Portrait Orientation Research Articles

Characterization of a new low-dose and low-energy Gafchromic film LD-V1.

To characterize the dose-response, energy dependence, postexposure changes, orientation dependence, and spatial capabilities of LD-V1, a new low-dose Gafchromic film for low-energy x-ray dosimetry. A single sheet of LD-V1 Gafchromic film was cut into 15 × 20mm2 rectangles with a notch to track orientation. Eight different doses between 5 and 320mGy were delivered by an MXR-160/22 x-ray tube using x-ray beams of 90, 100, and 120kVp filtered with 3mm of Al and 2mm of Ti. The 120kVp films were scanned at 1, 1.5, 2, 3, 12, 24, 48, 72, and 168h postexposure in portrait orientation and additionally scanned in landscape orientation at 24h. The 90 and 100kVp films were scanned at 24h postexposure in portrait orientation. Lastly, a 20 × 200mm2 strip of film was irradiated using a thin-slit imaging collimator and scanned 24h postexposure to test the film performance in an x-ray imaging application. Of the three color channels, the red channel was found to produce a dose-response curve with a large range of net optical density (netOD) values across the considered dose range. A prominent energy dependence was discovered, resulting in dose discrepancies on the scale of 17mGy between 90 and 120kVp for a dose of 80mGy. The measured postexposure changes suggest that the calibration irradiation-to-scan time should be longer than 12h with a±4h scanning time window for dose errors of<0.5%. An average dose difference of 3.4% was found between the two scanning orientations. Lastly, noise of 4% was measured in the thin slit collimator film for a dose of 30mGy. We have characterized the LD-V1 film for low-energy, low-dose x-ray dosimetry. Energy, scan-time, and orientation dependencies should be considered when using this film.

Breadth and orientation of pie menus for mid-air interaction: effects on upper extremity biomechanics, performance, and subjective assessment

ABSTRACT The number and layout of options within pie menus are crucial for determining the direction of radial swiping in mid-air interactions, influencing the physical demands imposed on users. This research examined six distinct option quantities, referred to as menu breadth, and investigated two layouts, designated as menu orientations. These orientations encompass landscape and portrait formats, with the former positioning a top option centred parallel to the horizontal axis, while the latter situates two top options on either side of the vertical axis. The study employed comprehensive metrics, including muscle activity, wrist movement, user performance, and subjective assessments. Our results indicated that the breadth should be controlled to no more than six to ensure high efficiency and align with users’ interactive experience, while breadth 2 should be avoided to eliminate the potential risk of wrist musculoskeletal disorders. Besides, the portrait orientation for breadth 3 and the landscape orientation for breadth 6 were recommended for their lower physiological loads and higher efficiency. Also, the landscape orientation for breadth 4 should be favoured as it outperformed portrait orientation in both wrist movement dimensions. These findings could provide scientific design principles for using pie menus in mid-air interaction within future HCI applications.

Comparative Analysis of Edge Soiling Resilience: Full-Cell vs. Half-Cell Photovoltaic Modules in Different Mounting Orientations

The performance of distributed PV systems is often hindered by edge soiling, mainly due to the challenges associated with centralized cleaning. In recent years, half-cell modules have gained popularity over conventional full-cell modules due to their potential for improved performance. However, limited research has been conducted to compare the effects of edge soiling on full-cell and half-cell modules, particularly in various mounting orientations. Furthermore, there is a scarcity of methods that integrate simulation and experimentation to analyze the characteristics of shaded PV modules. This study aims to optimize module selection and mounting orientation to mitigate the impact of edge soiling. Simulated models and experimental setups were developed for both full-cell and half-cell modules in both landscape and portrait orientations. The results reveal that the degree of shading correlates with the ratio of shaded substrings within a module. In addition, module performance can be significantly enhanced by altering the mounting orientation. Specifically, the findings demonstrate that half-cell modules outperform full-cell modules when mounted in the portrait orientation. However, in the landscape orientation, the advantage of half-cell modules diminishes. Remarkably, the choice of mounting orientation is found to be contingent on the severity of edge soiling for half-cell modules. This work significantly contributes to the understanding of shading effects in PV systems and offers practical guidance for optimizing distributed PV systems against edge soiling.

Predicting the performance of portrait-aligned vertical bifacial agrivoltaic arrays

This work simulated and contrasted the expected electrical output of portrait-oriented vertical bifacial (VBF) solar modules versus the more frequently installed landscape-oriented modules, designed and spaced apart suitably for an agrivoltaic installation. In the portrait orientation, the expected early morning and late afternoon inter-row shading is not protected by the module’s internal bypass diodes. Instead, the top and bottom halves of portrait-oriented modules operate at independent currents, leading to a different power output than a landscape-oriented module in the same circumstance. The effects of the module dimensions, module height, row spacing, and bifaciality are all taken into account. The overall annual output for the portrait orientation was comparable to that of the landscape orientation, though differences exist and the portrait modules exceeded the output of the landscape modules in specific situations. This suggests that a variety of racking options can be considered when designing VBF arrays. For an array with rows of portrait-oriented modules with bifaciality of 92 %, an energy output of over 157 MWh/acre/year (388 MWh/hectare/year) is expected with a row spacing of 20 feet (6.1 m).

Assessing Message Deployment During Public Health Emergencies Through Social Media: Empirical Test of Optimizing Content for Effective Dissemination.

During an infodemic, timely, reliable, and accessible information is crucial to combat the proliferation of health misinformation. While message testing can provide vital information to make data-informed decisions, traditional methods tend to be time- and resource-intensive. Recognizing this need, we developed the rapid message testing at scale (RMTS) approach to allow communicators to repurpose existing social media advertising tools and understand the full spectrum of audience engagement. We had two main objectives: (1) to demonstrate the use of the RMTS approach for message testing, especially when resources and time are limited, and (2) to propose and test the efficacy of an outcome variable that measures engagement along a continuum of viewing experience. We developed 12 versions of a single video created for a vaccine confidence project in India. We manipulated video length, aspect ratio, and use of subtitles. The videos were tested across 4 demographic groups (women or men, younger or older). We assessed user engagement along a continuum of viewing experience: obtaining attention, sustaining attention, conveying the message, and inspiring action. These were measured by the percentage of video watched and clicks on the call-to-action link. The video advertisements were placed on Facebook for over 4 consecutive days at the cost of US $450 and garnered a total of 3.34 million impressions. Overall, we found that the best-performing video was the shorter version in portrait aspect ratio and without subtitles. There was a significant but small association between the length of the video and users' level of engagement at key points along the continuum of viewing experience (N=1,032,888; χ24=48,261.97; P<.001; V=.22). We found that for the longer video, those with subtitles held viewers longer after 25% video watch time than those without subtitles (n=15,597; χ21=7.33; P=.007; V=.02). While we found some significant associations between the aspect ratio, the use of subtitles, and the number of users watching the video and clicking on the call-to-action link, the effect size for those were extremely small. This test served as a proof of concept for the RMTS approach. We obtained rapid feedback on formal message attributes from a very large sample. The results of this test reinforce the need for platform-specific tailoring of communications. While our data showed a general preference for a short video in portrait orientation and without subtitles among our target audiences on Facebook, that may not necessarily be the case in other social media platforms such as YouTube or TikTok, where users go primarily to watch videos. RMTS testing highlights nuances that communication professionals can address instead of being limited to a "one size fits all" approach.

Cancer Resource and Information Support (CRIS) for Bladder Cancer Survivors and Their Caregivers: Development and Usability Testing Study.

Bladder cancer survivors and their caregivers face profound practical (eg, use of stoma appliances and care for urinary diversion methods) and psychosocial (eg, depression and anxiety) challenges after surgical treatment with cystectomy. To improve the health-related quality of life and postsurgical outcomes of both bladder cancer survivors and their caregivers, the team, in collaboration with Sourcetop, Inc (software design) and Dappersmith (graphic design), developed the Cancer Resource and Information Support (CRIS) software. The purpose of this manuscript is to report on the development and usability testing of the CRIS software. The development of the CRIS software was guided by the Obesity-Related Behavioral Intervention Trials (ORBIT) model for developing behavioral treatments for chronic diseases. The ORBIT model is unique in that it proposes a flexible and progressive process with prespecific clinically significant milestones for forward movement and returns to earlier stages for refinement, and it facilitates communication among diverse groups by using terminology from the drug development model. This paper focuses on 2 phases of the ORBIT model: phase IA: define and IB: refine. During phase IA, the study team developed solutions for the stated clinical problem-adjustment to life post cystectomy-by reviewing the literature and collecting feedback from clinicians, professional organizations, bladder cancer survivors, and their caregivers. During Phase IB, the study team focused on tailoring content in the CRIS software to the user as well as usability testing with 7 participants. The finished product is CRIS, a web-based software for survivors of bladder cancer and their caregivers to serve as a health management and lifestyle resource after surgery. Overarching themes from phase IA (participant feedback) included how to use new medical equipment, tips and tricks for easier living with new medical equipment, questions about health maintenance, and questions about lifestyle modifications. To accommodate our target population, we also incorporated recommendations from the Americans with Disabilities Act for website design, such as large text size, large paragraph spacing, highly contrasting text and background colors, use of headings and labels to describe the purpose of the content, portrait orientation without the need for horizontal scrolling, multiple ways to access a web page within a set of pages, ability to navigate web pages in sequential order, and in-text links that are descriptive. Usability participants evaluated CRIS very positively, indicating that it was easy to use, the functions were well-integrated, and if available, they would use CRIS frequently. CRIS, developed over the course of 18 months by integrating feedback from experts, literature reviews, and usability testing, is the first web-based software developed for bladder cancer survivors and their caregivers to help them adjust to life following cystectomy. The efficacy of CRIS in improving patients' and caregivers' quality of life is currently being evaluated in a randomized controlled trial.

Research of the Pre-Processing Strategy Influence on the Tribological Properties of PEI Processed by Fused Filament Fabrication Technology

The aim of this study was to investigate the effect of Fused Filament Fabrication (FFF) layer generation strategies on abrasive wear resistance and compare the material loss of PEI (polyetherimide) plastic specimens based on different specimen building strategies. The study also compares a newly proposed path generation strategy (parallel paths in layers with 0.25 mm displacement of alternate layers) with samples from a previous study where samples were printed without displacement of alternate layers, i.e., layers stacked perpendicularly to each other. The primary focus was on the weight loss due to abrasive wear before and after the test. The tests were conducted on a tribometer constructed according to ASTM G65/16 standards using dry sand. Two printing directions were examined: X (longitudinal) and Z (portrait) orientations. For X construction, three orientations of deposition path generation were utilized, resulting in three samples for each orientation (nine samples in total for X construction). The same approach was applied to Z construction, resulting in another nine samples. In total, 18 samples were produced and tested. The deposited infill path width was 0.5 mm, and the layer thickness used in printing was 0.254 mm. Garnet abrasive Fe3Al2(SiO4)3 was employed in this test. Analysis of the experimental data revealed a relationship between the construction method (X and Z orientations) and the variation in different orientations (1X–3X and 1Z–3Z). The research results can be categorized as overall and partial. The overall results indicate poorer wear resistance for 1X–3X and 1Z–3Z specimens, while the partial results illustrate the findings within each individual specimen.

果园枝条收集机构的运动学仿真与动力学分析研究

The spring finger collection mechanism is a core component of balers. It is usually used to collect soft straw crops (corn straw, wheat straw, green forage), and rarely used for hard stem crops (such as branch pruning residues). Due to different biophysical characteristics of hard stem crops and soft straw crops, the collection mechanisms are also different. In China, branch pruning residues in apple orchards are collected manually. It is a heavy labor task. To this end, this article uses an improved spring finger mechanism to collect pruning residues in apple orchard branches, effectively replacing manual collection operations. A dynamic motion trajectory simulation platform is developed by analyzing each action using pitchforks or other agricultural tools throughout the entire collection process, and combined with the structure of the spring finger collection mechanism. The platform of the spring finger collection mechanism is improved to collect orchard branches, and redesign and manufacture the core components of the collection mechanism. In addition, comparative tests were performed on4 different placement orientation sunder the conditions of R=40±2 r/min and V=0.9-1.1 m/s. That is, 1) messy, 2) transverse, 3) portrait orientation (the treetop firstly contacts the collection device), and 4) portrait orientation (the thick stems of the branches first touch the collection device). The results indicate that 1) and 2) have similar success rates in picking branches, while 3) and 4) have lower success rates, especially with 4) being the lowest). The analysis found that some branches were directly inserted into the spring finger gap and moved under the machine, resulting in a large amount of losses. This study aims to improve the success rate of picking branches in the bundling machine and verify the relationship between different placement directions and the success rate of picking branches.

Characterization of scanning orientation and lateral response artifact for EBT4 Gafchromic film.

The purpose of this study was to investigate the impact of scanning orientation and lateral response artifact (LRA) effects on the dose-response of EBT4 films and compare it with that of EBT3 films. Dose-response curves for EBT3 and EBT4 films in red-green-blue (RGB) color channels in portrait orientation were created for unexposed films and for films exposed to doses ranging from 0 to 1000cGy. Portrait and landscape orientations of the EBT3 and EBT4 films were scanned to investigate the scanning orientation effect in the red channel. EBT3 and EBT4 films were irradiated to assess the LRA in the red channel using a field size of 15×15cm2 and delivered doses of 200, 400, and 600cGy. Films were scanned at the edge of the scanner bed, and the measured doses were compared with the treatment planning system (TPS) calculated doses at a position 100mm lateral to the scanner center. At a dose of 200cGy, the differences in optical density (OD) in the red, green, and blue color channels between EBT3 and EBT4 films were 0.035 (24.8%), 0.042 (49.7%), and 0.022 (64.4%), respectively. The EBT4 film slightly improved the scanning orientation compared to the EBT3 film. The OD difference in the different scanning orientations for the EBT3 and EBT4 films was 0.015 (6.8%) and 0.007 (3.9%), respectively, at a dose of 200cGy. This is equivalent to a 20 or 10cGy variation at a dose of 200cGy. Compared with the TPS calculation, the measurement doses for EBT3 and EBT4 films irradiated at 200cGy were approximately 16% and 13% higher, respectively, at the 100mm off-centered position. The EBT4 film showed an improvement concerning the impact of LRA compared with the EBT3 film. This study demonstrated that the response of EBT4 film to a dose in the blue channel was less sensitive and showed an improvement in the scanning orientation and LRA effects.

Effect of cleaning robot’s moving shadow on PV string

PV cleaning robots cast a shadow on the PV modules which they are cleaning, if used in daylight. The shadow affects the electrical characteristics (current and voltage) of the module string, and could potentially also create hot spots in modules' cells or bypass diodes. The severity of these effects depends on the layout of cells and bypass diodes and the module’s orientation, among other factors. In this study we tested a commercial cleaning robot on strings of two kinds of PV modules with different cell formats, connected to a grid-tied inverter. It was found that the string power was greatly reduced when modules were in landscape orientation, but barely affected in portrait orientation. The robot shadow caused slightly greater power reduction for full-cell than half-cut modules. While the robot was in motion, no heating of cells or bypass diodes was observed, although diode heating did occur if the robot stopped on a module. For the worst case of full-cell landscape modules, a simplified estimate of the energy loss due to one robot pass was roughly equivalent to 0.16% of the string’s daily energy production. The results suggest that if PV cleaning robots are used in daylight, the power loss from their shadow could be almost eliminated by installing modules in portrait orientation.

Map Design and Usability of a Simplified Topographic 2D Map on the Smartphone in Landscape and Portrait Orientations

Map design and usability issues are crucial when considering different device orientations. It is visible, especially in exploring the topographical space in landscape or portrait orientation on the mobile phone. In this study, we aim to reveal the main differences and similarities among participants’ performance in a map-based task. The study presents an original research scheme, including establishing conceptual assumptions, developing map applications with gaming elements, user testing, and visualizing results. It appears that the different phone orientation triggers different visual strategy. This transfers into decision-making about the path selection. It turned out that in landscape orientation, participants preferred paths oriented east–west. On the other hand, portrait orientation supported north–south path selection. However, considering the given task accomplishment, both mobile phones’ orientations are adequate for the exploration of topographical space.

A dedicated breast-PET/CT scanner: Numerical observer study of lesion detection.

Dedicated, breast-specific positron emission tomography (BPET)-cone-beam computed tomography (BPET/CT) systems have been developed to improve detection and diagnosis of cancer in women with indeterminate mammograms caused by radiodense breasts. The absorption of X-rays that often vexes mammography in this subset of women does not affect the detection of the high energy annihilation photons used in PET. PET imaging of the breast, however, is subject to limitations caused by their comparatively low spatial resolution (∼2mm) and often moderate radiotracer uptake in lesions. The purpose of this investigation is to explore the PET-based lesion detection capabilities of a BPET/CT scanner developed by the Department of Radiology Instrumentation group at West Virginia University. The PET component of the system consists of a rotating pair of 96×72 arrays of 2×2×15mm3 LYSO scintillator elements. The cone-beam-CT component utilized a pulsed X-ray source and flat panel detector operated in portrait orientation. The density maps created by the CT scanner were used to correct the BPET data for photon attenuation and Compton scattering. The nonuniform uptake of 18 F-fluorodeoxyglucose (FDG) in normal breast tissue was emulated in a specially designed phantom consisting of an acrylic cylinder filled with a mixture of acrylic beads and liquid containing FDG. FDG-avid lesions were simulated with agar spheres (3, 4, 6, 8, and 10mm diameters) containing vary amounts of FDG to produce target-to-background ratios (TBR) of 6:1, 8:1, and 10:1. The spheres also contained X-ray contrast agent to make even the smallest ones readily visible in CT images. Positions of all the lesions were identified in the CT images. These positions were used to extract signal present and signal absent sub-images from the PET images. The sub-images were then input to software that calculated areas-under-the-curve for two numerical model observers (Laguerre-Gauss channelized Hotelling observer and non-prewhitening matched filter). The results showed that the smallest detectable lesion with this system is no smaller than ∼3mm in diameter with a TBR of 6:1. Simulated lesions with diameters of 4mm and greater were calculated to have good to excellent likelihood of detection for all TBRs tested. The results from this investigation identified the detectability capabilities and limitations for a dedicated breast-PET/CT scanner. Its ability to detect relatively small simulated FDG-avid breast lesions for a range of TBRs indicates its potential for clinical application. Finally, the study used methodologies that could be applied to a detectability assessment of other PET/CT scanners.

Residual stress effects during additive manufacturing of reinforced thin nickel–chromium plates

Additive manufacturing (AM) is a powerful technique for producing metallic components with complex geometry relatively quickly, cheaply and directly from digital representations; however, residual stresses induced during manufacturing can result in distortions of components and reductions in mechanical performance, especially in parts that lack rotational symmetry and, or have cross sections with large aspect ratios. Geometrically reinforced thin plates have been built in nickel–chromium alloy using laser-powder bed fusion (L-PBF) and their shapes measured using stereoscopic digital image correlation before and after release from the base-plate of the AM machine. The results show that residual stresses cause potentially severe out-of-plane deformation that can be alleviated using either an enveloping support structure, which increased the build time substantially, was difficult to remove and wasted material, or using buttress supports to the reinforced edges of the thin plate. The buttresses were quick to build and remove, minimised waste but needed careful design. Plates built in a landscape orientation required out-of-plane buttresses while those built in a portrait orientation required both in-plane and out-of-plane buttresses. In both cases, out-of-plane deformation increased on release from the baseplate but this was mitigated by incremental release which resulted in out-of-plane deformations of less than 5% of the in-plane dimensions.

Oblong formaten en liedboeken in de zestiende eeuw

Abstract This article examines the earliest example of a Dutch printed songbook without musical notation in oblong format: Een Schoon Liedekensboeck (Antwerp, 1544), commonly known as the Antwerp Songbook. Its oblong format was probably inspired by music books, even if the advantages attached to this format only partially applied to songbooks without scores and notes. Even so, the Antwerp Songbook’s typography and lay-out do facilitate performance of the songs to some degree. Additionally, unlike contemporary books in oblong, this songbook’s title page is rotated 90 degrees to portrait orientation. This article contends that this hybrid shape underlines the book’s hybrid function: it was a music book intended for those who cannot or have no inclination to read music. Similarly, Een devoot ende profitelijck boecxken (Antwerp, 1539) stands out for having a comparable hybrid shape: it combines elements of music books (such as notes and the oblong format) with elements of vernacular song tradition and a title page in portrait orientation.

Impact of angular irradiance distributions on coupling gains and energy yield of cell interconnection designs in silicon solar modules in tracking and fixed systems

Cell interconnector designs such as light redirecting films (LRFs) and various geometric ribbon layouts are all aimed at improving the performance of crystalline silicon solar modules. However, due to the usually specular reflecting surface, the angular-dependent module performance, which is typically quantified with an incidence angle modifier, depends on the rotation of the module. We find that typical power measurements under standard test conditions at 1000 W m−2 and 25 °C cell temperature are not suited to identify the best performing design in real-world conditions. In this work, we therefore determine the optimum ribbon geometry based on its simulated energy yield in common installation configurations for solar modules based on industry-standard full and half-cut solar cells. We compare the effects of planar, triangular, LRFs, pentagonal and wire ribbon geometries, as well as fixed optimal inclination, building-integrated (façade), and single-axis tracking installation scenarios of modules in portrait and landscape orientation. Energy yield gains of 1.8% can be achieved for full cell modules with LRFs or pentagonal ribbons in single-axis tracking installation compared to a reference module with five planar ribbons. Critically, we find that changing the module orientation to landscape reduces this energy yield gain by nearly 50% for the modules with LRFs. This directional dependence is significantly reduced with the pentagonal ribbon structure. The installation scenario can have a similarly dramatic impact. The expectation of power gains for certain designs inferred from standard test conditions may not only show significantly lower gains in annual energy yield, but may even lead to yield losses, especially for building-integrated photovoltaic systems. For a typical full-cell module, for example, we have found that LRFs perform 2.5% better than standard planar ribbons under standard test conditions but can result in a 0.2% lower annual yield in a façade installation. Therefore, to fully evaluate the effectiveness of a specific ribbon design, the annual energy yield must consider the angular irradiance distribution and weather conditions at a specific location, the installation scenario, and the module orientation.

Improving Web user Experience by Adapting RWD

Responsive Web Design (RWD) is a design which focuses on responsively fitting in whatever device the website is accessed from. It involves writing code for all possible screen sizes and bundling them together. Hence when the website is accessed, the whole bundle alongside the code for all screen sizes are downloaded to the user’s device and acts responsively when the browser window is resized, or the mobile device is rotated to portrait or landscape orientation. RWD can provide a far better user experience than the other designs because it primarily focuses on the user experience. Despite the bundle size being large, this method has proved to be robust in providing a better user experience and has evolved with evolution of web technologies. Latest CSS Media Queries make it possible to even target devices with limited accuracy. CSS Media Queries form the fundamentals of RWD because it is the most used way of targeting devices with various screen sizes.

Characterization of radiochromic films as a micrometer-resolution dosimeter by confocal Raman spectroscopy.

Micrometer spatial resolution dosimetry has become inevitable for advanced radiotherapy techniques. A new approach using radiochromic films was developed to measure a radiation dose at a micrometer spatial resolution by confocal Raman spectroscopy. The commercial radiochromic films (RCF), EBT3 and EBT-XD, were irradiated with known doses using 50, 100, 200, and 300kVp, and 6-MV x rays. The dose levels ranged from 0.3 to 50Gy. The Raman mapping technique developed in our early study was used to readout an area of 100×100µm2 on RCF with improved lateral and depth resolutions with confocal Raman spectrometry. The variation in Raman spectra of C-C-C deformation and C≡C stretching modes of diacetylene polymers around 676 and 2060cm-1 , respectively, as a function of therapeutic x-ray doses, was measured. The single peak (SP) of C≡C and the peak ratio (PR) of C≡C band height to C-C-C band height with a spatial resolution of 10µm on both types of RCF were evaluated, averaged, and plotted as a function of dose. An achievable spatial resolution, clinically useful dose range, dosimetric sensitivity, dose uniformity, and postirradiation stability as well as the orientation, energy, and dose rate dependence, of both types of RCFs, were characterized by the technique developed in this study. A spatial resolution on RCF achieved by SP and PR methods was ~4.5 and ~2.9µm, respectively. Raman spectroscopy data showed dose nonuniformity of ~11% in SP method and <3% in PR method. The SP method provided dose ranges of up to ~10 and ~20Gy for EBT3 and EBT-XD films, respectively while the PR method up to ~30 and ~50Gy. The PR method diminished the orientation effect. The percent difference between landscape and portrait orientations for the EBT3 and the EBT-XD films at 4Gy had an acceptable level of 1.2% and 2.4%, respectively. With both SP and PR methods, the EBT3 and the EBT-XD films showed weak energy (within ~10% and ~3% for SP and PR methods, respectively) and dose rate dependence (within ~5% and ~3% for SP and PR methods, respectively) and had a stable response after 24-h postirradiation. A technique for micrometer-resolution dosimetry was successfully developed by detecting radiation-induced Raman shift on EBT3 and EBT-XD. Both types of RCFs were suitable for micrometer-resolution dosimetry using CRS. With CRS both lateral and depth resolutions on RCF were improved. The PR method provided superior characteristics in dose uniformity, dose ranges, orientation dependence, and laser effect for both types of RCFs. The overall dosimetric characteristics of the RCFs determined by this technique were similar to those known by optical density scanning. The CRS with the PR method is advantageous over other the traditional scanning systems as a spatial resolution of <10µm on RCF can be achieved with less deviations.

Mechanistic insights into artificial metalloenzymes towards imine reduction.

In the field of artificial metalloenzyme (ArM) catalysis, how to identify the critical factors affecting the catalytic activity and enantioselectivity remains a challenge. In this work, the mechanism of enantioselective reduction of imine catalyzed by using [Rh(Me4Cpbiot)Cl2]·S112H Sav (denoted as S112H) and [Rh(Me4Cpbiot)Cl2]·K121H Sav (denoted as K121H) was studied by using molecular dynamics (MD) simulations combined with density functional theory (DFT) calculations. Four binding modes of imine, two proton sources (hydronium ion and lysine) and eight proposed reaction pathways were systematically discussed. The results showed that due to the anchoring effect of the mutation site of ArMs, the rhodium complex which oscillated like a pendulum was bound to a specific conformation, which further determined the chirality of the reduced product. C-Hπ, cation-π and ππ weak interactions played an important role in imine binding, and the favorable binding mode of imine was catalyzed by S112H in landscape orientation and catalyzed by K121H in portrait orientation, respectively. LYS121 is the most possible proton source in the S112H catalytic process while the proton source in the K121H catalytic process is the hydronium ion of the active sites. Furthermore, based on the reaction mechanism, modification of Rh(Me4Cpbiot)Cl2 was carried out in S112H and K121H, and the results suggested that the reaction barrier could be effectively reduced by replacing the methyl groups on Cp* with an amino group. This work gives a fundamental understanding of the mechanism of ArMs toward the imine reduction reaction, in the hope of providing a strategy for reasonable designs of ArMs with high enantioselectivity.

Boats Against the Current: The Honeymoon Summer of Scott and Zelda: Westport, Connecticut, 1920

Boats Against the Current: The Honeymoon Summer of Scott and Zelda: Westport, Connecticut, 1920

Screen Orientation Aware DRAM Architecture for Mobile Video and Graphic Applications

The state-of-the-art mobile image and graphic applications demand not only a lot of computing power, but also high-quality memory services. Moreover, depending on the screen orientations of mobile systems, image and graphic data can be accessed in a complicated manner. Since conventional dynamic random access memories (DRAMs) do not provide successive image and graphic pixels on the same column address, however, they achieve extremely poor throughput, long latency, and high power consumption in any screen orientation of mobile systems. This paper presents a novel DRAM efficient for both portrait and landscape screen orientations of mobile systems. We develop a simple, but effective two-transistor, one-capacitor memory cell that can be activated not only by a row activation command like a conventional DRAM memory cell, but also by a new column activation command. Next, the proposed DRAM architecture makes all the new memory cells on the same row address, or the same column address successively accessed. Finally, new DRAM commands and operations that are completely compatible with the conventional DRAMs are presented. Experimental results show that the proposed DRAM has 3.6% larger area, but achieves 5.8% higher memory utilization, and 14.8% shorter memory latency, on average. In addition, it consumes 4.4% less memory power than the conventional DRAM, on average.