Potential Use Research Articles

Abnormal Magnetic Phase Transition in Mixed-Phase (110)-Oriented FeRh Films on Al2O3 Substrates via the Anomalous Nernst Effect.

Iron rhodium (FeRh) undergoes a first-orderanti-ferromagnetic to ferromagnetic phase transition above its Curie temperature. By measuring the anomalous Nernst effect (ANE) in (110)-oriented FeRh films on Al2O3 substrates, the ANE thermopower over a temperature range of 100-350 K is observed, with similar magnetic transport behaviors observed for in-plane magnetization (IM) and out-of-plane magnetization (PM) configurations. The temperature-dependent magnetization-magnetic field strength (M-H) curves revealed that the ANE voltage is proportional to the magnetization of the material, but additional features magnetic textures not shown in the M-H curves remained intractable. In particular, a sign reversal occurred for the ANE thermopower signal near zero field in the mixed-magnetic-phase films at low temperatures, which is attributed to the diamagnetic properties of the Al2O3 substrate. Finite element method simulations associated with the Heisenberg spin model and Landau-Lifshitz-Gilbert equation strongly supported the abnormal heat transport behavior from the Al2O3 substrate during the experimentally observed magnetic phase transition for the IM and PM configurations. The results demonstrate that FeRh films on an Al2O3 substrate exhibit unusual behavior compared to other ferromagnetic materials, indicating their potential for use in novel applications associated with practical spintronics device design, neuromorphic computing, and magnetic memory.

Phytochemistry and Pharmacological Activity of Malva sylvestris L: A Detailed Insight.

Malva sylvestris L., is commonly referred to as Mallow and is found in Europe, Asia and Africa. This has been traditionally used for inflammation, gastrointestinal disturbances, skin disorders, menstrual pains, and urological disorders. This review covers phytoconstituents and Pharmacological activities of M. sylvestris. The plant contains a large number of phytochemical constituents having diverse pharmacological activities. The plant contains many phenolic compounds responsible for its strong antioxidant activity. Coumarins from Mallow have a potential anticancer activity. Malva sylvestris also contains essential as well as non-essential elements and minerals. Many researchers have provided evidence that Malva sylvestris is a good candidate for use as a medicinal herb and has good nutritional value. The leaves, in particular, offer properties like anticancer, skin whitening, and anti-aging. Furthermore, the aqueous extract was recently shown to have an anti-ulcerogenic effect. Malva sylvestris has a high potential for use in cosmetics such as skin whitening and anti-aging treatments. Methanolic extracts of Malva sylvestris leaves, and flowers showed strong antibacterial activity against a common plant pathogen bacterium. The plant also contains Malvone A, which is responsible for antibacterial action. The plant also possesses anti-inflammatory, analgesic, wound healing properties and various other activities.

Effect of Prebiotic Supplementation on Probiotic Viability and Physicochemical Characteristics of Fermented Coconut Water with Bifidobacterium longum

Background: Probiotics and prebiotics are functional ingredients that provide health benefits to consumers but they are mainly incorporated in dairy products. Designing a non-dairy product in which probiotics and prebiotics would be incorporated would allow more consumers to benefit from their advantages. Objective: This study investigated the effect of supplementation of two different prebiotics, fructooligosaccharide (FOS) and inulin, on the viability of Bifidobacterium longum ATCC BAA-999 in coconut water. Methods: Two concentrations of prebiotics used were 1% and 2%. The physicochemical characteristics of fermented coconut water with B. longum for 9 h at 37oC and during refrigerated storage at 4oC for 2 weeks were analyzed. The viability of B. longum in fermented coconut water was maintained above the recommended therapeutic level (7 log CFU/mL) with or without supplementation with prebiotics. Results: Most distinct changes in colour (∆E > 3) occurred in fermented coconut water compared to unfermented coconut water. An increase in the total soluble solids was also observed in fermented coconut water with the increase in the concentration of prebiotics. There were no significant changes in the clarity, pH, and concentrations of shikimic and malic acids in the fermented coconut water with or without supplementation with prebiotics over the 2 weeks of storage. Acetic acid production was observed in the fermented coconut water with the highest acetic acid production in the fermented coconut water supplemented with 1% FOS after 2 weeks of storage. Conclusion: This study demonstrated the potential use of coconut water as a medium to produce a probiotic drink.

Medicinal (Radio)Chemistry: Building Radiopharmaceuticals for the Future.

Radiopharmaceuticals are increasingly playing a leading role in diagnosing, monitoring, and treating disease. In comparison with conventional pharmaceuticals, the development of radiopharmaceuticals does follow the principles of medicinal chemistry in the context of imaging-altered physiological processes. The design of a novel radiopharmaceutical has several steps similar to conventional drug discovery and some particularity. In the present work, we revisited the insights of medicinal chemistry in the current radiopharmaceutical development giving examples in oncology, neurology, and cardiology. In this regard, we overviewed the literature on radiopharmaceutical development to study overexpressed targets such as prostate-specific membrane antigen and fibroblast activation protein in cancer; β-amyloid plaques and tau protein in brain disorders; and angiotensin II type 1 receptor in cardiac disease. The work addresses concepts in the field of radiopharmacy with a special focus on the potential use of radiopharmaceuticals for nuclear imaging and theranostics.

Observation on Switching Properties of WO3-Based H2 Sensor Regulated by Temperature and Gas Concentration.

Transition metal oxide semiconductors have great potential for use in H2 sensors, but in recent years, the strange phenomena about gas-sensitive performance associated with their special properties have been more widely discussed in research. In some cases, the resistance of transition metal oxide gas sensors will emerge with some changes contrary to their intrinsic semiconductor characteristics, especially in gas sensor research of WO3. Based on the hydrothermal synthesis of WO3, our work focuses on the abnormal change of tungsten oxide resistance to different gases at low temperature (80-200 °C) and high temperature (above 200 °C). Through in situ FT-IR and in situ XPS, combined with density functional theory calculations, a new reasonable explanation of WO3 is proposed for the abnormal resistance change caused by temperature and the strange response due to gas concentration. The occurrence of these findings can be attributed to the synergistic effect resulting from the presence of two contributing factors. One of them is attributed to the alteration in the surface valence state of WO3 induced by gas, resulting in the reduction of W6+. The other one is due to the reaction between gas and adsorbed oxygen on the surface of WO3. This work presents a novel and rational concept for addressing the reaction mechanism between gas and transition metal oxide semiconductors, thereby paving the way for the development of highly efficient gas sensors based on transition metal oxide semiconductors.

Comparative analysis of the physical and chemical properties of dried products "KalmaKS" from the skin of the Commander and Pacific squid

The modern system of high-quality nutrition for the population includes the use of natural compounds from secondary products of animal origin. In the course of scientific substantiation of using secondary products from the processing of cephalopods, dried products from the skin of Pacific (Todarodes pacificus) and Commander squid (Berryteuthis magister) have been studied, their protein and amino acid composition and functional and technological characteristics have been analyzed. In samples from the skin of the Pacific squid, a high content of glutamic and aspartic acids (8–10 %) is noted; in samples from the skin of the Commander squid – glycine (20 %), proline (10 %) and arginine. High indicators of solubility, water-holding capacity and stability of foam structures are due to the significant content of type I destructured collagen (in a sample from the skin of Commander squid), and hydrophilic amino acids and type III collagen fragments (in a product made from Pacific squid skin). Infrared drying of products promotes denaturation and gelatinization of collagen in the skin of Commander squid, which is confirmed by the brighter color characteristics of the samples and high moisture-binding capacity when the temperature rises to 40 and 60 °C; this fact indicates an increase in the hydrophilic properties of the products of destruction of collagen fractions. Products made from skin, which is a secondary product of squid processing, have high potential for use in the food industry as water-retaining, fat-binding, and fat-emulsifying components.

Advanced catalytic and biomedical applications of silver functionalized SnCuO3 nanocomposites synthesized through novel surfactant mediated chemical approach

In the current contribution, silver impregnated and un impregnated bimetallic oxide nanocomposites of SnCuO3 were synthesized by a novel surfactant mediated chemical approach. The tween-80 was used as a surfactant to effectively modulate the morphological features of the nanocomposites. The synthesized nanocomposites were characterized by XRD, HRTEM, SEM, EDX, FTIR and XPS. The results revealed the rod-shaped surface morphology of the nanocomposites with length and diameter of 245 nm and 66 nm respectively. The synthesized nanocomposites were tested for catalytic and biomedical applications. The rate of catalytic degradation reaction of methylene blue by the SnCuO3 and Ag/SnCuO3 nanocomposites were found to be 10.2 and 8.5 respectively. Only in 10 min all the dye molecules were degraded. The synthesized nanomaterials SnCuO3 and Ag/SnCuO3 are potent antileishmanial agents having CC50 value 12728.03 and 3001.70 µg/mL respectively that were found to be biocompatible with very low toxicity as revealed by their hemolytic activity results. Moreover, the nanostructures exhibited promising antibacterial properties by effectively inhibiting the growth of both E. coli and S. aureus bacteria through photoinhibition. When subjected to visible light irradiation, the growth inhibition zone of Ag/SnCuO3 against E. coli and S. aureus was measured at (15 ± 0.4 mm) and (17 ± 0.3 mm), respectively. These nanostructures demonstrated the ability to impede bacterial proliferation and viability, underscoring their potential for use in water disinfection and as antibacterial coatings utilizing Ag/SnCuO3.

Multiple defect states engineering towards high thermoelectric performance in GeTe-based materials

GeTe is a promising material for thermoelectric (TE) applications. However, its low Seebeck coefficient and high thermal conductivity in the mid-temperature range of 298–550 K have hindered its widespread use in TE devices. In this work, we show that a combination of band engineering, Fermi level tuning, and miscibility gap exploration can significantly improve the energy conversion performance of GeTe. Bi provides the optimized carrier concentration and induces band convergence, while Ga possibly forms a resonant state. The synergistic effects of Bi and Ga significantly improve the Seebeck coefficient from 38 µVK−1 for undoped GeTe to over 120 µVK−1 for Bi and Ga-containing materials at 298 K and provide a high power factor over a wide temperature range. Phonon scattering is strengthened by optimizing the microstructure through Pb-induced spinodal decomposition and enhanced point defect scattering due to increased dopant solubility, resulting in a very low lattice thermal conductivity of about 0.5 Wm-1K−1 at 600 K for the triple-doped samples. The maximum thermoelectric figure of merit ZT was significantly increased to 2.1 at 600 K for the Ge0.87Pb0.05Bi0.06Ga0.02Te sample due to the improved power factor and reduced lattice thermal conductivity. Additionally, the average figure of merit ZTave for this sample achieved a very high value of 1.4 for Ge0.87Pb0.05Bi0.06Ga0.02Te at a temperature gradient of 475 K (Tc = 298 K). The developed material shows great potential for use in energy conversion devices, with an estimated energy conversion efficiency exceeding 17 %.

Iron Metabolism in Aminolevulinic Acid-Photodynamic Therapy with Iron Chelators from the Thiosemicarbazone Group.

Iron plays a crucial role in various metabolic processes. However, the impact of 5-aminolevulinic acid (ALA) in combination with iron chelators on iron metabolism and the efficacy of ALA-photodynamic therapy (PDT) remain inadequately understood. This study aimed to examine the effect of thiosemicarbazone derivatives during ALA treatment on specific genes related to iron metabolism, with a particular emphasis on mitochondrial iron metabolism genes. In our study, we observed differences depending on the cell line studied. For the HCT116 and MCF-7 cell lines, in most cases, the decrease in the expression of selected targets correlated with the increase in protoporphyrin IX (PPIX) concentration and the observed photodynamic effect, aligning with existing literature data. The Hs683 cell line showed a different gene expression pattern, previously not described in the literature. In this study, we collected an extensive analysis of the gene variation occurring after the application of novel thiosemicarbazone derivatives and presented versatile and effective compounds with great potential for use in ALA-PDT.

Artificial intelligence-enabled multipurpose smart detection in active-matrix electrowetting-on-dielectric digital microfluidics

An active-matrix electrowetting-on-dielectric (AM-EWOD) system integrates hundreds of thousands of active electrodes for sample droplet manipulation, which can enable simultaneous, automatic, and parallel on-chip biochemical reactions. A smart detection system is essential for ensuring a fully automatic workflow and online programming for the subsequent experimental steps. In this work, we demonstrated an artificial intelligence (AI)-enabled multipurpose smart detection method in an AM-EWOD system for different tasks. We employed the U-Net model to quantitatively evaluate the uniformity of the applied droplet-splitting methods. We used the YOLOv8 model to monitor the droplet-splitting process online. A 97.76% splitting success rate was observed with 18 different AM-EWOD chips. A 99.982% model precision rate and a 99.980% model recall rate were manually verified. We employed an improved YOLOv8 model to detect single-cell samples in nanolitre droplets. Compared with manual verification, the model achieved 99.260% and 99.193% precision and recall rates, respectively. In addition, single-cell droplet sorting and routing experiments were demonstrated. With an AI-based smart detection system, AM-EWOD has shown great potential for use as a ubiquitous platform for implementing true lab-on-a-chip applications.

THE EFFECT OF THE ELECTROLYTE COMPOSITION ON THE MICROSTRUCTURE AND MECHANICAL PROPERTIES OF STEEL 45 AFTER CATHODIC ELECTROLYTE-PLASMA NITRIDING

This research offers an in-depth exploration of the impact of cathodic nitriding on the structural and mechanical characteristics of 45 steel treated in different aqueous electrolytes. Through a combination of Xray diffraction and electron microscopy analyses, it was determined that the nitriding process facilitates the development of a multilayered surface structure, which includes oxide, nitride, and martensitic layers. The composition of the electrolyte plays a crucial role in determining the phase composition and thickness of the modified layers, directly influencing the steel's mechanical properties, as reflected by variations in hardness and wear resistance post-treatment. Notably, an electrolyte containing sodium carbonate (Na₂CO₃) and urea (CH₄N₂O) achieved a maximum microhardness of 986 HV due to the formation of a dense nitride layer. On the other hand, introducing ammonium nitrate to the electrolyte, while slightly decreasing the microhardness to 882 HV, resulted in the formation of a more intricate and stable phase structure, including additional nitrides and oxides, which contributed to enhanced corrosion resistance. These findings underscore the critical importance of optimizing electrolyte composition to improve the performance characteristics of steel, such as hardness, wear resistance, and corrosion resistance. This study underscores the effectiveness of cathodic nitriding as a method for significantly enhancing the mechanical and surface properties of 45 steel, thereby expanding its potential for use in high-load and aggressive environments.

Fabrication of injectable, adhesive, self-healing, superabsorbent hydrogels based on quaternary ammonium chitosan and oxidized pullulan

Injectable hydrogels, which are polymeric materials that are characterized by their ability to be injected in a liquid form into cavities and subsequently undergo in situ solidification, have garnered significant attention. These materials are extensively used in a range of biomedical applications. This study synthesized several injectable composite hydrogels through the mild Schiff base reaction while imposing different concentrations of quaternary ammonium chitosan and oxidized pullulan. Subsequent characterizations revealed a consistent and coherent porous structure within the hydrogels with smooth inner walls. The hydrogels were also determined to possess good adhesion, mechanical properties, self-healing ability, and injectability. Furthermore, antimicrobial tests against Escherichia coli and Staphylococcus aureus demonstrated antibacterial properties, which improved with increasing concentrations of quaternary ammonium chitosan. Co-culturing with skin fibroblasts demonstrated that the injectable hydrogels exhibited favourable biocompatibility and the capacity to boost cellular activity, thus underscoring its potential for use in biomedical applications.

Expediting adenovirus titer assays via an algorithmic live-cell imaging technique

Interest in virus-based therapeutics for the treatment of genetic and oncolytic diseases has created a demand for high-yield, low-cost virus-manufacturing processes. However, traditional analytical methods of assessing infectious virus titer require multiple processing steps and manual counting, limiting sample throughput, and increasing human error. This bottleneck severely limits the development of new manufacturing unit operations to drive down costs. In this work, we utilize an Incucyte Live-Cell Analysis System to develop a high-throughput infectious titer assay for adenovirus expressing a GFP-transgene. Although previous studies have demonstrated live-cell imaging’s potential for use with other viruses, they provide little guidance regarding the selection of the viewing and analysis parameters. To fill this gap, we develop an algorithmic approach to identify the optimum viewing and analysis parameters and create a statistical workflow for quantifying infectious adenovirus in a sample dilution series in a standard 24-well microplate. The developed assay is comparable to Hexon staining, the gold-standard for adenovirus infectious titer, with a Pearson correlation coefficient of 0.9. Finally, the developed algorithmic approach and statistical workflow were applied to create an assay for adenovirus titer using a 96-well microplate, allowing five times more samples to be quantified compared to the standard 24-well plate. While this assay uses a GFP-insert that precludes its use in a clinical environment, the key learnings surrounding the careful use of viewing and analysis parameters, and the statistical workflow are widely applicable to implementing life-cell imaging for dilution-series-based assays. Moreover, this method directly enables the fast and accurate evaluation of virus samples in a preclinical environment.

Ab-initio investigation of structural, electronic, thermoelectric and optical properties of Full-Heusler X2MnB (X = Ti, Zr) for energy harvesting applications

In this manuscript comprehensive first-principles calculations have been presented for Full-Heusler X2MnB (X = Ti, Zr) compounds. This work includes detailed observations of the structural stability, origin of the transport phenomenon, optical properties, and electronic response. Structural parameters support the previous findings by confirming structural stability in the non-magnetic phase. Ti2MnB (Zr2MnB) valence band maxima and conduction band minima have bandgaps of 0.217 (0.301) eV and 0.181 (0.209) eV for PBE-GGA (mBJ) approximations which lie between L-L symmetry points. Due to the comparative measurements of the two states, the DOS results show that the Ti1/Zr1, Ti2/Zr2 Mn eg, and t2g states mainly contribute to the valence band region for Ti2MnB and Zr2MnB alloys, confirming their ionic nature. The computation of the overall electronic parameters’ reveals semiconducting nature. Thermoelectric properties have been calculated as a function of temperature in the 100–1200 K range. The positive values of Seebeck coefficients specify p-type character of X2MnB While at 300 K, Zr2MnB and Ti2MnB showed the highest Seebeck coefficients, measuring roughly values of 268 (µK/V) and 243 (µK/V), respectively. These values suggest that the material exhibits high thermoelectric performance. Though high optical absorption coefficient and low reflectivity in the visible and ultra violet regions, confirms use of these materials in solar cell applications. These findings suggest that material holds great potential for use in thermoelectrical applications which can support in upcoming experimental considerations.

Forecasting Appropriate Habitats for Rare and Endangered Indocalamus Species in China in Response to Climate Change

China’s rare and endangered bamboo species belonging to the Indocalamus genus, specifically Indocalamus decorus Q. H. Dai, Indocalamus hirsutissimus Z. P. Wang & P. X. Zhang, and Indocalamus pedalis (Keng) P. C. Keng, possess notable value in biodiversity conservation and have significant potential for use in landscape design. Using an enhanced MaxEnt model, this study forecasted shifts in the species’ potential range under four separate climate scenarios (SSP1-RCP2.6, SSP2-RCP4.5, SSP3-RCP7.0, and SSP5-RCP8.5), considering both the historical period (1970–2000, referred to as “the current period”) and upcoming timeframes (2021–2040, 2041–2060, 2061–2080, and 2081–2100). The analysis disclosed that the present total potential habitat area for these species is approximately 251.79 × 104 km2, with high, medium, and low suitability areas occupying 0.15 × 104 km2, 125.39 × 104 km2, and 126.26 × 104 km2, respectively. The minimum temperature of the coldest month emerged as the critical determinant of their potential habitat distribution. Expected climate changes are likely to increase the suitable habitat for these species, although areas with low suitability might slightly diminish, with Guizhou and Chongqing showing the least impact. The distribution centers of suitable habitats for the three plant species consistently exhibit a westward shift under various climate scenarios. These results contribute valuable insights for the spatial distribution, continuous monitoring, sustainable management, and ex situ conservation in response to climate change.

Pontederia cordata Pickerel Weed

This document provides an overview of the pickerel weed (Pontederia cordata), a native aquatic plant found in Florida and other parts of eastern North America. It describes the plant’s habitat, growth characteristics, and ornamental features, highlighting its adaptability to shallow wetland areas and its attractive purple-blue flowers. The document also covers planting guidelines, including optimal water depth and spacing, and notes the plant’s aggressive growth habit and potential for use in water gardens and pond stabilization. Additionally, it mentions the plant’s pest resistance and propagation methods. Original publication date October 1999.

Advanced computational screening of X2CaH4 (X = Rb and Cs) for hydrogen storage applications

Utilizing cutting-edge computational screening methods, this study explores the hydrogen storage capacity of two complex metal hydrides, Cs2CaH4 and Rb2CaH4. We perform a thorough analysis of their structural, electrical, optical, and hydrogen storage properties using density functional theory (DFT). Within the I4/mmm space group, both compounds display stable tetragonal crystal structures, and their thermodynamic stability is confirmed by their formation energies. Notably, compared to Rb2CaH4, Cs2CaH4 is more stable. With band gaps of 2.99 eV for Cs2CaH4 and 3.28 eV for Rb2CaH4, the electronic properties show insulating behavior, which is beneficial for reducing electronic interference during hydrogen absorption and desorption. A comparative research reveals that the potential gravimetric hydrogen storage capacities of Cs2CaH4 (1.28%) and Rb2CaH4 (1.86%) are comparable to, albeit marginally less than, those of materials that are frequently explored, such as lithium borohydride. With their individual absorption and reflectivity peaks, the optical characteristics offer more information about how they interact with electromagnetic radiation, information that may be useful for improving their performance in real-world applications. Our results imply that Cs2CaH4and Rb2CaH4 have considerable potential for use in practical hydrogen storage systems, especially in situations where stability and minimal electronic interference are essential. Subsequent research endeavors may concentrate on enhancing the hydrogen storage capacity of these materials, so rendering their incorporation into existing hydrogen storage methods more feasible.

Snap&Nav: Smartphone-based Indoor Navigation System For Blind People via Floor Map Analysis and Intersection Detection

We present Snap&Nav, a navigation system for blind people in unfamiliar buildings, without prebuilt digital maps. Instead, the system utilizes the floor map as its primary information source for route guidance. The system requires a sighted assistant to capture an image of the floor map, which is analyzed to create a node map containing intersections, destinations, and current positions on the floor. The system provides turn-by-turn navigation instructions while tracking users' positions on the node map by detecting intersections. Additionally, the system estimates the scale difference of the node map to provide distance information. Our system was validated through two user studies with 20 sighted and 12 blind participants. Results showed that sighted participants processed floor map images without being accustomed to the system, while blind participants navigated with increased confidence and lower cognitive load compared to the condition using only cane, appreciating the system's potential for use in various buildings.

186Re]Re- and [99mTc]Tc-Tricarbonyl Metal Complexes with 1,4,7-Triazacyclononane-Based Chelators Bearing Amide, Alcohol, or Ketone Pendent Groups.

1,4,7-Triazacyclononane (TACN)-based chelators, such as NOTA and NODAGA, have shown great promise as bifunctional chelators for [M(CO)3]+ cores (M = 99mTc and 186Re) in radiopharmaceutical development. Previous investigations of TACN-based chelators bearing pendent acid and ester arms demonstrated the important role the pendent arms have in successful coordination of the [M(CO)3]+ core with the TACN backbone nitrogens. In this work, we introduce three TACN-based bifunctional chelators bearing amide, alcohol, and ketone pendent arms and evaluate their (radio)labeling efficiency with the [M(CO)3]+ core as well as the in vitro stability and hydrophilicity of the resulting radiometal complexes. Following their synthesis and characterization, the amide (2) and alcohol (3) chelators were successfully labeled with the [M(CO)3]+ cores (M = natRe, 99mTc, and 186Re), while the ketone (4) was not successfully labeled. Radiometal complexes M-2 and M-3 demonstrated hydrophilic character in logD7.4 studies as well as excellent stability in phosphate-buffered saline (pH 7.4), l-histidine, l-cysteine, and rat serum at 37 °C through 24 h. While the hydrophilicity and stability of these radiocomplexes are attractive, future TACN chelator design modifications to increase radiolabeling yields under milder reaction conditions would improve their potential for use in development of [M(CO)3]+ radiopharmaceuticals.

Reversed Mg-Based Smectites: A New Approach for CO2 Adsorption

Addressing climate change requires transitioning to cleaner energy sources and adopting advanced CO2 capture techniques. Clay minerals are effective in CO2 adsorption due to their regenerative properties. Recent advancements in nanotechnology further improve their efficiency and potential for use in carbon capture and storage. This study examines the CO2 adsorption properties of montmorillonite and saponite, which are subjected to a novel microwave-assisted acid treatment to enhance their adsorption capacity. While montmorillonite shows minimal changes, saponite undergoes significant alterations. Furthermore, the addition of silica pillars to smectites results in a new nanomaterial with a higher surface area (653 m2 g−1), denoted as reversed smectite, with enhanced CO2 adsorption capabilities, potentially useful for electrochemical devices for converting captured CO2 into value-added products.