The present study investigates the critical bond characteristics between glass fiber-reinforced polymer (GFRP) bars, which is essential for the application bars as corrosion-resistant components in structural concrete. The interfacial bond deterioration and stress transfer mechanisms have been investigated in the present study by employing acoustic emission (AE) monitoring in hinged-type GFRP-reinforced concrete (GFRP-RC) beam specimens. The bond strength of the test specimens, governed by chemical adhesion, mechanical interlocking, and frictional resistance, has been intricately examined. Various AE signal parameters as well as historic and severity indices derived from the AE signal parameters have been meticulously evaluated and correlated with bond stress and rebar slip variations. The present study has also introduced an innovative approach of using the sentry function for the assessment of bond deterioration and associated mechanisms. The results of the present study demonstrate the reliability of AE parameters in monitoring debonding and bond strength variation, the effectiveness of the sentry function in evaluating damage progression, and the utility of historic and severity indices in capturing micro-mechanism transformations. The accurate localization of debonding and the qualitative distribution of bond stress have also been demonstrated by through correlations between cumulative AE parameters and rebar slip, Additionally, the present study also highlights the significance of peak frequency variations in AE signals, serving as a crucial tool for quantifying the mechanical interlocking and interfacial friction. The results contribute significantly to precise assessments and development of effective strategies for mitigating bond deterioration in GFRP-RC elements.