The article is devoted to the study of issues related to the management of supply chains in the conditions of destabilization of the business environment during the martial law in Ukraine. In particular, the impact of the war in Ukraine on modern international supply chains and the reasons for the increase in transportation costs are analyzed. It is emphasized that the war in Ukraine due to the Russian attack led to the destruction and damage of the transport and logistics infrastructure the suspension of port operations in Ukraine, which in turn affected the efficiency of supply chains, changes in logistics routes, and as a result, the prices of goods and services. Attention is focused on the fact that the supply chain combines a set of different types of activities and is a complex business process in the combination of manufacturers and retailers at each stage of the distribution process from raw materials to delivery to the final consumer. It has been proven that the first disruptions in supply chains occurred due to the coronavirus pandemic, but military actions also had an additional impact, which ultimately created some uncertainty in the management of global supply chains and their inefficiencies. Four groups of key performance indicators of the supply chain are distinguished, namely, those related to the logistics product; with the search for information and financial sources; with transportation and pricing. It is proposed that the key performance indicators of the supply chain should be taken into account when forming a business strategy for the development of an enterprise in the context of a destabilizing environment, which will ensure success in the future. In the formation and management of supply chains, the most acute problem is uncertainty, which creates unpredictability of risks, complicates the process of their identification, assessment, development of a risk management strategy and monitoring. To support the reliability and stability of supply chains, a generalized scheme of risk management in supply chains has been developed. The implementation of such a scheme allows you to reduce risks, operational costs, increase key performance indicators of the supply chain, adhere to the environmental friendliness of business processes, and improve the level of customer service in conditions of destabilization of the business environment.