Abstract The morphology of BaCl2-crystallites (sizes ∼ 10-60 μm) in the form of rods and regular or semi-regular polygonal platelets having various shapes and formed within an NaCl-matrix, has been studied by optical microscopy and X-ray diffraction. The crystallites are variously of cubic/non-cubic phases. The orientational relationship established for the interface between the matrix and the broad faces of platelets of the cubic phase (fluorite structure) is as follows: These interfaces are coherent with the matrix. Microhardness measurements indicate that crystals containing rod-like crystallites are 50% harder than those containing platelets.