Since 1996, experimental and modeling approaches have led to the understanding of the main mechanisms controlling the Opalinus Clay pore water composition. By 2003, one of the main remaining uncertainties concerned the carbonate system. Consequently, to reduce this uncertainty, an innovative device for pore water sampling was implemented in 2004 in the Mont Terri Rock Laboratory. An ascending borehole was dry-drilled, using only N 2 gas and aseptic tools to avoid rock oxidation and microbiological perturbation. The borehole equipment allowed the circulation of gas, initially pure argon, in contact with the rock in a closed circuit and the sampling of formation water produced in the test interval. This experiment made it possible to monitor the composition of the circulating gas over several months and to collect seepage water at a flow rate close to 3 mL/day over more than 3 years. The sampled water composition remained stable over time and coherent with the previous understanding. CO 2 partial pressures calculated from water analyses are between 10 −2.4 and 10 −1.7 bar. Modeling of the evolution of CO 2 concentration in the circulating gas involved advection, diffusion, calcite precipitation and proton buffering surface processes. CO 2 partial pressure deduced from water analyses is a few mbars higher than that measured on the gas. Calcium carbonate precipitation and capillary effects could explain this discrepancy.