Polymerization Of Phenyl Isocyanide Research Articles

Facile Synthesis of Hybrid Silica Nanoparticles Grafted with Helical Poly(phenyl isocyanide)s and Their Enantioselective Crystallization Ability

In this contribution, we report on the facile synthesis of hybrid silica nanoparticles grafted with helical poly(phenyl isocyanide)s via both “grafting from” and “grafting to” strategies. First, triethoxysilanyl functionalized alkyne–Pd(II) initiator was anchored onto the surface of bare silica nanoparticles through silanization coupling reaction. Polymerization of phenyl isocyanide using the Pd(II)–anchored silica nanoparticles lead to the formation of hybrid nanoparticles grafted with helical poly(phenyl isocyanide)s. The surface-initiated polymerization was revealed to proceed in a living/controlled chain-growth manner, afforded the hybrid nanoparticles with controlled thickness. 31P NMR analysis indicated the initiation efficiency of the surface-anchored Pd(II) initiators is very high, and almost quantitative. The grafting density was determined to be ∼0.89 nm2/chain based on the thermal gravity analysis (TGA). Polymerization of optically active phenyl isocyanide bearing an l-alanine with a long decyl...

One-Pot Synthesis of Brush Copolymers Bearing Stereoregular Helical Polyisocyanides as Side Chains through Tandem Catalysis

An air-stable phenylethynyl Pd(II) complex containing a polymerizable norbornene unit was designed and synthesized. Such a Pd(II) complex can initiate the living/controlled polymerization of phenyl isocyanide, giving stereoregular poly(phenyl isocyanide)s in high yields with controlled molecular weights and narrow molecular weight distributions. The norbornene unit on the Pd(II) complex can undergo ring-opening metathesis polymerization (ROMP) with Grubbs’ second-generation catalyst, affording polynorbornene bearing Pd(II) complex pendants under a living/controlled manner. Interestingly, the Pd(II) complex pendants on the isolated polynorbornene are active enough to initiate the living/controlled polymerization of phenyl isocyanides, yielding well-defined brush-like copolymers with polynorbornene backbone and helical poly(phenyl isocyanide) as side chains. 31P NMR analyses indicate almost all the Pd(II) units on the polynorbornene participated in the polymerization, and the grafting density of the brush copolymer is high. Further studies revealed the brush copolymer can be readily achieved in one-pot via tandem catalysis. By using this method, a range of brush copolymers with different structures and tunable compositions were facilely prepared in high yields with controlled molecular weights and narrow molecular weight distributions. The synthesized brush copolymers were revealed to form worm-like cylindrical morphologies and helical rod architectures in film state by atomic force microscope observations.