Polymer Modified Asphalt Binders Research Articles

Sustainability of Asphalt Mixtures Containing 50% RAP and Recycling Agents

The substitution of virgin asphalt binder with reclaimed asphalt pavement (RAP) has environmental and economic merits, however, cracking susceptibility arises due to the aged asphalt binder within RAP. The objectives of this study are to (1) enhance the cracking resistance of asphalt mixtures containing 50% RAP utilizing recycling agents (RAs) derived from six petroleum-based and bio-based materials, (2) conduct an environmental impact assessment (represented by global warming potential “GWP”) for high-RAP mixtures including RAs, and (3) estimate the cost effectiveness of including high-RAP content in asphalt mixtures. Based on the RAP asphalt binder performance grade (PG), base asphalt binder PG, and RAP content, the RA contents were determined to achieve a target asphalt binder of PG 76-22. A control mixture was benchmarked for comparison, specified for high-traffic volume roads, and contained PG 76-22 polymer-modified asphalt binder. The engineering performance of studied asphalt mixtures was evaluated using the Hamburg wheel-tracking (HWT), semi-circular bend, Illinois flexibility index, Ideal cracking tolerance, and thermal stress-restrained specimen tensile strength tests. It was found that petroleum-derived aromatic oil, soy-based oil, and tall oil fatty acid-based RAs demonstrated a successful restoration of aged RAP asphalt binder without compromising the permanent deformation resistance. The 50% RAP mixtures emitted less GWP by 41% and 42.9% using petroleum- and bio-oil RAs, respectively, and achieved a 31% cost reduction compared to the control mixtures.

Performance enhancement of asphalt mixture through the addition of recycled polymer materials

Enhancing the performance of asphalt binders is essential for ensuring the long-term durability and serviceability of asphalt mixtures, as it can help reduce the frequency of maintenance and repair work, ultimately leading to the development of more sustainable transportation infrastructure. To achieve this goal, this study investigates the effects of incorporating recycled polymer materials, including reclaimed polyvinyl chloride (PVC) and polystyrene (PS) derived from household waste, into hot mix asphalt. The experimental work involved subjecting the polymer-modified asphalt binders to a range of physical tests, such as softening point, penetration, ductility, indirect tensile strength, Marshall stability, and moisture susceptibility, and the results showed that the addition of recycled polymers, with an optimal content of 4%, led to lower penetration values and higher softening point temperatures, indicating improved resistance to temperature changes. Further analysis of the asphalt mixture performance revealed several beneficial outcomes, including a decrease in flow, a boost in the asphalt mixture's resistance to moisture-induced damage, and an improvement in Marshall stability and indirect tensile strength, with the inclusion of 4% recycled polymers yielding increases in Marshall stability of 43.7% and 37.4% for PVC and PS-modified mixes, respectively, and increments in indirect tensile strength of 32.2% and 29.7% for the same mixes. The study concludes that the use of recycled polymers can effectively enhance the performance and durability of asphalt mixtures, contributing to the development of more sustainable asphalt pavement construction practices by utilizing locally available or reused materials, which could lead to the increased knowledge and application of stronger and more weather-resistant asphalt mixes, ultimately promoting the advancement of sustainable transportation infrastructure.

Thermal, rheological, and aging characterization of ethylene vinyl acetate polymer modified asphalt binder

Thermal, rheological, and aging characterization of ethylene vinyl acetate polymer modified asphalt binder

Comparative analysis of several short-term aging simulation methods and their impact on long-term aging performance of asphalt binders

The aging of the asphalt pavement is an essential factor to consider when constructing a road. Several methods, such as the Thin Film Oven Test (TFOT) and Rolling Thin Film Oven Test (RTFOT), have been used to simulate the short-term aging of asphalt binders. Based on the wide use of polymer-modified asphalt binder and the idea of research facilitation, 5 hours of Pressure Aging Vessel (5 h PAV) was proposed as an alternative to previous short-term aging methods of asphalt binders. However, the efficacy of this technique still needs to be wholly explored in all aspects and requires advanced research. The frequency sweep, temperature sweep, and Multiple Stress Creep Recovery tests were performed to evaluate the high-temperature performance of asphalt binders under aging conditions. In addition, the relaxation test was carried out to determine the low-temperature stress relaxation change and the fatigue cracking resistance of asphalt binders. The Chemical test explored the chemical change of asphalt binders under different aging conditions. The findings revealed that, in the case of neat asphalt binders N50, N70, and N90, the maximum disparity between the aging conditions of TFOT and 5 h PAV was found to be below 6 %. However, the difference between the aging conditions of 5 h PAV and RTFOT was observed to be approximately 20 %. Then, 5 h PAV can be highly recommended as an alternative to replacing TFOT. For SBS and high viscosity-modified asphalt binders HVMA-I and HVMA-II, the maximum gap between 5 h PAV and TFOT was estimated to be approximately 19.71 %. However, the gap between 5 h PAV and RTFOT was estimated to be less than 7 %. Then, 5 h PAV can be an alternative to replace RTFOT for modified asphalt binders if necessary. This study offers a thorough explanation and dispels doubts regarding the suitability of the 5-hour PAV as an alternative for simulating the short-term aging of asphalt binders, thereby enhancing research facilitation. Furthermore, the research delineates the impact of various short-term aging simulation methods on the long-term aging properties of asphalt binders, including the variation rates between them.

A review of polymer-modified asphalt binder: Modification mechanisms and mechanical properties

The significant increase in the number of vehicles, traffic speed, and load has significantly reduced the lifespan of pavements and increased maintenance costs. Therefore, the incorporation of polymers into bituminous binders is imperative to enhance pavement quality and performance. Nowadays, polymer-modified asphalt binders (PMBs) play a crucial role in pavement engineering. This polymer absorbs asphalt molecules to form a network connecting the entire binder, giving it better viscoelasticity than the base asphalt. Although polymers do enhance the properties of asphalt to some extent, there are still certain limitations hindering the future development of polymer-modified asphalt, such as high costs, low resistance to aging, and poor storage stability. Additionally, there is limited literature available that reviews the advantages and disadvantages of various polymer modifiers. The aim of this paper is to conduct a systematic review that evaluates the benefits and drawbacks of different polymer types in modifying asphalt materials. This comprehensive synthesis study thoroughly examines the historical evolution of polymer modified binders (PMBs) for asphalt pavement, including selection criteria for polymers used in asphalt modification, current state-of-the-art knowledge regarding the internal structure and morphology of PMBs, evaluation methodologies for PMB properties, binder specifications specific to PMBs, recommendations based on findings, and future research. This review will not only merit research from an academic perspective, but also provide guidance for pavement engineering.

Improving hydrophobicity of asphalt surfaces using pulverized recycled polyethylene terephthalate: Towards efficient roofing/waterproofing

Hydrophobic surfaces exhibit low wettability, low water and ice adhesion, etc. with an enhanced water resistance overall. Asphalt binder is popularly employed for roofing and waterproofing due to its intrinsic hydrophobicity. Yet, both unmodified and conventionally polymer-modified asphalt binders exhibit water contact angle (WCA) within the lower hydrophobic range (≤ 121°). Recent studies have shown that the hydrophobicity of asphalt binder can be enhanced via surface treatment using carefully selected materials. In this current study, the use of recycled polyethylene terephthalate (rPET) to improve the hydrophobicity of asphalt-binder was explored. The rPET was processed into micro-sizes and utilized to thermally treat the asphalt-binder at 100 °C. The morphology of the processed rPET and the treated-asphalt surfaces was examined using scanning electron microscopy (SEM). An optical surface profilometer was employed to quantify the roughness of the treated-asphalts. A video contact angle measurement system was used to measure the WCA of the unprocessed/untreated materials and the treated asphalt surfaces. The treated-asphalt showed average and maximum WCA of up to 144° and 148° respectively. This indicates that the rPET-treated asphalt surface could exhibit super-hydrophobicity (WCA ≥ 145°). The improvement in the WCA was due to the increase in surface roughness as a result of the embedment of rPET-particles onto the asphalt surface. The embedment resulted in the stretching of the asphalt surface, forming micro-valleys and -ridges of multiple hierarchies. Higher curing duration was found to yield treated-asphalts with hydrophobicity that last longer. It is found that micronized rPET with sizes smaller than 149 µm can be employed to successfully improve the hydrophobicity of asphalt binder surfaces.

Investigating the influence of polyethylene terephthalate fibres with different lengths on the cracking resistance of high-performance asphalt concrete

High-performance asphalt concrete is an innovative paving material that typically relies on the properties of polymer-modified asphalt binders. However, the application is limited due to their high cost and phase separation issues. A solution is explored in the present study by blending 12% asphaltenes and a straight-run asphalt binder with a true performance grade of 70.2–25.9, resulting in a true performance grade of 82.9–21.8, which elevates the binder’s stiffness. Three lengths of polyethylene terephthalate fibres are used to improve the cracking resistance of these asphaltenes-modified mixes. An indirect tensile cracking test is conducted at 25 and 37 °C, revealing a significant improvement in cracking tolerance and failure energy, particularly at 37 °C. The cracking tolerance index value peaked at 105 for 12 mm polyethylene terephthalate fabricated sample, while control asphaltenes-modified, 6 mm, and 18 mm polyethylene terephthalate fabricated samples achieved 61, 87, and 99, respectively, with failure energy increasing with longer fibres.

RMPD-22-12-09.R3 - Improvement in rheological properties of polymer-modified asphalt binder through sulfur addition using traditional and advanced analyses

The use of crosslinking agents, particularly sulfur, addresses compatibility issues in Polymer-modified binders (PmB), impacting storage stability and rheological properties. Through comprehensive rheological assessments, including Superpave grading and advanced techniques such as Glover-Rowe, master curves, Arrhenius and Power-law models, this study aimed to provide a deeper understanding of the role of sulfur as a crosslinking agent between asphalt and styrene-butadiene copolymer (SB), investigating its influence on the durability and performance of the asphalt binder. Results show sulfur levels up to 0.3%, enhanced PmB's elasticity, resistance to shear deformation, rutting, low-temperature cracking, and fatigue, making it suitable for a wider range of climatic conditions and heavier traffic levels. Beyond this threshold, the binder became very stiff and less workable, suggesting the potential onset of gelation. An optimal sulfur content in PmB enhanced compatibility, rheological properties, and overall efficiency of binder modification, potentially reducing polymer modification costs.

Investigation of LAS-based fatigue evaluation methods for high-viscosity modified asphalt binders with high-content polymers

The objective of this paper is to investigate the microstructure of high-viscosity modified asphalt binder (HVA) containing high-content polymers and its effect on fatigue performance, as well as the applicability of different analytical methods and failure criteria of linear amplitude sweep (LAS) test to HVA. In this paper, two types of HVAs with different polymer contents, a commercial HVA, a conventional polymer-modified asphalt binder, and a base asphalt binder were first prepared or selected. Fluorescence microscopy tests, time sweep tests, and LAS fatigue tests were then performed on these binders. Finally, the fatigue properties of the different binders were analyzed in depth using different analytical methods and failure criteria. The results show that the polymers in HVA crosslink with each other to form a strong cross-linking structure, and the phase inversion of the polymers renders them into a continuous phase, which significantly improves the fatigue damage resistance of the HVA; moreover, the evolutions of stress with shear strain for the fatigue process of HVAs is related to the polymer network. Besides, the two-dimensional damage characteristic curve (DCC) cannot accurately reflect the evolution of the fatigue performance of HVA, and this paper suggests the use of a three-dimensional DCC curve with strain information. Furthermore, the 35% reduction in C0 in the dissipative energy method is not a suitable failure criterion, a more accurate fatigue performance ranking can be obtained by using the yield stress as the failure criterion. Although the fatigue resistance of HVA after yield stress is theoretically considered using the pseudo-strain energy approach, HVA does not show a peak of stored pseudo-strain energy even when the strain is increased to 60% in the LAS test. Therefore, the maximum strain value (30%) in the standard LAS test is not sufficient in characterizing high-polymer HVAs because there is not enough fatigue accumulation of HVAs in this range, consequently, the maximum shear strain parameter in the LAS experiment needs to be reconsidered.

Evaluation of Rheological Properties of Polymer-Modified Asphalt Binders and Mastics with Organic Additive—Imidazoline

The article presents the results of testing the asphalt binder modified with SBS copolymer (5%) and its mixture with mineral fillers called asphalt mastics. The aim of the research and analysis was to check the possibility of using an organic additive in the form of imidazolines and to assess their impact on the viscoelastic properties of the obtained asphalt mastics. The main advantage of using imidazoline is the increased resistance of asphalt mixtures to low-temperature cracking at the top of the road route and reducing its maintenance costs. Based on the examination of the adhesion of the binder with the addition of various imidazolines to the aggregate, a selection was made from six analyzed subtypes. One of them was selected for further research. The tests were carried out in a dynamic shear rheometer in a wide temperature range from −36 °C to 82 °C, determining the most important parameters of the tested materials, i.e., dynamic shear modulus (|G*|), phase angle (δ) and the non-recoverable creep compliance (Jnr). The test results and their analysis confirmed the beneficial effect of imidazoline on the viscoelastic properties of mastics in the low-temperature range, even at the lowest content of 0.2%. Based on the results of the determination of Jnr and |G*|/sinδ in the range of high operating temperatures, no significant deterioration in permanent deformation parameters was observed. Moreover, the use of imidazoline reduces technological temperatures during the production of HMA used in the pavement and, therefore, reduces CO2 emissions into the atmosphere.

Effects of waste high-density polyethylene (HDPE) on asphalt binder and airfield mixes

ABSTRACT Flexible airport pavements may require polymer-modified asphalt binder for their asphalt concrete (AC) mixes to withstand heavy gear loading and slow traffic moving in taxiways and aprons. Waste plastics could be repurposed as a possible alternative to Styrene–butadiene-styrene (SBS) modifiers. In this study, the feasibility of using granulated recycled high-density polyethylene (HDPE) waste was evaluated as an asphalt binder modifier for airfield pavements. A base asphalt binder was modified with waste HDPE to obtain a Superpave performance grade (PG) of 70-22. Adding waste HDPE would increase binder’s stiffness and bond to aggregate, it slightly improved ductility and elasticity; but less than SBS polymer-modified binders. The AC mixes prepared with waste HDPE-modified binder showed less potential for rutting and cracking compared control AC mixes with PG 64-22. However, the rutting and cracking potential was higher when compared to their SBS-modified PG 70–22 counterparts. On the other hand, AC mixes containing waste HDPE-modified binder were less susceptible to moisture-induced damage. It appears that using waste HDPE-modified binder is feasible where improving adhesion and resistance to moisture-induced damage AC mixes are needed and embrittlement and elastic recovery are not critical, while meeting rutting and cracking potential regional thresholds.

Incorporating Environmental Impact Analysis into Louisiana’s Balanced Asphalt Mixture Design

To meet the asphalt pavement industry’s net zero carbon emission goals, increasing reclaimed asphalt pavement (RAP) levels to greater than 25% is considered a critical tactic. However, many state departments of transportation are cautious in adopting high RAP content into their designs because of durability issues resulting from aged RAP binders. This paper assesses the effectiveness of using the Lewis acid catalyst, FeCl3, in improving the cracking resistance of high-RAP asphalt mixtures to meet Louisiana’s balanced mixture design (BMD) criteria, and lower embodied carbon of asphalt mixtures. Four asphalt mixtures were designed and tested against permanent deformation, intermediate- and low-temperature cracking, and durability. Mixture 1 is conventional, which contains performance grade (PG) 76-22 polymer-modified asphalt binder with no RAP. Mixture 2 is unmodified PG 67-22 and 30% RAP without catalyst. Mixtures 3 and 4 incorporated an unmodified asphalt binder PG 67-22, a catalyst, and 30% and 50% RAP, respectively. A life cycle assessment (LCA) analysis was conducted on asphalt mixtures that complied with Louisiana’s BMD specifications to quantify global warming potential improvements. Because the performance of both mixtures is expected to be similar, the scope of the LCA analysis was limited to only those life cycle stages that are expected to be different, modules A1–A3 (i.e., cradle-to-gate stages). Results showed that the use of FeCl3 can improve asphalt mixtures’ cracking resistance containing high RAP contents, whilst it did not have a negative impact on permanent deformation resistance. Further, the addition of FeCl3 to asphalt mixtures with 30% and 50% RAP levels showed a reduction in greenhouse gas emissions by 28% and 43.4%, respectively.

Effect of Different Long-Term Aging Conditions on Cracking Resistance of Polymer-Modified Asphalt Binder and Mixes

Effect of Different Long-Term Aging Conditions on Cracking Resistance of Polymer-Modified Asphalt Binder and Mixes

Mechanism of physical hardening on the fracture characteristics of polymer-modified asphalt binder

This article aims to reveal the physical hardening mechanism of polymer-modified asphalt binder (PMA) and accurately assess its impact on the low-temperature fracture properties of asphalt binders. Base asphalt binder (BA), styrene–butadiene–styrene modified asphalt binder (SBSMA), and crumb rubber modified asphalt binder (CRMA) were used as the research objects. Molecular dynamics (MD) simulation and differential scanning calorimetry (DSC) test were used to investigate the physical hardening mechanism of PMA at the microscopic level. The fracture characteristics of PMA under physical hardening were analyzed based on the single-edge notched beam (SENB) test. The results show that under prolonged cold service conditions, the asphalt molecular mobility is weakened, the non-bond energy and the free volume are reduced, and the molecules undergo aggregation state transformation, leading to the physical hardening of asphalt materials. In the process of physical hardening of asphalt molecules in the micro-Brownian motion of the main active force from the aromatic and saturate fractions. Considering the effect of physical hardening, it is recommended that the method used to test the low temperature properties of asphalt binders should ensure a constant temperature for at least 24 h. The crack tolerance (Ct) is recommended as the evaluation index of low-temperature cracking resistance of PMA in cold regions. The Ct of BA, SBSMA, and CRMA are reduced by 52.88 %, 12.04 %, and 35.24 %, respectively, after 24 h of constant low temperature. This indicating that the polymer modifiers can improve the fluidity of asphalt molecules, inhibit molecular aggregation, and reduce the effect of physical hardening on asphalt binders. Thermo-oxidative aging can aggravate the physical hardening phenomenon of asphalt binder, and the higher the degree of thermo-oxidative aging, the more severe the physical hardening of asphalt binder. The related research results provide the theoretical basis and technical support for the accurate design and development of the low-temperature performance of asphalt binders for roads in cold regions.

Development of Plug Joint with Polymer-Modified Rubber Asphalt as Filling Material

Rising traffic volume, heavy loads, and construction activities have raised concerns about expansion joint device damage. This study focuses on developing an innovative expansion joint using polymer-modified rubber asphalt as the filling material to enhance its service life. Styrene–butadiene–styrene (SBS) emerged as a suitable modifier for rubber-modified asphalt, significantly improving elasticity and adhesion. Through the strategic combination of 3- and 2-block linear SBS, the elasticity and adhesion properties were significantly improved, resulting in the formulation of a well-suited polymer-modified rubber asphalt binder. The developed asphalt binder exhibits impressive elastic recovery (61.1% to 66.1%), surpassing commercial products, with enhanced constructability and workability (15% to 21% viscosity reduction). The carefully engineered mastic asphalt mixture showcases self-leveling characteristics at a moderate 210 °C, addressing historical constructability challenges. Settlement is 40% less than traditional hot mix asphalt for surface layers, with improved moisture and stripping resistance, enhancing existing asphalt plug joint durability and workability. Collectively, this novel mixture, comprising polymer-modified rubber and mastic asphalt, showcases the potential to enhance the durability of existing asphalt plug joints while ensuring superior constructability and workability.

Mechanical, thermodynamical, and microstructural characterization of adhesion evolution in asphalt binder-aggregate interface subjected to calcium chloride deicer

Frigid weather and freezing road conditions in cold regions result in reduced pavement surface friction, compromised vehicle maneuverability, leading to deteriorated transportation safety. Given their effectiveness and low cost, using chloride-based deicing agents such as CaCl2 has become a standard winter maintenance strategy for many highway agencies. However, coupled with freeze–thaw (F-T) cycles, CaCl2 can adversely affect the durability of asphalt pavements and cause complex distresses such as moisture-induced damage, among others. Despite this fact, the mechanisms and the extent of the damage made to the asphalt binder-aggregate interface due to use of chloride salts are not well-understood. This study was undertaken to characterize the mechanisms by which different eutectic concentrations of aqueous CaCl2 solutions and F-T cycles affect the adhesion between asphalt binder and different aggregates through a multi-scale characterization and testing program. Given the rise in use of polymer-modified asphalt binder a PG 64–34 asphalt binder and aggregates of granite, quartzite, and limestone mineralogies were evaluated. More specifically, pull-off strength of the aggregate-binder systems subjected to different aqueous concentrations of CaCl2 and F-T cycles were determined. In addition, surface free energy method as a thermodynamic-based approach was employed to determine the effect of salt concentration on the adhesion and debonding energies, and the moisture-induced damage potential of the binder-aggregate interfaces. Furthermore, atomic force microscopy was employed to evaluate the effect of salt concentration and F-T cycles on surface morphology, nanostructure, and adhesion of the asphalt binder. The applied multi-scale characterization provided invaluable information about the physio-chemical phenomena responsible for the accelerated damage in asphalt binder-aggregate interface when subjected to different aqueous concentrations of CaCl2. Gaining an accurate understanding of the damage mechanism is necessary for developing new materials and methods for combatting salt-accelerated moisture-induced damage in cold regions as a result of winter maintenance operations.

Performance of SMA Mix modified with waste plastic and fiber

Waste materials are harmful to the environment when incinerated, dumped in open water, or landfilled. Present-day society faces a serious challenge from the growing amount of waste materials and the need for a sustainable solution. Due to the limited amount of natural raw materials, there is a global need to minimize the amount of waste. Using suitable waste materials, such as waste plastic, as additives in asphalt mixtures is a viable strategy, offering an alternative to virgin materials like polymer-modified asphalt binders. This research studied the influence of waste fibers as a stabilizer and recycled Polyethylene waste as an asphalt modifier in the Stone Mastic Asphalt mix (SMA). Two categories of the SMA mixes were produced, base and modified mixes, with three different mixes under each category. The rheological properties of the Recycled Polyethylene Modified Asphalt (RPMA) have been assessed using different Recycled Polyethylene (RP) dosages at the upper-performance temperature. In addition, two Recycled Fibers (RF), cellulose and jute, were used as stabilizing materials for SMA mixes. The impact of RP and RF on the SMA mixes was investigated using three tests: Drain-down resistance, moisture sensitivity, and rutting performance. Statistical analysis was conducted to assess the effect of the additives on the measured SMA properties. The results showed that adding RP and RF improved the SMA mixes' ability to hold the asphalt and fine material inside the mix and solved the drain-down problem by 81.43%. In addition, adding RP as an asphalt modifier greatly enhanced the moisture and rutting resistance by 47.5% and 93%, respectively.

Properties of recycled facemask fiber modified asphalt binder: Comparative analysis of surface modification and composite modification method

Polymer-modified asphalt binders had been developed as a novel strategy for road and building materials. People generally use disposable facemasks to reduce the risk of respiratory diseases during travel and commuting. These discarded masks will become a serious environmental problem. Recycled facemask has great potential application in the modified asphalt, but its modification effect of modified asphalt needs to be studied. In this work, different kinds of fibers and their modified asphalts had been successfully prepared and comparatively analyzed after the surface of fibers treated by butyl acrylate (BA) and further modified by copper oxalate (CO) nanoparticles. From the test results, the activation energies of polypropylene fiber extracted from recycled facemask (RPF) modified asphalt (RPA), treated RPF (MRP) modified asphalt (MRPA), and MRP further decorated with CO (MRPCO) modified asphalt (MRPCOA) were 64.08 kJ/mol, 59.09 kJ/mol, and 62.32 kJ/mol, respectively. MRP and MRPCO were better dispersed in asphalt than RPF. MRPA performed a lower value of the viscoelastic than RPFA, but MRPCOA performed the higher value of viscoelastic than MRPA. Compared with RPA, the short-term aging factors of MRPA and MRPCOA decreased by 31.73% and 53.18%, while long-term aging factors of MRPA and MRPCOA decreased by 11.34% and 12.31%. From the nanoindentation data, the maximum depth of MRPA increased by 5.23% and the hardness decreased by 2.55% than RPA. The maximum depth of MRPCOA also decreased by 6.68% and its hardness also decreased by 4.45% than MRPA. These results indicated composite modification of RPF performed better than only surface modification based on the viscoelastic and aging properties of modified asphalts. It provided a meaningful study for the potential applications of various recycled polymeric fibers in modified asphalt binder in the future.

Laboratory Evaluation of High-Temperature Properties of Recycled PMA Binders

Various environmentally friendly additives have been used to mitigate significant damage, such as plastic deformation and cracking, in asphalt pavements over the long term. Despite the existence of research demonstrating the efficacy of the materials for asphalt mixture, there has been a lack of studies focusing on the recycling of modified asphalt binders. Therefore, this study conveys the laboratory evaluation of the high-temperature properties of 12 recycled polymer-modified asphalt (PMA) binders as basic research. The data evaluation was carried out using crumb rubber modifier (CRM), styrene-butadiene-styrene (SBS), and styrene-isoprene-styrene (SIS) modified binders, depending on their recycled binders. To assess the properties of each binder, the viscosity and viscoelasticity were measured. Overall, the results of this study revealed that (1) an increasing trend for the viscosity of all asphalt binders was seen as the recycled binder was added and showed their characteristics depending on modifiers; (2) the tendency for using each modified binder in the original and rolling thin-film oven (RTFO) condition appeared for modifiers to have their properties when reusing them; (3) from the Jnr and %rec values, each property of modifiers kept its inherent characteristics, but a potential limit was seen in that a styrene block copolymer was mainly effective on this test method. To sum up, modifiers in asphalt mixture can have their unique properties even after reusing them in recycled asphalt mixture. Therefore, it is recommended that modifiers in asphalt mixture are considered as a potential factor in utilizing reclaimed asphalt pavement (RAP).

Rutting Resistance Evaluation of Highly Polymer-Modified Asphalt Binder and Mixes Using Different Performance Parameters

This study focused on evaluating the rutting performance of three different highly polymer-modified asphalt (HiMA) binders (i.e., O, T and B) using binder-based [i.e., multiple stress creep recovery (MSCR) and force ductility (FD)] and mix-based [flow number (FN) and Hamburg wheel tracking test (HWTT)] rutting performance tests. The binder-based rutting indicators were compared with mix rutting performance to determine a parameter that can help in the correct prediction of HiMA rutting resistance. In addition, the study looked into application of a simple performance test, the indirect rutting tolerance index (IDEAL-RT), for HiMA mix rutting prediction. The MSCR test revealed different rankings of recovery at 0.1- and 3.2-kPa stress levels. Moreover, the T and B binders did not satisfy the stress sensitivity criteria (Jnr_difference) of Max 75%. The force ductility tests revealed that the peak force observed for polymer network phase in HiMA was significantly higher than base binder stiffness, which is in contrast with force distribution in polymer-modified binders (PMBs). The mix rutting resistance ranking (O>T>B) was similar in all the tests (i.e., FN, HWTT, and IDEAL-RT). Although IDEAL-RT can be used to compare the rutting resistances of HiMA mixes, detailed future work is required to establish its acceptability in comparing various types of mixes and the minimum requirements of RTIndex. The comparison between binder and mix rutting indicators demonstrated that MSCR testing on binder at stress levels of 6.4 kPa and higher can be used to predict the rutting resistance of HiMA binders. Parameters like slope and cohesion energy and a newly introduced parameter—work done for polymer activation (WPA)—from FD tests can be used to determine the polymeric phase dominance in HiMA binders. Overall, this study provides pavement stakeholders with a framework for rightly predicting the rutting resistance and polymeric phase dominance of HiMA binders and mixes using MSCR, FD, and IDEAL-RT tests.