Polylactide Acid Research Articles

Reversible halochromic PLA film for naked-eye detection at the extreme base condition

ABSTRACT Exposure to extreme base conditions in indoor environments may lead to adverse health effects on living beings. Proper ventilation and real-time detection are very important upon exposure. A simple and highly sensitive reversible base sensor is successfully prepared for real-time detection of the extreme base condition of aqueous base analytes. Halochromic poly lactid acid (PLA) pH film sensor containing thymolphthalein (THY) dye and polyethylene glycol (PEG) was developed by solution casting method. To increase the effectiveness of PLA pH film capabilities as a base sensor, the impact of altering the concentration of THY and PEG substrate was explored. The interactions between PLA, THY, and PEG were observed by Fourier transform infrared (FTIR), and the intensity of color changes was measured using UV-VIS spectroscopy. It was found that the PLA pH film has a clear color response from colorless to blue at pH 11–13 with a rapid response time within a minute. The results also revealed that varying PEG content showed a significant effect on response time compared to varying the THY content. Real-time visual color changes of the PLA pH film with different THY content and PEG content on total color difference, (∆E) values over pH and time were observed. Color changes after immersion in buffer solutions with different pH values were evaluated spectrophotometrically using CIELAB color space. The results indicated that varying the PEG content in the film leads to a faster and more distinct reversible color change. This outcome can be attributed to PEG ability to augment the free volume within the PLA material and enabling PEG and the dye and become trapped between PLA chain. The addition of PEG and THY has improved the flexibility of PLA film, which enables great potential in many applications such as medical, textile, and packaging in base environments.

PENGARUH TEMPERATUR CETAKAN TERHADAP STRUKTUR MIKRO DAN KEKERASAN PISTON HASIL PENGECORAN MENGGUNAKAN 3D PRINTING

Motorcycle users in 2019 reached 133,617,012 units in Indonesia. The impact of a large number of motorcycle certainly attracts the interest of the industry to produce two-wheeled automotive vehicles. The piston is part of the engine that functions as a compression barrier in the combustion chamber, the piston material is aluminum alloy. Therefore, research was carried out on making pistons with investment casting methods, physical and mechanical patterns from 3D printers on pistons. This research starts from drawing the piston using CAD (computer-aided design), making a printed pattern from a 3D Printer machine with PLA (polylactide acid) material. The mold pattern is coated with a mixture of gypsum cement and silica powder. The casting process with a pouring temperature of 750ᵒC and a mold temperature of 200 ᵒC, 250 ᵒC, 300 ᵒC, 350 ᵒC, and 400 ᵒC. The results showed the largest grain size at a mold temperature of 400ᵒC. The highest hardness at 200 ᵒC mold temperature is 47.00 HRB and the lowest hardness at 400 ᵒC mold temperature is 40.56 HRB. The higher the temperature of the mold used, the level of porosity of a material will decrease. This is due to the temperature difference when pouring the molten metal and the lower mold temperature. This makes the metal solidification time longer. The higher the mold temperature, the slower the solidification time, the larger the grain structure, and the decreased hardness.

Microwave heating of graphene nanoplatelet polymer composites: Experimental and finite element study

AbstractCompared with contemporary electrofusion techniques that use embedded wires for Joule heating, microwave heating may facilitate the joining of thermoplastic polymer components, promising shortened fusion periods, superior heating uniformity, and reduced energy consumption. This study investigates the fabrication of multifunctional polylactide acid (PLA) composites with strong microwave absorption using graphene nanoplatelets (GNP). GNP/PLA nanocomposites were fabricated using a two‐step scalable manufacturing method, that is, solution blending and hot compression molding. The GNP content of the composites ranged from 0% to 8% by weight. The samples were characterized for dielectric permittivity, heat capacity, and electrical and thermal conductivity. Thermal imaging was used to investigate the efficacy of microwave heating in GNP/PLA nanocomposites as a function of microwave power and filler weight fractions. The microwave heating process in GNP composites was studied using multi‐physics finite element software. The experimental results were compared to numerical model predictions for maximum temperature and microwave energy absorbed. The produced nanocomposites were discovered to have strong microwave absorption characteristics and hence rapid heating, making this type of composite a prospective choice for gasket materials that facilitate fusion bonding for thermoplastic‐based components via localized heating.

THE EFFECT OF DIFFERENT STRUCTURE AND GRADIENT INFILL ON MECHANICAL BEHAVIOR POLYLACTIDE ACID MATERIALS (PLA)

The purpose of this study is to analyze the effect of our gradient infill on the mechanical behavior of polylactide acid (PLA) materials resulting from 3d printing, which has an impact on the efficiency of material use while still providing good mechanical support. In this study, the specimens were designed using nTopology software and there were 4 variations of the structure, namely square, honeycomb, diamond, and gyroid, each of which was made gradient and non-gradient, then a bending test was carried out to determine its mechanical behavior thats PLA materials. The results of this study indicate that a comparison between specimens with gradient and non-gradient models with 50% porosity can increase the deflection of the specimen, namely square 15.7-19.1 mm, honeycomb 16.3-20.6 mm, Diamond 19.7-21.8 mm, and gyroid 20.3-22.1 mm, with an average deflection of 2.04 mm. In addition, there is a linear correlation of the relationship between thickness to deflection and flexural modulus whereas the thickness value increases, the deflection and flexural modulus will increase. The conclusion of this research is that giving a gradient to the structure can improve mechanical behavior, especially deflection.

Controlling the sp2/sp3 ratio of amorphous hydrogenated carbon layers (a-C:H) on polylactide acid (PLA) at constant distance but angle-dependent deposition

The biopolymer polylactide acid (PLA) is suitable as an eco-friendly substitute for conventional polymers, but polymer surfaces often do not meet industrial requirements and thus severely limit applications. Surface adhesion, substrate related decomposition and barrier permeability can be modified with plasma-deposited thin amorphous hydrogenated carbon (a-C:H) coatings. Their properties depend significantly on the sp2/sp3 ratio, here to be controlled by changing the coating geometry between sample and plasma source. A 50 µm PLA film was a-C:H coated at different angle settings (30° intervals) for 2.5, 5.0, 7.5 and 10.0 min to analyze angle-dependent layer growth. Surface morphology was recorded by scanning electron and atomic force microscopy, and the surface free energy (SFE) and contact angle were determined. Modified barrier properties such as the water vapor transmission rate were investigated and showed a reduction in permeability of up to 47% for defined coating geometries and times. In addition, investigations of the top a-C:H layers by synchrotron assisted X-ray techniques revealed angle-dependent changes in the sp2/sp3 binding ratio. The angle-dependent coating not only changes the chemical composition of the layer, but also improves the barrier properties and extends the SFE of PLA by an increased polar fraction.

Technology and mechanical properties of reinforced continuous fiber 3D-printed thermoplastic composite

Background. Additive technologies based on Fused Deposition Modeling (FDM) modeling methods attract a lot of attention from both industry and research groups, which is explained by low investment costs, ease of production, etc. If the processing parameters are correctly selected, products with mechanical properties close to products obtained by traditional technologies can be obtained. Objective. Practical implementation of the modernized technology for 3D printing of Polylactid Acid (PLA) samples reinforced with continuous Kevlar fiber using the FDM method and determination of their mechanical properties. Methods is based on experimental and theoretical studies of the limit of tensile strength and modulus of elasticity of the composite and includes testing of samples on the SHIMADZU AGS-X testing machine and solving the inverse problem. Results. Experimental samples of thermoplastic composite (PLA+Kevlar fiber Æ0.3 mm) were tested for tension. It was found that the tensile strength of the reinforced composite compared to the unreinforced one with a Kevlar volume fraction of about 12% increases by 2.38 times, and the modulus of elasticity increases by 1.45 times. With a confidence interval of 0.68, the error of determining the ultimate tensile strength is 3.5%, and the modulus of elasticity is 4.5%. A theoretical dependence was obtained for predicting the modulus of elasticity of thermoplastic composites in the range of changes in the degree of reinforcement up to 15%. Conclusions. The application of additive technologies based on FDM for 3D printing of thermoplastic composites with increased mechanical properties is substantiated.

Clinical experience of thoracoplasty with absorbable rib substitutes

PurposeMalignant chest wall tumors are rare in pediatrics. They require multimodal oncological treatment and local surgical control. Resections are extensive; therefore, thoracoplasty should be planned to protect intrathoracic organs, prevent herniation, future deformities, preserve ventilatory dynamics, and enable radiotherapy.MethodsWe present a case series of children with malignant chest wall tumors and our surgical experience with thoracoplasty using absorbable rib substitutes (BioBridge®), after local surgical control. BioBridge® is a copolymer made of a polylactide acid blend (70% L-lactic acid y 30% DL-lactide).ResultsIn 2 years, we had three patients with malignant chest wall tumors. Resection margins were negative, without recurrence at follow-up. We achieved good cosmetic and functional results, and no postoperative complications.ConclusionAlternative reconstruction techniques such as absorbable rib substitutes provide protection, guarantee a flexible chest wall, and do not interfere with adjuvant radiotherapy. Currently, there are no management protocols in thoracoplasty. This option represents an excellent alternative for patients with chest wall tumors. Knowledge of different approaches and reconstructive principles is essential to offer children the best onco-surgical option.

Tensile Strength of 3D Printing Scaffold Design Truncated Hexahedron for Tuberculosis Drug Delivery

Mechanical properties are important characteristics of scaffolds as biomaterials implant in tissue engineering. This study focused on the analysis of the tensile strength of the 3D printing scaffold with a geometric design of the truncated hexahedron unit with pore size variation and combinFive variations of pore size of the scaffold (600, 800, 1,000, 1,200, and 1,400 µm) were fabricated from Polylactide acid (PLA) filament using the Fused Deposition Modelling (FDM) method through an ordinary commercial 3D printer. The IBS paste was synthesized from hydroxyapatite (HA), gelatin, hydroxypropyl methylcellulose (HPMC), and streptomycin. The characterization performed in this study were the pore size test with a digital microscope, tensile strength, elongation test, porosity, and contact angle. The 3D printed scaffold formed micropores after injected with IBS paste from a range of 130-230 µm. The tensile test results showed that the tensile strength of the 3D printing scaffold increased after being injected with IBS paste. In addition, the elongation test also shows a positive trend with increasing values of elongation after injection of IBS paste. The contact angle test results indicated that the scaffold was hydrophilic. From those characterizations, it could be concluded that 3D printing scaffold meet the criteria of scaffold for bone tissue engineering and drug carrier for tuberculosis.

Resistencia mecánica de matrices óseas de ácido poliláctico desarrolladas por impresión 3D para la reconstrucción de defectos óseos

IntroductionBone defects are one of the main limitations in orthopedic surgery and traumatology. For this reason, multiple bone replacement systems have been developed, either by prosthetic implant or by substitution with osteoforming substances, whose limitations are their survival and lack of structurality, respectively. The objective of this work is the generation of a new material for the creation of biologically active structures that have sufficient tensile strength to maintain the structure during remodeling. Material and methodsA new filament based on the fusion of natural polylactide acid (PLA) powder was designed for the generation of pieces by means of fused deposition modeling (FDM) on which to carry out tensile mechanical tests of osteosynthesis material. A total of 13 groups with different cortical thickness, filling and layer height were carried out, with 10 tensile tests in each group, defining the tensile breaking limit for each group. The regression lines for each group and their mechanical resistance to traction on the filament used were determined. ResultsThe filament ratio per contact surface unit with the osteosynthesis used was the main determinant of the mechanical resistance to traction, either at the expense of the increase in cortical thickness or by the increase in the percentage of cancellous bone filling. Layer height had a minor effect on tensile strength. The regression value was high for cortical thickness and cancellous filling, being elements with a predictable biomechanical behavior. ConclusionsThe new methodology allows the creation of personalized neutral and implantable PLA bone matrices for the reconstruction of large bone defects by means of 3D printing by FDM with a mechanical resistance to traction greater than that of current biological support structures.

Correlation between Processing Parameters, Morphology, and Properties of Injection-Molded Polylactid Acid (PLA) Specimens at Different Length Scales.

Polylactic acid (PLA) is one of the most promising bioplastic representatives that finds application in many different areas, e.g., as single-use products in the packaging industry, in the form of mulch film for agriculture, or in medical devices. For the development of new areas, especially in terms of long-term applications and the production of recyclable products, the material properties controlled by processing must be known. The state of the art is investigations at the global scale (integral values) without consideration of local structure inhomogeneities and their influence on the material properties. In this work, morphological, thermal, and mechanical properties of injection-molded PLA tensile bars are investigated at different length scales (global and local) as a function of processing parameters. In addition to the processing parameters, such as melt temperature, mold temperature, and cooling time in the mold, the influence of the D-isomer content on the crystallization behavior and the resulting material properties are investigated. The material was found to form crystalline structures only when cooled in a mold tempered above Tg. In addition, PLA with a lower content of D-isomer was found to have a higher degree of crystallinity. Since the mechanical properties obtained by tensile tests could not be correlated with the degree of crystallinity, detailed analysis were performed showing a characteristic inhomogeneous morphology within the tensile bars. By means of micromechanical investigations on samples with different microstructure ranges, the relationship between local morphology and failure behavior could be explained.

Deformation Behavior of 3D Printed Auxetic Structures of Thermoplastic Polymers: PLA, PBAT, and Blends

Auxetic structures have a negative Poisson's ratio and therefore expand transversely to the direction of loading instead of tapering. This unique behavior is not caused by the materials used, but by the structure, and thus offers completely new functionalities and design possibilities. As a rule, auxetic structures have a very complex geometry, which makes cost-effective production possible only by means of additive manufacturing processes. Due to the high design freedom of the strand deposition method, it makes sense to manufacture auxetic structures using this process. Therefore, in this project, polylactide acid (PLA), polybutylene adipate terephthalate (PBAT), and blends of the two polymers were produced and characterized. Filaments of the two polymers and a blend were extruded, processed into auxetic structures by strand deposition process (SDP), and investigated for their properties, primarily their Poisson's ratio. The Poisson's ratio was determined and the influence of the material on it was identified. A specific number of 5 × 5 unit cells has been found to be ideal for investigation. Dual printed specimens showed a similar auxetic behavior as the specimens made of pure PBAT. Likewise, multiple loading and unloading of the structure is possible. Furthermore, in-situ computed tomography revealed the detailed characterization of the initial state, including the warpage of the structures, damage, and traced auxetic behavior in detail.

Predicting the Printability of Poly(Lactide) Acid Filaments in Fused Deposition Modeling (FDM) Technology: Rheological Measurements and Experimental Evidence

In this work, the authors aimed to identify a potential correlation between the printability and crucial rheological characteristics of materials involved in fused deposition modeling (FDM) technology. In this regard, three different poly(lactide) acid (PLA)-based filaments (two commercially available (here called V-PLA and R-PLA) and one processed in a lab-scale extruder (here called L-PLA)) have been considered. Dynamic rheological testing, in terms of frequency sweep at five different temperatures (130, 150, 170, 190, and 210 °C), was performed. Rheological properties expressed in terms of viscoelastic moduli and complex viscosity curves vs. frequency, characteristic relaxation times, activation energy (Ea), zero shear viscosity (η0) and shear thinning index (n) were derived for each material. A characteristic relaxation time of around 0.243 s was found for V-PLA, a similar value (0.295 s) was calculated for R-PLA filaments, and a lower value of about an order of magnitude was calculated for L-PLA filament (~0.0303 s). The activation energy and shear thinning index resulted to be very comparable for all the filaments. On the contrary, V-PLA and R-PLA possessed a zero-shear viscosity (~104 Pa*s at 170 °C) much higher than L-PLA (~103 Pa*s). All the filaments were processed in a 3D printer, by attesting the effect of nozzle temperature (180, 190, and 210 °C, respectively) on printing process, and macroscopic shaping defects in printed objects. Final considerations allowed us to conclude that polymer relaxation time, zero-shear viscosity, and melt viscosity (affected by printing temperature) were critical parameters affecting the printing quality.

Optical photothermal infrared spectroscopy with simultaneously acquired Raman spectroscopy for two-dimensional microplastic identification

In recent years, vibrational spectroscopic techniques based on Fourier transform infrared (FTIR) or Raman microspectroscopy have been suggested to fulfill the unmet need for microplastic particle detection and identification. Inter-system comparison of spectra from reference polymers enables assessing the reproducibility between instruments and advantages of emerging quantum cascade laser-based optical photothermal infrared (O-PTIR) spectroscopy. In our work, IR and Raman spectra of nine plastics, namely polyethylene, polypropylene, polyvinyl chloride, polyethylene terephthalate, polycarbonate, polystyrene, silicone, polylactide acid and polymethylmethacrylate were simultaneously acquired using an O-PTIR microscope in non-contact, reflection mode. Comprehensive band assignments were presented. We determined the agreement of O-PTIR with standalone attenuated total reflection FTIR and Raman spectrometers based on the hit quality index (HQI) and introduced a two-dimensional identification (2D-HQI) approach using both Raman- and IR-HQIs. Finally, microplastic particles were prepared as test samples from known materials by wet grinding, O-PTIR data were collected and subjected to the 2D-HQI identification approach. We concluded that this framework offers improved material identification of microplastic particles in environmental, nutritious and biological matrices.

Tissue equivalence of 3D printing materials with respect to attenuation and absorption of X-rays used for diagnostic and interventional imaging.

Three-dimensional printing is a promising technology to produce phantoms for quality assurance and dosimetry in X-ray imaging. Crucial to this, however, is the use of tissue equivalent printing materials. It was thus the aim of this study to evaluate the properties of a larger number of commercially available printing filaments with respect to their attenuation and absorption of X-rays. Apparent kerma attenuation coefficients (AKACs) and absorbed doses for different X-ray spectra (tube voltages, 70-140kV) were measured and simulated by Monte-Carlo computations for a larger number of fused-deposition-modeling (FDM) materials. The results were compared with the respective values simulated for reference body tissues. In addition, the properties of polylactide acid samples printed with reduced infill densities were investigated. Measured and simulated AKACs and absorbed doses agreed well with each other and in case of AKACs also with attenuation coefficients derived from the reference database of the National Institute of Standards and Technology (NIST). For lung, adipose, muscle, and bulk soft tissue as well as for spongiosa (cancellous bone), printed materials with equivalent attenuation as well as absorption properties could be identified. In contrast, none of the considered printed materials was equivalent to cortical bone. Several FDM materials have been identified as well-suited substitutes for body tissues in terms of the investigated material characteristics. They can therefore be used for in-house production of individualized and task-specific phantoms for image quality assessment and dose measurements in X-ray imaging.

PLA/PHB-Based Materials Fully Biodegradable under Both Industrial and Home-Composting Conditions.

In order to make bioplastics accessible for a wider spectrum of applications, ready-to-use plastic material formulations should be available with tailored properties. Ideally, these kinds of materials should also be “home-compostable” to simplify their organic recycling. Therefore, materials based on PLA (polylactid acid) and PHB (polyhydroxybutyrate) blends are presented which contain suitable additives, and some of them contain also thermoplastic starch as a filler, which decreases the price of the final compound. They are intended for various applications, as documented by products made out of them. The produced materials are fully biodegradable under industrial composting conditions. Surprisingly, some of the materials, even those which contain more PLA than PHB, are also fully biodegradable under home-composting conditions within a period of about six months. Experiments made under laboratory conditions were supported with data obtained from a kitchen waste pilot composter and from municipal composting plant experiments. Material properties, environmental conditions, and microbiology data were recorded during some of these experiments to document the biodegradation process and changes on the surface and inside the materials on a molecular level.

Polylactide/Carbon Black Segregated Composites for 3D Printing of Conductive Products.

One of the most important directions in the development of additive manufacturing or three-dimensional (3D) printing technologies is the creation of functional materials, which allow not only prototyping but also the manufacturing of products with functional properties. In this paper, poly-lactide acid (PLA) /carbon black (CB) composites with segregated (ordered) structure have been created. Computer simulation based on the Mamunya geometrical model showed that the CB content within φ = 2.5–5 vol.% in the polylactide matrix leads to the formation of a continuous electrically conductive phase with an increase of electrical conductivity σdc above the percolation threshold. The simulation results were experimentally confirmed by optical microscopy and studies of the electrical conductivity of the composites. It was found that increasing CB content from φ = 1 vol.% to φ = 7 vol.% in the composites causes insignificant (due to the segregated structure) phase changes in the polylactide matrix and improves the thermal properties of composites. Electrically conductive filaments for Fused Deposition 3D Printing (FDM) were developed from PLA/CB composites and then 3D printed. A correlation between the electrical conductivity σdc and the CB content φ for base composites, filaments produced from them, and final 3D samples, has been found. Conductivity varies within σdc = 3.1·10−11 − 10·10−3 S/cm for the filaments and σdc = 3.6·10−11 − 8.1·10−4 S/cm for the final 3D-products.

OPTIMASI MULTIRESPON PADA PROSES 3D PRINTING MATERIAL PLA DENGAN METODE TAGUCHI GREY

The use of manufacturing additives or commonly known as 3D Printing is increasingly widespread. The type of additive manufacturing that is often used is FDM (Fused Deposition Modeling). The most frequently used filament for prototyping and research is PLA (Poly Lactide Acid) type filament. This research will use multiresponse optimization, namely Taguchi-grey. So that later in this study will use 9 conditions with 3 parameters and 3 levels. The parameters used were orientation (0 °, 45 °, 90 °), nozzle temperature (190 °C, 200 °C, 220 °C), and bed temperature (0 °C, 30 °C, 60 °C). The purpose of this study was to find the most optimal parameters based on response time, dimensional accuracy and tensile strength. Based on analysis using Taguchi-grey, ANOVA results show that the most significant contribution is nozzle temperature (51%) and orientation (42%). From ANOVA, it can be seen that the most optimal condition is condition 6 which has been printed, with orientation of 45°, nozzle temperature of 220°C and bed temperature of 0°C.

Corrigendum: Study of mechanical and rheological properties, morphology, and miscibility in polylactid acid blends with thermoplastic polymers

Corrigendum: Study of mechanical and rheological properties, morphology, and miscibility in polylactid acid blends with thermoplastic polymers

Enhancement of PCL/PLA Electrospun Nanocomposite Fibers Comprising Silver Nanoparticles Encapsulated with Thymus Vulgaris L. Molecules for Antibacterial and Anticancer Activities.

Silver nanoparticles (AgNPs) have been recognized for their outstanding antibacterial activities, which are required for antibacterial coating materials in therapeutic applications. A bacterial-resistant electrospun nanofibrous mat made of polycaprolactone (PCL) in combination with polylactide acid (PLA) containing silver nanoparticles encapsulated with Thymus vulgaris L. (thyme) extract (eAgNPs) was fabricated in order to assess the potential of applicability in biomedical applications such as cancer treatment, wound healing, or surgical sutures. In the current study, PCL and PLA used as the basis polymers were blended with biosynthesized eAgNPs, pure AgNPs, and thyme extract (TE) to observe the effects of additives in terms of antibacterial and anticancer activity and morphologic, thermal, mechanical, biocompatibility, and biodegradability properties. The biological characteristics of fabricated electrospun nanofibrous mats were evaluated in vitro. Physicochemical characteristics of the nanofibrous mats were examined by UV-vis spectrophotometry, scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), energy dispersive X-ray (EDX), Fourier-transform infrared spectroscopy (FTIR), mechanical tensile testing, X-ray diffraction (XRD), thermogravimetric examination (TGA), and water contact angles (WCAs). The results showed that a biodegradable nanofiber scaffold with a mean fiber diameter of 280 nm is morphologically homogeneous and highly hydrophobic, has higher tensile strength than PCL/PLA nanocomposite fiber, and is resistant to Escherichia coli and Staphylococcus aureus. The cytotoxic and anticancer properties of nanomaterials were defined using L929 and SK-MEL-30 cells. The developed material inhibited cell proliferation and led to apoptosis of cell lines. It can be suggested that the use of Thymus vulgaris L. extract-encapsulated silver nanoparticle-doped PCL/PLA nanofibers produced by the electrospinning method has the potential for cancer therapy in skin tumor cell lines.

Investigation and Improvement of Processing Parameters of a Copper‐Filled Polymer Filament in Fused Filament Fabrication as a Basis for the Fabrication of Low‐Porosity Metal Parts

AbstractIndividualized and complex additively manufactured metal components are increasingly used in an industrial environment. One possibility to manufacture such metal components is the fused filament fabrication (FFF) process. Here, a metal powder‐filled polymer filament is processed (green part). For the realization of purely metallic components, the FFF‐manufactured components are subjected to a post‐process, which corresponds to the metal injection molding (MIM) process chain. In a first step, the polymer binder contained in the components is removed (brown part). Afterwards, the metal particles are sintered (white part). For the production of high‐quality components, the porosity of the components must be considered. Essentially, the porosity of the components results from the characteristic FFF structure caused by the deposition of single strands. This has a direct influence on the porosity of the white parts and accordingly on the resulting part properties. Within this study, a filament consisting of copper particles and a polymer binder matrix of polylactide acid (PLA) is used. This filament offers the possibility to produce complex, thermally conductive, and electrically conductive components. During the examinations, the influence of the FFF‐specific process parameters on the manufactured green parts is investigated. For this purpose, the stationary and non‐stationary extrusion areas will be considered. The aim is to achieve a homogeneous strand geometry and, thus, the highest possible part density. This should lead to the reliable processing of copper‐filled polymer filaments in FFF and provide a good basis for the production of pure copper components.