Systematic analysis of the effect of various factors on the behavior of polymer solutions used for forming the porous structure by impregnation of nonwoven fibrous substrates in the process of fabrication of synthetic composite materials and coatings is performed. Scientific foundations of a targeted control of the phase separation of polymer solutions on their modification with interpolymer complexes of different compositions and structures in order to obtain products and materials with a porous structure and set of performance characteristics required for various applications.