straw biochar adsorbed the studied herbicides simultaneously, and the adsorption amount decreased as follows: simazine > atrazine > prometryn. The competition adsorption of the selected herbicides on the biochar presented a lower adsorption affinity than that when they are adsorbed individually. The adsorption isotherm was best fitted by the Freundlich model. The half-lives of prometryn, atrazine, and simazine were 9.8~12.6 d, 5.2~8.1 d, and 3.7~5.6 d, respectively. Biochar addition increased the degradation of the evaluated herbicides in soil. The rice straw biochar could be the potential sorbents that can be implemented for the removal of pesticides.

Chitosan cross-linked and grafted with epichlorohydrin and 2,4-dichlorobenzaldehyde as an efficient adsorbent for removal of Pb(II) ions from aqueous solution

Epichlorohydrin-modified chitosan-Schiff base composite (CS/24Cl/ECH) prepared via the one-pot reaction as characterized by Fourier transform Infra-Red spectroscopy (FT-IR), X-ray powder diffraction (XRD), Differential scanning calorimetry (DSC) and Scanning electron microscope (SEM). Its removal ability of Pb(II) ions from aqueous solution was investigated. The adsorption of Pb(II) ions carried out at different initial pH, dose of CS/24-Cl/ECH, contact time and co-existing ions. The maximum adsorption capacity of Pb(II) ions was 170 mg/g. Finally, based on the absorption results, the adsorption of Pb(II) ions was fitted by single-layer Langmuir isotherm model and the pseudo-second-order (PSO) kinetics model. The absorption mechanism of Pb(II) ions was controlled by chemical coordination Pb(II) ions with the active sites on the surface of CS/24Cl/ECH composite. Also, CS/24Cl/ECH showed excellent recyclable efficiency up to 5 cycle and potential sorbent for other heavy metal ions.

Effects of simulated acid rain and carbon-rich water on mercury mobilization in soils amended with aluminum-based drinking water treatment residuals

Mercury (Hg) contamination in soils is of concern because of its known adverse effects on ecosystem functions and human health. Research on how to reduce Hg contamination in soil is still needed, mainly because of the difficulties in remediating Hg-contaminated soils while minimizing adverse effects on treated systems. We investigated the potential of a waste substrate, aluminum (Al)-based drinking water treatment residuals (Al-WTRs), as a low-cost sorbent for immobilizing the mobile fraction of Hg in contaminated soils using column leaching studies. Because of the known role of acidic deposition and dissolved organic matter on the environmental cycling of Hg, columns packed with Hg-contaminated alluvial soils collected from the watershed of Poplar Creek in Tennessee of USA were leached using either the synthetic precipitation leaching procedure (SPLP) to simulate the effects of acid rain or low pH dissolved organic carbon (DOC) rich river water (Suwannee River water, pH 4.20) to mimic soil flooding events with DOC-rich waters. The results show that, for soils with very high mobile Hg fractions, control columns without Al-WTR leached with the SPLP solution retained only 51% of total-Hg, which was significantly less (p ​< ​0.05) than in the Al-WTR treated soil columns (up to 80%). Leaching with DOC-rich river water (53.3 ​mg ​C/L) decreased the sorption capacity of Al-WTR. Using waters with increasing DOC concentrations (from 5.33 to 40 ​mg ​C/L) resulted in the removal of 63% of the initial mass of Hg in the control columns compared to 22–29% in the columns amended with 2 and 5% Al-WTR. Overall, Al-WTR can immobilize Hg under extreme leachability conditions and should be considered as a potential sorbent for in situ remediation of Hg-contaminated soils. However, further studies are needed on the fate of Al-WTR-immobilized Hg.

Effect of Arginine-Based Deep Eutectic Solvents on Supported Porous Sorbent for CO2 Capture Analysis

Carbon dioxide (CO2) as one of the heat-trapping gases, has caused global warming. Being a greener and more economical material, amino acid-based deep eutectic solvents (AADES) have attracted interest in CO2 capture applications. In this paper, the effect of L-arginine (Arg) in binary AADES of arginine-ethylene glycol (Arg-EG) and ternary AADES of choline chloride-ethylene glycol-arginine (ChCl-EG-Arg) on adsorption of CO2 was studied. The solubility, basicity, and physicochemical characteristics were compared with the binary DES (ChCl-EG) before and after being impregnated into a silica gel (SG) via the wet impregnation method. The AADES/SG adsorbents were evaluated for CO2 sorption performance using an automated gas sorption analyzer at 100% CO2 loading and thermogravimetric analysis (TGA) at flue gas conditions (15% CO2/85% N2). Findings show the basicity and the nitrogen content (N%) of AADES/SG were increased as Arg was added and DES/AADES functional group peaks (amino, hydroxyl, alkyl groups) were observed after the impregnation. The CO2 sorption of 16.0 mg/g at 25 °C and 1 atm was achieved by 30% Arg-EG(1:8)/SG followed by 30% ChCl-EG-Arg (1:2:0.1)/SG (14.8 mg/g) and 30% ChCl-EG/SG(1:2) (14.5 mg/g) using an Autosorb iQ2 instruments with 100% CO2 loading. The CO2 uptake was increased almost linearly with increasing pressure and decreased with increasing temperature. The Arg-EG(1:8)/SG shows the highest selectivity toward CO2 than other sorbents with 8.10 mg/g adsorption for 1 h at 15% CO2 loading at 25 °C with higher thermal stability and surface area. Considering environmental, technological, and economic viewpoints, the Arg-EG(1:8)/SG can be explored more as a potential solid sorbent for CO2 capture.

Design and construction of cobalt-organic framework with outstanding adsorption properties assembled by 3-(3,5-dicarboxylphenoxy)pyridine

Removal the hazards of Azo organic dyes from waterbody through porous heterogeneous materials is considered as a low-cost and high-efficient method. Intriguingly, two metal organic frameworks (MOFs), {[Co3(L)3(H2O)]·3.5(C4H2O2)}n and [Co4(L)4(bit)2]n designated as MOF 1 and 2, have been synthesized through the traditional solvothermal method. MOF 2 exhibits significant removal effect on organic dye (congo red (CR)) from waterbody owing to more imidazole rings in the structure than 1. After optimizing the experimental conditions, the highest adsorption capacity (810.7 mg g-1) and high removal rate (97.28%) of 2 are obtained in 500 ppm CR solution. Pseudo second-order kinetics and Langmuir isotherms more accurately described the adsorption process of 2. In addition, 2 exhibits high recyclability, stability and adsorption performance through a simple organic solvent release system. Moreover, 2 also exhibits high adsorption performance in real wastewater. The possible mechanism of selective adsorption involves the π-π stacking interaction, hydrogen bond, synergistic effect of electrostatic interaction and pore filling. All the bench experiments have indicated that 2 is a promising potential sorbent in the practical wastewater treatment and CR dyes recovery.

Template-assisted synthesis of molecularly imprinted polymers for the removal of methyl red from aqueous media

This study entails the synthesis of molecularly imprinted polymers (MIPs) with good selectivity coefficients for azo dye as a potential sorbent material to extract azo dye from polluted aqueous media. A series of MIPs for methyl red (MR) as a template, were synthesized by changing the molar ratio of functional monomers, via precipitation polymerization format of non-covalent approach. Water-soluble functional monomer; acrylic acid (AA) was used to weave the frame work of polymers while ethylene glycol dimethacrylate (EGDMA) was utilized as crosslinking monomer. The impact of different experimental parameters, such as mole ratio of monomer (functional) to crosslinking monomer on the molecular recognition was investigated. The highly efficient and selective MR-MIP was used for the removal of spiked MR dye from different water samples. The selected imprinted polymer, MR1-MIP was able to selectively remove the MR molecules from aqueous media. A significant amount of dye was removed by MR1-MIP from the river water samples with a high degree of removal efficiency i.e. 92.25%. The imprinting factor of 3.75 for MR1-MIP indicated that the high selectivity in terms of adsorption for MR. A minimum loss of only ~ 3.35% in the removal efficiency within ten sequential cycles of adsorption–desorption study evidenced that MR-MIPs could be used as the most cost effective and best sorbent for the removal of MR from polluted water. Furthermore, the structural properties of MR-MIPs were characterized by FTIR and EDX, whereas TGA, SEM and BET were used to describe the thermal, morphological and surface structures of the particles, respectively.Graphical

Reduction of cadmium content in 29 % and 54 % P2O5 phosphoric acid by manganese oxide material birnessite-type Na-MnO2

This paper presents a new approach for the purification of 29% and 54% P2O5 phosphoric acid contaminated with cadmium ions using synthesized lamellar material based on manganese (Na-MnO2). The removal efficiencies of cadmium ions were 35 % and 31 % for 54% and 29% P2O5 phosphoric acid. The kinetic and isotherm studies of cadmium adsorption were performed. After the phosphoric acid purification process, Na-MnO2 material was characterized by XRD, SEM, and TGA-DTA. All the results enable the refinement of the final phase by the Rietveld method. A proposed mechanism of cadmium ion removal by Na-MnO2 was given. The stability of the material was also controlled in the acid medium 29 % and 54 % P2O5. The results confirmed that Na-MnO2 material could be a potential sorbent for the efficient removal of heavy metals from phosphoric acid solutions. This simple process can be further developed and thus opens an avenue in the industrial sector to process larger quantities using high-performance materials based on manganese. Self-consistent ab initio calculations, based on DFT (Density Functional Theory) approach and using the FLAPW method (Full potential Linear Augmented Plane Wave), were performed to investigate both the electronic and magnetic properties of materials.

Under-coordinated selenide enriched amorphous cobalt selenide prepared under ambient conditions for highly efficient immobilization of gaseous elemental mercury

The limited adsorption capacity of commercialized sorbents towards elemental mercury (Hg0) remains a major challenge facing their extensive applications under the regulation of the Minamata Convention. Metal selenides were recently found to be promising alternatives to commercialized sorbents for capturing Hg0 from industrial flue gas due to the high affinity between Hg0 and selenide. In metal selenides, under-coordinated selenide sites play critical roles in oxidation and subsequent immobilization of Hg0, while there is still no simple way to increase the abundance of under-coordinated selenide in metal selenides under ambient conditions. In this work, an effective and facile precipitation pathway was proposed to prepare amorphous cobalt selenide (a-CoSe2) with under-coordinated selenide enriched surface under ambient conditions. The a-CoSe2 as synthesized achieved outstanding Hg0 uptake capacity and adsorption rate (534.2 mg g−1 and 483.1 μg g−1 min−1), far surpassing those of crystalline cobalt selenide (c-CoSe2) by magnitudes. The characteristic results demonstrated that the under-coordinated selenide enriched nature of a-CoSe2 is the principal reason causing the significant performance improvement, which is fully in line with our hypothesis and purpose. This work not only proposes a potential sorbent for efficient Hg0 sequestration from industrial flue gas but also inspires the further development of synthesis strategies for amorphous materials.

Rhodamine 6G Dye Adsorption Using Magnetic Nanoparticles Synthesized With the Support of Vernonia Amygdalina Leaf Extract (Bitter Leaf)

This study reports the synthesis of magnetic nanoparticles (MNPs) using the co-precipitation method with the support of Vernonia Amygdalina (VA) (bitter leaf) extract for the efficient sequestration of rhodamine 6G dye (Rhd 6G) from a water-soluble solution. The prepared MNPs were characterized using Transmission electron microscopy (TEM,) X-ray Diffraction (XRD), Fourier-transform infrared (FTIR) and Ultraviolet–visible (UV–Vis) spectrometry. The average particle sizes from TEM and XRD analyses were 4.81 ± 2.2 nm and 5.61 nm respectively. The sorption of Rhd 6G dye to the MNPs was pH-dependent, with ideal confiscation of dye molecules observed at pH 10 (∼91.4%)\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\sim 91.4\\%)$$\\end{document}. The sorption process of Rhd 6G dye was reported to follow the Freundlich (FRH) isotherm model, while the pseudo-first-order model (PFOM) best depicted the sorption process of Rhd 6G dye to the MNPs from the non-linear modelling. The determined sorption capacity of the MNPs was established to be 454 mg.g−1. Also, the sorption of Rhd 6G dye to the MNPs was observed to be thermodynamically spontaneous, endothermic and with increasing randomness between the interface of the water-soluble solution and the MNPs. Hence, the prepared MNPs have proven to be an effective potential magnetic sorbent for the removal of cationic dyes from an aqueous solution.Graphical

Development of a Pt-graphene nanocomposite-based solid-phase extraction coupled with ultra-performance liquid chromatography-tandem mass spectrometry for the determination of carbamate pesticides in fish.

In the present work, a potential solid-phase extraction (SPE) material based on graphene anchored with platinum nanoparticles (Pt-Graphene) was prepared and characterized by scanning electron micrographs and transmission electron micrograph. The carbamates residues in fish were enriched by SPE filled with Pt-Graphene and detected by ultra-performance liquid chromatography-tandem mass spectrometry (UPLC-MS/MS). The proposed extraction protocol exhibited satisfactory recoveries (76.5-115.6%), low limit of quantitation values in μg kg-1 level, and good precision for the studied ten carbamates. These results demonstrated the feasibility of the proposed protocol. The developed Pt-Graphene nanoparticles showed excellent performance for extracting analytes at trace levels, indicating that it could be used as a potential SPE sorbent in food residue analysis.

Boron Nitride from Ammonia Borane and Alkali Amidoboranes and Its Features for Carbon Dioxide Capture

Herein, three boranes are studied as potential precursors of boron nitride (BN) and their carbon dioxide adsorption capacity is evaluated. The selected boranes are ammonia borane (AB, NH3BH3), lithium amidoborane (LiAB, LiNH2BH3), and sodium amidoborane (NaAB, NaNH2BH3), and they are pyrolyzed at four different temperatures. All the characterization techniques show the formation of BN from the three boranes. However, LiAB and NaAB form hexagonal BN (h‐BN) at a lower temperature in comparison with AB. The insertion of the alkali metal inside the BN structure is also evidenced. These materials show interesting results when they are exposed to a CO2 atmosphere. The materials are able to adsorb CO2 at nearly ambient conditions, and the best results are achieved with samples that do not present a crystalline structure. AB treated at 600 °C uptakes 34 cm3 g−1 (66.8 mg g−1) at 1.5 bar CO2 and 30 °C. Considering that the materials developed in this study are nonporous, the results are promising, opening new perspectives as potential sorbents for CO2.

Oil shale kerogen-derived adsorbents and their application to trichloroethylene adsorption from aqueous solutions

This paper examines microporous oil shale kerogen-derived semicokes as potential sorbents for environmental cleanup applications. This carbonaceous residue (“semicoke”) left behind during the processing of oil shale kerogen is the main source of adsorptive potential in the processed oil shale. The surface area and porosity of model microporous semicokes were determined using N2 and CO2 adsorption techniques. The model semicoke material had a BET surface area of 494 m2/g of char (net of the minerals), which could be increased by mild thermal activation in the air at 698 K (425 °C) to 857 m2/g-char. The semicokes were tested as potential sorbents by measuring their efficacy at removing trichloroethylene (TCE) from aqueous solutions at 295 K in the concentration range from about 0.1 to 7 mg/L. TCE adsorption isotherms were determined for seven different sorbents – the model semicoke, the air-activated model semicoke, raw unprocessed oil shale, three commercially prepared semicokes, and, for reference, a commercial granulated activated carbon. The present results show that the kerogen-derived carbons have TCE adsorptive capacity values which are comparable to those of a commercial activated carbon (e.g., 70 mg/g-C). The results pointed to the importance of a particular micropore size range for adsorption. While air activation increased the pore volume and surface area of the materials as measured by nitrogen and carbon dioxide, this did not result in an increase in adsorptive capacity for TCE. The critical pore size appears to be in the range of 0.5–0.8 nm.

Efficient removal of synthetic dye by employing H2O2/nZVI-rGO nanocomposite system

We reported a method for the removal of crystal violet (CV) dye from wastewater excreted by textile industries. Here, we employed the use of reduced graphene oxide-supported nanoscale zero-valent iron (nZVI/rGO) nanocomposite along with H2O2 for CV removal. For this purpose, nZVI/rGO nanocomposite was prepared by reduction of ferrous sulfate heptahydrate (FeSO4·7H2O) and graphene oxide (GO) with sodium borohydride (NaBH4) and used as a potential sorbent for removal and/ or minimization of CV from aqueous solution. Zeta, transmission electron microscopy (TEM), UV–Visible spectroscopy, and Fourier-transform infrared spectroscopy (FTIR) were performed to characterize nZVI/rGO nanocomposite. Further, the chemical method for dye removal was also investigated using hydrogen peroxide (H2O2) as a chemical reductant. The effects of nanocomposite concentration, temperature, and time were examined to evaluate their role in dye elimination. The concentration of CV in the aqueous solution was calculated by studying absorbance using a UV–Visible spectrophotometer. The use of both H2O2/ nZVI-rGO provided a synergistic effect and resulted in efficient and fast removal of CV from an aqueous solution.

Modeling, Simulation, Optimization, and Experimental Verification of Mercury Removal onto Natural and Sulfur-Impregnated Zeolite Clinoptilolite—Assessment of Feasibility for Remediation of Mercury-Contaminated Soil

In this paper, a series of equilibrium and kinetic experiments of Hg(II) removal in a single-stage batch reactor on natural (NZ) and sulfur-impregnated zeolite (SZ) were performed. Batch sorption of Hg(II) on zeolites was studied using different isothermal and kinetic models. It was found to be best described by the Brouers-Sotolongo isotherm and the Vermeulen’s approximation, which were applied in optimizing the mass and contact time in two-stage cross-current and counter-current flow batch reactors based on the desired criterion of 99.9% removal efficiency. Mathematical models for minimizing zeolite mass and contact time were developed and experimentally verified. The optimum minimum masses of NZ and SZ were calculated for all systems, and a significant saving in SZ consumption was found when the counter-current design was applied. The toxicity characteristic leaching procedure (TCLP) was applied to mercury contaminated soil from the Idrija mine region in Slovenia to evaluate potential soil toxicity. The results showed that the soil is extremely contaminated and represents hazardous waste. The addition of zeolites significantly reduced the concentration of leached Hg, with the most satisfactory results obtained with SZ. It was found that at the lowest dose of 0.25 g of SZ, the leached Hg concentration was reduced below the maximum concentration criterion of 0.2 mg/L according to the TCLP test. This study revealed that SZ could be a potential sorbent for in situ remediation of mercury contaminated soil.

Advancements in Clay Materials for Trace Level Determination and Remediation of Phenols from Wastewater: A Review

The wide spread of phenols and their toxicity in the environment pose a severe threat to the existence and sustainability of living organisms. Rapid detection of these pollutants in wastewaters has attracted the attention of researchers from various fields of environmental science and engineering. Discoveries regarding materials and method developments are deemed necessary for the effective detection and remediation of wastewater. Although various advanced materials such as organic and inorganic materials have been developed, secondary pollution due to material leaching has become a major concern. Therefore, a natural-based material is preferable. Clay is one of the potential natural-based sorbents for the detection and remediation of phenols. It has a high porosity and polarity, good mechanical strength, moisture resistance, chemical and thermal stability, and cation exchange capacity, which will benefit the detection and adsorptive removal of phenols. Several attempts have been made to improve the capabilities of natural clay as sorbent. This manuscript will discuss the potential of clays as sorbents for the remediation of phenols. The activation, modification, and application of clays have been discussed. The achievements, challenges, and concluding remarks were provided.

Brown Seaweed Sargassum-Based Sorbents for the Removal of Cr(III) Ions from Aqueous Solutions

In this study, zinc oxide nanoparticles (ZnO NPs) were biosynthesized with the use of an extract derived from seaweed (Sargassum sp.) and used as a sorbent for the removal of Cr(III) ions from wastewater. The biosorption properties of the seaweed itself as well as of the post-extraction residue were investigated for comparison. ZnO NPs were characterized with UV–vis, ICP-OES, FTIR, XRD, and SEM techniques. The sorption capacity of the (bio)sorbents was investigated as a function of contact time at different pH values and initial concentrations of metal ions. Sorption kinetics and isotherms were studied in order to comprehend the sorption nature and mechanism. The sorption kinetic data were well-fitted with the pseudo-second-order model, and the highest sorption capacity was calculated for ZnO NPs (137 mg/g), whereas those calculated for Sargassum sp. (82.0 mg/g) and the post-extraction residue (81.3 mg/g) were comparable (at pH 5 and 300 mg of Cr(III) ions/L). The adsorption isotherms for all sorbents were well described using the Langmuir model. According to these findings, ZnO NPs were superior to the sorption properties of the tested biosorbents and can be used as a potential sorbent for the removal of metal ions from wastewater. Renewable seaweed biomass can be used for the sustainable biosynthesis of nanoparticles used for environmental protection.

Uptake of BF Dye from the Aqueous Phase by CaO-g-C3N4 Nanosorbent: Construction, Descriptions, and Recyclability

Removing organic dyes from contaminated wastewater resulting from industrial effluents with a cost-effective approach addresses a major global challenge. The adsorption technique onto carbon-based materials and metal oxide is one of the most effective dye removal procedures. The current work aimed to evaluate the application of calcium oxide-doped carbon nitride nanostructures (CaO-g-C3N4) to eliminate basic fuchsine dyes (BF) from wastewater. CaO-g-C3N4 nanosorbent were obtained via ultrasonication and characterized by scanning electron microscopy, X-ray diffraction, TEM, and BET. The TEM analysis reveals 2D nanosheet-like nanoparticle architectures with a high specific surface area (37.31 m2/g) for the as-fabricated CaO-g-C3N4 nanosorbent. The adsorption results demonstrated that the variation of the dye concentration impacted the elimination of BF by CaO-C3N4 while no effect of pH on the removal of BF was observed. Freundlich isotherm and Pseudo-First-order adsorption kinetics models best fitted BF adsorption onto CaO-g-C3N4. The highest adsorption capacity of CaO-g-C3N4 for BF was determined to be 813 mg. g−1. The adsorption mechanism of BF is related to the π-π stacking bridging and hydrogen bond, as demonstrated by the FTIR study. CaO-g-C3N4 nanostructures may be easily recovered from solution and were effectively employed for BF elimination in at least four continuous cycles. The fabricated CaO-g-C3N4 adsorbent display excellent BF adsorption capacity and can be used as a potential sorbent in wastewater purification.

Formic Acid Electrospun Composite Fibers Based on Poly Β-Hydroxybutyrate/ In Situ Poly(Vinyl Formate), Loaded with Natural Montmorillonite as Potential Dye Sorbents

Formic Acid Electrospun Composite Fibers Based on Poly Β-Hydroxybutyrate/ In Situ Poly(Vinyl Formate), Loaded with Natural Montmorillonite as Potential Dye Sorbents

Sugarcane Bagasse and Corn Stalk Biomass as a Potential Sorbent for the Removal of Pb(II) and Cd(II) from Aqueous Solutions

Heavy metal pollution in the water supply is a serious environmental problem that affects human health around the world. The goal of this study was to investigate the adsorption behaviour of sugarcane bagasse (SB) and corn stalk (CS) biomass for Pb(II) and Cd(II) removal from metal-contaminated water. When the doses of biomass were increased in solutions containing Pb(II) and Cd(II), the SB and CS showed a trend of increasing metal removal efficiency. The removal efficiency of biomass for Pb(II) decreased as the pH of the solution increased from 5.0 to 7.0, with an optimum pH range of 5 to 6. However, pH has little influence on the removal efficiency of biomass for Cd(II). Adsorption equilibrium is reached in about 15 min. Adsorption for at least four cycles improves Pb(II) removal efficiency (up to 98 %) in solutions containing only Pb(II). The best fitness of the adsorption isotherm to Freundlich suggests multilayer adsorption of metal ions onto CS. Higher qmax and Kf suggest that SB and CS have a greater affinity for Pb(II) than for Cd(II). Pb(II) adsorption potential was found in biomass derived from SB and CS, but it was less effective as a Cd(II) adsorbent. For application in environmental clean-up, we suggest further study on the structural modification of biomass to enhance its metal removal capacity, the regeneration of biomass for better results, and field trials for practical application. HIGHLIGHTS The adsorption behaviour of sugarcane bagasse and corn stalk biomass for Pb(II) and Cd(II) removal from metal-contaminated water was studied The removal efficiency of Pb(II) increases with increased doses of biomass and decreases with increased solution pH and metal initial concentrations Adsorption for at least four cycles improves metal removal efficiency in the case of Pb(II) Freundlich’s isotherm suggests multilayer adsorption of Pb(II) and Cd(II) onto corn stalk biomass Higher qmax and Kf values suggest that sugarcane bagasse and corn stalk have a higher affinity for Pb(II) than Cd(II)