Pore Collapse Research Articles

Correlation between geomechanical and sedimentary facies and their implications for flow unit definition in the pre-salt carbonate reservoir, Brazil

Carbonate reservoirs are of great economic importance due to their frequent association with high permeability and hydrocarbon storage capacity. One of the most significant discoveries of this type of reservoir in recent decades has been the Brazilian Pre-salt. This deep reservoir has unusual depositional features, consisting of a wide variety of textures with different compositions, influenced by diagenetic overprinting that modify most of its mechanical, elastic and petrophysical properties. Despite the marked heterogeneity, these carbonates are characterized by excellent reservoir quality. The objective of this study is to establish a correlation between geomechanical behavior and sedimentary facies and its implications for the definition of flow units in the Barra Velha Formation, the main reservoir of the Brazilian Pre-salt. Thus, using a database from the Buzios field composed of well logs (conventional and advanced), well tests, thin sections, and laboratory petrophysics, geomechanical facies (GMFs) were defined using dynamic geomechanical modeling and an unsupervised algorithm (K-mean clutering), followed by textural classification of sedimentary facies and definition of flow units (FUs) on the decametric scale. These classifications were compared using frequency histograms. The geomechanical model revealed that the in-situ stress state exhibits a dual regime, between normal and strike slip. In addition, it was found that the direction of the maximum horizontal stress is in the NE-SW azimuth. In this context, four geomechanical facies were defined, which showed a notorious variation in mechanical strength. The strongest GMFs consisted mainly of well-cemented Grainstones and Packstones with no apparent porosity or microcrystalline porosity and correlated with the FU with the worst production rates. On the other hand, the weaker GMFs were mainly composed of Grainstones and Spherulistones with high intergranular porosity generated by dissolution processes, with higher risk of pore collapse and correlated with the FUs with the best production rates. However, this classification also identified laminated mudstones with microporosities associated with FUs that act as flow barriers. Geomechanical facies have also been incorporated into reservoir development by evaluating wellbore stability, fault reactivation risk, and brittleness index for future CO2 injection projects.

Preparation of hyperbranched hydrophobic nano-silica and its superior needling-effect in PDMS defoam agent

Hydrophobic nano silica powder is a kind of important synergist to silicone defoaming agents. The large pore volume and branched chain conformation of silica nanoparticles present superior effects on defoaming properties. However, silica nanoparticles synthesized by liquid phase easily aggregate and pore collapse because of their high surface activity and polarity, leading to poorer dispersity and limited practicability. In this paper, a novel hydrophobic silica with a hyperbranched structure was designed through in-situ modifying method with hexamethyldisilazane (HMDS) and polydimethylsiloxane (PDMS) in the liquid phase. The trimethylsilanol generated by HMDS hydrolysis reacts quickly with the highly active hydroxyl groups on the silica, causing the surface properties of the nanoparticles to transform from polar to non-polar properties. The steric hindrance of the trimethyl silicon and the reduction of the surface polarity effectively prevent silica pores from collapsing and maintain the macropore structures to realize the hyperbranched silica. At the same time, the −Si (CH3)2− from PDMS endowed the hyperbranched silica with excellent hydrophobicity. When applied in the defoaming agent, the hydrophobicity of silica contributes to dewetting the foams, and the hyperbranched spatial structures play an enhanced needling effect. Therefore, this hydrophobic hyperbranched silica exhibited a surprising defoaming effect, which significantly reduced the defoaming time from 464.4 s to less than 2 s, superior to commercial defoaming silica (155.3 s). The defoaming efficiency reached 100 % within 2 s of the end of the shaking, and the defoamer antifoaming ability was improved to reach 27.5 min, which was 77 % higher than that of commercial defoamer.

In situ synthesis of porous metal-organic frameworks NH2-UiO-66 on tea stem biochar and application in odours adsorption

Multiple odour nuisance in livestock farming is a notorious problem that has a significant impact on the living environment of surrounding communities. Adsorbents based on metal-organic framework (MOF) materials show great promise for controlling odour pollution, as they offer a high specific surface area, a controllable structure and an abundance of active sites. However, the MOF formation process is prone to problems such as pore clogging or collapse and reduced porosity, which limits its further application. In this study, a series of odour adsorbents were prepared by in situ growth of NH2-UiO-66 on tea stem biochar (TSBC) using a hydrothermal method and named UiO (Zr)-TSBCx. The physical and chemical properties and composition of UiO (Zr)-TSBCx have been systematically characterized using SEM, TEM, XRD, FT-IR, N2 adsorption-desorption and XPS. The release of odours from the pig farm effluent was monitored using in-situ continuous Proton-Transfer-Reaction Mass Spectrometry (PTR-MS), and the obtained primary compositions were tested for further adsorption. In dynamic adsorption experiments focused on butyric acid, UiO (Zr)-TSBC2 showed a high adsorption capacity of 3.99 × 105 μg/g and exceptional structural stability. UiO (Zr)-TSBC2 showed variable adsorption efficiencies for different odorous gases, with the best performance for the removal of ammonia, toluene and butyric acid. It also demonstrated the ability to rapidly mitigate instantaneous high concentrations of hydrogen sulfide (H2S), methanethiol and toluene resulting from agitation. Additionally, based on the relationship between the adsorption amount and the structural characteristics of the adsorbent as well as the nature of the odours, a possible adsorption mechanism of UiO (Zr)-TSBC2 for a variety of odours released from pig farm effluent was proposed. This work demonstrates a novel approach to promote deodorization applications in livestock and poultry farming environments by the in-situ growth of NH2-UiO-66 on biochar prepared from tea stem.

Postsynthetic modification of yttria‐stabilized zirconia aerogels with silica coatings for enhanced thermal stability

AbstractMaintaining high surface area and porosity at high temperatures is important when considering aerogels for use in thermal management systems. The mesoporous structure of aerogels results in extremely low thermal conductivity, making them lightweight, high performance insulating materials. Maintaining these properties requires innovative routes to suppress sintering and pore collapse as use temperatures rise. The current work aims to improve the pore structure stability of yttria‐stabilized zirconia aerogels by the addition of a SiO2 coating. The functionalization of surface hydroxyl groups by the addition of SiO2 is hypothesized to mitigate condensation reactions, which are a driving force for shrinkage and pore structure collapse. Zirconia aerogels with 0, 10, and 30 mol% yttria (YO1.5) additions were coated in a tetraethyl orthosilicate (TEOS) solution and exposed to temperatures up to 1200°C. Crystal structure, pore structure, and aerogel morphology were investigated to understand changes in aerogel thermal stability. The SiO2 coating exhibited a greater influence on pore stability over yttria concentration, with specific surface area of the coated aerogels being twice that of the uncoated aerogels up to 1000°C. However, the presence of the SiO2 coating promoted rapid sintering and densification at 1200°C, establishing an upper use temperature for SiO2 and a need to develop other coating chemistries.

Introducing the area under stress–velocity curve: Theory, measurement and association with rock properties

AbstractSince many years ago, ultrasonic velocity has been used to investigate the physical and mechanical behaviour of rocks, thereby playing an important role in reservoir characterization and seismic interpretation. In order to develop the knowledge of ultrasonic tools, we performed a noble analysis on the ultrasonic behaviour of rocks under confining stress and evaluated a distinctive property of porous media that is measured as the area under the stress–velocity curve (here defined as S*). We further investigated its relationship with elastic and mechanical behaviours of rock. To validate the theoretical framework developed in this work, 20 core plugs from various rock units with complex microstructures were subjected to triaxial compressional tests to calculate their area under the curve. Calculations were made for crack‐closing, elastic and post‐elastic stages (e.g. pore collapse) along the ultrasonic velocity–stress curve. Moreover, the selected samples had their microstructure investigated by thin‐section studies to quantify their porosity and pore type. The results were analysed to check for the effect of pore type on S* in different stages of the stress–velocity curve. Based on the outputs of the analysis of variance and Pearson's correlation coefficient analysis, the curve had its shape and underlying area closely related to the porosity and pore geometry. Indeed, the results showed that the shale and sandstone with micro cracks and carbonate with stiff pores correspond to smaller and larger areas under the curve in crack‐closing and inelastic stages, respectively. Cross‐correlating the results to compressibility (inverse of bulk modulus), it was figured out that the calculated area under curve was well consistent with the compressibility. In addition, S* represents both static and dynamic behaviours of the rock, and the results revealed that the shape and curvature of the stress–velocity curve give valuable information about the rock microstructure. Another finding was the fact that the type of fluid and wave velocity seemingly affect the S*. Our findings can help interpret wave velocity behaviour in reservoir rocks and other stressful porous media.

A discrete approach for modelling the permeability evolution of granite under triaxial and true-triaxial stress conditions

In deep underground engineering, modelling the seepage characteristics of rock masses under complex stress conditions is crucial for the safe construction and stable operation of a project. The permeability of the rock mass is not only controlled by its internal pore structure but is also closely related to the deformation and fracturing of the rock. Although discrete methods offer advantages in describing the formation and development of fractures, these methods still face challenges due to the difficulties in establishing microscopic seepage models. This paper introduces a new hydro-mechanical coupled numerical model. In this model, a simple method is proposed to couple the Rigid-Body-Spring Method (RBSM) for rock deformation and fracturing simulation and the Equivalent Matrix-Fracture Network (EMFN) for seepage simulation. Subsequently, the model is employed to simulate the permeability of granite under three-dimensional stress conditions. The simulation results show that under hydrostatic stress conditions, the model accurately captures the decrease in permeability due to pore compression and collapse. Additionally, under deviatoric stress conditions, it reveals the stage-wise increase in permeability caused by granite fracturing. Finally, the model is applied to study the permeability evolution behaviour of rocks under true triaxial stress conditions. The results unveiled the significant impact of the intermediate principal stress on permeability evolution and revealing the microscopic mechanisms underpinning these effects. This paper paves a way for enhancing the application of discrete methods in forecasting the permeability evolution behaviour of intricate rock masses.

Shock-induced plastic deformation of nanopowder Ti during consolidation and spallation.

Consolidating nanopowder metals via impact loading is a potentially significant method for synthesizing and processing bulk nanocrystalline materials. However, until now, the microstructural features, plastic deformation during consolidation, and corresponding mechanisms have been seldom revealed. Using molecular dynamics (MD) simulations, we have studied the plastic deformation, densification, spallation, and micro-jetting in nanopowder titanium (np-Ti) during shock. Upon impact, np-Ti undergoes a transition from heterogeneous plasticity, including basal stacking faults (SFs) and {101̄2} twinning, to homogeneous disordering, as the impact velocity increases. Then the nanopowder structure evolves into a bulk nanostructure after the final densification, contributed by pore collapse. The subsequent detwinning arises during the release and tension stage, conducing to a partial structural recovery. When the impact velocity up ≥ 1.0 km s-1, the spallation is following, prompted via GB-sliding and disordering. Upon shock impact, it also facilitates micro-jetting owing to the presence of nanopores, contributing to the pressure gradient and transverse velocity gradient.

Multi-network PVA/SA aerogel fiber: Unveiling superior mechanical, thermal insulation, and extreme condition stability

Aerogels are highly sought-after in thermal insulation textiles due to their exceptional porosity and low density. However, Current research on aerogels mainly centers on their fixed two- and three-dimensional structures, lacking design flexibility, which significantly restricts their practicality. In contrast, one-dimensional aerogel fibers, while offering design flexibility, face complex fabrication, challenges in continuous molding, and pore collapse issues. In this study, utilizing polyvinyl alcohol (PVA) and sodium alginate (SA) as raw materials, a cost-effective wet spinning, freeze-thaw cycling, and freeze-drying technique were employed to continuously produce multi-functional PVA/SA aerogel fibers with a stable network pore structure through the design of a multi-crosslinked interlocking network structure. The optimal preparation process for the aerogel fibers was explored and characterized. The resulting aerogel fibers exhibited a stable hierarchical pore structure at the microscale, featuring large pores, nested mesopores, and micropores. These fibers possessed a high specific surface area (115.88 m²/g), high porosity (92.42 %), low density (0.0632 g/cm³), low thermal conductivity (0.0378 W/(m·K)), and flame resistance (LOI: 26.8 %). Furthermore, their stable internal network scaffold structure endowed them with outstanding mechanical properties (3.6 cN/tex) and stability in extreme environments. These composite aerogel fibers offer great potential for high-performance thermal insulation textiles and products.

Porosity and specific surface area dependence of shock-induced plasticity and melting in open-cell nanoporous Cu

We systematically study the plasticity and melting behavior in shock loading, as well as their dependence on porosity (ϕ) and specific surface area (γ) for nanoporous copper (NPC), by conducting large-scale non-equilibrium molecular dynamics simulations. During shock compression, the plasticity (i.e., dislocation slips) is dominant at lower impact velocities, while melting is governing at higher impact velocities. With increasing ϕ, both the plasticity and melting undergo the transitions from “heterogeneity” to “homogeneity” along the transverse directions. The increase in γ prompts an apparent heat release and gives rise to the transition from local plasticity to uniform solid disordering at lower impact velocities, while accelerates the melting at higher impact velocities, by converting more surface energy into internal energy. Upon impact, shock-induced pores collapse accelerates the consolidation of NPCs and is controlled by two mechanisms, i.e., the shearing ligament, prompted by plasticity, under low-velocity impact, and the internal micro-jetting facilitated by melting under high-velocity impact.

Challenging the paradigm for reactive material's ignition from shear to pressure: Thermomechanical study of Al-PTFE

Structural reactive materials (SRMs) are attracting growing interest in the warheads industry, while the Al-PTFE system is probably the most popular. Due to their final application, high-strain rate (impact) testing is the most realistic method for SRMs. For this purpose, a synchronized Split Hopkinson (Kolsky) Pressure Bar with high-speed infrared and optical cameras is used to characterize the sintered Al-PTFE system, thus enabling the simultaneous investigation of its thermal energy release and mechanical properties under impact. The characteristic specimen heating rates during such experiments are of the order of 3.85 × 108 °C/min, which most likely caused evaporation of the reaction products, that were therefore not identified in a post-mortem analysis of the remaining fragments. Whereas the conventional wisdom has it that shear loading causes SRM ignition, the main result of this work just points to the opposite, showing unambiguously that pressure is the reaction-triggering loading mode, with the potential involvement of a pore collapse mechanism.

Thermal Maturity Constraint Effect and Development Model of Shale Pore Structure: A Case Study of Longmaxi Formation Shale in Southern Sichuan Basin, China

When the thermal maturity of the Longmaxi Formation in the southern Sichuan Basin is too high, the pore structure of shale becomes poor. Therefore, to investigate the effect of organic matter thermal maturity on shale pore structure, a study was conducted. Using the Longmaxi Formation shale in the southern Sichuan Basin as an example, the intrinsic relationship between shale porosity, pore structure parameters, organic matter laser Raman maturity, and organic matter graphitization degree was examined using X-ray photoelectron spectroscopy, particle helium porosity measurement, organic matter micro-laser Raman spectroscopy, and gas adsorption experiments. The results indicate that thermal maturity is the macroscopic manifestation of the graphitization degree of organic matter, and the correlation coefficient between the two is 0.85. A thermal maturity of 3.5% (with a corresponding organic matter graphitization degree of 17%) aligns with the highest values of shale porosity, pore volume, and pore-specific surface area across all pore size conditions. The evolution model of shale pore structure can be divided into two stages. The first stage is characterized by a thermal maturity between 2.0% and 3.5% (with a corresponding degree of graphitization of organic matter between 0% and 17%). During this stage, the number and connectivity of micro-macropores increase with increasing thermal maturity. The second stage is marked by a thermal maturity between 3.5% and 4.3% (with a corresponding degree of graphitization of organic matter between 17% and 47.32%). Basement faults are present, leading to abnormally high thermal maturity, poor preservation conditions, continuous generation of micropores, better connectivity, and a reduced number of pores. Medium macropores with good connectivity suffer from gas loss in the fracture network, leading to the collapse and disappearance of pores. The results mentioned in the statement have an important guiding role in the efficient exploration of shale gas in the Longmaxi Formation in the southern Sichuan Basin.

An effective stress-based approach to modeling the hydro-mechanical behavior of unsaturated soils

A constitutive model of unsaturated soils is developed by incorporating the concept of intergranular stress into the framework of the modified Cam–Clay model. Within this context, the degree of saturation is viewed as an internal state variable, so that the soil–water retention function appears naturally as an evolution equation for the volume fraction of water. The new model not only has a neat structure but also includes fewer material parameters compared to the other models. A new volumetric-hardening law is proposed by taking into account the effect of wetting-induced pore collapse. It is shown that the collapsing void ratio (the current void ratio minus the void ratio at full saturation under the same effective stress) is dominated by the degree of pore air saturation (one minus the degree of water saturation) and practically independent of intergranular pulling forces, highlighting the important effect of soil fabric on the wetting-induced pore collapse. The proposed model is applied to simulate different types of experiments on unsaturated soils subjected to various combined hydraulic and mechanical loadings, showing its capability and diversity in modeling the hydraulic and mechanical behavior of unsaturated soils.

Role of moisture content in coal oxidation during the spontaneous combustion latency

The role of moisture content in coal oxidation during the spontaneous combustion latency was studied by an isothermal flow reactor. The physical and chemical changes during the drying and oxidation process were investigated using low-pressure nitrogen gas adsorption (LP-N2GA) experiments, Electron spin resonance (ESR) experiments and X-ray photoelectron spectroscopy (XPS) experiments. Experimental results reveal that moisture acts either as a promoting or an inhibiting agent under different contents. The differences in total temperature rise (TTR) of varying coal samples are the result of a complex set of competing factors. The LP-N2GA experiments reveal no pore collapse until the moisture reaches 3.05 %. Collapse clearly occurs with the micropore and mesoporous size range. When the moisture content is higher 3.05 %, the specific surface and pore volume increases with the removal of moisture. In addition, the evaporation of water also re-exposes the previously covered active sites and increases the concentration of free radicals. However, the removal of moisture makes the generation of peroxides more difficult due to moisture acts as a catalyst in the formation of such peroxide species.

Experimental study of the effect of ultralow temperature on the fracture toughness of sandstone

Fractures are widely present in subsurface formations, and fracture extension under ultralow temperature conditions is important for tasks such as liquid nitrogen fracturing and underground storage of liquid natural gas or liquid air. Therefore, the fracture toughness of sandstone under ultralow-temperature conditions was investigated using three-point bending tests of the NSCB specimens. The specimen damage processes were monitored using the DIC technique, and the changes in the pore microscopic characteristics after ultralow-temperature treatment were observed using CT and SEM. The results show that fracture toughness of dry sandstone was insensitive to the variations of the ultralow temperature (-30 to −120 ℃), whereas that of saturated sandstone increased gradually with the decrease of temperature due to the cementing effect of ice. DIC analysis showed that the peak strain around the fracture tip increased, and the fracture extension time was shortened with a decrease in temperature for both dry and saturated sandstone samples. The minerals shrank and the samples became more compacted with a decrease in temperature for the dry samples, resulting in their brittle characteristics under ultralow temperatures. The enhanced cementation effects of ice under ultralow temperatures induced high internal stress and rapid energy release upon failure of the saturated samples. Large pores shrank owing to pore collapse and filling after the one-cycle ultralow-temperature freeze–thaw treatment.

Effect of oxidation treatment on structural characteristics and combustion behavior of residual carbon from coal gasification fine slag

Improving the combustion reactivity of residual carbon (RC) is an important prerequisite for effective combustion of coal gasification fine slag (CGFS). This study investigates the oxidation of RC using air and CO2. Compared to raw RC, the oxidation process results in a lower burnout temperature of oxidized RC, and reduced combustion time. Additionally, RC oxidized by CO2 shows better combustion performance than that oxidized by air. The enhanced combustion performance of oxidized RC primarily stems from structural modification. The combustion behavior of oxidized RC is jointly determined by its carbon microstructure, functional groups, and pore structure, with pore structure being the predominant factor. Furthermore, increasing the oxidation temperature facilitates the formation of small-sized pore structures on the surface of the oxidized RC, which promote the oxygen diffusion and the heat transfer during combustion. However, the pore collapse caused by excessive oxidation inhibits the combustion performance of the corresponding oxidized RC.

Self-sensing concrete masonry structures with intrinsic abilities of strain monitoring and damage detection

Self-sensing cementitious materials are emerging technologies for Structural Health Monitoring (SHM) of civil structures. Their application for SHM of concrete masonry elements was not investigated in previous studies. The effects of triaxial strain/stress states of masonry joints and units on their self-sensing response are still unknown. Therefore, this work aimed to investigate mechanical and self-sensing properties of masonry elements produced with self-sensing mortar joints, solid concrete bricks and/or hollow concrete blocks fabricated with carbon black nanoparticles. The intrinsic abilities of strain monitoring and damage detection were evaluated in piezoresistive tests of masonry prisms, based on variations in the type of unit, mortar bedding approach, bonding arrangement, relative strength of mortar and units, joint thickness and location of self-sensing regions. These variations did not affect significantly the gauge factor of cementitious sensors embedded into the prism units. In contrast, the gauge factor of self-sensing horizontal or vertical joints was statistically affected by most of these variations. Stages of balance and abrupt increases in fractional changes in electrical resistivity (FCRs) during the plastic regime of the prisms provided an anticipated warming associated with the propagation of vertical and diagonal cracks associated with tensile splitting and crushing failure of units. The strong non-linearity on the electrical output of self-sensing joints provided an evidence of the mortar pore collapse. In conclusion, the self-sensing units and mortar joints were found to be promising alternatives for strain monitoring and damage detection in smart concrete masonry structures.

Precise control over gas-transporting channels in zeolitic imidazolate framework glasses

Porous metal–organic frameworks have emerged to resolve important challenges of our modern society, such as CO2 sequestration. Zeolitic imidazolate frameworks (ZIFs) can undergo a glass transition to form ZIF glasses; they combine the liquid handling of classical glasses with the tremendous potential for gas separation applications of ZIFs. Using millimetre-sized ZIF-62 single crystals and centimetre-sized ZIF-62 glass, we demonstrate the scalability and processability of our materials. Further, following the evolution of gas penetration into ZIF crystals and ZIF glasses by infrared microimaging techniques, we determine the diffusion coefficients and changes to the pore architecture on the ångström scale. The evolution of the material on melting and processing is observed in situ on different length scales by using a microscope-coupled heating stage and analysed microstructurally by transmission electron microscopy. Pore collapse during glass processing is further tracked by changes in the volume and density of the glasses. Mass spectrometry was utilized to investigate the crystal-to-glass transition and thermal-processing ability. The controllable tuning of the pore diameter in ZIF glass may enable liquid-processable ZIF glass membranes for challenging gas separations.

A Nanocavitation Approach to Understanding Water Capture, Water Release, and Framework Physical Stability in Hierarchically Porous MOFs.

Chemically stable metal-organic frameworks (MOFs) featuring interconnected hierarchical pores have proven to be promising for a remarkable variety of applications. Nevertheless, the framework's susceptibility to capillary-force-induced pore collapse, especially during water evacuation, has often limited practical applications. Methodologies capable of predicting the relative magnitudes of these forces as functions of the pore size, chemical composition of the pore walls, and fluid loading would be valuable for resolution of the pore collapse problem. Here, we report that a molecular simulation approach centered on evacuation-induced nanocavitation within fluids occupying MOF pores can yield the desired physical-force information. The computations can spatially pinpoint evacuation elements responsible for collapse and the chemical basis for mitigation of the collapse of modified pores. Experimental isotherms and difference-electron density measurements of the MOF NU-1000 and four chemical variants validate the computational approach and corroborate predictions regarding relative stability, anomalous sequence of pore-filling, and chemical basis for mitigation of destructive forces.

Surface collapse of fine powders ground from HKUST-1 big crystals investigated by positron annihilation lifetime spectroscopy

Big crystals of HKUST-1 were synthesized under solvothermal conditions, and HKUST-1 fine powders were also ground from them and directly synthesized. The specific surface areas of the powders were found to be much smaller than that of the big crystals, indicative of micropore collapse in the powders. Interestingly, positron annihilation lifetime spectroscopy (PALS) showed two long ortho-positronium (o-Ps) lifetimes for the powders representing o-Ps annihilation in two types of inherent pores of HKUST-1, whereas only one long lifetime in the relatively larger pores could be derived for the big crystals. Meanwhile, continuous positron lifetime analysis showed two well-decomposed o-Ps lifetime distributions accompanied by relatively higher total o-Ps intensities in the powders. Due to the nature of o-Ps atoms in porous materials, they may diffuse in well-interconnected pores, and preferentially be localized and merely annihilate in larger pores in the big crystals of HKUST-1 with intact frameworks, resulting in only one o-Ps lifetime in them. The abnormal PALS results can be well explained for the collapse of large surface pores and the formation of a dense layer on the surfaces of fine powders of HKUST-1, demonstrating PALS is a useful method for studying the pore structures of metal–organic frameworks (MOFs).

Fuel Performance Analysis of Fast Flux Test Facility MFF-3 and -5 Fuel Pins Using BISON with Post Irradiation Examination Data

Using the BISON fuel-performance code, simulations were conducted of an automated process to read initial and operating conditions from the Pacific Northwest National Laboratory (PNNL) database and reports, which contain metallic-fuel data from the Fast Flux Test Facility (FFTF) MFF Experiments. This work builds on previous modeling efforts involving 1977 EBR-II metallic fuel pins from experiments. Coupling the FFTF PNNL reports to BISON allowed for all 338 pins from MFF-3 and MFF-5 campaigns to be simulated. Each BISON simulation contains unique power and flux histories, axial power and flux profiles, and coolant-channel flow rates. Fission-gas release (FGR), fuel axial swelling, cladding profilometry, and burnup were all simulated in BISON and compared to available post-irradiation examination (PIE) data. Cladding profilometry, FGR, and fuel axial swelling simulation results for full-length MFF metallic pins were found to be in agreement with PIE measurements using FFTF physics and models used previously for EBR-II simulations. The main two peaks observed within the cladding profilometry were able to be simulated, with fuel-cladding mechanical interaction (FCMI), fuel-cladding chemical interaction (FCCI), and thermal and irradiation-induced creep being the cause. A U-Pu-Zr hot-pressing model was included in this work to allow pore collapse within the fuel matrix. This allowed better agreement between BISON-simulated cladding profilometry and PIE measurements for the peak caused by FCMI. This work shows that metallic fuel models used to accurately represent fuel performance for smaller EBR-II pins may be used for full-length metallic fuel, such as FFTF MFF assemblies and the Versatile Test Reactor (VTR). As new material models and PIE measurements become available, FFTF MFF assessment cases will be reassessed to further BISON model development.