Composed of thermochemical reactions, chemically accelerated laser processing (CALP) is a hybrid process that integrates thermal energy with chemical processes. It uses laser activation of material dissolution in chemical environments via localized temperature gradients for streamlined processing, notably for self-passivating materials. This research sheds light on how the dynamic interaction occurs during the fabrication of multiple patterns on SDSS-2507 uniquely by employing an orbit-in-orbit laser positioning strategy in CALP. Current CALP and fabricated surface feature may be useful for micro-reactor applications. So artificial chemical environments (H3PO4, NaCl, and NaNO3) and their concentration, along with controllable laser processing windows like energy and scan factors, were used to simulate actual CALP conditions to study SDSS-2507′s material dissolution and surface characteristics. As SDSS-2507 holds a dual phase with varied thermal characteristics, this article examined each phase’s sensitivity to laser-induced chemical reactions and attacks from aggressive and non-aggressive ions during CALP. In order to acquire insight into the CALP effect on SDSS-2507, phase analysis, surface morphology, CALP-induced crack behavior, surface chemistry, crystallite size, residual stress, mechanical property, and lattice strain were also studied. In the post-CALP, the SDSS-2507′s resistance against aggressive Cl- ions was also scrutinized through electrochemical corrosion analysis. It has been found that, by taking advantage of orbit-in-orbit scan mode during CALP, NaCl exhibited superior performance in terms of material dissolution rate among the three chemical environments, whereas the H3PO4 environment solely performed well in terms of a clean surface without any leftover residue compared to NaCl and NaNO3. In comparison to NaNO3, NaCl, and before CALP, a decrease in crystallite size of up to 22.49%, 19.12%, and 26.23% was also seen. On top of that, when compared to NaCl, NaNO3, and before CALPed surfaces, the corrosion rate was found to be 62.63%, 19.04%, and 35.84% lower, respectively. The findings suggest that, CALP in H3PO4 environment significantly refines the grains compared to B-CALP. This, in turn, stimulates the CALP to somewhat further strengthen the grain boundary and increase its corrosion resistance.
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