Post Heat Research Articles

Structural Changes in Manganese Oxides on Zeolite Y in Benzene Oxidation with Ozone and Post-Heat Treatment

Structural Changes in Manganese Oxides on Zeolite Y in Benzene Oxidation with Ozone and Post-Heat Treatment

Tribological performance of 410L martensitic stainless steel parts manufactured by Laser directed energy deposition

The processing of AISI 410L martensitic stainless steel (MSS) by laser directed energy deposition (L-DED) for additive manufacturing (AM) of wear-resistant components is an alternative to the high C-content MSS grade, with difficult processability. This work assesses the tribological performance of low C-content 410L MSS additively manufactured by L-DED. Two sets of L-DED parameters were investigated, one targeting Production and high deposition rates, and the other for Resolution and increased geometric freedom. Half of the multilayer samples were subjected to a post heat-treatment route. Samples were evaluated by the dry-sliding linearly reciprocating ball-on-flat tribological test (ASTM G133) in the as-built and heat-treated states. Commercially annealed 410 MSS was the reference material. In the L-DED as-built, microstructures were composed of ferrite with martensite at the grain boundaries. Heat-treatment provides recrystallization, martensite tempering, and hardness decrease. The more refined microstructure of L-DED resolution as-built led to greater hardness and lower wear coefficient in the ASTM G133 test. Wear tracks revealed wider bands of compact tribolayers on its surface, which reduced the action of adhesive and abrasive mechanisms. The other L-DED as-built and heat-treated conditions, and 410 reference material demonstrated a large amount of free debris, indicating lower wear resistance.

Microstructural analysis of Inconel 718 manufactured via direct energy deposition: response surface methodology for process parameters optimisation and post-heat treatment

Microstructural analysis of Inconel 718 manufactured via direct energy deposition: response surface methodology for process parameters optimisation and post-heat treatment

Programmable mechanical properties of additively manufactured novel steel

Abstract Tailoring thermal history during additive manufacturing (AM) offers a feasible approach to customise the microstructure and properties of materials without changing alloy compositions or post-heat treatment, which is generally overlooked as it is hard to achieve in commercial materials. Herein, a customised Fe–Ni–Ti–Al maraging steel with rapid precipitation kinetics offers the opportunity to leverage thermal history during AM for achieving large-range tunable strength-ductility combinations. The Fe–Ni–Ti–Al steel was processed by laser-directed energy deposition (LDED) with different deposition strategies to tailor the thermal history. As the phase transformation and in-situ formation of multi-scale secondary phases of the Fe–Ni–Ti–Al steel are sensitive to the thermal histories, the deposited steel achieved a large range of tuneable mechanical properties. Specifically, the interlayer paused deposited sample exhibits superior tensile strength (∼1.54 GPa) and moderate elongation (∼8.1%), which is attributed to the formation of unique hierarchical structures and the in-situ precipitation of high-density η-Ni3(Ti, Al) during LDED. In contrast, the substrate heating deposited sample has an excellent elongation of 19.3% together with a high tensile strength of 1.24 GPa. The achievable mechanical property range via tailoring thermal history in the LDED-built Fe–Ni–Ti–Al steel is significantly larger than most commercial materials. The findings highlight the material customisation along with AM’s unique thermal history to achieve versatile mechanical performances of deposited materials, which could inspire more property or function manipulations of materials by AM process control or innovation.

Enhancing nitrous oxide chemiresistive sensing performance by reducing ionic Oxygen species adsorption in Gold functionalized Tungsten Trioxide nanofibers

Low-cost nitrous oxide (N2O) gas sensor is in great need to provide real-time information to various stakeholders. Herein, various gold functionalized tungsten trioxide nanofibers (Au-WO3 NFs) with different composition and crystallinity were synthesized by controlling electrospinning solutions and post heat treatment. These sensing materials were systematically exposed to various N2O concentrations at different operating temperatures (i.e., 250 to 450 °C). Among different samples, 1 at % gold functionalized WO3 nanofibers (1 at % Au-WO3 NF) annealed at 600 °C for 24 h shows the highest sensitivity (S = Ra/Ro) of 38.5 toward 100 ppm at 250 °C with experimentally determined limit of detection (LOD) at 2.5 ppm. Although recovery and recovery time improved, the sensitivity reduced with an increase in operating temperatures. The detailed sensing mechanism studies indicated that the high N2O sensing was achieved when there were limited adsorbed ionized oxygen species (e.g., O-). Moreover, N2O adsorption and desorption activation energy were estimated to be 0.13 and 0.87 eV where desorption was more strongly temperature dependent than adsorption.

Exploring the Impact of Heat Treatment on Residual Stress, Microstructure, and Mechanical Behavior of Laser Powder Bed Fusion Additively Manufactured Ti-6Al-2Sn-4Zr-2Mo Alloy

In the field of additive manufacturing (AM), a promising alloy that is gaining attention is the near-α Ti-6Al-2Sn-4Zr-2Mo (Ti6242) alloy. This alloy is known for its remarkable resistance to creep and corrosion at elevated temperatures. However, the production of Ti6242 components via Laser-based AM technologies faced with several challenges, such as the formation of residual stress in the as-built state that originates from the nature of these processes. Therefore, this study has a dual objective: first, to evaluate the microstructure and residual stresses in the as-built Ti6242 produced through laser powder bed fusion. Secondly, to investigate the impact of a promising post heat treatment on mitigating residual stresses, inducing alterations in the microhardness of the Ti6242 alloy and its ductility, phase transformations and microstructure evolution. The as-built specimen exhibited a significant residual stress of 1357 MPa, which was caused by the pronounced temperature gradients experienced during the fabrication process. It is interesting to note that this promising post heat treatment was highly effective in eliminating 99% of the residual stress. After heat treatment, the amount of α' present in the as-built specimen decreased. This resulted in the activation of diffusion of elements such as molybdenum, causing a proportion of the α' to decompose into the more ductile α+β structure. Additionally, it is revealed that the microstructural changes and relieved stresses from the heat treatment process caused a lower microhardness and a higher ductility under compressive loading, as the elongation and toughness reached 20.5% and 23.255 kJ/mm3 in the heat-treated samples, respectively. The outcomes of this work facilitate the use of this alloy in the production of complex shape components through laser-based AM technologies.

Influence of post-heat treatments on the microstructure and mechanical properties of Inconel 738 produced by laser directed energy deposition

Influence of post-heat treatments on the microstructure and mechanical properties of Inconel 738 produced by laser directed energy deposition

Mimicking the Architecture and Dissolution Chemistry of Cancellous Bone Tissue to Optimize the Biocompatibility of Bioactive Scaffolds.

Synthesis of mechanically stable porous scaffolds with an architecture analogous to cancellous bone tissue poses significant challenges to bioactive glass (BG) based scaffolds. This is primarily due to densification and crystallization of the BG's during heat treatment. This study presents a modified BG series (42SiO2-xTiO2-24Na2O-21CaO-13P2O5, where x = 8 and 16 TiO2). TiO2 replaced the SiO2 concentration in the glass and was incorporated due to its biocompatibility and influence on glass structure. Material characterization determined that TiO2 did not induce crystallization within the glass but did increase the glass transition temperature (Tg) from 520°C to 600°C thereby indicating a more stable network connectivity. Scaffolds were synthesized using the foam replication method, resulting in scaffolds with a pore size of approximately 500 μm with the BG-4 composition (30SiO2-12TiO2-24Na2O-21CaO-13P2O5) retaining its amorphous character post-heat treatment. Scaffold ion release was monitored over 5-60 days in simulated body fluid (SBF). Si4+ release was found to decrease, while Ca2+ levels increased in SBF as TiO2 replaced SiO2 within the glass series. Cytocompatibility studies revealed that MC3T3 Osteoblast cells proliferated on the BG-4 scaffold surface and at its interface within culture media, and cell numbers were not significantly reduced.

Enhancing the Mechanical Properties of Co-Cr Dental Alloys Fabricated by Laser Powder Bed Fusion: Evaluation of Quenching and Annealing as Heat Treatment Methods.

Residual stresses and anisotropic structures characterize laser powder bed fusion (L-PBF) products due to rapid thermal changes during fabrication, potentially leading to microcracking and lower strength. Post-heat treatments are crucial for enhancing mechanical properties. Numerous dental technology laboratories worldwide are adopting the new technologies but must invest considerable time and resources to refine them for specific requirements. Our research can assist researchers in identifying thermal processes that enhance the mechanical properties of dental Co-Cr alloys. In this study, high cooling rates (quenching) and annealing after quenching were evaluated for L-PBF Co-Cr dental alloys. Cast samples (standard manufacturing method) were tested as a second reference material. Tensile strength, Vickers hardness, microstructure characterization, and phase identification were performed. Significant differences were found among the L-PBF groups and the cast samples. The lowest tensile strength (707 MPa) and hardness (345 HV) were observed for cast Starbond COS. The highest mechanical properties (1389 MPa, 535 HV) were observed for the samples subjected to the water quenching and reheating methods. XRD analysis revealed that the face-centered cubic (FCC) and hexagonal close-packed (HCP) phases are influenced by the composition and heat treatment. Annealing after quenching improved the microstructure homogeneity and increased the HCP content. L-PBF techniques yielded superior mechanical properties compared to traditional casting methods, offering efficiency and precision. Future research should focus on fatigue properties.

Research on the microstructure and properties of metastable β type Ti-8V4Mo3Cr3Zr3Al alloy with high strength and toughness

In this paper, a new type of Ti-8V-4Mo-3Cr-3Zr-3Al metastable β-type titanium alloy is designed based on alloy design parameters such as valence electron concentration (VEC), Bo, and Md, and combines them with the empirical criterion of molybdenum equivalent fractionation. Optimize the microstructure of the alloy through processes such as cold rolling, annealing, and aging treatment to obtain good mechanical properties. The microstructure of cold rolling and post rolling heat treatment was observed and analyzed using optical microscopy (OM), scanning electron microscopy (SEM), X-ray diffraction (XRD), and transmission electron microscopy (TEM), and the tensile properties of the alloy were tested. The characteristics of the alloy in terms of microstructure and properties were summarized and analyzed. The results show that the cold formability of the alloy after solid solution treatment is good, with a cold rolling reduction of over 85 %, and a large number of deformation twins generated during the cold rolling process. The yield strength after annealing and recrystallization is up to 1160 MPa, and elongation is 18.9 %. The final performance of the aged alloy is 1510 MPa for yield strength and 5 % for elongation.

A Preliminary Study on Structural and Optical Properties of Heat Treated Nb2O5 Nanostructure

Annealing is a heat treatment that alters the physical and sometimes chemical properties of a material to improve their crystalline structure and other important properties. This work presents the effect of post heat treatment on optical, structural, morphological, and surface roughness of Nb2O5 thin films at different temperatures (200-700oC) which to the best of our knowledge not been extensively studied yet. A clear modification in surface morphology and other studied properties was obtained. XRD results show a significant enhancement in the film’s structural properties such as a reduction in the dislocation densities and stress. The optical properties of the treated films show a clear decrease in the transmission and energy gap values which their values were found to reduce from (4.35 to 2.9) eV with heat treatment up to 600oC and re-increase at 700oC. The surface roughness was also enhanced as a result of increasing the grain size from (9.95 – 34.7) nm Finally, SEM images of the films show an obvious change in their morphology and an increase in film uniformity as a result of heat treatment. Therefore, heat treatment could be considered as a helpful method to control film characteristics. Main result should be presented quantitatively.

Compressive strength of nano concrete materials under elevated temperatures using machine learning

In this study, four Artificial intelligence (AI) - based machine learning models were developed to estimate the Residual compressive strength (RCS) value of concrete supported with nano additives of Nanocarbon tubes (NCTs) and Nano alumina (NAl), after exposure to elevated temperatures ranging from 200 to 800 degrees. These models were developed via adapting meta- heuristic models including the Water cycle algorithm (WCA), Genetic algorithm (GA), and classical AI models of Artificial neural networks (ANNs), Fuzzy logic models (FLM), in addition to the statistical method of Multiple linear regression (MLR). 156 post heating experimental results available as a literature data (represents four input parameters of temperature change, heat exposure duration, nanomaterial type, and replacement proportion) are used to achieve the study’s objective. Results of the developed models demonstrated that ANN and FLM have strong potential in predicting RCS. However, it is often infeasible to generate practical equations that relate input and output variables from these models. Upon analysing the results of the WCA and GA, it was found that WCA yielded the most accurate predictions based on all performance indicators. Furthermore, RCS prediction equations with superior accuracy were derived utilizing the meta-heuristic AI models of WCA and GA, with Mean absolute errors (MAEs) of 3.09 kg/cm² and 3.53 kg/cm² for the training, 1.91 kg/cm² and 2.72 kg/cm² for the validation, and 1.91 kg/cm² and 2.72 kg/cm² for the testing data sets, respectively. Additionally, sensitivity analysis via neural networks weights and SHAP investigation were performed to reveals the impact and relationship of the input variables with the output variables. Both techniques reveal that temperature degree and time of exposure had the highest positive impact on RCS value, followed by NAl and NCTs, in order.

Advancements in biomedical coatings: A comprehensive review of DC magnetron sputtering on Ti–6Al–4V alloy

This study investigates the application of DC magnetron sputtering (MS) technology for producing TiN and ion-substituted Ca-P coatings on dental implant materials, demonstrating ultimate tensile strength (UTS) of 887 MPa, a modulus of elasticity of 11.3 × 106 MPa. The influence of various physical vapor deposition (PVD-MS) parameters—such as substrate temperature, post-heat treatment, deposition duration, discharge power, and bias voltage—on the characteristics of these coatings is examined. The research evaluates the advantages and limitations of PVD-MS in fabricating TiN and Ca-P coatings, with an emphasis on their impact on surface topography and chemical composition, which are critical factors influencing cellular behavior. The study reveals that while ion-substituted HA coatings can enhance cell adhesion, they may also exhibit cytotoxic effects, potentially limiting cell growth. It compares osteogenic cell proliferation rates between low-crystalline HA coatings and highly crystalline variants on Ti-based substrates, highlighting significant performance disparities. Additionally, PVD-MS demonstrates robust adhesion capabilities and facilitates the incorporation of therapeutic ions, effectively replicating bioapatite properties. The addition of coating on the substrate promotes additional strengthening mechanisms of the layers, leading to improved wear resistance compared to an alloyed substrate. Estimated values for hardness range between 7.2 and 8.4 GPa, and for Young's modulus, they range from 126 to 162 GPa. The study highlights the potential of PVD-MS in creating nanostructured Ca-P coatings on biodegradable metals, alloys, and polymeric biomaterials. This technology improves corrosion resistance, biocompatibility, chemical stability, wear resistance, and overall performance in various biomedical applications.

Development of highly oriented crystals in the magnetoplumbite structure of metal (Sr, Cr, Sc) doped M-type BaFe12O19 hexaferrite films with improved optical and magnetic properties

We have deposited magnetoplumbite (P63/mmc) structured Ba-hexaferrite (BaFe12O19) and its metal (T: Sc and Cr) doped (Ba0.7Sr0.3Fe12O19 and BaFe11.5T0.5O19) films on Si substrate using the Pulsed Laser Deposition technique. The as-grown films showed preferential orientation of the crystals along (2 0 3), (2 0 7), (1 1 14), and (4 0 5) directions. The post-heat treatment oriented the crystals only along (2 0 7) direction. The Fe ions varied it charge state from +3 at the surface of the films to a mixed charge state in the interior, which promoted a local clustering of Fe3O4-like phase. Ferrimagnetic properties of the hexaferrite films have been modified due to metal doping. The bi-phased magnetic structure, arising from clustering of the soft ferrimagnetic Fe3O4 phase in the matrix of hard ferrimagnetic hexaferrite films, is suitable for tuning the magnetic coercivity and moment over a wide range of temperatures. The optical band gap in the range of 3.40–3.50 eV and a strong magneto-optical Kerr signal are promising for potential applications of the films in magneto-optical devices working in UV regime of radiation.

Novel post-heat treatment green biodegradable PLA@SiO2 nanocomposite membrane for water desalination

Membrane distillation (MD) has received significant attention because of its energy efficiency and ability to treat industrial wastewater and salty water. However, the synthetic nature of commonly used membranes raises environmental disposal concerns, requiring the development of alternative eco-membranes. To address this issue, a novel, eco-friendly membrane using polylactic acid (PLA) coated with green silica nanoparticles (SiO2 NPs), modified by post-heat treatment, was developed for effective direct contact membrane distillation (DCMD). Herein, two nanofibrous membranes were fabricated via electrospinning/electrospraying: one, PLA, with a 12.5 wt% PLA solution, and another, PLA@SiO2, with 2 % (w/v) SiO2 NPs coating. The PLA@SiO2 membrane demonstrated enhanced hydrophobicity. Various post-heat treatments were applied to optimize membrane properties, such as structure, pore size, hydrophobicity, liquid entry pressure (LEP), thickness, and thermal stability. In addition, the desalination performance of all membranes was evaluated using a DCMD unit for 6 h. Results showed that the heat-pressed then annealed PLA@SiO2 membrane (denoted M44) exhibited notable improvements, including an LEP of 128.7 kPa, a tunable pore size of 0.21 μm, and a contact angle of 135.9°. Furthermore, the M44 membrane demonstrated a porosity of 80.5 %, a stable permeate flux of 14.3 kg.m−2.h−1, and an exceptional salt rejection of 99.99 % over a 24 h DCMD test. This novel eco-membrane shows promising potential for efficient desalination and represents a significant advancement in sustainable MD applications.

Self-Modification of Dynamic Network Valence Bonds in ZeinNFs via Post-Heat Treatment: Preparation of an Efficient and Environmentally Friendly Ethylene Adsorbent

Self-Modification of Dynamic Network Valence Bonds in ZeinNFs via Post-Heat Treatment: Preparation of an Efficient and Environmentally Friendly Ethylene Adsorbent

Effect of Pre-sodium Hydroxide and Post-heat Treatments on Copper Oxide-Based Photocathode: A Perspective on Photoelectrochemical Water Splitting and CO2 Reduction

Effect of Pre-sodium Hydroxide and Post-heat Treatments on Copper Oxide-Based Photocathode: A Perspective on Photoelectrochemical Water Splitting and CO2 Reduction

Reversibly Compressible Silanated Cellulose Nanofibril Aerogel for Triboelectric Taekwondo Scoring Sensors.

The integration of bio-based materials into triboelectric nanogenerators (TENGs) for energy harvesting from human body motions has sparked considerable research attention. Here, a silanated cellulose nanofibril (SCNF) aerogel is reported for structurally reliable TENGs and reversely compressible Taekwondo scoring sensors under repeated impacts. The preparation of the aerogel involves silanizing cellulose nanofibers (CNFs) with vinyltrimethoxysilane (VTMS), following by freeze-drying and post-heating treatment. The SCNF aerogel with crosslinked physico-chemical bonding and highly porous network is found to exhibit superior mechanical strength and reversible compressibility as well as enhanced water repellency and electron-donating ability. The TENG having a tribo-positive SCNF layer exhibits exceptional triboelectric performances, generating a voltage of 270V, current of 11µA, and power density of 401.1mWm-2 under an applied force of 8N at a frequency of 5Hz. With its inherent merits in material composition, structural configuration, and device sensitivity, the SCNF TENG demonstrates the capability to seamlessly integrate into a Taekwondo protection gear, serving as an efficient self-powered sensor for monitoring hitting scores. This study highlights the significant potential of a facilely fabricated SCNF aerogel for the development of high-performance, bio-friendly, and cost-effective Bio-TENGs, enabling their application as self-powered wearable devices and sports engineering sensors.

ИССЛЕДОВАНИЕ ВЛИЯНИЯ ПОСТТЕРМООБРАБОТКИ НА СТРУКТУРУ АЛИТИРОВАННОГО СЛОЯ НА ТИТАНЕ ВТ1-0

The study results of the post-heat treatment effect on the structure of the aluminized layer on VT1-0 titanium are presented. It is shown that the coating after heat treatment at 700 and 850 °C for 20 h consists of two layers. In the outer layer, rounded TiAl3 particles are separated by aluminum oxide Al2O3. A continuous diffusion zone of ~10 μm thickness is formed at the boundary with titanium, consisting of several layers representing TiAl2, TiAl and Ti3Al aluminides.

EFFECTS OF HEAT TREATMENT ON THE IMPROVED WEAR RESISTANCE OF SHOT BLAST MACHINE BLADE MATERIAL

The blade is a component of the shot blast machine that functions as a thrower of small steel balls (steel shot). During its use, the blade undergoes impacts and friction with the steel shot, causing wear and a shortened lifespan. The material typically used for blades is white cast iron. Hence, the blade must possess good hardness and wear resistance. This study analyzed the causes of blade failure and proposed solutions in the form of hardening and tempering treatments. The tests conducted in this research included composition analysis, metallographic examination, hardness testing, and wear resistance testing. Based on the composition and hardness tests, the failure was attributed to material composition and hardness not meeting the ASTM A532 standards. The solution to this failure involves heat treatment to achieve hardness that complies with ASTM A532 standards, specifically hardening at 900°C for 40 minutes, followed by cooling with oil as the quenching medium. Then, the tempering process was carried out at 200°C, 250°C, and 300°C with holding times of 80 and 120 minutes. Post-heat treatment, the optimal hardness value, and the lowest wear rate were obtained at a tempering temperature of 300°C with a holding time of 120 minutes. The hardness value of the blade material under these conditions reached 63.8 HRC, and the wear rate was 1,21E-04 mm3.kg-1.m-1. A low wear rate indicates that the material has high wear resistance.