Microporous Structure Research Articles

2D MOF‐Based Filtration‐Sensing Strategy for Trace Gas Sensing Under Intense F‐Gas Interference at Room Temperature

AbstractThe detection of trace impurity gases in fluorinated gas (F‐gas) that are widely used in the industry offers a significant avenue for equipment status monitoring and mitigating unnecessary emissions. However, the formidable electron affinity (EA) and adsorption propensity of F‐gas molecules render the identification of trace impurities within a high‐concentration F‐gas atmosphere exceptionally challenging. Herein, the filtration‐sensing strategy is proposed to realize highly sensitive and selective Room Temperature (RT) sensing of trace gases in the F‐gas environment. Through the innovative construction of a bilayer structure, comprising Co3(HITP)2 as the overlayer and SnO2 nanofibers (NFs) as the sensing layer, remarkably sensitive detection of trace impurity gases under intense F‐gas interference conditions is achieved. The efficacy of the Co3(HITP)2 overlayer is further corroborated through the incorporation of Pd‐SnO2 and MoS2‐SnO2 sensors, concurrently facilitating targeted quantitative identification within a complex gas mixture environment. The underlying sensing mechanism is predominantly attributed to interatomic adsorption interactions and the modulation of gas diffusion by microporous structures. This work provides pioneering insights into trace impurity detection within high‐concentration F‐gas atmosphere while presenting a potentially viable solution for the operational maintenance of F‐gas‐based industrial equipment (F‐equipment) in industrial applications.

Magnetic hydrogel scaffold based on hyaluronic acid/chitosan and gelatin natural polymers.

Owing to their native extracellular matrix-like features, magnetic hydrogels have been proven to be promising biomaterials as tissue engineering templates In the present work, magnetic hydrogels scaffold based on chitosan, gelatin, hyaluronic acid, containing Fe3O4 as magnetic nanoparticles (IONPs) were prepared. The prepared hydrogels were loaded with ciprofloxacin hydrochloride as a model drug. The magnetic hydrogel was prepared using different volumes of chitosan, 1%, gelatin, 10%, and hyaluronic acid, 1% in glutaraldehyde as the crosslinking agent and Fe3O4 as magnetic nanoparticles. The hydrogel scaffold and magnetic scaffold hydrogel samples were characterized by scanning electron microscopy (SEM), vibrating sample magnetometry (VSM), and Fourier-transform infrared spectroscopy (FTIR). The porosity, mechanical properties, swelling degree, and antibacterial activity of the hydrogel scaffold were also determined as well as the drug release profiles of the hydrogels. SEM imaging revealed that the magnetic hydrogel scaffold showed a relatively rough morphology with an irregular surface. The data obtained indicated that the hydrogel surface has three-dimensional porous microstructures and the porosity varied depending on the hydrogel formulation. The breaking load of the hydrogel scaffold increased from 1.361 Kgf to 4.98 Kgf by increasing the glutaraldehyde concentration from 0.2 mL to 0.8 mL. Swelling degree values in water were from 250 to 2000% after 24h. The antibacterial activity of the hydrogel scaffold ranged from 54% to about 97% for Gram-positive bacteria (S. aureus) and from about 26-92% for Gram-negative bacteria (E. coli). The ciprofloxacin hydrochloride loaded hydrogel has a sustained release of ciprofloxacin hydrochloride over 10h. The presence of IONPs gave a faster release of ciprofloxacin hydrochloride.

Structure and characterization of an extracellular polysaccharide from Paenibacillus polymyxa 88A.

Levan-type polysaccharides, produced by various organisms, are nontoxic, biocompatible, and biodegradable polymers with a wide range of biological activities. They have high potential for use in medicine, cosmetology, and industry. A large amount of levan (41.1 g L-1) was recovered by ethanol precipitation from a liquid nutrient medium of Paenibacillus polymyxa 88A that contained 15 % w/v sucrose as a carbon source. The levan was fractionated by gel-permeation and anion-exchange chromatography and was analyzed by DRIFT and NMR spectroscopy. It was found that levan was represented by slightly branched chains composed of β-(2→6)-Fruf residues. The average molecular mass of the levan was about 1.9 MDa. When shear stress was applied at different temperatures, aqueous levan solutions showed pseudoplastic behavior. As found by SEM, a freeze-dried powdered levan sample had a microporous structure. The levan had excellent emulsifying activity toward sunflower oil, forming an emulsion with long-term stability. Analysis of the antioxidant activity of the levan showed a higher, dose-dependent activity toward ABTS, as compared with that toward DPPH. Finally, the bioactivity of the levan was examined by MTT assay by using human cervical carcinoma (HeLa) cells.

Multifunctional Electromagnetic Responsive Porous Materials Synthesized by Freeze Casting: Principles, Progress, and Prospects

AbstractFreeze casting is a solidification technique utilized in the fabrication of porous materials. However, the freeze casting process is quite complex, and significant challenges remain in precisely controlling the pore size and shape of porous structures. This study aims to investigate the customization of multifunctional electromagnetic wave (EMW) absorbers with 3D porous structures via freeze casting. This review initially presents the fundamental principles underlying the freeze casting technique and examines the correlation between internal and external factors during the preparation process and porosity. The emerging trends in constructing novel and intricate macroscopic structures through freeze casting are subsequently outlined. Furthermore, this review focuses on the fabrication of composites with various porous microstructures through freeze casting of low‐dimensional building blocks, and their EMW response and multifunctional properties. By regulating the internal and external influencing mechanisms of freeze casting, porous EMW absorption materials exhibit outstanding advantages such as electromagnetic property manipulation, controllable structure, high porosity, high specific surface area, lightweight, and flexibility. These features broaden their applications in electromagnetic shielding, mechanical property, radar stealth, thermal insulation and fire prevention, flexible sensors, antifreeze ability, etc. In addition, we discuss the challenges and prospects of high‐performance EMW absorbers using freeze casting techniques.

Freezing‐Assisted Direct Ink Writing of Customized Polyimide Aerogels with Controllable Micro‐ and Macro‐ Structures for Thermal Insulation

AbstractPolyimide (PI) aerogels have attracted attention in thermal management due to their low thermal conductivity, high porosity, and robust mechanical properties. However, building PI aerogels with elaborately tailored micro‐ and macro‐ structures for optimized thermal insulation performance in specific scenarios remains a challenge. Here, a scalable approach is reported to prepare PI aerogels with controllable micro‐ and macro‐ structures by freezing‐assisted direct ink writing (FADIW) of poly(amic acid) (PAA) inks. This FADIW strategy can enable continuous ink deposition and transient low‐temperature‐induced gelation, contributing to the facile construction of spatially free geometries with structural complexity and shape fidelity. Importantly, controllable construction of microstructures of the aerogels is achieved by controlling the extrusion substrate temperature. The resulting customized PI aerogels show good thermal insulation owing to the porous microstructure and customized macrostructure, enabling good thermal management for portable electronics. In addition, this FADIW strategy is universal and allows for multi‐material integration, broadening the functionality of PI aerogels. Significantly, such FADIW approach can be promisingly applied to realize on‐demand design of PI aerogels and other polymer aerogels with targeted micro‐ and macro‐structures, offering an alternative avenue for the manufacture of customized aerogels toward widespread applications.

Leveraging Ligand Desymmetrization to Enrich Structural Diversity of Zirconium Metal-Organic Frameworks for Toxic Chemical Adsorption.

The discovery of metal-organic frameworks (MOFs) with novel structures provides significant opportunities for developing porous solids with new properties and enriching the structural diversity of functional materials for various applications. The rational design of building units with specific geometric conformations is essential to direct the construction of MOFs with unique properties. Herein, we leverage a ligand desymmetrization approach to construct a series of new MOFs. A flexible tetratopic carboxylate ligand with a tetrahedral geometry was designed and assembled with a Zr6 cluster, generating four Zr-based MOF structures: NU-2600, NU-2700, NU-2800, and NU-1802, in which the ligand configurations and Zr6 cluster connectivities can be controlled by varying solvents and modulators during synthesis. Except for NU-1802, these represent entirely new topologies. Notably, NU-1802 exhibits structural flexibility, with up to a 74% reduction in the unit cell volume as confirmed by single-crystal X-ray diffraction studies. Given their microporous structures, we studied the adsorption behaviors of n-hexane and 2-chloroethyl ethyl sulfide to explore the structure-property relationships of these MOFs. Overall, this work highlights ligand desymmetrization as a powerful method to enrich MOF structural diversity and access complex MOFs with non-default topologies suitable for applications such as toxic gas capture.

Leveraging Ligand Desymmetrization to Enrich Structural Diversity of Zirconium Metal–Organic Frameworks for Toxic Chemical Adsorption

The discovery of metal–organic frameworks (MOFs) with novel structures provides significant opportunities for developing porous solids with new properties and enriching the structural diversity of functional materials for various applications. The rational design of building units with specific geometric conformations is essential to direct the construction of MOFs with unique properties. Herein, we leverage a ligand desymmetrization approach to construct a series of new MOFs. A flexible tetratopic carboxylate ligand with a tetrahedral geometry was designed and assembled with a Zr6 cluster, generating four Zr‐based MOF structures: NU‐2600, NU‐2700, NU‐2800, and NU‐1802, in which the ligand configurations and Zr6 cluster connectivities can be controlled by varying solvents and modulators during synthesis. Except for NU‐1802, these represent entirely new topologies. Notably, NU‐1802 exhibits structural flexibility, with up to a 74% reduction in the unit cell volume as confirmed by single‐crystal X‐ray diffraction studies. Given their microporous structures, we studied the adsorption behaviors of n‐hexane and 2‐chloroethyl ethyl sulfide to explore the structure‐property relationships of these MOFs. Overall, this work highlights ligand desymmetrization as a powerful method to enrich MOF structural diversity and access complex MOFs with non‐default topologies suitable for applications such as toxic gas capture.

Preparation and Antibacterial Properties of Poly (l-Lactic Acid)-Oriented Microporous Materials

In this manuscript, an efficient self-reinforcing technology—solid hot drawing (SHD) technology—was combined with green processing supercritical carbon dioxide (SC-CO2) foaming technology to promote poly (l-lactic acid) (PLLA) to form an oriented micropore structure. In addition, Polydimethylsiloxane (PDMS), with a high affinity of CO2 and biological safety, was introduced to enhance the nucleation effect in SC-CO2 foaming and co-regulate the uniformity of oriented micropores’ structure. The results showed that orientation induced PLLA crystallization, so the tensile strength was improved; the maximum tensile strength of the oriented micropores’ PLLA reached 151.2 MPa. Furthermore, the micropores mainly improved the toughness; the maximum elongation at break reached 148.3%. It is worth mentioning that PDMS can form an antibacterial film on the surface of the material, so that the material has a continuous antibacterial effect.

Jujube Syrup and Starter YF‐L922 Co‐Fermentation of Yak Yogurt: Effects of Quality Properties, Antioxidative Activities and Structure

ABSTRACTDifferent percentages of jujube yrup (0%, 3%, 6% and 9%) were incorporated into yak milk and fermented using the fermenting agent YF‐L922. The quality characteristics and antioxidant activity of the resulting yogurt were evaluated at days 0, 7, 14, 21 and 28. The results indicated that the pH and acidity of the yogurt were not significantly influenced by the varying additions of jujube syrup during storage (p > 0.05). However, the addition of jujube syrup significantly reduced the water‐holding capacity of the yogurt (p < 0.05). Furthermore, the levels of jujube syrup were significantly and positively correlated with both antioxidant activity and free radical scavenging ability (p < 0.05). The live bacterial count of the yogurt decreased significantly by day 28, although the count of live lactic acid bacteria remained above 106 CFU/mL. Notably, yak yogurt with a 3% addition of jujube syrup achieved a favorable sensory score. The incorporation of jujube syrup resulted in a firmer texture and a more porous microstructure, demonstrating a higher degree of syneresis. Additionally, the inclusion of jujube syrup substantially diminished the animalic odor associated with yak milk, improved flavor acceptability and enhanced the antioxidative properties of yak yogurt. Therefore, yak yogurt augmented with jujube syrup represents a novel product with high nutritional value.

Saturation model for pore-type gas hydrate based on additional muddy conductive digital core

Abstract Original natural gas hydrate rock samples readily decompose under environmental changes during extraction, presenting challenges to conventional rock electrical analysis. This results in difficulty obtaining the cementation factor m and saturation exponent n of hydrate samples, thereby complicating the evaluation of hydrate saturation. Therefore, a method for revising the rock electrical parameters by digital core technology is proposed. Utilizing X-ray CT images of artificial gas hydrate samples, digital core models of natural gas hydrates were established. An erosion algorithm was employed to simulate the variation in mud content within the digital core, followed by the calculation of resistivity using the finite element method after meshing. Through analyzing the primary micro-pore structure parameters that influence the rock electrical parameters, the saturation model was subsequently refined. The results showed that the resistivity of hydrate digital core magnifies with increasing saturation of hydrate, tortuosity, and pore-throat ratio, but decreases with increasing coordination number and mud content. The rock electrical parameters were changed with the alteration of micro-pore structure. Based on the relationship between m, n, and micro-pore structure parameters, established a correction equation for them, further improved the Indonesian equation. The saturation of hydrate reservoir in Shenhu Sea area was evaluated using the modified Indonesian equation. The modified equation reduced the relative error from 34.8% to 15.6%, significantly enhanced the calculation accuracy.

Shape/properties collaborative intelligent manufacturing of artificial bone scaffold: structural design and additive manufacturing process.

Artificial bone graft stands out for avoiding limited source of autograft as well as susceptibility to infection of allograft, which makes it the current research hotspot in the field of bone defect repair. However, traditional design and manufacturing method cannot fabricate bone scaffold that well mimics complicate bone-like shape with interconnected porous structure and multiple properties akin to human natural bone. Additive manufacturing, which can achieve implant's tailored external contour and controllable fabrication of internal microporous structure, is able to form almost any shape of designed bone scaffold via the layer-by-layer process. As additive manufacturing is promising in building artificial bone scaffold, only combining excellent structural design with appropriate additive manufacturing process can produce bone scaffold with ideal biological and mechanical properties. In this article, we sum up and analyze state of art design and additive manufacturing methods for bone scaffold to realize shape/properties collaboratuve intelligent manufacturing. Scaffold design can be mainly classified to design based on unit cells and whole structure, while the basic additive manufacturing and 3D bioprinting are the recommended suitable additive manufacturing methods for bone scaffold fabrication. The challenges and future perspectives in additive manufactured bone scaffold are also discussed.&#xD.

Comprehensive Approach to Evaluating the Macro- and Micropore Structures of Textile Materials

Introduction. The assessment of the macro- and microporous structure of textile fabrics is increasingly relevant for predicting their permeability, dyeability, and decorative potential. This evaluation plays a crucial role in determining the hygienic properties of clothing materials, optimizing dyeing and finishing processes, and assessing the filtration capabilities of technical fabrics in various dispersed media.Problem Statement. Challenges persist in accurately predicting the permeability of textile fabrics, as well as in determining the optimal parameters for dyeing and finishing processes.Purpose. The purpose of this research is developing a rapid, cost-effective, and accurate method to evaluate the macro- and microporous structure of textile materials is essential for assessing their permeability and suitability for dyeing and fi nishing processes.Materials and Methods. To study the porous structure of textile fabrics, we select the fabrics that varied in the thread structure — yarn produced by traditional and shortened methods — and in the fibrous composition. The first fabric is made from complex polyamide threads in a plain weave, the second from twill-woven polyester fiber yarn, and the third differs from the second in the structure of the weft thread. The macro- and microporous structures of these textile fabrics have been assessed by means of drying methods and sorption thermograms.Results. The micro- and macroporous structures of textile fabrics made from polyamide threads and polyester fibers have been compared. It has been found that the fabric made from polyamide threads exhibits a significantly higher sorption capacity than the fabric made from polyester fibers. This finding suggests that the fabrics made from polyamide threads possess a more developed microporous structure. This fact enhances their dyeing and decorating capabilities as compared with the fabrics made from polyester fibers. A comprehensive approach, utilizing both drying methods and sorption thermograms, has been employed to evaluate the macro- and microporous structures of the textile fabrics. Conclusions. The proposed comprehensive approach enables comparative studies of various textile materials, allowing for the refinement of technological processes for dyeing and decorating, as well as the identification of potential applications for these materials.

Pore Microstructure and Dynamic Evolution Characteristics of Unfrozen Water during the Freezing Process of Coal with Different Moisture Contents

Pore Microstructure and Dynamic Evolution Characteristics of Unfrozen Water during the Freezing Process of Coal with Different Moisture Contents

Poly(bis(1‐methylpiperazin‐1‐ium‐amide) Nanofilm Composite Membrane with Nanochannel‑Enabled Microporous Structure and Enhanced Steric Hindrance for Magnesium/Lithium Separation

AbstractEfficient lithium/magnesium (Li+/Mg2+) separation attainment is fundamental to the extraction of lithium from brine by nanofiltration membrane separation process, which is essential for resource recovery and a circular water economy. However, for poly(piperazine‐amide) nanofilm composite membranes, the higher electronegativity affects the Mg2+ rejection and consequently Li+/Mg2+ separation performance. Manipulating the positive charge density and pore size regulation of the nanofiltration membranes are determinative of the Li+/Mg2+ separation performance improvement. Here, a new monomer 1,1′‐(hexane‐1,6‐diyl)bis(1‐methylpiperazin‐1‐ium) bromide containing bis‐quaternary ammonium cations is employed as a molecular building block to fabricate polyamide nanofilms via interfacial polymerization. The dual quaternary ammoniums and the rod‐shaped conformation of the monomer confer enhanced electropositivity, steric hindrance, loosely packed microporous network structure (pore diameter∼0.8–1.35 nm), and high free volume. The resultant membrane exhibits high water permeance of 28.34 L m−2 h−1 bar−1 with good Li+/Mg2+ selectivity of up to 76.9. In addition, the membrane also exhibits chlorine stability performance owing to the lack of the chlorine sensitive −NH groups in the formed tertiary amide structures. Computational insights on the structural properties, nanofilm formation, and transmembrane water and ion transport behaviors are provided. This study offers insightful theoretical and technological concepts to design and construct membrane materials for energy‐efficient separations.

N, P co-Doped Hard Carbon Anodes for High-Performance Lithium-Ion Batteries with Enhanced Capacity Retention and Cycle Stability.

Compared to the traditional graphite anode, heteroatom-doped polymer carbon materials have high capacity retention due to their high porosity and porous structure. Therefore, they have great potential for application in lithium-ion battery (LIB) anodes. In this work,an N, P co-doped precursor polymer material (MBPp), synthesized via a one-pot method using bisphenol-A (C-source), melamine (N-source), and 9,10-Dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (P-source). The resulting N, P-co-doped hard carbon materials (MBPs) were prepared at various pyrolysis temperatures, yielding microporous, mesoporous, and macroporous structures. MBP materials demonstrated excellent electrochemical performance as LIB anodes. Notably, MBP-900 achieved a reversible capacity of 262 mAh g-1 at 1000 mA g-1 (in 0.005-2.0 V voltage range) with a capacity retention rate of 97.2% after 1000 cycles. These findings highlight the significance of MBP materials, which possess numerous defects, large layer gaps, and excellent cycle stability, in advancing the development of polymer anode materials for LIBs.

Deeply buried clastic rock diagenesis evolution mechanism of Dongdaohaizi sag in the center of Junggar fault basin, Northwest China

Abstract To reveal the diagenetic sequence of reservoir rocks in the central part of the deep depression basin, the Wuerhe Formation in Junggar Basin was taken as an example to conduct the detailed studies on its sedimentary facies, diagenetic sequence, and the micropore structure evolution rules based on the comprehensive data from a super deep exploration well C-6 (approximately 7,000 m in depth). First, an arid environment fan delta sedimentary model of the Wuerhe Formation was established, and its sedimentary evolution law was clarified as a gradual transition from a fan delta front to a fan delta plain during the water-regression process until the lake dried up. Then, the diagenesis types and evolution sequence of the Wuerhe Formation, and the influence degrees of the compaction, cementation, and dissolution on the rock formation process were clarified. Finally, the diagenesis and pore evolution model was established, and the greatest impact factors of the late reservoir densification were clarified. Based on this research, the diagenesis and pore evolution processes of the deep rocks in the studied deep central sag were ultimately revealed to provide useful guidance for the deeply buried oil and gas reservoir exploration.

Surface Coating of ZIF-8 Nanoparticles with Polyacrylic Acid: A Facile Approach to Enhance Chemical Stability for Biomedical Applications.

Nanoparticles of zeolitic imidazole framework-8 (ZIF-8 NPs), which are the subclass of metal-organic frameworks consisting of Zn ion and 2-methylimidazole, have been identified as promising drug carriers since their large microporous structure is suited for encapsulating hydrophobic drug molecules. However, one of the limitations of ZIF-8 NPs is their low stability in physiological solutions, especially in the presence of water and phosphate anions. These molecules can interact with the coordinatively unsaturated Zn sites at the external surface to induce the degradation of ZIF-8 NPs. In this study, herein a facile approach is reported to enhance the chemical stability of ZIF-8 NPs by surface coating with polyacrylic acid (PAA). The PAA-coated ZIF-8 (PAA-ZIF-8) NPs are prepared by mixing ZIF-8 NPs and PAA in water. PAA coating inhibits the degradation of ZIF-8 NPs in water as well as phosphate-buffered saline over 6 days, which seems to be due to the coordination of carboxyl groups of PAA to the reactive Zn sites. Furthermore, the PAA-ZIF-8 NPs loaded with the anticancer drug doxorubicin (Dox) show cytotoxicity in human colon cancer cells. These results clearly show the feasibility of the PAA coating approach to improve the chemical stability of ZIF-8 NPs without impairing their drug delivery capability.

Boosting Hydrogen Transport in Mixed Matrix Membranes Through Continuous Spillover Via Pd‐Functionalized MOF Gel Networks

AbstractMembrane‐based gas separation offers notable energy efficiency benefits for hydrogen purification, yet it is often hindered by the inherent trade‐off between permeability and selectivity. To address this challenge, a novel mixed matrix membrane (MMM) design is presented to boost H2 separation performance via continuous hydrogen spillover mechanisms for the first time. The MMM incorporates a palladium‐functionalized ZIF‐67 gel (Pd@ZIF‐67 gel) network into a polymer of intrinsic microporosity (PIM‐1) matrix. The ZIF‐67 gel network serves as a uniform dispersion medium for palladium nanoparticles (Pd NPs), thereby generating a multitude of active sites. These exposed sites, in conjunction with the microporous structure of ZIF‐67, facilitate hydrogen dissociation and establish a continuous hydrogen spillover pathway throughout the membrane. This synergistic MMM design leads to substantial improvements in both hydrogen transport and selectivity. At an optimal loading of 28 wt% Pd@ZIF‐67 gel, the MMMs exhibit a H2 permeability of 3620 Barrer and a remarkable 417% enhancement in H2/CH4 selectivity (24.9), surpassing the 2008 upper bound. This approach paves the way for the development of advanced materials tailored for gas separation applications.

Photopolymerization enabled in-air highly oleophobic and hydrophilic SiC membranes with improved antifouling performance in oil-in-water emulsion separation

Ceramic membranes with tailored surface wettability have gained increasing attention for improving their separation efficiency and antifouling ability, while most of the previous work focused on the underwater oleophobic behavior. In this work, in-air highly oleophobic and hydrophilic SiC membranes were achieved through the UV irradiation triggered polymerization and controlled crosslinking between oleophobic perfluorodecyl acrylate (TFOA) and hydrophilic methacrylic acid (MAA). These key processing parameters including MAA content, soaking time and irradiation duration were systematically studied through examining the changes in porous microstructure, surface wettability and separation performance in oil-in-water emulsion. Results showed that the flux attenuation rate of SiC membranes can be effectively reduced by regulating the content of hydrophilic components. Due to the alternation of the surface wettability to highly oleophobic in air, the oil droplets can hardly attach on the surface of modified SiC membranes at the beginning of filtration process, and the membrane fouling was significantly slow down yet dominated by the intermediate blocking. Correspondingly, a combined cleaning procedure was proposed to regenerate the fouled SiC membranes. Further, the antifouling ability of modified and original SiC membranes was comparatively studied under the conditions of a fixed permeate volume (15 ml) and various oil concentrations (200 ∼ 1000 ppm) in the separation of oil-in-water emulsion. The advantages of modified SiC membranes become more notable when used for highly concentrated oil–water emulsion as reflected by the slower flux decline and higher stable flux. This work provides a feasible pathway to realize the in-air highly oleophobic and hydrophilic surface on ceramic membranes, and primarily demonstrates the advantages of antifouling ability in oil-in-water emulsion separation.

Coupled electrostatic induction strategy toward polyaniline-derived hard carbon with uniformly microporous boosts high-rate sodium storage

Constructing a uniform and controllable hard carbon anode with suitable micropores can effectively improve the overall sodium storage performance. Herein, an electrostatic induction strategy was used to change the structure of micelles by adding surfactant content to form polyaniline (PANI) with different morphologies. The presented synthesis method is characterized by the introduction of oppositely charged surfactants to induce rapid nucleation and the formation of foams with small pore sizes, which are then transformed into homogeneous microcellular pores by high-temperature carbonization. Thus, the microporous structures in hard carbon anode provide excellent electrochemical storage sites for sodium ion storage. As a consequence, the sodium dodecyl benzene sulfonate (SDBS) electrostatic induced PANI-derived hard carbon (SD-HC) showed a uniform pore structure with low surface area (14.54 m2 g−1) and uniform micropores (1.54 nm), which used as an anode material for sodium storage can provided high reversible capacity of 282.4 mAh g−1 at 50 mA/g, excellent rate performance (196 mAh g−1 at 5 A/g) and cycling stability (93.3 % capacity retention after 1000 cycles at 1 A/g). This simple and efficient synthesis strategy provides an effective guide for the design of nanostructures for the preparation of similar functional polymeric materials.