Abstract This article provides the first rigorous estimates of how industrial air pollution from coal burning affects long-run city growth. I introduce a new theoretically grounded strategy for estimating this relationship and apply it to data from highly polluted British cities from 1851 to 1911. I show that local industrial coal use substantially reduced long-run city employment and population growth. Moreover, a counterfactual analysis suggests that plausible improvements in coal-use efficiency would have led to a higher urbanisation rate in Britain by 1911. These findings contribute to our understanding of the effects of air pollution and the environmental costs of industrialisation.