Polyvinyl Chloride Film Research Articles

Meat Substitution with Oat Protein Can Improve Ground Beef Patty Characteristics.

The consumer acceptance of alternative plant-focused ingredients within the meat industry is growing globally. Oat protein is insoluble and used to increase product yield and fat retention. Furthermore, inclusion of oat protein can provide manufacturers another option for extending beef supplies. As the consumer diet shifts for improvements in nutritional density, oat protein is an alternative ingredient that lacks information on inclusion in a ground beef formulation. Coarse ground beef was allocated to one of four treatments, mixed with oat protein (0%, 1.5%, 3.5% and 4.5%), water, salt, pepper, textured vegetable protein, soy protein concentrate, and sodium tripolyphosphate. Meat blocks (n = 3 batches) were finely ground and formed into patties (N = 65/treatment). Patties were placed onto an expanded polystyrene tray, overwrapped with polyvinyl chloride film and displayed for 7 days. Instrumental color (L*, a*, and b*) decreased throughout simulated display (p = 0.0001). Increased usage rates of oat protein in patties resulted in greater cook yields (p = 0.0001). Objective measures of Allo-Kramer shear force values increased as oat protein inclusion rates increased (p = 0.0001). Oat protein can be incorporated in ground beef patties with positive effects on cook yield, but inclusion rate may have a deleterious impact on color and instrumental tenderness.

Sonochemical Synthesis of Laurate Sucrose Ester as Bio-Based Plasticizer and Bio-Additive for PVC

The present study shows the results obtained in the ultrasonic synthesis of sucrose esters with lauric acid, the identification of products, and the study of their possible use as bio-additives with a plasticizing effect in the processing of plastics. Fourier transform infrared spectroscopy (FTIR) and NMR (1H and 13C NMR) were used to identify the synthesized esters. The plasticizing effect of sucrose laurate was assessed by determining the glass transition temperature of thin polyvinyl chloride films by differential scanning calorimetry (DSC). The results show a decrease in the glass transition temperature with an increase in the ester concentration in the polymer, which confirms the plasticizing effect of the obtained esters.

Effect of Modified Silica Materials on Polyvinyl Chloride (PVC) Substrates to Obtain Transparent and Hydrophobic Hybrid Coatings

In this research, we report a simple and inexpensive way to prepare transparent and hydrophobic hybrid coatings through deposition of different silica materials on polyvinyl chloride (PVC) substrates. The silica materials were prepared using an acid-catalyzed sol–gel method at room temperature (25 ± 2 °C), using alkoxysilanes: tetraethoxysilane (TEOS), as the silica source, and ethoxydimethylvinylsilane (DMVES), triethoxyoctylsilane (OTES), and trimethoxyhexadecylsilane (HDTMES), as modifier agents. The obtained materials were characterized (either as powders or as thin films) by Fourier-transform infrared spectroscopy (FTIR), UV/Vis spectroscopy, transmission electron microscopy (TEM), thermogravimetric analysis (TGA), atomic force microscopy (AFM), spectroscopic ellipsometry (SE), and water contact-angle measurements. UV/Vis spectra showed that the PVC substrate coated with the silica material containing TEOS/DMVES/OTES had a transmittance of about 90% in the wavelength range of 650–780 nm. The water contact angles increased from 83° for uncoated PVC substrate to ~94° for PVC substrates coated with the sol–gel silica materials. These PVC films with hybrid silica coatings can be used as the materials for outdoor applications, such as energy-generating solar panel window blinds or PVC clear Windmaster outdoor blinds.

Reconstruction of Lamb Wave Dispersion Curves in Different Objects Using Signals Measured at Two Different Distances.

The possibilities of an effective method of two adjacent signals are investigated for the evaluation of Lamb waves phase velocity dispersion in objects of different types, namely polyvinyl chloride (PVC) film and wind turbine blade (WTB). A new algorithm based on peaks of spectrum magnitude is presented and used for the comparison of the results. To use the presented method, the wavelength-dependent parameter is proposed to determine the optimal distance range, which is necessary in selecting two signals for analysis. It is determined that, in the range of 0.17–0.5 wavelength where is not higher than 5%, it is appropriate to use in the case of an A0 mode in PVC film sample. The smallest error of 1.2%, in the distance greater than 1.5 wavelengths, is obtained in the case of the S0 mode. Using the method of two signals analysis for PVC sample, the phase velocity dispersion curve of the A0 mode is reconstructed using selected distances x1 = 70 mm and x2 = 70.5 mm between two spatial positions of a receiving transducer with a mean relative error , and for S0 mode, x1 = 61 mm and x2 = 79.7 mm with . In the case of the WTB sample, the range of 0.1–0.39 wavelength, where is not higher than 3%, is determined as the optimal distance range between two adjacent signals. The phase velocity dispersion curve of the A0 mode is reconstructed in two frequency ranges: first, using selected distances x1 = 225 mm and x2 = 231 mm with mean relative error ; and second, x1 = 225 mm and x2 = 237 mm with .

Synthesis and Characterization of Epoxidized Silkworm Pupae Oil and Its Application as Polyvinyl Chloride.

More and more industries demand environmental friendliness. Silkworm pupae oil (SPO), extracted from the desilked silkworm pupae, can serve as a promising substrate alternative to use in plasticization. This study aimed to prepare epoxidized silkworm pupae oil (ESPO) and investigate their effects on the thermal stability and plasticization of polyvinyl chloride (PVC) films. A chemo-enzymatic method of ESPO was developed in the presence of Lipase SMG1-F278N and H2O2 in natural deep eutectic solvents (DESs). Lipase SMG1-F278N could initiate the epoxidation reaction effectively at room temperature with a negligible loss of activities 10 batches. A maximum oxirane value of 6.94% was obtained. The formation of oxirane ring in ESPO was confirmed by FTIR and 13C NMR spectra. Moreover, ESPO showed a better thermal stability and lower freezing point than epoxidized soybean oil (ESO). It was demonstrated that ESPO had a good frost resistance. In addition, ESPO showed a significantly improved plasticizing effect on flexible polyvinyl chloride (PVC). Compared with ESO, ESPO could increase the tensile elongation at break effectively. A significantly lower migration rate of plasticizer was observed in PVC plasticized with ESPO.

Surface-Modifying Effect of Zwitterionic Polyurethane Oligomers Complexed with Metal Ions on Blood Compatibility.

To prevent unsolved problems of medical devices, we hypothesized that combinatorial effects of zwitterionic functional group and anti-bacterial metal ions can reduce effectively the thrombosis and bacterial infection of polymeric biomaterials. In this research, we designed a novel series of zwitterionic polyurethane (zPU) additives to impart anti-thrombotic properties to a polyvinyl chloride (PVC) matrix. We have synthesized zPUs by combination of various components and zPUs complexed with metal ions. Zwitterion group was prepared by reaction with 1,3-propane sultone and Nmethyldiethanolamine and metal ions were incorporated into sulfobetaine chains via molecular complexation. These zPU additives were characterized using FT-IR, 1H-NMR, elemental analysis, and thermal analysis. The PVC film blended with zPU additives were prepared by utilizing a solvent casting and hot melting process. Water contact angle demonstrated that the introduction of zwitterion group has improved hydrophilicity of polyurethanes dramatically. Protein adsorption test resulted in improved anti-fouling effects dependent on additive concentration and decreases in their effects by metal complexation. Platelet adhesion test revealed anti-fouling effects by additive blending but not significant as compared to protein resistance results. With further studies, the synthesized zPUs and zPUs complexed with metal ions are expected to be used as good biomaterials in biomedical fields. Based on our results, we can carefully estimate that the enhanced anti-fouling effect contributed to reduced platelet adhesion. Schematic explanation of the effect of zwitterionic polyurethane additives for blood-compatible and anti-bacterial bulk modification.

Simultaneous Measurement of Thickness and Elastic Properties of Thin Plastic Films by Means of Ultrasonic Guided Waves.

Ultrasonic guided waves are already used for material characterization. The advantage of these waves is that they propagate in the plane of a plate and their propagation characteristics are sensitive to properties of the material. The objective of this research was to develop an ultrasonic method that could be used to measure the properties of thin plastic polyvinylchloride films (PVC). The proposed method exploits two fundamental Lamb wave modes, A0 and S0, for measurement of a thin film thickness and Young’s modulus. The Young’s modulus is found from the measured phased velocity of the S0 mode and the film thickness from the velocities of both A0 and S0 modes. By using the proposed semi-contactless measurement algorithm, the Young’s modulus and thickness of different thickness (150 µm and 200 µm) PVC films were measured. The uncertainty of thickness measurements of the thinner 150 µm PVC film is 2% and the thicker 200 µm PVC film is 3.9%.

Postharvest quality of papaya fruit wrapped with polyvinyl chloride film added with silver

ISHS V International Symposium on Postharvest Pathology: From Consumer to Laboratory-Sustainable Approaches to Managing Postharvest Pathogens Postharvest quality of papaya fruit wrapped with polyvinyl chloride film added with silver

Effects of Modified Atmospheric Packaging on Ground Chicken Color and Lipid Oxidation

The objective of the current study was to evaluate the color changes and lipid oxidation of ground chicken patties packaged in polyvinyl chloride (PVC) film, high-oxygen (HiOx)–modified atmospheric packaging (MAP; 80% oxygen + 20% carbon dioxide [CO2]), and carbon monoxide (CO)-MAP (0.4% CO + 19.6% CO2 + 80% nitrogen) and stored at 2°C. Surface color was measured using a HunterLab MiniScan spectrophotometer on days 0, 1, 2, and 4. Lipid oxidation, pH, and aerobic plate count were determined on days 0 and 4 of storage. Fatty acid profiles were determined on day 0 to characterize saturated and unsaturated fatty acids. Patties packaged in PVC had greater (P < 0.05) pH than HiOx-MAP and CO-MAP. Gas chromatography analysis indicated that ground chicken has 72.8% unsaturated fatty acids and 27.2% saturated fatty acids (based on total lipids and fatty acid methyl ester). The formation of carboxymyoglobin on ground chicken patty surface was confirmed by peaks at 420 and 570 nm, whereas oxymyoglobin had peaks at 410 and 580 nm. Instrumental color analysis indicated both HiOx-MAP and CO-MAP had greater (P < 0.05) redness (a* values) than PVC on day 4 of storage. Patties packaged in HiOx-MAP had greater (P < 0.05) chroma values than CO-MAP and PVC on day 4 of storage. Visual panelists noted less (P < 0.05) surface discoloration in CO-MAP than PVC and HiOx-MAP on day 4 of storage. Lipid oxidation was greater (P < 0.05) in PVC and HiOx-MAP than CO-MAP. CO inclusion at 0.4% level effectively inhibited lipid oxidation and stabilized surface redness during refrigerated storage of ground chicken.

Abiotic soil properties affecting interpretation of IRIS sensors in tidal and freshwater soils

AbstractIndicator of Reduction in Soils (IRIS) films are visual sensors used to document weakly or moderately reducing conditions in soils based on the reduction and removal of brown manganese (Mn) oxide or orange iron (Fe) oxide paints, respectively, from underlying white polyvinyl chloride (PVC) films. Paint removal is largely assumed to result from anaerobic microbial reduction using metal oxides on the PVC films as electron acceptors. If true, IRIS films could indicate conditions favorable to other biogeochemical processes that occur at similar redox potentials to those facilitating paint removal. Our objective here was to assess the effects of selected abiotic soil properties on IRIS film paint removal to determine whether removal can accurately be attributed to biotic processes alone. Through field deployments and laboratory incubation experiments using IRIS films, we investigated relative sulfide concentration and dissolved organic matter as two abiotic factors potentially capable of removing paint from Mn IRIS films. Our results showed that abundance of reactive soluble sulfides cause rapid and extensive abiotic paint removal from Mn films, whereas ambient concentrations of dissolved organic matter in freshwater wetland porewater does not drive abiotic removal. Furthermore, we found that the visible formation of black iron monosulfides on Fe films can be used to detect sulfide concentrations that will remove paint from Mn films. This study suggests that whereas some abiotic soil properties (e.g., sulfide concentration) can cause paint removal, IRIS films may be a viable tool to approximate biotic process rates where abiotic paint removal can be ruled out.

Synthesis of biomass‐based plasticizer with excellent durability for high transparent polyvinyl chloride film

AbstractThe objective of this study is to synthesis biomass‐based plasticizer epoxy p‐phenylenedioleic acid ester (EPAE) using linoleic acid as raw materials via esterification and epoxidation. EPAE was used as main plasticizer of polyvinyl chloride (PVC) to replace diisobutyl phthalate (DIBP). The plasticizing effect of EPEA on the performance of PVC films was investigated. The results showed that epoxy groups were covalently bonded on branched chains of EPAE. EPAE play a plasticizing role by forming hydrogen bond between epoxy group and a‐hydrogen on PVC. When the mass of EPAE was 0.8 g in 2 g PVC, Tg of flexible PVC reached 36.1°C, the elongation at break of flexible PVC was 321.12 ± 6.13%, while the tensile strength reached 19.45 ± 1.35%. The transmittance of DIBP‐0.8 and EPAE‐0.8 at 800 nm is nearly 70%, indicating relatively high homogeneous amorphous aggregation structures. EPAE showed marginal resistance to volatilization and solvent extraction. The mechanism behind the results was discussed.

A study on shelf life of prepackaged retail-ready Korean native black pork belly and shoulder butt slices during refrigerated display.

ObjectiveIn most retail centers, primal pork cuts for sale are usually prepared into retail-ready slices and overwrapped with air-permeable plastic film. Also, meat of Korean native black pig (KNP) is reputed for its superior quality, however, its shelf life during retail display has not been studied. Thus, the objective of this study was to evaluate shelf life of prepackaged retail-ready KNP belly and shoulder butt slices during refrigerated display.MethodsBellies and shoulder butt obtained at 24 h post-mortem from finishing KNP were used. Each belly or shoulder butt was manually cut into 1.5 cm-thick slices. The slices in each cut type were randomly taken and placed on white foam tray (2 slices/tray) overwrapped with polyvinyl chloride film. The retail-ready packages were then placed in a retail display cabinet at 4°C. Shelf life and sensory quality of the samples were evaluated on day 1, 3, 6, 9, 12, and 15 of display.ResultsThe shoulder butt reached the upper limit (20 mg/100 g) of volatile basic nitrogen for fresh meat after 9 days while, the belly remained within this limit throughout the display time (15 days). Both the cuts reached a thiobarbituric acid reactive substances level of above 0.5 mg malondialdehyde/kg after 9 days. The a* (redness) values remained unchanged during first 9 days in both cuts (p>0.05). After 9 days, off-flavor was not found in either cut, but higher off-flavor intensity was found in shoulder butt after 12 days. The shoulder butt was unacceptable for overall eating quality after 12 days while, belly still was acceptable after 12 days.ConclusionThe belly showed a longer shelf life compared to the shoulder butt, and a shelf life of 9 and 12 days is recommended for the prepackaged retail-ready KNP shoulder butt and belly slices, respectively.

Performance assessment of polyvinyl chloride films plasticized with Citrullus lanatus seed oil based novel plasticizer

Biobased plasticizers for polymers is a necessity to replace conventional phthalates based plasticizers. In the present study, Citrullus lanatusseed oil (ECLO) was epoxidized in a magnetically stirred reactor. Polyvinyl chloride (PVC) films were synthesized using different concentrations of ECLO. At 40% of ECLO, films showed better surface morphology and exhibited maximum strength and elongation at break. Plasticized PVC film shown tensile strength of 18.6 MPa and elongation at break of 136.18%. No migration was observed in water, designating hydrophobic characteristics of the films. In gasoline, acid (Acetic acid) and alkali (Sodium hydroxide), plasticized samples exhibited a low resistance for migration. X-ray diffraction analysis confirmed no change in crystallinity of PVC after addition of ECLO. Thermogravimetric analysis presented the plasticized PVC films are thermally stable. Differential scanning calorimetry established the plasticizing effect of ECLO as a glass transition temperature (Tg) of plasticized films was shifted to a lower temperature.Furthermore, Fourier transform infrared spectroscopy revealed interaction of ECLO with PVC as peaks of C–Cl bond (833 cm−1) and CO stretch (1739 cm−1) were detected. Thus, the present study delivered a better substitute for phthalates as it endorses the application of ECLO in the PVC blend as a plasticizer.

Anti-thrombotic polymer surfaces modified with zwitterionic and fluorinated surface-migrating oligomers

For the development of anti-thrombotic biomaterials, blending a surface migrating oligomer (SMO) in a biomedical polymer has been focused as a promising alternative way to conventional coatings. In this study, novel SMOs with the polyurethane backbone containing zwitterion and fluorine were synthesized and blended it with polyvinyl chloride (PVC) to confer synergistic anti-thrombotic performance through anti-fouling effect. Studies using elemental analysis, FT IR, 1H NMR and ion chromatography demonstrated the successful incorporation of sulfobetaine and fluorine in the SMOs. The thermal analysis characterized PVC/SMO-blended films with varied glass transition temperatures. X-ray photoelectron spectroscopy represented high compositions of sulfur and fluorine atoms at the surface of SMOs-blended PVCs, proving that SMOs effectively migrated toward the surface during the film preparation. The SMOs-blended PVC films not only improved resistivity to the adsorption of albumin and fibrinogen but also inhibited the adhesion and activation of human platelets, meaning enhanced anti-fouling effect and thereby anti-thrombogenicity. In particular, the SMOs-blended PVCs with both sulfobetaine and fluorine were synergistically effective in the reduction in cell/platelet adhesion and protein adsorption. In summary, our results give a positive cue that the novel type of SMOs containing both sulfobetaine and fluorinated segments can be a promising material for anti-thrombogenic surface modification in cardiovascular applications.

Effect of benzene ring and alkane chain contained bio-based plasticizers on the plasticizing performance of polyvinyl chloride films

Effect of benzene ring and alkane chain contained bio-based plasticizers on the plasticizing performance of polyvinyl chloride films

Preparation of highly reflective silver metallized PVC film by autocatalytic deposition

AbstractMetallized polymer films, used in many optical applications because of their high reflectivity, are usually prepared under complex conditions. In this work, a two‐step autocatalytic deposition method was adopted to prepare an Ag‐deposited polyvinyl chloride (PVC) film (Ag/PVC composite film) with high reflectivity. When Ag particles were used as a coating, the formed face‐centered cubic crystal endowed a higher reflectivity than other crystals. Therefore, Pd metal was introduced as the catalytic center for Ag deposition to promote the formation of face‐centered cubic crystals, thereby obtaining a highly reflective PVC film. Moreover, we improved the reflectivity of the Ag/PVC composite film by adjusting different process parameters, and the maximum reflectivity of the Ag/PVC composite film could reach as high as 93%. The two‐step autocatalytic deposition we used was a simple, efficient, and low‐energy method to prepare highly reflective films. The optimum process parameter was also significant for further research on highly reflective films.

In vitro biocompatibility study of microwave absorbing conducting polymer blend films for biomedical applications

Abstract In the present communication, microwave absorbing property in the frequency range of 12.4–18 GHz and in vitro biocompatibility studies of light weight, flexible, biocompatible, and environment friendly polymer blend films of polyvinylchloride (PVC)-polyvinylpyrrolidone (PVP) (taken in ratio 1:1) and doped with various percentage weight concentration of polypyrrole (PPy) are reported. Addition of PPy in the PVC-PVP matrix exhibited a synergetic effect in improving microwave absorbing property. PVC-PVP blend film with 40 and 50% concentrations of PPy were seen to absorb microwaves of the order of 28–50 dB in ku band of microwave region indicating that this composition can suitably find application as microwave absorbing material. In vitro biocompatibility skin irritation study of PVC-PVP (taken in ratio 1:1) with 50% weight concentration of PPy indicated that the prepared film did not have any irritation upon administration and hence is safe for topical application. Moreover, the blood compatibility study of this film exhibited compatibility with blood and can safely be used in any blood contacting mask/device. Hence, this biocompatible film can potentially be used as microwave absorbing material for masking some parts of human body or can be interfaced to biological systems or devices.

Bioremediation of polyvinyl chloride (PVC) films by marine bacteria

Polyvinyl chloride (PVC) is the third one after polyethylene and polypropylene in the production demand. It intends to grow further, causing an increase in the risk of health and ecological problems due to environmental accumulation and incineration. In the present study, we determined the biodegradative abilities of marine bacteria for PVC. Three potential marine bacterial isolates, T-1.3, BP-4.3 and S-237 (Vibrio, Altermonas and Cobetia, respectively) were identified after preliminary screening. They led to active biofilm formation, viability and protein formation on the PVC surface. The highest weight loss (1.76%) of PVC films was exhibited by BP-4.3 isolate after 60 days of incubation. Remineralization of PVC film was confirmed by CO2 assimilation assay. Change in surface topography was confirmed by field emission scanning electron microscopy (FE-SEM) and atomic force microscopy (AFM). The functional group peak intensity was decreased for the terminal chlorine group at the region 1000–1300 cm−1, which indicated the dechlorination. Thermogravimetric, tensile strength and contact angle analysis showed a decline in the mechanical properties and a rise in PVC film's hydrophilic nature after biodegradation. These results demonstrated promising evidence of PVC degradation by marine bacteria.

Effects of active and passive modified atmosphere packaging on biochemical properties of cut Dendrobium orchid flowers

Optimal storage conditions are essential to preserving the quality of postharvest produce and cut flowers during transportation, especially to overseas destinations. As a result, this research investigated the effects of active and passive modified atmosphere packaging (MAP) on the biochemical properties of cut Dendrobium Sonia orchid flowers. In active MAP, the orchid flowers were wrapped in MAP plastic film filled with 5 % carbon dioxide (CO2) and 2 % oxygen (O2). Meanwhile, in passive MAP the flowers were stored inside MAP plastic film without filling with 5 % CO2 and 2 % O2. The experimental MAP plastic films were polyethylene, low density polyethylene, high density polyethylene, polypropylene, and polyvinyl chloride films. The biochemical parameters included storage life, respiration rate, ethylene production, internal O2 and CO2, anthocyanin content, protein degradation, and electrolyte leakage. The results showed that the average storage life of orchid flowers under passive MAP condition was 9–15 days, depending on the plastic film types. The longest storage life of 15.66 days was achieved with polypropylene film. The storage life of orchid flowers in active MAP was 9.33 days on average. Without MAP (control), the storage life was 7 days under normal atmosphere condition (0.03 % CO2 and 21 % O2). The experiments also demonstrated that MAP efficiently reduced respiration rate, ethylene production, anthocyanin degradation, protein degradation, and electrolyte leakage. Unlike existing research on MAP which focused primarily on extending the shelf life of fresh produce or cut flowers, this study comparatively investigated the biochemical properties of cut orchid flowers stored in MAP environment, in addition to the storage life.

Recording, Storage, and Reproduction of Information on Polyvinyl Chloride Films Using Shape Memory Effects.

Partial dissolution and plasticization are used for recording, storing, and reproducing information with modified industrial screen-printing equipment and aqueous solutions of colorless organic liquids on small surface area shape memory polymer films. To justify the choice of “ink” and evaluate the effectiveness of using organic liquids as high-speed polymer solvents, the new method for recording hidden information uses the calculation of the solubility parameter, differential scanning calorimetry, and the method of one-sided swelling of films under isometric conditions. Using the example of tactile marking of shrink labels made of polyvinyl chloride, the optimal conditions for recording hidden information on a film are established in terms of the concentration of an aqueous solution of tetrahydrofuran, the contact time, and the processing temperature of the polymer using screen printing equipment.