Temperature Coefficient Research Articles

Thermal characterization of ceramic pills at millimeter waves with a TE01δ cavity resonator

The progress in 5G/6G technology prompts a demand for new materials operating at millimeter waves that can be exploited as substrates for electronic devices or antennas. In particular, a rapid development of millimeter wave band communication technology demands ceramic materials, which could be applied in low temperature cofired ceramic (LTCC) techniques. This kind of ceramics should possess a low dielectric constant (εr), a low loss tangent (tanδ) and a near-zero temperature coefficient. In the view of above, there is an urgent need for accurate and reliable material microwave characterization techniques that can operate at frequencies well above 15 GHz. Due to the fact that the majority of LTCC ceramic materials can be produced in a cylindrical shape, a suitable characterization method exploits a cylindrical resonator operating at a TE01δ mode, which is dedicated to the characterization of low-loss materials also as a function of temperature.

Strontium tantalate ceramics for dielectric resonator and antenna applications

Bulk SrTa2O6 ceramics were produced via solid-state reactive sintering, characterized by x-ray diffraction, scanning electron microscopy and energy dispersive spectroscopy, and their dielectric properties determined via resonant cavity in the 5G frequency domain. Two polymorphs were obtained. Orthogonal β phase ceramics, obtaining much lower relative densities, achieved, at ∼5 GHz, an effective permittivity (εeff) of ∼22, dielectric losses (tanδ) around 1 × 10−2 and temperature coefficient of resonant frequency (τf) of around 250 ppm/°. Tetragonal tungsten bronze β’ phase ceramics achieved relative densities of ∼87%, and at ∼2.8 GHz a higher εeff between 79-85, lower ‘tanδ’ around 5 × 10−3, and a ‘τf’ of about 300 ppm/° at 90°C. Both phases are found to be Sr-deficient, which may have caused a liquid-phase sintering in the powder bed configuration used for these ceramics. The performance of a prototype dielectric resonator antenna incorporating a β’ ceramic was demonstrated to validate the measured dielectric properties.

One-step synthesis of Li2Mg2Mo3O12-(Li1/2Bi1/2)MoO4 composite ceramics with a stable temperature coefficient for ULTCC applications

One-step synthesis of Li2Mg2Mo3O12-(Li1/2Bi1/2)MoO4 composite ceramics with a stable temperature coefficient for ULTCC applications

Influence of TiO2 addition on the Mg4Nb2O9 ceramic phase and its application in the radiofrequency region

In this work, the dielectric properties of (1-x) Mg4Nb2O9 – (x) TiO2 composite ceramics in radiofrequency and the microwave region were evaluated. X-ray diffraction demonstrated that Mg4Nb2O9 (MNO) reacted with TiO2 resulting in the formation of new crystalline phase Mg5(Nb0.625Ti0.375)4O15. Complex Impedance Spectroscopy (CIS) analysis was realized to analysis the electrical properties of materials, whereas was observed that activation energy (Ea) decrease from 1.64 to 1.37 eV with an increase in TiO2 concentration. Temperature capacitance coefficient (TCC) was obtained and showed that at different frequencies all materials could be used as Class 1 ceramic capacitors according to EIA RS-198. In the Microwave region, MNO – TiO2 demonstrated ε’r between 12.07 (MNO) and 14.08 (MNO18T), tan δ values varying of 2.64 × 10-4 (MNO) up to 5.92 × 10−4 (MNOT14). Regarding the temperature coefficient of resonant frequency (τf) was observed that the values decreased with the increase in TiO2, with the value closest to zero being that of pure MNO (τf = −27 ppm.°C−1). The results presented show that materials evaluated could be utilized in devices that can be act in radio frequency (RF) and microwave (MW) regions.

Effect of high pressure torsion on magnetic properties and corrosion resistance of MnBi/NdFeB composite magnets

The MnBi/NdFeB composite magnets have been fabricated by high pressure torsion (HPT). The effects of NdFeB content, torsional pressure and torsional degree on the microstructures, magnetic properties, and corrosion resistance of the MnBi/NdFeB composite magnets are systematically investigated. The results show that the remanent magnetization (Mr) of MnBi/NdFeB composite magnets increases with the Nd2Fe14B content. A peak value of the maximum energy product ((BH)max) = 5.61 MGOe is obtained while the Nd2Fe14B content is 75 wt%. Addition of MnBi increases the coercivity temperature coefficient and the density of MnBi/NdFeB composite magnets. The MnBi/NdFeB composite magnets preprared by HPT show perpendicular anisotropy, which can be explained by the (0kl) texture in the perpendicular direction observed by TEM. With the increase of degree of HPT, the intrinsic coercivity (Hcj) difference between perpendicular direction and parallel direction is more obvious, the (0kl) texture is enhanced by the degree of HPT. The first-order reversal curve (FORC) demonstrates that MnBi/NdFeB composite magnets exhibits weaker exchange coupling compared with pure MnBi magnet. Besides, a remarkably improvement in electrochemical stability for the MnBi/NdFeB composite magnet is achieved with the MnBi added.

Substitution of Sn in the high-permeability MnZn ferrite for wide temperature applications

To meet the challenge of varied working temperatures of inductance components in new energy vehicle and 5G communication, the high-TC high-permeability MnZn ferrite with excellent temperature stability was developed by the addition of SnO2. In this series of samples, initial permeability μi maintains large values in a wide temperature range. With increasing the SnO2 content, the temperature of the second permeability peak Tsp decreases and meanwhile Curie temperature TC maintains as high as 160 °C. For the best sample with 6000 ppm SnO2, μi at 25 °C is 7244 and exhibits the excellent temperature stability with the low specific temperature coefficient of 0.35×10-6 °C-1 between 25 and 130 °C. The addition of SnO2 generates Fe2+ and adjusts the magneto-crystalline anisotropy constant K1 = 0 point, which is responsible for the wide-temperature high permeability. The effect of SnO2 addition on magnetization process has also been clarified.

Neutronic characteristic analysis of the GAMA microreactor

The GAMA Microreactor is a low-power nuclear power plant dedicated for remote area with a power output of 300 kWe. The primary characteristics of the GAMA Microreactor are its system compactness, design simplicity, and safe operation without moving parts. The fuel is uranium hydride powder, which works simultaneously as a moderator, contained within a stainless-steel vessel and surrounded by a graphite reflector. Liquid sodium-filled heat pipes are embedded in the fuel powder to extract fission-generated heat via passive coolant flow due to capillary action. As a part of the design process, neutronic parameters of the GAMA Microreactor have been determined using SCALE6.2 and OpenMC codes. Among the analyzed parameters are the excess reactivity as a function of burn-up, shutdown margin, control rod worth, temperature coefficient of reactivity (TCR), fuel density coefficient of reactivity (DCR), and reactivity coefficient due to hydrogen dissociation. From the calculation results, the GAMA Microreactor has a maximum excess reactivity of 0.049 at the operational temperature (700 °C) and 0.0788 at ambient temperature. The TCR value is negative (−2.267 pcm/°C) at the beginning of the cycle (BOL) and −4.9618 pcm/°C at the end of the cycle (EOC). Hydrogen dissociation imposes negative reactivity on the reactor both at the BOL (−0.2631 Δk/k-%dissociation) and EOC (−0.3524 Δk/k-%dissociation). Therefore, the GAMA Microreactor maintains its inherent safety characteristics over a considerably long operation time.

Improvement of magnetic performance of Nd-Ce-Fe-B sintered magnets via Pr-Co-Ga grain boundary reconstruction

Grain boundary reconstruction is a commonly used method to improve the coercivity of Nd-Ce-Fe-B magnets but at the expense of a notable reduction in remanence. In this study, we present an effective approach to achieving a balance between remanence and coercivity of Nd-Ce-Fe-B magnets through Pr-Co-Ga grain boundary reconstruction. Compared to the original Nd0.7-Ce0.3-Fe-B magnet, the remanence of the magnet with 4wt.% Pr-Co-Ga addition decreased only from 13.09 kGs to 12.8 kGs, while the coercivity remarkably increased from 10.95kOe to 14.84kOe. Additionally, the coercivity temperature coefficient (20–150°C) was improved from –0.606%/°C to –0.547%/°C, and the Curie temperature was increased from 278.4°C to 285.1°C, demonstrating excellent thermal stability. XRD refinement analysis showed a slight decrease in the main phase ratio, accompanied by a slight increase in orientation, resulting in a slight decrease in remanence. SEM and EPMA observations revealed that Pr preferentially replaced Ce on the grain surface, forming a “Pr-rich” shell with an enhanced anisotropy field. TEM analysis showed that the magnets with PCG addition exhibit a continuous Fe-lean grain boundary phase, weakening the exchange coupling of the adjacent grains. The synergistic effect of the “Pr-rich” shell formation and grain boundary optimization effectively enhanced the coercivity.

Improvement of thermal stability by co-introducing Dy and Co with dual-alloy method in NdFeB magnets

A dual-main-phase magnet with excellent thermal stability was prepared by co-mixing two types of magnetic powders, which was the conventional N55-grade powder without Dy elements, while the Co and Dy contents reached 50 wt.% and 6 wt.% respectively in another Co-rich powder. Studies showed that the magnetic properties along with the thermal stabilities of the magnets exhibited significant differences with the changes in the mixing ratio of the two powders. Especially, when mixing the two powders in equal proportions, a great remanence temperature coefficient of -0.0725 %/°C at 20-100 °C was obtained with a rather high Curie temperature of 581 °C, possessing its magnetic properties with Br=12.58 kGs, Hcj=15.9 kOe, and (BH)max=36.88 MGOe. Note that as the proportion of Co-rich powder increased to 2/3, although the Curie temperature of the prepared magnets further increased to 622 °C, both the remanence temperature coefficient and the magnetic properties deteriorated significantly. The phase composition and microstructure analyses revealed that when the proportion of added Co-rich component exceeded 1/2, the RE(Fe,Co)2B phase transformed into the RE(Fe,Co)4B phase, and a significant amount of RE(Fe,Co)1.8B0.2 phase precipitated at the grain boundaries, leading to a deterioration in magnetic performance. In addition, dynamic domain evolution analyses under variable temperature conditions demonstrated the positive effect of the appropriate introduction of Co/Dy on the anti-demagnetization in high temperatures. This work provides insights and an experimental foundation for the development of high-performance magnets with high thermal stability, used in high-temperature environments.

Dynamics and thermal stability of the bypass polymerase, DinB homolog (Dbh).

The DinB homolog polymerase (Dbh) is a member of the Y-family of translesion DNA polymerases that can synthesize using a damaged DNA template. Since Dbh comes from the thermophilic archaeon Sulfolobus acidocaldarius, it is capable of functioning over a wide range of temperatures. Existing X-ray structures were determined at temperatures where the protein is least active. Here we use NMR and circular dichroism to understand how the structure and dynamics of Dbh are affected by temperature (2°C-65°C) and metal ion binding in solution. We measured hydrogen exchange protection factors, temperature coefficients, and chemical shift perturbations with and without magnesium and manganese. We report on regions of the protein that become more dynamic as the temperature is increased toward the functional temperature. Hydrogen exchange protection factors and temperature coefficients reveal that both the thumb and finger domains are very dynamic relative to the palm and little-finger (LF) domains. These trends remain true at high temperature with dynamics increasing as temperatures increase from 35°C to 50°C. Notably, NMR spectra show that the Dbh tertiary structure cold denatures beginning at 25°C and increases in denaturation as the temperature is lowered to 5°C with little change observed by CD. Above 35°C, chemical shift perturbation analysis in the presence and absence of magnesium and manganese reveals three ion binding sites, without DNA bound. In contrast, these bound metals are not apparent in any Dbh crystal structures of the protein without DNA. Two ion binding sites are confirmed to be near the active site, as reported in other Y-family polymerases, and we report a novel ion binding site in the LF domain. Thus, the solution-state structure of the Dbh polymerase is distinct from that of the solid-state structures and shows an unusually high cold denaturation temperature.

Corrosion, wear and machinability studies on scrap aluminium alloy wheel based metal matrix composite

Recycled materials, especially scrap aluminum alloy wheels with reinforcement castings, are gaining applications in various fields such as aerospace, naval, military, and automobile. In this research, Honda car alloy wheels are stir-cast with 5% alumina as reinforcement and subjected to corrosion, wear, and machinability studies. Corrosion studies were conducted to evaluate the corrosion current density (ICorr), corrosion potential (ECorr), and corrosion rate for the cast aluminum metal matrix composite. The wear studies with different loads, i.e., 50 N, 60 N, 70 N, and 80 N, were performed on the specimen and investigated the coefficient of friction, frictional force, and pin temperature. The sliding load has a significant effect on wear performance, and for the sliding load of 80 N, the wear recorded was 2574.83 µm. The electrochemical machinability studies with voltage, duty cycle, and concentration of citric acid electrolyte are performed on the machining rate and surface corrosion factor. Analysis of the electrochemical machining process with PROMETHEE-II shows that 7 V, 60% duty cycle, and 30 g/L electrolyte concentration are estimated to be the best combination for a higher machining rate and a lower surface corrosion factor. KEY WORDS: Alumina, Machining rate, Nyquist plot, Electrochemical machining, PROMETHEE-II Bull. Chem. Soc. Ethiop. 2024, 38(4), 1163-1175. DOI: https://dx.doi.org/10.4314/bcse.v38i4.27

Geometrically engineered mass sensing CMOS-MEMS resonators for temperature compensation via folded anchors

We present, for the first time, a single-layer plate resonator with specific folded anchors capable of reducing the temperature coefficient of frequency (TCF) by two orders of magnitude compared to straight beams. Folded anchors provide differential strain through either compressive or tensile thermal stress depending on the anchor design and, in turn, allow for positive and negative temperature-induced frequency change components. With a nominal 2 MHz frequency, we experimentally report a frequency shift of 2500 ppm over a temperature span from 0ºC to 90ºC using an optimal anchor folding aspect ratio. The frequency-temperature curve exhibits a turnover point at 27ºC granting a unique opportunity to, in a future application, complement this passive strategy with an active micro-oven for negligible TCF. The proposed approach main advantage relies on its mechanical design-level implementation exploiting a geometrical engineering strategy than can be directly extended to other topologies. This technique reveals as particularly suited for ultra-sensitive mass sensing applications based on microelectromechanical systems (MEMS) resonators where single-layer resonators are optimal thanks to their minimum footprint, attaining minimum mass structures. Results demonstrate that adoption of the proposed folded anchors strategy decreases effectively the thermally induced frequency fluctuations within the system intrinsic noise level.

Investigation of the Positive Temperature Coefficient Resistivity of Nb-Doped Ba0.55Sr0.45TiO3 Ceramics

The demands of low-Curie-temperature (~−10 °C) positive temperature coefficient (PTC) thermistors are increasing in advanced precision integrated circuits and other industries. In this paper, the Nb-doped Ba0.55Sr0.45TiO3(BST)-based PTC resistivity materials are reported. The effects of the sintering process, especially the cooling rate on the PTC properties of the material, are investigated. The results indicate that the Ba0.55Sr0.45Ti0.9985Nb0.0015O3 composition of the prepared PTC ceramics demonstrates promising PTC characteristics. These include a Curie temperature as low as −13 °C, a high temperature coefficient of 0.296 at −3.4 °C, a large enough resistivity change of 3.1 over a narrow phase transition temperature range of approximately 38 °C, and moderate resistivity below the Curie temperature. Such properties suggest that the Ba0.55Sr0.45Ti0.9985Nb0.0015O3 ceramics are likely suitable for use in thermal management systems designed for low-temperature control.

Strain and Temperature Sensing Based on Different Temperature Coefficients fs-FBG Arrays for Intelligent Buoyancy Materials.

The temperature and strain fields monitoring during the preparation process of buoyancy materials, as well as the health status after molding, are important for mastering the mechanical properties of buoyancy materials and ensuring the safety of operators and equipment. This paper proposes a short and high-density femtosecond fiber Bragg grating (fs-FBG) array based on different temperature coefficients fibers. By optimizing the parameters of femtosecond laser point-by-point writing technology, high-performance fs-FBG arrays with millimeter level gating length and millimeter level spatial resolution were prepared on two types of fibers. These were successfully embedded in buoyancy materials to achieve in-situ online monitoring of the curing process and after molding. The experimental results show that the fs-FBG array sensor has good anti-chirp performance and achieves online monitoring of millimeter-level spatial resolution. Intelligent buoyancy materials can provide real-time feedback on the health status of equipment in harsh underwater environments. The system can achieve temperature monitoring with an accuracy of 0.56 °C and deformation monitoring with sub-millimeter accuracy; the error is in the order of micrometers, which is of great significance in the field of deep-sea exploration.

A high‐precision voltage reference with a curvature‐compensated bandgap for fluorescence detection

SummaryFluorescent optical fiber temperature sensors require accurate online temperature monitoring in hazardous environments with strong electromagnetic fields, high voltages, flammability, or explosiveness. This imposes stringent requirements on the temperature coefficient stability of the bandgap reference (BGR) circuit. To address these challenges, this paper proposes a high‐order curvature compensation bandgap reference (HCC_BGR) circuit fabricated using a 0.18‐μm bipolar‐CMOS‐DMOS (BCD) process. A traditional first‐order bandgap reference (TRA_BGR) circuit is also fabricated for comparison. Experimental results demonstrate that the proposed HCC_BGR circuit generates a stable 1.22‐V reference voltage with a low‐temperature coefficient of 5.56 ppm/°C from −20°C to 85°C. Compared to the TRA_BGR circuit, the HCC_BGR reduces the temperature coefficient by 3.07 times. Furthermore, the low‐dropout regulator (LDO) using the proposed HCC_BGR exhibits excellent line sensitivity of 1.52%/V from 3.4 to 5 V.

In situ high-temperature transmission electron microscopy investigation of dynamic element migration for Sm-Co-Fe-Cu-Zr sintered magnets

The investigation delved into the dynamic migration of elements and the evolution of interface structures within the Sm(CobalFe0.09Cu0.09Zr0.03)7.2 magnet as temperature increased, employing high-temperature transmission electron microscopy. Notably, the Cu distribution exhibited temperature susceptibility. Elevating the temperature from room temperature (RT) to 400 °C led to a notable expansion in the distribution width of Cu, ranging from 28.5 to 50.8 nm. Simultaneously, the average Cu content at the cell boundaries decreased from 14.4 to 11.6 at.%. According to the high-temperature in-situ experimental results of the transmission electron microscopy thin-film samples, the derived diffusion coefficients, D300°Cand D400°C, were determined as 0.0525 nm2/s and 1.414 nm2/s, respectively. The significantly higher D400°C compared to D300°C underscores the considerable influence of temperature on Cu element diffusion behavior. The simulation results demonstrate that the trend of magnetic properties variation at different temperatures closely aligns with the observed trend. Subsequent calculation of the temperature coefficient of intrinsic coercivity (β) reveals that |β300–400°C| is notably higher than |βRT-300°C|. This suggests a substantial impact of Cu diffusion-induced deterioration on the β. Moreover, micromagnetic simulation results delineated the reverse magnetization process for magnets at varying temperatures, revealing that the presence of the Cu diffusion region diminished the pinning effect of the cell boundary phase. Furthermore, a wider Cu diffusion region facilitated easier magnetic moment reversal at the cell boundary phase, resulting in a marked deterioration of intrinsic coercivity. This elucidates that the formation of the Cu diffusion region stands as one of the primary reasons for the sharp decline in magnetic properties of Sm2Co17-type magnets under high-temperature conditions.

Influence of positive temperature coefficient and battery aging on external short circuit for 18,650-type battery

Influence of positive temperature coefficient and battery aging on external short circuit for 18,650-type battery

Electrical actuation of single-crystal diamond MEMS resonators at high temperatures

Achieving efficient low-voltage actuation of microelectromechanical system (MEMS) resonators in high-temperature environments poses a difficult topic due to the thermal interference and the risk of high-temperature failure. In this work, the single-crystal diamond (SCD) resonators fabricated through the ion implantation-assisted lift-off (IAL) technique exhibit a SCD-on-SCD cantilever structure. We propose an electrical actuation system based on the electrostatic effect specifically designed for SCD MEMS resonators with a low radio-frequency amplitude of ∼ 100 mV. The SCD resonators demonstrate stable and efficient actuation across a wide temperature range, from room temperature to 500 °C. Importantly, the actuation voltage exhibits little impact on the resonance frequency and the Q factor of the resonator. The SCD resonator showcases exceptional thermal stability in resonance frequency, with a low temperature coefficient of frequency (TCF) below −12 ppm/°C up to 500 °C. The developed actuation scheme holds tremendous potential as a robust platform for realizing SCD MEMS devices, particularly in applications requiring high integration at high temperatures.

Development of new materials for electrothermal metals using data driven and machine learning.

After adopting a combined approach of data-driven methods and machine learning, the prediction of material performance and the optimization of composition design can significantly reduce the development time of materials at a lower cost. In this research, we employed four machine learning algorithms, including linear regression, ridge regression, support vector regression, and backpropagation neural networks, to develop predictive models for the electrical performance data of titanium alloys. Our focus was on two key objectives: resistivity and the temperature coefficient of resistance (TCR). Subsequently, leveraging the results of feature selection, we conducted an analysis to discern the impact of alloying elements on these two electrical properties.The prediction results indicate that for the resistivity data prediction task, the radial basis function kernel-based support vector machine model performs the best, with a correlation coefficient above 0.995 and a percentage error within 2%, demonstrating high predictive capability. For the TCR data prediction task, the best-performing model is a backpropagation neural network with two hidden layers, also with a correlation coefficient above 0.995 and a percentage error within 3%, demonstrating good generalization ability. The feature selection results using random forest and Xgboost indicate that Al and Zr have a significant positive effect on resistivity, while Al, Zr, and V have a significant negative effect on TCR. The conclusion of the composition optimization design suggests that to achieve both high resistivity and TCR, it is recommended to set the Al content in the range of 1.5% to 2% and the Zr content in the range of 2.5% to 3%.

Electrothermal Instabilities in Barium-Titanate-Based Ceramics

An electrothermal analysis for barium-titanate-based ceramics is presented, combining the Heywang–Jonker model for the electric resistivity with a heat dissipation mechanism based on natural convection and radiation in a one-dimensional model on the device level with voltage as the control parameter. Both positive-temperature-coefficient (PTC) and negative temperature coefficient (NTC) effects are accounted for through the double Schottky barriers at the grain boundaries of the material. The problem formulated in this way admits uniform and non-uniform multiple-steady-state solutions that do not depend on the external circuit. The numerical bifurcation analysis reveals that the PTC effect gives rise to several multiplicites above the Curie point, whereas the NTC effect is responsible for the thermal runaway (temperature blowup). The thermal runaway phenomenon as a potential thermal shock could be among the possible reasons for the observed thermomechanical failures (delamination fracture). The theoretical results for the NTC regime and the thermal runaway are in agreement with the experimental flash sintering results obtained for barium titanate, and 3% and 8% yttria-stabilized zirconia.