This study investigates the gas permeability, diffusion coefficients, and solubility coefficients of CO2 and N2 in PIM-1 over the temperature range of 35 °C–135 °C. During the first heating-cooling cycle, both gases' permeability exhibited hysteresis, which diminished during the second cycle. Thermal mechanical analysis confirmed volume relaxation occurring at temperatures above 95 °C, indicating physical aging. By calculating the relaxation time associated with volume relaxation, the influence of physical aging was minimized through measurements on samples annealed at 135 °C for 15 h. This approach enabled a successful evaluation of the temperature dependence of gas permeability under conditions where the impact of physical aging could be disregarded. The results revealed that the permeability of CO2 decreased, and that of N2 increased with increasing temperature. The diffusion coefficients showed positive temperature dependence, while the solubility coefficients decreased. Physical aging significantly affected the diffusion coefficients but had minimal impact on the solubility coefficients. Heat of sorption and activation energies for gas permeability and diffusion estimated, and it was found that the decrease in CO2 permeability with temperature was mainly attributed to the large heat of sorption for CO2.
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