Polyvinyl Acetate Adhesives Research Articles

Utilization of Siwalan (Borassus flabellifer L.) Plantation Waste for Kraft Paper Production

Borassus flabellifer L., one of the palm-based commodities in Indonesia which is grows in dry areas especially around the north coast of Java Island. An abundant waste of this plant is a leaf midrib and fruit fiber have an opportunity as a source of lignocellulose for the paper industry. In this study, Kraft paper production was conducted to know the influence of the proportion of Borassus flabellifer L. leaf midrib pulp and fruit fiber pulp, and the concentration of Polyvinyl Acetate (PVAc) adhesives on the sensory and physical quality of kraft paper. The research method used was Randomized Block Design (RBD) with two factors. The Friedman test was used to determine the sensory quality of kraft paper. The physical quality of kraft paper was used ANOVA analysis. The results showed that the treatment of raw material proportion and PVAc adhesive concentration had significant effect on color, surface texture, yield, and tensile resistance, but not significantly different between treatment of gramature and tear resistance. The best treatment of sensory tests was kraft paper with proportion of leaf midrib pulp 50% and fruit fiber pulp 50% and a 7.5% PVAc adhesive concentration. It has a yield value of 72.11%, gramature of 162.80 g/m2, tensile strength of 1.70 %, and tear resistance of 197.6 gf.

The Effect of Fiberboard Modification on Adhesion Strength to Polyvinyl Chloride (PVC) Sheets or Eastern Beech (Fagus orientalis L.) Veneers

The adhesion strength was evaluated for polyvinyl chloride (PVC) and Eastern beech (Fagus orientalis L.) veneers glued onto specially produced fiberboards using urea-formaldehyde (UF), polyvinyl acetate (PVAc), and polyurethane (PU) adhesives. Inorganic fillers including rock salt (NaCl), calcite (CaCO3), borax pentahydrate (Na2B44O7•5H2O), or talc (3MgO•4SiO2•H2O) were incorporated into the fiberboards at levels of 3%, 6%, and 9%. The adhesion strength of the samples was determined in accordance to Turkish Standard TS EN 311 (2005). Scanning electron microscopy (SEM) was employed to determine the structural morphology at the bonding interface of the veneers and the modified fiberboards. The results of this study indicated that veneer adhesion strength was reduced by the addition of inorganic fillers to the fiberboard. The highest adhesion strength was obtained with Eastern beech veneer that was glued using UF adhesive on the control samples without inorganic fillers. It was concluded that UF and PVAc adhesives are not suitable for bonding PVC veneers onto fiberboard surfaces.

Synergistic Effects of Impregnation Agents Used in Plywood Production Relative to the Shear Strength of Bonded Joints

The main objective of this research was to analyse the synergistic effects of impregnation agents that are most commonly used in plywood production on the strength of bonded joints. Two water-based impregnations (Teknol aqua 1410-01 and Cetol WV 885 BPD+) and one solvent-based impregnation (Gori 605) were used in this study. The tested adhesives were polyvinyl acetate (PVAC) ADHESIVE 3384 (1-component PVAC adhesive), EPI (emulsion polymer isocyanate) system 1920/1993, and polyurethane (PUR) 1968 (1-component PUR adhesive). Test specimens were made from European beech timber (Fagus sylvatica L.) for plywood production according to EN 205 (2017). Individual tests were conducted according to EN 204 (2001) for PVAC adhesives, and according to EN 12765 (2001) for PUR adhesives. Although the effect of impregnation on bond strength was demonstrated, it was different depending on the type of adhesive. A clear positive synergistic effect on the bond strength was shown for isocyanate-based adhesives in almost all of the tests. The synergistic effect of PVAC adhesive was very variable in each individual test and showed a negative influence of higher moisture content and dipropylene glycol content in solvent-based impregnation.

Properties and thermal analysis study of modified polyvinyl acetate (PVA) adhesive

Polyvinyl acetate (PVA) adhesive is one of the most common types of adhesives has been used in the wood industry for decades. However, many drawbacks are still associated with this adhesive including low water resistance, poor bond strength, and low viscosity. In this reported study, two additives, sulfanilamide and N,N-dimethylethylenediamine, were used to modify a PVA adhesive to improve its comprehensive practical performance. The prepared adhesive samples were characterized by Fourier transform infrared spectroscopy (FT-IR). Furthermore, the thermal decomposition characteristics of the PVA adhesives were studied using Thermal Gravimetric Analysis (TGA) and Differential Scanning Calorimetry analysis (DSC) combined with the Kissinger method. The experimental results showed that when compared to the pure PVA adhesive, the solid content, viscosity, dry bond strength, and wet bond strength of the modified PVA adhesive (PVA + N,N-dimethylethylenediamine + sulfanilamide) were improved by 34.8, 41.4, 47.0 and 35.2%, respectively. FT-IR analysis indicate that these two additives altered the chemical bond ratio that resulted from the generation of new chemical bonds, which explained the improved performance of the modified PVA adhesive. The pure PVA adhesive possessed two thermal decomposition steps, while the modified PVA adhesive (PVA + N,N-dimethylethylenediamine + sulfanilamide) exhibited only one thermal decomposition step. The thermal decomposition process of the pure PVA adhesive is characterized by a quick thermal decomposition stage and a slow thermal decomposition stage. Since the ΔH > 0, ΔS < 0 and ΔG > 0 in the thermal decomposition process it can be concluded that the decomposition reactions of the PVA adhesive were non-spontaneously endothermic and the entropy decreased during the reaction.

Technological Feasibility of Hovenia dulcis thunb. Species for the Production of Edge Glued Panels

ABSTRACT This study aims to evaluate the use of Hovenia dulcis wood to produce Edge Glued Panels – EGP. To this end, joints with dimensions of 5.0 × 31.0 × 2.5 cm (Width × Length × Thickness) were put together using polyvinyl acetate (PVAc) and emulsion polymer isocyanate (EPI) adhesives at a spread rate of 200 g.m-2 and the chemical characterization of the wood was performed. The strength of glued joints was evaluated through shear tests based on the procedures described by established standards. The results showed that the EPI adhesive achieved the best results in edge gluing to produce EGP. The use of PVAc adhesive did not show satisfactory results for edge gluing under these conditions. Hovenia dulcis wood is indicated for producing higher value-added wood products - (VAWP) for external use purposes.

Ability of finger-jointed lumber to maintain load at elevated temperatures

This article presents a test method that was developed to screen adhesive formulations for finger-jointed lumber. The goal was to develop a small-scale test that could be used to predict whether an adhesive would pass a full-scale ASTM E119 wall assembly test. The method involved loading a 38-mm square finger-jointed sample in a four-point bending test inside of an oven with a target sample temperature of 204°C. The deformation (creep) was examined as a function of time. It was found that samples fingerjointed with melamine formaldehyde and phenol resorcinol formaldehyde adhesives had the same creep behavior as solid wood. One-component polyurethane and polyvinyl acetate adhesives could not maintain the load at the target temperature measured middepth of the sample, and several different types of creep behavior were observed before failure. This method showed that the creep performance of the one-component adhesives may be quite different than the performance from short-term load deformation curves collected at high temperatures. The importance of creep performance of adhesives in the fire resistance of engineered wood is discussed.

Utilization of Siwalan (Borassus flabellifer L) Plantation Waste for Kraft Paper Production

Borassus flabellifer L., one of the palm-based commodities in Indonesia which is grows in dry areas especially around the north coast of Java Island. An abundant waste of this plant is a leaf midrib and fruit fiber have an opportunity as a source of lignocellulose for the paper industry. In this study, Kraft paper production was conducted to know the influence of the proportion of Borassus flabellifer L. leaf midrib pulp and fruit fiber pulp, and the concentration of Polyvinyl Acetate (PVAc) adhesives on the sensory and physical quality of kraft paper. The research method used was Randomized Block Design (RBD) with two factors. The Friedman test was used to determine the sensory quality of kraft paper. The physical quality of kraft paper was used ANOVA analysis. The results showed that the treatment of raw material proportion and PVAc adhesive concentration had significant effect on color, surface texture, yield, and tensile resistance, but not significantly different between treatment of gramature and tear resistance. The best treatment of sensory tests was kraft paper with proportion of leaf midrib pulp 50% and fruit fiber pulp 50% and a 7.5% PVAc adhesive concentration. It has a yield value of 72.11%, gramature of 162.80 g/m2, tensile strength of 1.70 %, and tear resistance of 197.6 gf.

Determination of the Effect of Surface Roughness on the Bonding Strength of Wooden Materials

The purpose of this study was to determine the effect of surface roughness on bonding strength in Oriental beech, cherry, Scots pine, and Taurus cedar woods. In conformance with this objective, after planing the wooden materials under different conditions, their surface roughness values were determined in accordance with various standards using scanning equipment. The bonding strength test specimens were prepared using polyvinyl acetate (PVAc) and polyurethane (PUR) adhesives after the wooden materials were separated into three groups of varying surface roughness values, after which bonding strength experiments were carried out. The data obtained from the experiments were evaluated statistically at a 95% level of confidence. According to the test results, the highest bonding strength was obtained in the Oriental beech (9.27 N/mm2), whereas the lowest bonding strength was obtained in the Scots pine (3.65 N/mm2). There was not a statistically significant difference between the bonding strength of the cherry and Oriental beech woods. The PVAc adhesive (7.61 N/mm2) produced more successful results than the PUR adhesive (5.63 N/mm2). Furthermore, it was found that in the specimens with low surface roughness values for each wood type and used adhesives had high bonding strengths.

Bondability of Black locust (Robinia pseudoacacia) and Beech wood (Fagus sylvatica) with polyvinyl acetate and polyurethane adhesives

In the previous years, black locust wood (Robinia pseudoacacia) has been participating in the European subsidizing programme of tree species cultivation, aiming in the establishing of new plantations in many European countries, therefore large quantities of this species is going to be harvested in the forthcoming years and the examination of its properties would be very crucial for future utilization. In the present research, the bondability of black locust wood is examined using two different adhesives, Polyvinyl acetate and Polyurethane and two different pressure levels. Beech wood is also included in the research for comparative reasons. According to the results, the shear bond strength of black locust wood was found to be satisfying, especially in the presence of Polyvinyl acetate adhesive and the less intensive pressure used during the specimens’ construction, although it was found lower compared to beech wood, referring both to Polyvinyl acetate and Polyurethane adhesive.

Effect on Shear Strength of Machining Methods in Pinus nigra Arnold Bonded with Polyurethane and Polyvinyl Acetate Adhesives

Specimens taken from Pinus nigra Arnold were subject to surfacing techniques by being cut with a circular saw, planed with a thickness machine, and sanded with a calibrating sanding machine (with P80 grit sandpaper). First, their surface roughness values were measured; then, the specimens were processed in the machines in a radial and tangential process. Afterwards, the change in shear strength (adhesiveness resistance) was analyzed as a result of bonding with various adhesive types (PVAc, PU) and pressure applications (0.45 N/mm² or 0.9 N/mm²). Approximately 600 specimens were prepared with the purpose of identifying the effect of variables on the bonding performance, and they were subjected to shear testing. The greatest shear strength achieved for both the tangential and radial surfaces in terms of cutting was observed in specimens processed in the thickness machine, on which polyvinyl acetate adhesive and 0.9 N/mm². pressure were applied. Specimens bonded with polyvinyl acetate adhesive displayed higher shear strength in general in comparison to those bonded with polyurethane for both tangential and radial surfaces.

Effects of adding nano-clay (montmorillonite) on performance of polyvinyl acetate (PVAc) and urea-formaldehyde (UF) adhesives in Carapa guianensis, a tropical species

The aim of this study was to improve the bond strength resistance of polyvinyl acetate (PVAc) and urea-formaldehyde (UF) adhesives modified with nano-clay (montmorillonite) with a tropical species of wood known to exhibit adhesion related problems. These adhesives were evaluated with 1.0 and 1.5wt% nano-clay concentrations with lap shear strength (SS), and the percentage of wood failure (PWF) in dry and wet conditions being evaluated. An additional aim of this study was to observe the presence of nano-clay within both adhesive types using Atomic Force Microscopy (AFM) and the Transmission Electron Microscopy (TEM). Color, viscosity and the thermostability of these adhesives with nano-clay were also evaluated. First, AFM and TEM studies showed adequate dispersion and impregnation of nano-clay. The viscosity of PVAc adhesive was not affected by the incorporation of nano-clay, whereas the UF adhesive was. With both PVAc and UF adhesives, the presence of nano-clay increased the L⁎ and b⁎ color parameters, especially when 1.5wt% nano-clay was used. The incorporation of the nano-clay improved thermostability, as determined by thermogravimetric analysis (TGA). Finally, it was shown that the nano-clay incorporation improved SS and PWF. The highest values of SS were obtained when nano-clay was added at 1.5wt% concentration in the PVAc adhesive under dry conditions. SS was not affected by nano-clay addition in the UF adhesive under dry conditions. However, under wet conditions, both 1.0 and 1.5wt% loadings of nano-clay increased SS with both adhesive types. The addition of nano-clay in both proportions increased PWF by approximately 15% and between 20–30% in dry and wet conditions, respectively, for the PVAc adhesive. For the UF adhesive, PWF increased by approximately 10% under dry conditions and 25–50% in wet conditions.

Effect of Surface Roughness on the Shear and Tensile Strength of Hardwood Adhesive Joints: A Linear Elastic Model

This study analyzed the bond line strength of Eucalyptus sp. specimens submitted to shear and perpendicular to grain tensile forces, depending on the wood quality machined surface. The woods plans were glued with two different polyvinyl acetate adhesives. The bonding surfaces were milling with three different feed speeds; 6.0, 11.0 and 15.0 m/min, corresponding to the feed per tooth of the cutting tool; 0.86, 1.57 and 2.14 mm, respectively. The specimen types corresponded to the standards according to ABNT NBR 7190/1997. The cutting plane considered only the geometry of milling due to the bond line joint strength. To explain the experimental results, was proposed a linear elastic model to machined wood and bond line. For the two adhesives used, the experimental results suggest that the greatest perpendicular to grain tensile strength and shear strength were obtained to bond surface machined with the intermediate feed speed namely 11 m/min, for others two feed speeds and in the shear strength case, was not observed a distinction between them, in the perpendicular to grain tensile strength, the feed speed 6.0 m/min presented a higher strength than the machined surface with 15.0 m/min. The model reproduces the behavior of the experimentally results obtained for the two tests, and so it can be readily applied as a tool for evaluate the machining feed speed and the bond line joint strength.

Impact of cold temperatures on the shear strength of Norway spruce joints glued with different adhesives

As wood construction increasingly uses engineered wood products worldwide, concerns arise about the integrity of the wood and adhesives used. Bondline strength is a crucial issue for engineered wood applications, especially in cold climates. In this study, Norway spruce (Picea abies) joints (150 mm × 20 mm × 10 mm) were bonded with seven commercially available adhesives: polyurethane (PUR), polyvinyl acetate (PVAc), emulsion-polymer-isocyanate (EPI), melamine-formaldehyde (MF), phenol-resorcinol-formaldehyde (PRF), melamine-urea-formaldehyde1 (MUF1), and melamine-urea-formaldehyde2 (MUF2). Each adhesive was tested at six temperatures: 20, −20, −30, −40, −50 and −60 °C. Generally, within the temperature test range, temperature changes significantly affected the shear strength of solid wood and wood joints. As the temperature decreased, the shear strength decreased. PUR adhesive in most cases resulted in the strongest shear strength and MUF adhesive resulted in the weakest. MF and PRF adhesives responded to temperature changes in a similar manner to that of the PUR adhesive. The shear strengths of wood joints with PVAc and EPI adhesives were more sensitive to temperature change. At low temperatures, the variability of shear strengths increased with all adhesives. Percent wood failures of joints bonded with different adhesives in most cases were not sensitive to temperature changes.

Compression and flexural properties of finger jointed mango wood sections

In this paper, an attempt was made to assess the effectiveness of finger jointing in utilising mango wood sections for various end uses like furniture. The study was based on the estimation of Modulus of elasticity and Modulus of rupture under static bending and Maximum Crushing Stress and Modulus of elasticity under compression parallel to grain of finger jointed sections and comparing them with the values measured for clear wood sections from the same lot. For joining the sections, the Poly Vinyl Acetate and Urea Formaldehyde adhesives were used. It was found that the Modulus of elasticity of the sections joined by either adhesive showed significantly better values than that of unjointed clear wood sections. The Modulus of rupture values of sections joined with Urea Formaldehyde were similar to those of unjointed clear wood sections. However, sections jointed with Poly Vinyl Acetate adhesive exhibited lower Modulus of rupture. Under compression, the parameters of the jointed sections joined with either adhesive were either similar or better than those of the unjointed clear wood sections. The study demonstrates the utility of finger jointing of mango wood sections for furniture parts especially with the Urea Formaldehyde adhesive.

Influence of Moisture Content on the Bond Strength and Water Resistance of Bonded Wood Joints

Bonding processes play a significant role in the wood and furniture industry. They allow for the creation of fixed joining of construction elements, creation of new materials and, last but not least, aesthetic appreciation of parts. However, the quality of bonded joints is affected by many factors, one of which is the moisture of the bonded material – wood. The main objective of this research was to determine the influence of wood moisture on the strength of bonded joints formed by polyvinyl acetate (PVAc) and polyurethane (PUR) adhesives. In current practice these adhesives are being increasingly used for their properties and zero formaldehyde content. The procedure for determining the bond strength (tensile shear strength of lap joints) corresponded to standard EN 205. It was ascertained that in addition to actual moisture of bonded wood, the quality of the joint is also affected by the environment to which the glued joint is subsequently subjected. In a normal environment, the strength of the tested joint PVAc adhesive decreases with increasing wood moisture, but it still meets the requirement of the standard. In a humid environment, the strength falls below the limit of the standardized value. In a normal environment the joint strength bonded with PUR adhesive is similar, but the decrease in strength is lower. In a humid environment it shows the highest strength at 20% wood moisture and meets the specified standard minimum strength (4 MPa). Graphs were created from the measured values that clearly show the influence of wood moisture on the final bond strength of a joint.

Modulus of elasticity in scarf-jointed wooden beams: a case study with polyvinyl acetate and isocyanate adhesives

In the present study, elastic properties of scarf-jointed oak (Quercus castaneifolia) timbers with the application of two different types of adhesives (polyvinyl acetate and isocyanate) were evaluated using free flexural vibration of free–free beam method in different flexural directions of vibration, i.e., tangential and redial directions. Samples were taken from trees of Hyrcanian forests in Iran with nominal dimensions of 20 × 20 × 360 mm3. Comparing the results of elastic properties of clear oak wood beams with scarf-jointed samples wood showed that scarf joints with the bonding angles of 70° and 75°, covered by polyvinyl acetate adhesive, did not demonstrate any significant effect on modules of elasticity. Scarf-jointed beams with smaller joint angles (60° and 65°) were considerably weaker or totally unreliable in their moduli of elasticity. It is also shown that the magnitude of effect gets worst by using isocyanate rather than polyvinyl acetate adhesive.

Strength performance of mortise and loose-tenon furniture joints under uniaxial bending moment

We determined the effects of adhesive type and loose tenon dimensions (length and thickness) on bending strength of T-shaped mortise and loose-tenon joints. Polyvinyl acetate (PVAc) and two-component polyurethane (PU) adhesives were used to construct joint specimens. The bending moment capacity of joints increased significantly with increased length and thickness of the loose tenon. Bending moment capacity of joints constructed with PU adhesive was approximately 13% higher than for joints constructed with PVAc adhesive. We developed a predictive equation as a function of adhesive type and loose tenon dimensions to estimate the strength of the joints constructed of oriental beech (Fagus orientalis L.) under uniaxial bending load.

Elastic Properties of Oak Wood Finger Joints with Polyvinyl Acetate and Isocyanate Adhesives

In this study, the elastic properties of 23 specimens of oak timber (Quercus castaneifolia), including the longitudinal modulus of elasticity (MOE), acoustic coefficient (K), and acoustic converting efficiency (ACE) in free vibration using the free-free beam method with different planes of vibration, i.e. tangential (LT) and radial (LR), were studied. These elastic parameters were examined in both sound wood and finger jointed timbers with two different lengths of fingers (5- and 10-mm finger lengths) and individually glued with two different types of adhesives (isocyanate and polyvinyl acetate). Comparing the elastic properties of solid beams with finger jointed beams of oak wood in both (LT) and (LR) planes, 10-mm finger joints with polyvinyl acetate adhesive did not cause any serious change to the studied elastic properties of the beams, while shorter finger length (5 mm) with isocyanate adhesive severely changed the acoustic properties; therefore, beams having longer finger lengths may have enhanced acoustical properties.

A feasibility study of using two-component polyurethane adhesive in constructing wooden structures

This investigation was conducted to determine the feasibility of using a two-component polyurethane (PUR) adhesive, with special waterproof properties, in constructing wooden structures. We designed and conducted tests to compare the shear strength and adhesion performance of PUR with polyvinyl acetate (PVAc) adhesive on block-shear specimens constructed of oriental beech (Fagus orientalis L.), fir (Abies alba Mill.), poplar (Populus deltoides Bartr.), white oak (Quercus alba L.), sycamore (Platanus orientalis L.) and white walnut (Juglans cinerea L.). The values of the percentage of wood failure were also determined in specimens constructed with each adhesive. The highest shear strength values of both adhesives were obtained in specimens constructed of beech, while the lowest shear strength values were obtained in fir and poplar specimens. Average shear strength of the PUR adhesive was 16.5% higher than that of the PVAc adhesive. Specimens constructed of fir, poplar and sycamore were characterised by the highest percentages of wood failure, whereas the lowest average percentages of wood failure were obtained in beech and oak specimens. With the exception of oak specimens, there was no statistically significant difference between percentage of wood failure among the PUR and PVAc adhesives. Generally, the PUR adhesive showed an acceptable adhesion performance on wood materials used in our study.

Utilization of extract of fresh tree leaves as extender in synthetic adhesives for laminated veneer lumber (LVL)

This study investigated potential utilization of the extraction yield of ash and cedrus tree leaves as extender in urea–formaldehyde (UF) and polyvinylacetate (PVAc) adhesives. The extraction solutions of ash and cedrus leaves (10% by weight) were added into the liquid UF and PVAc adhesives. 9-layer laminated veneer lumber (LVL) boards were produced using the UF and PVAc adhesives modified with the extraction solution. For comparison of the extraction solution, water (10wt%) was added in the adhesives. The LVLs bonded with extraction solution/UF adhesive were hot pressed for 10min at 105°C while the ones bonded with the extraction solution/PVAc adhesive were hot pressed for 2h at 20°C. As compared to the addition of water, the bending strength and splitting strength in transverse direction of the LVLs increased by 8.2% and 13.9%, respectively, as the extraction solution of ash leaves were incorporated into the UF adhesive. The extract of ash leaves had better adhesion performance in the UF and PVAc adhesives than that of cedrus leaves. The extract of the leaves was more compatible with the UF adhesive than the PVAc adhesive. Based on the findings of the study, it was concluded that the extracts of ash and cedrus leaves could be efficiently used as extender in the UF adhesive.