Polymerization Of Acrylamide Research Articles

Mechanoresponsive self-reinforcement composite hydrogels with triple-network structures

Composite hydrogels featuring multiple-network structures hold immense potential owing to their superior mechanical attributes and exceptional capacity for dissipating energy. Nonetheless, many multiple-network hydrogels lack mechanoresponsive self-reinforcement capabilities, rendering them susceptible to enduring structural fractures. Hence, it exists a critical need to engineer composite hydrogels with both multiple-network structures and mechanoresponsive self-reinforcement abilities. In this study, we devised a triple-network (TN) hydrogel employing poly (2-acrylamido-2-methylpropane sulfonic acid) sodium salt (PNaAMPS) as the first network, which can generate mechanical radicals upon fracture. While polyvinyl alcohol (PVA) and carboxymethyl cellulose (CMC)-Al3+ served as the secondary and tertiary networks, respectively, so that to optimize its mechanical properties effectively. Upon breakage, the fragmented PNaAMPS chains could act as radical initiators, catalyzing the polymerization of the N-isopropyl acrylamide (NIPAM) monomers within the TN hydrogels to form PNIPAM chains. Furthermore, through successive network disruptions and the infusion of NIPAM monomers, the mechanical strength of the triple-network gel could be significantly enhanced. Furthermore, we evaluated the extent of mechanoresponsive self-reinforcement using the fluorochrome 8-Anilino-1-naphthalene sulfonic acid (ANS) as a fluorescent probe. This probe enabled the quantification of the PNIPAM production visually, which provided valuable feedback of the mechanical strength self-reinforcement levels by the fluorescence signals. Our approach set the stage for the development of mechanoresponsive composite hydrogels with fluorescence feedback capabilities for self-reinforcement assessment.

Light‐Assisted Polyproton Dissociated PAAm‐PA Hydrogel‐Based Moisture‐Driven Electricity Generator with a Broad Operating Range

AbstractDue to its widespread availability and spontaneity, moisture electricity generation (MEG) holds unique advantages in self‐powered systems. However, it faces challenges, including the limitations of relying on a single kind of power generation and insufficient output performance. Inspired by the mechanisms of water absorption of plants, this paper explores a light‐moisture coordinated electricity generating hydrogel (L‐MEGH) device with flexible, scalable, and highly efficient energy conversion performance, which is obtained through the UV polymerization of hydrophilic acrylamide (AAM) and phytic acid (PA) in the presence of photosensitizers. The obtained hydrogel demonstrates superior moisture absorption and remarkable electricity generation stability across a range of humidity conditions. Notably, the open‐circuit voltage (Voc) of the L‐MEGH increased from 0.675 to 0.838 V after the addition of photosensitizers (Erythrosin B, E) (the significant enhancement, up to 24%), and the short‐circuit current (Isc) reaching 635.543 µA. This L‐MEGH can realize stable electrical output even under extreme temperatures, producing 0.5 V at −20 °C for 45 h. The scalable L‐MEGHs (connected on‐demand in series/parallel) can power various commercial electronics, including nighttime illumination, mobile phones, and health monitoring sensors. This work pioneers a sustainable power generation pathway capable of enhancing performance through the hybrid collection of multiple natural energy sources.

Flexible tactile sensing of magnetic hydrogel composites based on electrical impedance tomography

Flexible and stretchable tactile sensors show promising applications in robotics, prosthetics, and wearable electronics. This paper demonstrates an electrical impedance tomography (EIT) based highly flexible, touch-sensitive pressure sensor using magnetic hydrogels. EIT technology has been explored for continuous distributed strain sensing and tactile imaging. Magnetic hydrogel composites are synthesized by simultaneous polymerization and crosslinking of acrylamide with magnetic carbonyl iron particles (CIPs). The effects of CIPs percentage on morphology, sensitivity, and electrical/mechanical properties is investigated. EIT accurately discerns pressure quantity, shape, and spatial distribution. Lower CIPs volume fractions (3%) exhibit maximum sensitivity to strain fields. Mechanical testing show the hydrogels have excellent fatigue resistance, ideal for repeated compression loading. The results demonstrate the potential of EIT with magnetic hydrogel composites for tactile sensing and imaging, with applications in soft robotics, prosthetics, and wearable electronics. The tunable sensitivity and multifunctionality make these soft composites promising materials for flexible electronics.

Synthesis of grafted copolymers of cod collagen and acrylamides in the presence of alkylborane – p-quinone system

The graft polymerization of acrylamide and N-isopropylacrylamide onto collagen in the presence of triethylborohexamethylenediamine complex and a number of p-quinones, including benzoquinone, naphthoquinone, 2,5-di-tretbutyl-p-benzoquinone, and duroquinone, was studied. In all cases, p-quinones act as polymerization retarders, reducing monomer conversion. An exception is the graft polymerization of acrylamide onto collagen in the presence of benzoquinone, which acts as a polymerization inhibitor. The proportion of the synthetic fragment in the obtained copolymers is determined by the structure of the monomer and p-quinone. The molecular weight distribution curves contain modes related to unreacted collagen, which differ significantly from those of the initial collagen in terms of intensity. This is related to the formation of a grafted copolymer of cross-linked structure, which cannot be analyzed by gel permeation chromatography. The degradation of copolymers under the action of enzymes was controlled by gel permeation chromatography. Enzymatic hydrolysis of copolymers proceeds slower than that of collagen, which confirms the formation of a copolymer. Following three hours after the onset of hydrolysis, the molecular weight distribution curves contain low-molecular weight modes of collagen and low-intensity modes related to polyacrylamide. The morphology of copolymers differs from that of collagen and polyacrylamides. Cytotoxicity evaluation of copolymers is an important research stage, determining their prospects as the basis of materials for regenerative medicine. An analysis of extracts obtained from the copolymers using culture medium by MTT assay showed a high rank of their toxicity, which can be reduced by dilution of collagen and N-isopropylacrylamide copolymer extracts with aqueous solutions. For the copolymers of collagen and acrylamide, the toxicity is maintained due to the high toxicity of the monomer. Their toxicity can be reduced by extraction of unreacted acrylamide with chloroform.

A Stealthiness Evaluation of Main Chain Carboxybetaine Polymer Modified into Liposome.

Background: Acrylamide polymers with zwitterionic carboxybetaine (CB) side groups have attracted attention as stealth polymers that do not induce antibodies when conjugated to proteins. However, they induce antibodies when modified onto liposomes. We hypothesized that antibodies are produced against polymer backbones rather than CB side groups. Objectives: In this study, we designed and synthesized a polymer employing CB in its main chain, poly(N-acetic acid-N-methyl-propyleneimine) (PAMPI), and evaluated the blood retention of PAMPI-modified liposomes in mice. Results: The non-fouling nature of PAMPI-modified liposomes estimated from serum protein adsorption was found to be not inferior to PCB- and PEG-modified liposomes. However, to our surprise, the PAMPI-modified liposomes showed an instantaneous clearance less than 1 h post-injection, comparable to the naked liposomes. Conclusions: The extent of the blood retention of polymer-modified liposomes cannot be predicted by their susceptibility to serum protein adsorption and semi-flexible conformation.

Transforming watermelon (Citrullus lanatus) rind into durable superabsorbent hydrogels for enhanced soil water retention properties and adsorbs dye in water

Innovative superabsorbent hydrogels were synthesized from watermelon rind (WR), an abundant agricultural waste. The process involved free radical polymerization of acrylic acid (AA) and acrylamide (AAm) with WR particles activated by ammonium persulfate (APS), resulting in (AA-co-AAm)/WR hydrogels with high equilibrium swelling capacities of 749 ± 32 g/g. Notably, after eight cycles, the WR hydrogel maintained 94.88 % of its initial swelling capacity, significantly outperforming the (AA-co-AAm) hydrogel without WR (13.80 % retention). This durability, combined with excellent water retention across various soil textures and high adsorption capacity for methylene blue (MB), underscores the WR hydrogel as a superior soil moisture conservation agent. This study marks a significant advance in recycling organic waste and enhancing water management in agricultural soils, demonstrating the potential for sustainable hydrogel development.

Organic-Inorganic Copolymerization Induced Oriented Crystallization for Robust Lightweight Porous Composite.

Porous composites are important in engineering fields for their lightweight, thermal insulation, and mechanical properties. However, increased porosity commonly decreases the robustness, making a trade-off between mechanics and weight. Optimizing the strength of solid structure is a promising way to co-enhance the robustness and lightweight properties. Here, acrylamide and calcium phosphate ionic oligomers are copolymerized, revealing a pre-interaction of these precursors induced oriented crystallization of inorganic nanostructures during the linear polymerization of acrylamide, leading to the spontaneous formation of a bone-like nanostructure. The resulting solid phase shows enhanced mechanics, surpassing most biological materials. The bone-like nanostructure remains intact despite the introduction of porous structures at higher levels, resulting in a porous composite (P-APC) with high strength (yield strength of 10.5MPa) and lightweight properties (density below 0.22 gcm-3). Notably, the density-strength property surpasses most reported porous materials. Additionally, P-APC shows ultralow thermal conductivity (45 mWm-1k-1) due to its porous structure, making its strength and thermal insulation superior to many reported materials. This work provides a robust, lightweight, and thermal insulating composite for practical application. It emphasizes the advantage of prefunctionalization of ionic oligomers for organic-inorganic copolymerization in creating oriented nanostructure with toughened mechanics, offering an alternative strategy to produce robust lightweight materials.

Innovative glycochenodeoxycholic Acid-Acrylamide Nanopolymer carriers: Regulating upper critical solution temperature on neurorehabilitation

Neurorehabilitation focuses on restoring function in patients with central and peripheral nervous system disorders, yet effective therapeutic options remain scarce. This study introduces a novel nanocopolymer, CaCO3-PAAm-GDCA, synthesized through reversible addition-fragmentation chain transfer polymerization of glycodeoxycholic acid, acrylamide, and CaCO3. This nanocopolymer exhibits a sharp and reversible insoluble-to-soluble transition in water at a temperature related to its upper critical solution temperature (UCST), which can be finely adjusted to a practical range around 37 °C, suitable for biomedical applications. The addition of β-cyclodextrin (β-CD) modulates this transition temperature by forming host-guest complexes, further enhancing the copolymer’s adaptability. When loaded with compound 1, the resulting CaCO3-PAAm-GDCA@1 significantly promoted the proliferation of damaged neuronal HT22 cells and inhibited ferroptosis through the modulation of Nrf2 and GPX4 pathways. This study provides a strong foundation for the development of neuroprotective drugs, highlighting the potential of tailored nanocopolymers in advanced neurorehabilitation therapies.

Mechanical properties and micro-mechanism of seawater cementitious materials reinforced by in-situ polymerization

Understanding the potential mechanism of in-situ polymerization of acrylamide (AM) for modifying seawater cementitious materials is crucial for designing high-strength and durable marine concrete. Herein, the acrylamide (AM) in-situ polymerization was investigated for its effects on the hydration behavior, micro-morphology, and pore structure of cementitious materials mixed with seawater and freshwater through a series of elaborately designed microscopic characterization methods. The results reveal that the hydration process of cementitious materials proceeds simultaneously with in-situ polymerization. However, compared with freshwater mixtures, seawater provides a large number of metal ions and SO42- ions, which can cross-link with the generated polyacrylamide (PAM) during in-situ polymerization to form a three-dimensional network structure. The synergistic effect of the hydration, in-situ polymerization, and cross-linking processes of cementitious materials can improve the pore structure of seawater-mixed paste, enhance erosion resistance, and improve the stability and toughness of microstructure. These findings were further confirmed by comparing infrared spectroscopy results, hydration products, pore size, and micro-morphology analysis as well as flexural performance tests. This is of great significance to guide the design of novel materials in marine infrastructure.

Preparation and Stability Study of an Injectable Hydrogel for Artificial Intraocular Lenses.

Currently available intraocular lenses (IOLs) on the market often differ significantly in elastic modulus compared to the natural human lens, which impairs their ability to respond effectively to the tension of the ciliary muscles for focal adjustment after implantation. In this study, we synthesized a polyacrylamide-sodium acrylate hydrogel (PAH) through the cross-linking polymerization of acrylamide and sodium acrylate. This hydrogel possesses excellent biocompatibility and exhibits several favorable properties. Notably, the hydrogel demonstrates high transparency (94%) and a refractive index (1.41 ± 0.07) that closely matches that of the human lens (1.42). Additionally, it shows strong compressive strength (14.00 kPa), good extensibility (1400%), and an appropriate swelling ratio (50 ± 2.5%). Crucially, the tensile modulus of the hydrogel is 2.07 kPa, which closely aligns with the elastic modulus of the human lens (1.70-2.10 kPa), enabling continuous focal adjustment under the tension exerted by the ciliary muscles.

Lignin hydrogel sensor with anti-dehydration, anti-freezing, and reproducible adhesion prepared based on the room-temperature induction of zinc chloride-lignin redox system

In recent years, flexible sensors constructed mainly from hydrogels have received increasing attention. However, conventional hydrogels need to be prepared by high-temperature or radiation-induced polymerization reactions, which limits their practical applications due to their suboptimal electrical conductivity and weak mechanical properties. In this paper, using sodium lignosulfonate as the raw material, a dynamic catechol-quinone redox system formed by lignin‑zinc ions was constructed to initiate rapid free radical polymerization of acrylamide (AM) monomer at room temperature. In addition, Deep eutectic solvent (DES) can form a strong hydrogen bonding network within the molecules and between the molecules of the hydrogel, resulting in a hydrogel with good tensile properties (hydrogel elongation at break of 727.19 %, breaking strength of 84.09 kPa), and provides the hydrogel with high electrical conductivity, anti-dehydration, anti-freezing, and anti-bacterial properties. Meanwhile, the addition of lignin also improved the adhesion and UV resistance of the hydrogel. This hydrogel assembled into a flexible sensor can sense various small and large amplitude movements such as nodding, smiling, frowning, etc., and has a wide range of applications in flexible sensors.

Microfluidics-Driven Dripping Technique for Fabricating Polymer Microspheres Doped with AgInS2/ZnS Quantum Dots.

Fluorescent microspheres are at the forefront of biosensing technologies. They can be used for a wide range of biomedical applications. They consist of organic dyes and polymers, which are relatively immune to photobleaching and other environmental factors. However, recently developed AgInS2/ZnS quantum dots are a water-soluble, low-toxicity class of semiconductor nanocrystals with enhanced stability as fluorescent materials. Here, we propose a simple way for making microspheres: a microfluidic dripping technique for acrylamide polymer spheres doped with quantum dots. Analyses of their spectra show that the emission of quantum dots, dispersed in water, is saturated with an increasing pump intensity, while quantum dots embedded into polymer microspheres exhibit a more sustained emission. Moreover, our study unveils a remarkable reduction in the luminescence lifetime of quantum dots embedded in microspheres: the mean value of the decay time for quantum dots in solutions was 91 and 3.5 ns for similar quantum dots incorporated into polymer microspheres.

Advancing DBD Plasma Chemistry: Insights into Reactive Nitrogen Species such as NO2, N2O5, and N2O Optimization and Species Reactivity through Experiments and MD Simulations.

This study aims to fine-tune the plasma composition with a particular emphasis on reactive nitrogen species (RNS) including nitrogen dioxide (NO2), dinitrogen pentoxide (N2O5), and nitrous oxide (N2O), produced by a self-constructed cylindrical dielectric barrier discharge (CDBD). We demonstrated the effective manipulation of the plasma chemical profile by optimizing electrical properties, including the applied voltage and frequency, and by adjusting the nitrogen and oxygen ratios in the gas mixture. Additionally, quantification of these active species was achieved using Fourier transform infrared spectroscopy. The study further extends to exploring the aerosol polymerization of acrylamide (AM) into polyacrylamide (PAM), serving as a model reaction to evaluate the reactivity of different plasma-generated species, highlighting the significant role of NO2 in achieving high polymerization yields. Complementing our experimental data, molecular dynamics (MD) simulations, based on the ReaxFF reactive force field potential, explored the interactions between reactive oxygen species, specifically hydroxyl radicals (OH) and hydrogen peroxide (H2O2), with water molecules. Understanding these interactions, combined with the optimization of plasma chemistry, is crucial for enhancing the effectiveness of DBD plasma in environmental applications like air purification and water treatment.

Zwitterionic hydrogels with high interfacial affinity for zinc metal batteries

Zinc metal batteries are expected to be the next generation of energy storage devices due to their high safety, but their application is hampered by irreversible hydrogen evolution reaction and surface side reactions of zinc anodes. Here, a zwitterionic hydrogel electrolyte is reported based on polymerization of acrylamide and 1-(3-Sulfopropyl)-2-Vinylpyridinium betaine, and it exhibits the following advantages: the sulfonic acid group of 1-(3-Sulfopropyl)-2-Vinylpyridinium betaine can be preferentially adsorbed on metal Zinc to avoid side reactions and refine the affinity at the zinc-electrolyte interface; and the coordination of the negatively charged sulfonic acid group with Zn2+ alters the solvation structure of Zn2+, which further improves the restriction ability of side reactions. Consequently, Zn||Zn symmetric batteries can be stabilized for 1, 200 h of plating stripping at 1 mA cm−2. Zn||Cu batteries exhibit an impressive average coulombic efficiency of 99.8 % over a remarkable span of 1, 800 cycles at a current density of 15 mA cm−2. Furthermore, the Zn||MnO2/Carbon nanotube batteries have been cycled more than 2, 000 cycles at a current density of 0.5 A g−1, and the zinc hybrid capacitors for more than 18, 000 cycles at 1 A g−1. And an ionic skin (i-skin) based on acrylamide and 1-(3-Sulfopropyl)-2-Vinylpyridinium betaine of polymer hydrogel electrolyte is assembled and it can stably detect physiological signals.

Enhancing cement-based composites via regulated hydration and concurrent construction of robust organic-inorganic network

Cement-based materials with excellent mechanical properties are in high demand in the civil engineering. This work utilized an innovative in-situ copolymerization approach for synergistic modification of cement-based materials. Vinyl hybrid silica microspheres (VSM) were synthesized through the sol-gel method. Subsequently, With the assistance of initiators and cross-linking agents, the VSM and acrylamide (AM) in-situ copolymerization and were uniformly dispersed in the cement matrix, leading to the successful development of a modified cement-based material. The copolymerization of VSM and AM resulted in the creation of a comprehensive three-dimensional hybrid network structure, interconnected by covalent bonds between the constituent components. Experimental results unequivocally demonstrate that the mechanical properties of the composite have undergone remarkable enhancement. Notably, the flexural strength experienced a substantial increase due to the in-situ polymerization of AM. Furthermore, the compressive strength was significantly improved, achieving a 21.4 % increase compared to samples modified with 2 wt% AM alone. The enhancement can be attributed to the synergistic effect of the in-situ copolymerization structure and the VSM attached to it. The microspheres not only aided in the development of a robust cement matrix and a higher compactness, but also bolstered the compressive modulus of the flexible polymer chains. Collectively, these factors contributed to an increase in the overall resistance to deformation, comprehensively enhancing the mechanical performance of the material. This study addresses the challenges posed by the loss of compressive strength during in-situ polymerization modification, introduces an innovative methodology aimed at significantly enhancing the mechanical properties of cement-based materials.

Efficient Synthesis of μ-A(BC)C Miktoarm Star Polymer Assemblies via Aqueous Photoinitiated Polymerization-Induced Self-Assembly.

In this study, green light-activated photoiniferter reversible addition-fragmentation chain transfer (RAFT) polymerization of glycerol methacrylate was performed using an ω,ω-heterodifunctional macro-RAFT agent. Because of the different RAFT controllability of two RAFT groups toward methacrylic monomers, only one RAFT group was activated under green light irradiation, leading to the formation of a diblock copolymer macro-RAFT agent with one RAFT group located at the chain end and the other RAFT group located between two blocks. The obtained diblock copolymer macro-RAFT agent was then used to mediate aqueous photoinitiated RAFT dispersion polymerization of diacetone acrylamide (DAAM), which formed μ-A(BC)C miktoarm star polymer assemblies with a diverse set of morphologies. Comparing with the ABC triblock copolymer, it was found that the architecture of the μ-A(BC)C miktoarm star polymer facilitated the formation of higher-order morphologies. Kinetic studies indicated that the aqueous photoinitiated RAFT dispersion polymerization exhibited ultrafast polymerization behavior, with quantitative monomer conversion being achieved within 5 min. Size exclusion chromatography analysis confirmed that good RAFT control was maintained during the polymerization. A morphological phase diagram for μ-A(BC)C miktoarm star polymer assemblies was constructed by varying the monomer concentration and the [DAAM]/[Macro-RAFT] ratio. We expect that this study not only develops an approach for the preparation of miktoarm star polymer assemblies but also provides mechanistic insights into the polymerization-induced self-assembly of nonlinear polymers.

-Effects and mechanisms of acrylamide-based polymer containing N-vinylpyrrolidone on drilling fluids at high temperature

The exploration of ultra-deep oil and gas presents higher temperature resistance requirements for water-based drilling fluids. However, the lack of temperature resistance mechanism of drilling fluid polymers limits the development of key materials and drilling fluids. In this paper, by comparing the preparation of acrylamide polymers for drilling fluids, the influence of cyclic monomer N-vinylpyrrolidone (NVP) on the properties of polymers for drilling fluids was investigated, and the mechanism of NVP was deeply discussed. The results show that the NVP-containing copolymer PAAN has superior viscosity enhancement and filtration control in high-temperature drilling fluids. This is mainly due to the fact that PAAN has a more stable and complex polymer chain structure than PAA, the polymer that does not contain NVP, and its thermal stability is improved by 18.6 % up to 268°C. At the same time, NVP provides more adsorption spots, and the high-temperature clay adsorption capacity of PAAN in drilling fluids is increased by more than 66.9 % compared with that of PAA, which improves clay hydration and promotes clay dispersion, and ultimately reduces filtration of drilling fluids and stabilizes drilling fluids at high temperatures by more than 23.7 %. The introduction of NVP and the in-depth analysis of its action mechanism supplemented the anti-temperature mechanism of drilling fluid polymers, aiming to support the research and development of ultra-deep drilling fluid technology.

Preparation and chromatographic evaluation of hydrophilic polymer brushes grafted-silica with post modification of silicon/carbon dots as a green liquid chromatography stationary phase.

Polar stationary phases were prepared by grafting hydrophilic acrylamide (Am) polymer brushes with post modification of carbon dots (CDs) and silicon dots (SiDs) onto SiO2 particles. The prepared stationary phases, SiO2-PAm-CDs, SiO2-PAm-CDs/SiDs, and SiO2-PAm-SiDs, were packed as chromatographic columns, respectively. Using nucleic bases, organic acids, and β-agonists as targetsubstances to investigate the influence of chromatographic conditions on retentionand separation, the packed columns showed the partitioning and adsorption of mixed retention behavior in hydrophilic interaction liquid chromatography mode and successfully separated thepolar compounds. Most importantly, under per aqueous liquid chromatography mode (using 100% water as mobile phase), those columns still had goodseparation ability toward nucleic bases, β-agonist, and organic acids. Because AM isa temperature-sensitive monomer, the resulting van't Hoff curves exhibited a nonlinear relationship, having temperature-responsive chromatographic characteristic under pure water separation. Hence, building on temperature-sensitive characteristics and pure water of separation conditions, the separation selectivity toward hydrophilic compounds greatly improved. Compared with the commercial hydrophilic columns, the efficiency of our developed column had the superior ability in separation and detection of betaine in Goji berry with the enhanced resolution achieved in the proposedgreen separation method(just using pure water as mobile phase).

Polymer Physics Experiment Teaching Design - Taking the Preparation and Performance Research of Conductive Ion Gel as an Example

Polymer physics is a required course for materials majors. Promoting teaching with scientific research is an important way to improve the quality of teaching in colleges and universities. In this paper, ionic liquid was used as multifunctional components to prepare ion gels by photoinitiated polymerization of acrylamide and acrylic acid monomers, and the effect of the content of ionic liquids on the mechanical properties and ionic conductivity of ion gels was further investigated. This experiment can cultivate students comprehensive experimental ability and in-depth understanding of the influence of polymer structure on performance. Through this experimental teaching reform, students can master knowledge principles and experimental skills, stimulate their enthusiasm for learning, and cultivate scientific thinking and scientific research innovation capabilities.

Single proton anti-freezing hydrogel electrolyte with enhanced ion migration number enabling high-performance supercapacitor

Compared with traditional binary ion electrolytes, single-ion electrolytes have higher ion migration number and can avoid concentration polarization. In this work, single proton hydrogel electrolytes were prepared by one-step free radical polymerization of acrylamide and 2-acrylaminoamido-2-methyl-1-propane sulfonic acid in ethylene glycol (EG)/water binary solvent. The electrolyte possesses good mechanical strength and excellent anti-freezing ability. A high conductivity of 1.28 mS cm−1 at −40 °C is achieved by adjusting monomer ratio and EG content. The proton hopping along the ion channel formed by the anionic polymer chain and the Grotthuss transport are responsible for the high conductivity. An extremely high ion migration number of 0.87 is obtained. The fixed anionic group endows the hydrogel electrolyte with good anticorrosion ability. The hydrogel electrolyte assembled supercapacitor (SC) exhibits excellent electrochemical performance in a wide temperature range from −40 °C to 60 °C and can be stored at −30 °C for 10 months without capacitance attenuation. The capacitance retention rate of the SC is as high as 92% after 15,000 cycles at both room temperature and − 40 °C. The single proton hydrogel electrolyte provides a new route for the further development of storage device based proton transport.